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By M. C. Fuerstenau

The zero-points-of-charge of apatite, calcite, and fluorite are pH 6.4, 10.8, and 10.0, respectively. Scheelite is negatively charged above at least pH 3. Flotation responses of these minerals in the presence of potassium oleate and sodium silicate are presented and compared with electrokinetic data. Colloidal silica appears to be the species principally responsible for calcite depression, while silicate anion is the species responsible for fluorite depression. Additions as high as 1 x 10-3 mole/liter silicate have no effect on the flotation responses of apatite and scheelite. Selective flotation of nonmetallic minerals is difficult to achieve with fatty acids or soaps by themselves. As a result, specific reagents are added to aid these separations, and one of the reagents commonly employed for this purpose is sodium silicate. Flotation separations of various calcium¬ bearing minerals such as fluorite from calcite (1,2,3) and scheelite from calcite(24) and apatite(2,5) almost always involve the use of sodium silicate, for example. The mechanisms by which sodium silicate functions as a depressant are still not understood; this fact is probably due to a number of reasons. That is, the dissolution process of sodium silicate is complex, giving rise to a number of ionic and colloidal species. (6) In addition, the type and concentration of these species depend on the ratio of Na20 to Si02, the concentration of sodium silicate, and the pH of the system. (6) At the present time, it is not known which species, colloidal silica or silicate anion, is responsible for depression. If colloidal silica is the species that is adsorbing, then adsorption must occur by electrostatic attraction between the colloid and the mineral surface. Silicate anion, on the other hand, may adsorb either physically or chemically. The objective of this paper is to determine first the active species of sodium silicate and then the conditions under which this species will adsorb and function as a depressant.

Jan 1, 1968

By G W. Wilson

Net solar radiation is one of the key factors affecting evaporation from soil covers on waste rock dumps. While net solar radiation is normally taken as a uniform parameter over a site for modelling purposes, there can be significant variation in the radiation actually received on various portions of the dump. These variations are a function of the difference in the cover slope and direction of exposure. A predictive model has been developed to calculate the actual radiation received on the dump surfaces, based on the net radiation data measured at a weather station on a horizontal surface. The model has been designed for application at any mine site in the world, and can be used in conjunction with evaporative flux models to help estimate the effect of three-dimensional variations in the cover surface exposure. The waste rock dump at Equity Silver site (located in British Columbia, Canada) has a barrier-type soil cover system to limit oxygen entry and water infiltration. This cover has been monitored for the past nine years. The new net solar radiation model has been applied to this site and the predicted net radiation was compared to the values of actual net radiation measured on the site. The predicted variations in net radiation over the three-dimensional surface of the waste rock dump have been applied to calculate spatial variations in potential and actual evaporation (or evapotranspiration) from the site. Preliminary analyses indicate actual evaporation from a site at this latitude could vary by a factor of two for exposed versus shaded slopes. The implications of these variations for the site are considered.

Jan 1, 2003

By F. F. Aplan, G. Simkovich

"A review is given of the effects of solid state point imperfections upon a number of mineral benefication processes and a metal extraction process. It has been found in numerous flotation studies that small amounts of aliovalent impurities (dopants) in binary compounds may show major effects upon flotation behavior. Both semiconducting and ionic conducting compounds are affected. These effects are also seen in hydrometallurgical studies as well as in electrostatic operations. Additionally, de-copperization of lead melts appears to be strongly influenced by similar defects. It is hypothesized that the effects observed in these studies are present in actual operations and should be considered in designing processes. A few speculations concerning future efforts are advanced. IntroductionImperfections [point (e.g., vacancies, interstials, quasi-free electrons, electron holes, impurity ions), line (e.g., dislocations), two dimensional (e.g., grain boundaries) and three dimensional (e.g., 2nd phases) defects] are generally present in solid materials and these imperfections may, and often do, have important effects upon a variety of properties and processes. In general, one may, in most cases, attain elimination of three dimensional defects by a separation process of one type or another (e.g., gravity, electrostatic, magnetic, flotation, hydrometallurgical etc.,). Thus, this type of defect has rarely been investigated in a systematic fashion. Two dimensional defects are always present in non-single crystal materials but have also escaped systematic studies in processes primarily because the control of such defects is not easily attained. Line defects are non-equilibrium entities which are present in ill-defined quantities so that they present a variable that cannot be easily controlled although through careful systematic experiments one can attain some reproducible relations pertaining to this type of defect.Contrary to the lack of studies concerned with the effects of 1, 2 and 3 dimensional types of defects there has been some activity concerned with point defects and their effects upon a number of mineral/metallurgical processes, especially flotation processes. Thus, this article will present a review primarily of point defects in relation to their effects upon flotation although other processes and defects will also be mentioned."

Jan 1, 1988

By G. Kugler, M. Tercelj

"The use of the up-to date light alloys and their development are in the sharp ascent especially in transportation industry. In the last years the use of the magnesium alloys for the various purposes was strongly increased. The aim of present research was to study the influence of solidification rate on hot workability and on obtained mechanical properties of AM60 magnesium alloy. The study was also focused on possibility to omit prior homogenisation process which would result in cost reduction. The solidification of gravity cast alloy has been investigated with various methods of the thermal analysis: in situ simple thermal analysis and simultaneous thermal analysis. In order to reveal optimal hot working conditions the deformation behaviour was studied in the temperature range 200-450°C and strain rates between 0.001-lOs-1. Mechanical properties have been studied with tensile and impact toughness testing.IntroductionIn recent years, the increased demand for magnesium alloys has been mainly driven by the need of automotive and transportation industry to reduce the weight, as this is the most important parameter to reduce the energy consumption. Beside their very low weight in comparison to other metals, the magnesium alloys are characterized by good machinability, corrosion resistance and good mechanical properties, and can thus compete with aluminium alloys and for some applications even with steels. Due their decreased workabilty they are typically used as cast alloys, but in recent years also the research of their wrought state has become more extensive [1-7]. Decreased hot workability of magnesium alloys originates from their hexagonal close-packed structure. One of the most popular magnesium alloys with great potential for many applications is AM60 (MgA16Mn), which is predominately used for casting. But its application could be increased if the mechanical properties, could be improved. This can be done by hot working. Namely it is well known that wrought microstructure is characterized by better mechanical properties in comparison to as-cast state. On the other hand due to its low hot workability the homogenization process is required prior hot deformation, which results in increased production costs. Thus the aim of the present research was to study the influence of solidification rate on hot workability of AM60 alloy in order to improve its mechanical properties and to check the possibility of producing near-net-shape casting products omitting homogenisation process by employing small additional deformations after casting. Within the framework of this research the solidification of gravity cast AM60 alloy has been investigated with various methods of the thermal analysis."

Jan 1, 2011

By Dennis S. Kostick

Soda ash is produced in over 39 countries by the Solvay ammonia-soda process or by mining natural sodium carbonate deposits. The total production of soda ash in 1980 is estimated at slightly over 29 million metric tons. Synthetic production accounted for over 75% of this amount with the balance of production originating from natural sources (either trona or sodium carbonate-rich brines) found primarily in the United States, Mexico, Kenya, and Chad.

Jan 1, 1981

By B. A. Obadele, R. Machaka, M. L. Raganya, M. E. Makhatha, N. A. Moshokoa

The influence of solution treatment on the phase evolution and tensile properties of Ti-Mo alloys was investigated to assess their potential use in biomedical applications. Phase formation and microstructural evolution were studied using X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The mechanical properties were characterized by means of tensile tests and bending strength. XRD analysis showed that solution treatment increased the volume fraction of β phase and supressed the α" phase. The microstructures of the as-cast alloys consisted of β equiaxed grains with sub-grain structures of different sizes, while the solution treated alloys comprised β equiaxed grains only except for Ti- 10.02Mo, which comprised needle-like α" structures. EBSD showed an increase in the volume fraction of the ω and α" phases in all the alloys after solution treatment. The elastic modulus and UTS of all the alloy significantly decreased after solution treatment, except for Ti-15.05Mo,whereas the elongation significantly increased. The fracture surfaces of all the alloys after solution treatment indicated more ductile behaviour than brittle

Jun 10, 2024

From the viewpoint of mechanical efficiency, charges should be fully coupled and, upon detonation, should just fail to break the rock in compression. But because mining thrives on its cost-effectiveness rather than its mechan- ical efficiency, the explosive which generates maximum energy per $ should generally be used, even though the mechanical efficiency of this explosive's detonation products may be sub- optimum. Wherever possible, each charge should have a length:diameter ratio of about 20 or more and should shoot to a concavely biplanar free face that is both parallel and reasonably close to the blasthole. Success in obtaining parallel effective faces often demands the drilling of angled blastholes and, hence, will require intensified research and development efforts by drilling manufacturers, especially where hard strong rocks are encountered. Blastholes should be drilled on equilateral triangular grids and fired in a Vl or shallower V-type sequence using inter-row delays which ensure that good pro- gressive relief of burden is achieved. The conventional method of calculating Se/Be values (on the basis of planar effective faces) is often invalid.

Jan 1, 1986

During the extensive research which has been conducted in the Metallurgy Department of the University of Melbourne, into the properties of lead and its dilute alloys, the Brinell test has been used for the determination of hardness.The work described herein represents part of an investigation into the influence of various factors on such determinations, particularly when carried out on different qualities of "pure" lead. It is intended to publish the more theoretical and controversial aspects of this research elsewhere.MATERIALS USED AND THEIR PREPARATION FOR TESTINGThe tests to be reported have been conducted on a specially pure electrolytic lead, and several brands of commercially "pure" lead. The analyses of the samples upon which most of the work has been carried out are given in Table 1.Note: Oxygen was not determined, but from the work of H. W. Worner, in the Rosenhain Memorial Laboratory, it appears probable that it was approximately 0-0003% in all samples.

Jan 1, 1940

By Roger Altman

The solubility of copper in primary spinel crystals encountered in reverberatory slag samples has been determined by electron microprobe analysis. These spinels, which ranged in composition from 22% A12O3 to pure magnetite, contained small quantities of dissolved copper (0-0.4%). Based on literature data it was estimated that the solubility limit of copper in solid magnetite is no greater than about 1% at 1200°C and about 2% at 1250°C. However, it was found that practically every spinel crystal examined contained significant amounts of matte inclusions. Further examination of converter slag revealed large quantities of irregularly shaped precipitated magnetite crystals which contained a large proportion of copper inclusions. Additional experimentation showed that the total copper content in reverberatory slag samples was greater than the sum of the estimated en- trained plus dissolved matte in the slag. This difference is believed to be significant and is due to the presence of matte inclusions in the spinel crystals. In the present reverberatory slag samples these inclusions accounted for about 1/2 of the amount of sulfide directly entrained in the slag.

Jan 1, 1976

The corrosion behaviour of a low carbon steel was investigated in synthetic seawaters with and without Sr2+. It was found that strontium substitutes for calcium in aragonite, rather than precipitating as discrete strontianite (SrCO3). The aragonite deposits that formed in the presence of Sr2+ were finer than those that formed in the absence of Sr2+. It is believed that an increase in the strontium content of aragonite induces a decrease in its solubility, which in turn results in a higher nucleation rate of the precipitates. Furthermore, the growth rate of aragonite is decreased by the presence of Sr2+in the solution. It is concluded that Sr2+is an essential ingredient in any artificial seawater when calcareous deposits are investigated on steel. Keywords: corrosion, seawater, calcareous deposits, strontium, aragonite.

Jan 1, 2007

By M. Mpofu, B. Maphalala, S. Khan, S. Ngobese, D. Roberts

This paper details an assessment of stemming practices at a South African opencast coal mine and their influence on ground vibration and air blast. Quantitative and qualitative analysis methods were used for the study. The parameters assessed for the quantitative analyses included stemming length, stemming material type, blast-hole depth, burden, and spacing. Pre-blast data from the mine was analysed to determine the deviation between actual and mine design stemming parameters. Mine design stemming length was also compared to the rule-of-thumb stemming lengths. Peak particle velocity (ground vibration) and air blast data from seismograph stations around the mine was analysed to determine the correlation between stemming length and excessive ground vibration and air blast. The qualitative analysis involved observations of blasting procedures at the mine to determine compliance with mine procedures. Some level of non-compliance of actual stemming parameters to design stemming parameters was found, which initially suggested that non-compliance may have contributed to excessive air blast. However, further analysis of the seismograph results indicated no direct correlation between stemming length and excessive air blast and ground vibration. Since stemming parameters are interrelated, it is crucial that all blasting procedures, including stemming, are executed in accordance with best practice, and recorded accurately. There is a need for digital systems for capturing on-bench blasting parameters, as the currently used manual data recording and reporting systems are inefficient and prone to error. Improvements to blast designs are possible through efficient and accurate data recording and reporting systems.

Jan 1, 2021

By HASAN SERKAN GOKCEN, SERKAN CAYIRLI

Manufacturers have improved various stirred mill types to be well adapted to fine and ultrafine grinding applications. These stirred mills, which are operated in wet or dry conditions, may be classified as horizontal — such as AHM-horizontal agitated media mill, IsaMill and Drais mill — or vertical — such as tower mill, Vertimill, Maxmill, Stirred Media Detritor and ATR vertical agitated media mill. The main difference between vertical and horizontal structures is in their operational variations. Additionally, the scaling-up of mills is also an important parameter for selecting the suitable orientation [1]. The purpose of this study was to investigate the dry grindability of calcite powders in a vertically and horizontally orientable laboratory batch-type stirred mill. The experimental results were evaluated using stress intensity analysis. The results showed that the d50 values decreased with increasing stress energy down to a certain point and then increased for both milling orientations. Even though the optimum stress energies for both vertical and horizontal orientations were in the range of 1 × 10−3 to 5 × 10−3 Nm at 750 and 1,500 kJ/kg energy consumption, the product size was finer for the horizontal orientation at the same stress energy value.

By HASAN SERKAN GOKCEN, SERKAN CAYIRLI

The purpose of this study was to investigate the dry grindability of calcite powders in a vertically and horizontally orientable laboratory batch type stirred mill. The experimental results were evaluated using stress intensity analysis. The performance was also compared in terms of mill orientation. The results showed that the d50 values decreased with increasing stress energy down to a certain point and then increased for both milling orientations. Even though the optimum stress energies for both vertical and horizontal orientations were in the range of 1*10−3 to 5*10−3 Nm at 750 and 1500 kJ/kg energy consumption, the product size was finer for the horizontal orientation at the same stress energy value. Additionally, to the best of the authors’ knowledge, this is the first study to compare mill orientation (vertical vs. horizontal) for the same mill and under the same test conditions.

Apr 21, 2021

By Larkings RH

The high gas emissions associated with the depth of mining and very high coal extraction at some Australian Collieries have provided a need to investigate the influence of geological and mining conditions on levels of gassiness. The introduction of longwall extraction in particular is associated with complex strata control problems and quick changes in gassiness. To this stage of Australian coal mining, no standard method has been developed to predict the different levels of gassiness associated with the various geological and mining conditions; and the relationship between coal output and total methane make has not been established. For local conditions, with a large number of coal seams lying in close proximity to the working seam, the significant contribution of gas emissions from adjacent strata was expected, especially as strata relaxation occurred during longwall mining. This depends mainly on geological conditions, strata control and coal production. For the deepest of the B.H.P. Collieries in the Newcastle region, the relationship between coal output and total methane make has been investigated by systematic gas balance measurement during longwall extraction. The computer method of iteration was used to approximate the mathematical equation from the initial graphs of coal production versus quantity of methane in the ventilation system for various strata conditions. The angle of caving was established for local geological and mining conditions, for planning and design of the positions of cross measure boreholes.

Jan 1, 1986

By John L. Hill

Over 50 mines of the Appalachian and Illinois Basins are presently experiencing poor ground conditions believed to be caused by overlying stream valleys. The Bureau of Mines is conducting research into the causes of this problem with the aim of developing a predictive method for determining the safe limits of mining beneath stream valleys. In addition, the factors that control instability in these regions will be analyzed to provide design guidelines for adjusting support requirements. This paper presents the theorized causes of poor ground conditions beneath stream valleys and compares the theories with the results of a Bureau study of the Birchfield Mine No. 1 and a preliminary investigation of the Davidson Mine, both of southern West Virginia. The Birchfield Mine excavated four main entries beneath a 50-ft wide stream with only 50 ft of overburden. The valley flood plain is over 500 ft wide, flanked by valley wall slopes of 25 deg and relief of over 950 ft. In-mine monitoring of strata movement and detailed geologic mapping revealed that roof rock strength was greatest under high cover and weakest along outcrops and beneath the valley, with localized areas of decreases in rock mass quality. To improve the rock mass quality beneath the stream and reduce the threat of inundation, an extensive drilling program was undertaken to inject grout into the overburden from the surface. As a result, mining beneath the stream was practically routine from a ground control perspective, and water was not encountered until mining had advanced to a point beneath the floodplain that had not been grouted. The only ground control problems which were encountered were entirely a result of localized poor rock mass quality. In contrast to the Birchfield Mine, the Davidson Mine experienced failure of intact roof rock at a depth of 300 ft beneath a V-notch shaped valley with no change in rock mass quality. Finite element analysis was conducted to study the premining in situ stress at the two sites. The results are discussed within this paper and provide insight into the causes for the types of failure seen beneath valleys of varying shapes and depths.

Jan 1, 1988

By Charles W. Schwartz, Subash Kolluru

INTRODUCTION Creep of rock in situ, like most rock mass behavior, will be largely governed by the behavior of the natural discontinuities -- bedding planes, faults, and joints, in particular, Several past studies have investigated various aspects of the time-dependent deformation of rock discontinuities; examples include Amadei and Curran (1980), Engelder and Scholz (1976), Johnson (1975), Kaiser and Morgenstern (1979), Solberg et al. (1978), and Wawersik (1974). These studies have provided much insight into the general phenomenon, but they have also produced some inconsistent conclusions and left many unanswered questions. This paper will attempt to shed some light on one of these questions: What is the influence of stress level on the creep of unfilled rock joints? The discussion will follow a two-part approach to the problem: (1) laboratory creep experiments on small scale jointed specimens, (2) a simple theoretical mechanism to explain, at least in qualitative terms, some of the results from the experimental program. EXPERIMENTAL PROGRAM Uniaxial creep tests were conducted on intact and jointed samples of a specially formulated gypsum plaster "synthetic rock." Synthetic rock materials have several advantages over natural rock for long-term creep testing: (a) higher creep rates, (b) lower strength and therefore lower loading requirements, (c) simpler specimen preparation, and (d) more controlled and consistent properties. Gypsum based plasters have been used previously in studies of short-term strength and deformability of jointed samples (Patton, 1966; Einstein and Hirschfeld, 1973). Furthermore, Williams and Elizzi (1977) demonstrated that natural gypsum, at least, creeps in a manner similar to that of most other creep-susceptible natural rocks.

Jan 1, 1982

By B Indraratna, A Dey

The surface geometry of a rock bolt plays a very important role in the rock/resin/bolt load transfer mechanism. Very little work has so far been reported on the influence of the bolt surface geometry on the bolt/resin interface failure mechanism. This paper examines the behaviour of bolt surface roughness under constant normal stiffness condition in the laboratory. To study the shear behaviour of the bolt/resin interface a series of shear tests with an initial normal stress between 0.1 to 7.5 MPa has been conducted on the flattened bolt surface of two most popular bolt types currently being used in Australia. Bolts with deeper ribs offered better shear resistance at low initial normal stress conditions whereas bolts with shallow and closer ribs offered better shear resistance at high normal stress conditions. The maximum dilation occurred at a shear displacement of 60 per cent of the rib spacing irrespective of the bolt type and depth of the rib.

Jan 1, 2000

By Kai Zhang, Aijun Huang, Jeremy H. Rao, Xinhua Wu, Paul Rometsch

"As one of the most typical additive manufacturing (AM) technologies, selective laser melting (SLM) removes many of the shape restrictions that limit materials design, thereby allowing computationally optimised and high performance structures to be directly produced and tested. Due to the high reflectivity and lower absorptivity of Al alloy A357 powder during high temperature laser melting, one of the issues SLM might bring is the surface roughness and defects present on the parts. In this regard, this study investigates the surface roughness – fatigue property relationship for a heat-treated aluminium alloy A357 after SLM. Via the adjustment of SLM parameters, an ultrafine microstructure can be obtained due to the fast solidification rate. Therefore, comparable or even better mechanical properties can be achieved with respect to traditional A357 casting counterparts. Meanwhile, the surface roughness conditions of the SLMed Al alloy are also influenced by various processing parameters, raw powder properties, and sample building methods. For selective laser melted Al alloy A357 specimens, a dense part with a smoother surface would be expected to correspond with a good fatigue performance.INTRODUCTION Additive Manufacturing (AM), also known as 3D printing, is a process in which a complex part is fabricated layer by layer from a digital design package (Martin et al., 2017). AM has the potential to conserve raw materials, reduce the energy consumption, part cost, and fabrication time. Furthermore, as a typical additive manufacturing (AM) process, selective laser melting (SLM) was originally developed from selective laser sintering (SLS) based on higher quality lasers (Rao, Zhang, Fang, Chen, Wu, & Davies, 2017b). Different from conventional casting consuming valuable time and energy, SLM is now used as a cost effective method for the manufacturing of metals, such as Al-Si alloys, to produce almost full density parts using fine metallic powder and high power laser beam (Tang & Pistorius, 2017)."

Jan 1, 2018

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By J. K. Jeyapalan, A. P. S. Selvadurai

Plate loading tests which use surficial loading of a rock mass are employed quite extensively for the determination of in situ deformability characteristics of rock masses. The cable jacking method is essentially a surficial plate load test in which the test load is provided by reaction against a cable anchored at some depth below the rock surface. The results of the test are usually evaluated within the framework of the classical theory of elasticity to generate estimates for the bulk deformability properties of the rock mass. In the conventional evaluation of this test it is assumed that the test plate is rigid and that the embedded anchor load has no influence on the test plate settlement. The purpose of this paper is to examine the possible influences of the plate flexibility and the anchor load location on the effective settlement of the test plate. The variational estimates presented in the paper are valid for moderately flexible test plates which are characterized by a relative rigidity parameter Numerical results are developed in the form of correction factors that should be applied to the cable jacking results to arrive at the deformability characteristics of the tested rock mass.

Jan 1, 1982