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By James A. Finch, Xiangzhou Ding, Yue Hua Tan

"The Jameson Cell is one of the choices of flotation machine in coal, base metal processing and other specialist applications. This paper determines the effect on vacuum pressure and bubble size of two design variables, orifice size and downcomer length, and the operating variable air-to-water (AWR) ratio. The main findings are: orifice size and downcomer length impact the vacuum but have limited effect on bubble size; AWR < 1 favours high vacuum, conditions are identified where vacuum is maintained at AWR > 1, and water flowrate has slightly greater impact on bubble size than air flowrate.INTRODUCTIONFroth flotation, the most common technique for mineral separation, has been in use for over a century. The process takes advantage of the difference in wettability of mineral surfaces to achieve the separation of valuable minerals from non-valuable minerals, or gangue. Numerous flotation machines have been invented and patented over the years. The Jameson Cell, invented by Professor Graeme Jameson in the late 1980s, is one successful example. First trialed at Mount Isa Mines (Queensland, Australia), Jameson Cells have been installed at operations around the world for the recovery of fine coal (Mohanty and Honakeri, 1999; Cowburn et al., 2006; Hacifazlioglu and Toroglu, 2007; Uçurum 2009), minerals of copper (Farr 1992; Atkinson et al., 1993; Harbort et al., 1997), lead/zinc (Rohner, 1993; Munro, 2003) and gold (Bennett et al., 2012; Lauder et al., 2003), and in water treatment (Yan and Jameson, 2004), solvent extraction de-oiling (Miller and Readett, 1992; Miller et al., 1997; Harbort et al., 2003; Young et al., 2006), oil sands processing (Neiman et al., 2012), and various food industries (Brenneman, 2014). One of the largest units is the 650 cm diameter separation tank with 24 downcomers installed in an Anglo American operation (Osborne and Euston, 2015). Scale up is relatively straightforward: to increase capacity the number of downcomers is increased with corresponding increase in size of separation tank.The Jameson Cell comprises two main parts: a vertical tube (downcomer) which provides self-aspiration and intense bubble-particles contact, and a (separation) tank where particle-bubble aggregates disengage from the pulp. The intense bubble/slurry mixing in the downcomer with air holdups reaching 60% (Marchese et al., 1992) accelerates particle collection enabling the greatly reduced cell volume compared with mechanical flotation cells and columns. The disengagement of the particle-loaded bubbles from the slurry in the separation tank is usually aided by addition of washwater."

Jan 1, 2018

By Helmut Thielsch

IN recent years an ever increasing amount of interest has been directed toward research studying the principles and various applications of sonic and supersonic waves. Though still in their early stages of practical development, sonic vibrations are already used in the emulsification and degasification of liquids. Metals exposed to sonic or ultrasonic vibrations while solidifying show a considerable amount of grain refinement. Often sound waves are applied instead of radiography to test engineering materials for internal cracks and flaws.1 In the field of pure research these waves are used in dispersion and also in coagulation of particles or liquids in gaseous or, under certain conditions, in other liquid systems. In the settling and thickening of slurries considerable time is necessary to compress the solid particles and to squeeze out the liquid to obtain as low a dilution (liquid to solid ratio) as possible. Various methods have been developed to increase the amount of coagulation of the very fine solids (colloidal or semicolloidal) and to shorten the over-all time. The addition of small amounts of electrolytes and the warming of the suspension represent merely the more important techniques. Some of the effects of supersonic vibrations have been reported previously.2,6 From preliminary studies, therefore, it was hoped that by application of sonic vibrations it would be possible to reduce the time required to thicken such materials to a specific dilution, as well as to thicken to lower ultimate dilutions than could be obtained by quiescent settling alone. By increasing the volume thickened per unit time-i.e., improving the plant efficiency-great savings in equipment and time would be obtained for industrial processes. Also, faster settling rates should result if coagulation of particles could be increased. Experiments have been conducted for a period of several months in the Allis-Chalmers laboratory to study the effect of sonic vibrations on settling of particles of different sizes and concentrations. APPARATUS The sedimentation apparatus used in these experiments is illustrated in Figs. I and 2. The essential features are the stationary field coil and the movable voice coil. Both windings are placed around a solid iron core. A leather diaphragm connected to the steel frame holds the voice coil in place. A brass rod is fastened to the voice coil with a metal disk connected to the other end. This disk is sealed to the lucite cylinder with a flexible rubber diaphragm. The lucite tube is 17 in. long; its inner diameter is 2 ½in. and the wall thickness is ¼ in. The tube is calibrated on the outside in 10 c.c. divisions for a total of 1000 cubic centimeters.

Jan 1, 1946

By Stephen C. Tadolini, Yunqing Zhang, Thomas M. Barczak

Standing crib supports have been applied in underground mining programs to resist large roof movements and sustain high-loads. The strength and deformation capability of these systems has been documented under both laboratory and field conditions. The parameter that has not been examined and is not well understood is the effect that a crib or other types of standing support has on the primary and secondary bolting systems. A crib support system with low system stiffness may allow large amounts of closure and deformation and cause the bolting systems to yield or even fail. Conversely, cribs or standing support that are too stiff may experience brittle or buckling failures, negating the advantage of the intrinsic supports previously installed. Utilizing a combination of field measurements and 3-dimensional finite element modeling techniques, the relationship between system stiffness and the subsequent performance of the installed bolting system is evaluated. Additionally, a simple method for calculating the combined system stiffness for standing supports, when using materials with different strengths such as steel, concrete, wood, etc., is presented.

By Stephen Tadolini

Standing crib supports have been applied in underground mining programs to resist large roof movements and sustain high¬loads. The strength and deformation capability of these systems has been documented under both laboratory and field conditions. The parameter that has not been examined and is not well understood is the effect that a crib or other types of standing support has on the primary and secondary bolting systems. A crib support system with low system stiffness may allow large amounts of closure and deformation and cause the bolting systems to yield or even fail. Conversely, cribs or standing support that are too stiff may experience brittle or buckling failures, negating the advantage of the intrinsic supports previously installed. Utilizing a combination of field measurements and 3-dimensional finite element modeling techniques, the relationship between system stiffness and the subsequent performance of the installed bolting system is evaluated. Additionally, a simple method for calculating the combined system stiffness for standing supports, when using materials with different strengths such as steel, concrete, wood, etc., is presented.

Jan 1, 2003

By J. A. Wates

Stope backfilling in South African gold mines uses the coarser cyclone fraction of the gold tailings. The disposal of the overflow from the cyclones, which is finer and of higher moisture content than normal gold tailings, presents some problems. This paper describes an investigation undertaken to define the parameters that are required for a quantitative and qualitative assessment of the operation and stability of slimes dams built of such material. However, seeing the investigation was conducted on the slimes from only one mine, it is recommended that, until a wider range of data becomes available, tests should be conducted for each individual mine.

Jan 1, 1988

By A. P. E. Dirige

In order to maximize the recovery of ore in variably dipping ore zones of moderate width, cemented backfill is normally placed to serve as structural support. With the intention of saving on costs, backfill of low cement content can be used, which are often supported by a sillmat of higher strength. The stability of the low cement backfill face, exposed during adjacent mining, must be carefully studied to provide very effective, safe and economic mining operations. Improper design of these stope support structures may result in fill mass failure resulting in relaxation and failure of the stope walls, with consequent losses of production, ore dilution, and in safety problems. This paper presents a study conducted to assess fill performance during adjacent pillar mining and to provide a comprehensive understanding of backfill behaviour, the failure modes that may occur and the consequences to production, ore dilution and to safety problems, and accurately predict their stability. The design study investigated the effects of stope width and height, orebody geometry and inclination, and wall roughness on the stability of cemented backfill during adjacent pillar mining. Fill properties used were based on paste fill specimens cured for 28 days. Paste fill performances were assessed based on analytical and numerical modeling studies for the different mining conditions. Analytical modeling was carried out using limiting equilibrium analysis and numerical modeling was carried out using FLAC3D. The modeling results suggested that, for stopes that are inclined with smooth wall rock conditions, backfill failure, driven by the fill self-weight, has minimum dependency on the binder content and is reduced by resisting forces developed on the footwall-fill contact. For inclined stopes with rough wall rock conditions, wall roughness contributes significantly to the stability of the backfill during adjacent pillar mining. The analytical modeling approach was demonstrated to be useful in providing some approximate parameters for predicting the behaviour of paste fill exposed faces during adjacent mining, but cannot predict the mode or mechanisms of failure. Numerical modeling not only assess the stability behaviour of paste fill free faces, but also is able to provide a better idea of paste fill failure modes and possible failure mechanisms. The depth of failure and the potential for instability for a simulated stope filled with paste fill can be predicted, and may be useful in estimating the mass of material that could possibly fail and ore dilution levels.

May 1, 2009

By William A. Dupree, Mark J. Schultz, William J. Francart

Maintaining intake escapeways clear of contaminants from mine fires has been an issue for many years. Removing fire sources from these entries reduces the risk of contamination greatly. In recent years, concerns have been raised related to contamination of the intake escapeways by leakage when fires occur in adjacent airways. This paper discusses measured leakage rates for multiple stoppings at various pressure drops across stopping lines in a number of actual coal mines. Also addressed are methods for reducing the contamination risks for the intake escapeways, considering the ventilation system employed. The Effects of Air Leakage The effects of air leakage through ventilation controls has been well documented. While normal leakage is expected through stoppings, overcasts and other structures, abnormally high leakage results in an inefficient ventilation system and can increase operational costs for a mine. In addition, excessive leakage results in less control over mine ventilation airsplits. This may compromise the isolation of mine escapeways, and allow adjacent entries to be rapidly contaminated by products of combustion in the event of a mine fire. A study was conducted at ten mines in which air pressure and quantity measurements were taken near the active sections. The method used to construct the ventilation controls to separate airways was also noted. Stopping Construction Table 1 shows the type of stopping construction commonly used in the 10 mines included in this study. Main entry stoppings were normally built with mortared joints (wet stacked) with sealant applied to the high pressure side of the stopping. In most cases the entire face of the stoppings were sealed. In one case only the joints between blocks were sealed but the perimeters were sealed in all cases. Some mines also sealed the low pressure side of the stopping. Solid blocks were normally used for main entry construction and hollow blocks were sometimes used for longwall panel development. [ ]

Jan 1, 1993

By G. Mousavian, R. Bagheri, N. Dalili

Polypropylene (PP) and its composites have an increasing use in automobile and domestic industries. Since the published results on strain rate effect on yield behavior do not match, and there is a high attention paid for effect of nanometeric fillers on deformation behavior of composites, in this research the strain rate effect on yield behavior of PP and the effect of nanometeric fillers on deformation behavior of PP have been studied. Microscopic observations and tensile tests in different strain rates on neat PP samples and on samples filled with 5, 10 and 15 %wt have been used. A dramatic change in behavior for the modulus and post-yield slope curves when the strain rate is between 0.0433-0.05 s-1 has been observed. Microscopic observations on PP indicate a change in deformation mechanism from shear yield to crazing at the same strain rate that the change in behavior of curves occurs. It has been observed that in PP nanocomposites with higher amount of calcium carbonate, fracture in early stages of deformation occurs in lower strain rates. In other words for a fixed stain rate there is a critical filler percentage such that if the filler percentage is higher then early-stage fracture will occur. Similarly for a fixed filler percentage there is a critical strain rate and in higher strain rates early fracture will occur. The critical stain rate will decrease as the filler percentage increases and vice versa.

Jan 1, 2006

By M. Jahazi, P. P. Bhattacharjee, K. Chadha

The present work investigated the effect of strain reversal during high pressure torsion on the evolution of microstructure, texture and hardness properties of two different materials with different dynamic recovery behavior, namely, high purity (99%) Aluminum (2N-Al) and Aluminum-Magnesium (Al-2.5%Mg) alloy. In the two aluminum alloys subjected to different routes, the evolution of the ultrafine structure followed same trend. At lower strain level, sub grains with prominent LAGBs network were observed and at higher strains, ultrafine equiaxed grains separated by HAGBs were observed throughout the disk. The texture evolution in monotonically and strain reversal processed 2N-Al and Al-2.5%Mg showed presence of typical torsion texture components at different strain levels. The strength of the components was observed to follow different trends depending on the processing routes.

Jan 1, 2015

By J Slade, R Trueman

Unplanned dilution has the potential to seriously undermine the economic viability of a mine, and in some cases results in mine closure. The effect of stress damage on dilution has become increasingly relevant as mining depths increase. In the case of narrow vein mining, the incremental extraction of long-hole rings has the potential to result in a moving high stressed zone at the stope brow. This leads the hanging wall and footwall to experience a spike in the stress to strength ratios as the brow passes. In some cases, the stress to strength ratio may be high enough to result in fracturing or damage to the rock mass. The aim of the study described in this paper was to investigate whether stress damage results in a significant increase in dilution. The study involved analysis of overbreak from 410 case studies from the Kundana Gold mine in Western Australia. Site personnel had already undertaken calibration studies of the stress levels that result in rock mass damage. This calibration, in conjunction with numerical modelling showed that stress damaged stope walls at this mine had on average 50 per cent more overbreak than stope walls where stresses had not exceeded the damage criterion. For a design mining width of 1.5 metres, and with both walls impacted, this represents 36 per cent increase in dilution. After adjustment for possible sources of bias the difference reduced to an average 0.10 metres per stope wall, representing 13 per cent dilution for the mining width under consideration. The potential for stress damage related overbreak should therefore be considered as part of any assessment of narrow vein dilution.

Jan 1, 2005

By R. W. Hughes, R. Koopmans

This paper investigates the effect of varying stress levels on the determination of deformation moduli and examines the sensitivity of the borehole dilatometer in measuring rock mass scale features and its ability to represent rock mass characteristics. Cubical blocks of sandstone, limestone and granite were tested in the laboratory under triaxial stress conditions. Field programs were conducted in both granite and sandstone rock masses surrounding underground openings. The dilatometer&apos;s zone of influence was determined by conducting tests within an instrumented concrete cylinder and by performing a finite element analysis. Laboratory and field results suggest that the deformation modulus of a rock mass can be substantially affected by the stress field and that the borehole dilatometer is sensitive enough to profile deformation moduli as dictated by the in situ rock mass characteristics.

Jan 1, 1986

By James G. Tilton

Subsidence resulting from mining operations, has been the object of sporadic study for many years. Reports have shown that subsidence has ranged from minor settlement detected only by precise measurements to great slips where buildings are destroyed, roads disrupted, and large fissures opened at the surface. For years, a controversy has raged over the question of whether there is a positive or negative angle-of-draw. None of these questions can be given a flat answer for the variables controlling, subsidence are infinite. Generalizations can be made for various situations and areas but some means of control must be executed.

Jan 1, 1966

By S. S. Makgato

In this study, coke oven tar additions over a range of 0?8 wt.% were evaluated as a possible substitute for imported coal fractions. The coke oven tar used was collected from tar decanters in the byproducts section of the coking plant. The moisture content in the tar varied depending on the residence time and water carryover from the coke oven tar separators to the storage tanks. Moisture contents of 1 wt.%, 3 wt.%, and 6 wt.% were investigated in order to evaluate the effect on coal blend, carbonization, and coke properties. At 6 wt.% moisture content with 6 wt.% coke oven tar, although the coke quality improved the yield showed a 4% decrease. On the other hand, 1 wt.% moisture content with coke oven tar of 6 wt.%, increased the yield by 1% and the coke quality improved. However, the latter process was characterized by an excessive increase in wall pressure and pushing energy, both of which are detrimental to the oven walls. The optimum moisture content in coke oven tar was found to be 3 wt.% with a coke oven tar addition of 6 wt.% in the coal blend. With these conditions, the coke properties improved and wall pressure and pushing energy were acceptable. However, a decrease in coke yield of up to 2% was observed. Despite this, coke oven tar addition is considered to be a viable option based upon economic factors of a reduction in the quantity and cost of imported coking coals that is required to achieve the same optimum final coke product. Keywords coal substitution, coke oven tar, tar moisture, coal blend, coke, coke quality.

Nov 1, 2013

By Tumilty JA, Schmidt CG

Sulphide ion is a powerful poison in gold cyanidation, however, the detrimental effect is less severe in plant practice. This is thought to be due to the presence of depassivating elements in the ore, mainly lead. Trace amounts of lead can counteract the poisonous effect of considerable amounts of sulphide. The reaction is instantaneous and is likely to be a direct involvement in the electrochemical surface reaction. Lead addition cannot be regarded as an all-round cure when experiencing poor leach efficiencies. A possible beneficial effect depends on the mineralogy of the ore and has to be determined individually for every material.

Jan 1, 1989

By Carle Hayward

SULPHUR has long been one of the banes of the steel manufacturer and often no effort and expense have been spared in order to reduce it to a small per cent. in the finished product. This condition is clue to a general conviction that in many cases where steels have failed in service, sulphur has been the cause. But there has been a growing feeling in recent years that the verdict against sulphur has been unnecessarily severe. In cases of segregation it was present in augmented amounts along with other impurities, but it had not caused the segregation. High sulphur in pig iron is caused by poor furnace conditions and the sulphur is merely one indication of an iron that has not been properly reduced. No amount of subsequent treatment under oxidizing conditions in the open-hearth furnace can remedy the defects, although the per cent. of sulphur may be considerably reduced. In other words, the causes of bad steel can frequently be traced back to bad pig iron, and sulphur is merely one indication that the pig iron is bad. The writer recently visited a steel plant where a mass of evidence had been accumulated which substantiated this fact, and the superintendent was .emphatic in stating that high sulphur was not harmful provided the steel was not otherwise poor due to insufficient reduction in the blast furnace. The presence of a moderate amount of sulphur is desirable from the standpoint of the man who machines the steel. The low-sulphur material drags and the production of a smooth surface is very difficult. A slight increase in sulphur enables the machinist to produce a smooth surface without difficulty. Since, therefore, such large quantities of steel are subjected to machining, it becomes highly important that the sulphur controversy should be settled, and if its presence is proved to be harmless the ban on it should be lifted.

Jan 10, 1916

By C. R. Hayward

THE CHAIRMAN (ALBERT SAUVEUR, Boston, Mass.).-I am sure we are indebted to Prof: Hayward for his addition to our knowledge of the influence of sulphur on steel. As he has said in this paper, sulphur has had many defenders in recent years. It seems to me, however, that, while it may be old school to believe in the detrimental action of sulphur, it is not yet old school to believe in segregation; that while it may be that 0.1 per cent. of sulphur has no very great effect on the physical properties of steel, a ladle analysis of 0.1 per cent. of sulphur may readily result in 0.2 or 0.3 per cent. sulphur being present in the segregated portion of the ingot, and that, it seems to me, might be a rather serious matter. J. S. UNGER, Pittsburgh, Pa.-Prof. Hayward has presented the results of an investigation along a line to which I have devoted considerable time and attention, and I am particularly pleased to note that his results are in accord with my own and further tend to prove the fact that the old, established prejudice against sulphur is based more on belief than actual facts. I have felt for years that tooo much stress was placed on the harmful influence of certain elements in steel such as sulphur, phosphorus, copper, etc., but it has only been within recent years that efforts have been made to, establish the truth. Practically all the investigations made to date have proven that these elements within reasonable limits are harmless and, in fact, that for certain purposes the addition of these elements is beneficial. In referring to copper, J. E. Stead, Vice-President of the British Iron and Steel Institute, said at their last meeting: "Even today one comes across steel specifications in which copper is barred, which can only be regarded as ail indication of ignorance, if not stupidity, of those who prescribe the composition of steel, for it has been long ago proved that copper in steel, instead of being an evil, is quite harmless, and is sometimes distinctly beneficial." Sulphur owes its evil name to the early days of the manufacture of steel. Chemical analyses were crude, and failure due to either poor raw materials or metallurgical treatment were many. Sulphur being a comparatively easy element to determine with reasonable accuracy, particular attention was called to the amount of sulphur, and the failure was attributed to it, without giving any consideration to other causes. A pre-

Jan 4, 1917

By Ranklin W. J

The mechanism and rate-limiting step of carbonaceous reduction of zinc from slags was investigated in the laboratory. Disks of graphite were rotated in ZnO-containing slags at various speeds for fixed periods at 1250 to 1325¦C. The mass loss was used as a measure of the amount of ZnO reduced. Application of the Levich equation indicated that at rotation speeds at which it is valid, the reduction was chemically controlled with an activation energy of 27 kcal/mol. At zero rotation speed the reduction of ZnO by carbon appeared to be slag-phase mass transfer controlled with an activation energy of 38 kcal/mol. An increase in the FeO content of the slag increased the rate of reduction while an increase in sulphur content decreased the rate of reduction. When FeO was present in the slag, reduction appeared to occur by a combination of indirect reduction of ZnO by carbon and by reduction by FeO with reduction of Fe203 back to FeO by carbon. The effect of sulphur was consistent with a surface blockage mechanism due to the surface active nature of sulphur in slags.

Jan 1, 1993

The addition of copper sulfate to mineral slurries in order to ?activate? sulfide mineral surfaces for enhanced collector molecule adsorption, and hence enhanced recovery via flotation, is a com-mon mineral processing practice. It has been established in a laboratory situation that the addition of CuSO4 in conjunction with xanthate collector increases the flotation rate of pentlandite as compared to the addition of collector alone. However, it remains unclear whether the addition of CuSO4has a similar effect within mineral processing circuits. We examine here the effect of pre-activation oxidation on the copper activation of pentlandite and monoclinic and hexagonal pyrrhotite. All activation experiments were carried out at pH 9 using a total solution content of copper ions equivalent to one monolayer (0.210 -4 moles, 110-4M). Copper loss from solution was extremely rapid in all cases with less than 10 % remaining after 10s. EDTA extraction and solution analysis clearly demonstrated that copper activation was via direct surface adsorption and not an ion exchange process, as is the case for sphalerite, and that most copper on the surfaces is in the form of Cu(I). ToF-SIMS analyses of the mineral surfaces subsequent to copper activation show increased surface oxidation on increased conditioning time prior to copper activation. However, there is a significant decrease in surface oxidation on comparison of samples that have otherwise been prepared in the same manner but where one has been exposed to copper solution rather than water. This suggests that copper activation stabilises the surface and reduces the propensity for oxidation. Regardless of the length of pre-activation oxidation time only Fe(III) (no Fe(II)-S) was observed by XPS analysis, indicating a highly oxidised surface layer dominated by Fe-O-OH species. The presence of Cu(II) on the mineral surface is indicative of the formation of Cu(II)-containing precipitates and indicates non-mineral specific activation resulting in increased recovery but lower grade. Mineral specific copper adsorption, as evidenced by the presence of Cu(I), is required to improve both grade and recovery. Prolonged oxidation prior to copper activation causes a reduction in the Cu(I) to Cu(II) ratio on the mineral surfaces as compared to either fresh surfaces or surfaces oxidised for 1 minute only. This strongly indicates that the copper activation process is less effective on highly oxidised surfaces.

Jan 1, 2014

By J. Stachurski

Flotation tests were carried out on 6 coal samples of different rank as well as their oxidized samples. A mixture of diesel oil and alcohols was used in these tests. Surface oxidation caused a distinct decrease of the flotation recovery with some improvement in the grade The reduction in the recovery increased with increasing the concentration of the oxidizing agent. The floatability of low rank coals was affected by oxidation to a higher degree than medium and high rank coals. The recovery size curves of oxidized samples mere similar in shape to that of non-oxidized coals.

Jan 1, 1990

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which &apos;collected&apos; unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004