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By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By W. E. Wallace, V. Castranova, F. Saus, D. Bates, C. A. Hill, V. Vallyathan, M. J. Keane

"Two in vitro systems are being developed to model initial stages in the interaction of respired dusts with the acinar region of the lung. Incubation of quartz and kaolin with dipalmitoyl glycerophosphorylcholine, a major component of pulmonary surfactant, suppresses the prompt C)1otoxicity of both dusts as measured by in vitro enzyme release from pulmonary macrophages or assay by erythrocyte hemolysis. Additional data is presented to quantitate the detoxification of quartz and kaolin by dipalmitoyl lecithin. Subsequent incubation of lecithin treated dusts with phospholipase enzymes results in partial to complete restoration of the assayed cytotoxic potentials, dependent on the lipase activity applied, the incubation time, and the mineral. Restored cytotoxic potential is due to removal of the prophylactic lecithin surface coating and/or due to residual lysolecithin which is produced by the partial enzymatic digestion of lecithin. Data is presented on the contribution of each mechanism to the restored toxicity. Again, this is dependent on the mineral used, the lipase activity applied, and digestion time. Additionally, a system is under development to challenge pulmonary macrophages in culture with native and surfactant treated dusts. A preliminary test of the dipalmitoyl lecithin - quartz rabbit pulmonary macrophage system is presented to illustrate the method.IntroductionRespirable quartz dust exposure is known to cause librotic lung disease; respirable clay dust exposure is less likely to do so as indicated by epidemiologic data on occupational exposures and by animal model studiesP·7) The hypothesis that damage to pulmonary macrophages in the acinar region of the lung by respired dusts is an early event in the disease process requires consideration because kaolin clay and quartz dusts are comparably cytotoxic to pulmonary macrophages in vitro.(3•9)"

Mar 1, 1989

By K. Oraee

Proven and probable coal reserves in Iran are estimated to be in excess of 5 Billion tons while the annual coal production is a mere 2 Million tons. Underdevelopment of the industry has proved higher production levels to be impossible, despite growing demand for energy supplies. The existences of numerous legislation are thought to have a detrimental effect on coal mining activities to the extent that some business entities have become uneconomical in many areas. This paper provides an analysis of the prevailing mining laws, policy making, legal frameworks and obstacles. It also outlines some other obstacles enshrined in the law and also highlights areas where foreign direct investment should be encouraged. The costs of lost opportunities are then estimated. The paper concludes by demonstrating that deregulations, amendments and in some cases complete abolishment of the incumbent legislations governing the coal mining industry will greatly enhance development of the industry. The analysis provided in this paper together with the results obtained, can prove useful to macro-economic policy makers both at local and national levels.

Feb 27, 2013

By Peck RC

The ore body at Elura contains fine grained galena and sphalerite in a matrix which is mostly pyrite. A differential flotation circuit concentrates lead and silver in the first section and zinc in the second. The lead section, shown in figure 1, was sampled in detail previously and the metallurgical performance assessed on a size by size basis. That assessment took no account of liberation and given the fine grained nature of the ore body, this could lead to an incomplete picture of the flotation performance. Liberation measurements were made using the QEM*SEM system on four size fractions of samples taken from seven different streams in the lead section. Using the mineral flows obtained from the mass balance around the lead section an excellent liberation balance was obtained which enabled the effect of liberation on the flotation performance to be assessed. The measurements indicated that only 17 per cent of the galena and 28 per cent of the sphalerite in the flotation feed was liberated. On the other hand 31 per cent of the gangue iron sulphides were liberated. The final concentrate was largely composed of locked galena and locked iron sulphides with 85 per cent of the product being locked. There was a small but significant fraction of liberated pyrite.

Jan 1, 1991

By Mark Sherman, M. Dennis, Raj Rajamani

"The two Alumbrera 36ft (10.97m)dia. SAG mills were sized, using the FDW ""Grindpower 'I program, to treat an average of 1852 tph each. This paper describes how modelling of the shell lifter design, using the Millsoft program, identified milling inefficiencies caused by poor charge motion. This explained the ""as built"" circuit's inability to achieve the throughput rates predcted by the circuit's designer. Use of the Millsoft program to design a new, dramatically different lifter configuration, in conjunction with a different approach to variable speed drive utilization, has resulted in an improved charge motion and a 30% increase in hard ore milling rates. The new lifter design has allowed the designer's predicted average throughput rates to be achieved.IntroductionThe Alumbrera project grinding circuit consists of two 36ft dia. X 17ft EGL, 13 500 kW, variable speed, gearless drive SAG mills coupled to four 20ft dia. X 30ft EGL, 6 000 kW fixed speed, gear driven, ball mills. The circuit is configured as two identical grinding aisles, each consisting of one SAG mill and two ball mills. No pebble crushing circuit was installed due to the expected absence of a critical size fraction in the first years of production. However, the grinding circuit layout does incorporate space for a pebble crushing retrofit. At present, only about 5% - 10% of the new mill feed reports as trommel oversize and is recycled back to each SAG mill using a water cannon.The circuit was designed to be ball mill limited and to treat the four major Alumbrera ore types at rates varying between 68 000 tpd, and 89 750 tpd, depending on ore hardness. Average throughput rate, and hence nominal design rate, for the grinding circuit was 80 000 tpd (1 852tph per line at 90% availability)."

Jan 1, 1999

By H. A. Kortmann

For the commercial production of iron ore pellets from hematite ores, as it is practiced in various pellet plants, the addition of lime has shown to be an efficient means with a view to improving cold compression and abrasive strength of the indurated pellets considerably. Unfortunately, it has also been shown at the same time, that the metallurgical properties as, for instance, swelling behavior, softening during reduction under load and disintegration of the grain, can be adversely affected to a high degree. In the course of smelting tests carried out by renowned steelworks, blast furnace operation was heavily disturbed by the swelling and early softening of the pellets, also by their disintegration in the low-temperature range, which altogether led to a considerable lowering of the smelting rate (1, 2, 3).

Jan 1, 1972

By Glenn A. Hazen

Longwall mining is the preferred method for removing underground coal since a larger amount of coal can be removed faster and with less waste when compared to the room-and pillar type mining. Thus, the coal tonnage removed each year by longwall mining methods has increased dramatically. However, a high extraction rate results in surface subsidence which has adverse effects on the environment and on surface structures. Predictions of structural damage are dependent on the magnitude of the expected horizontal strains. Three methods for predicting subsidence characteristics are considered in this paper: the graphical method, the profile method, and the finite element method. All three methods can be used to predict ground movements and horizontal strains. However, the finite element method, which takes into account the structural properties of the stratigraphy and equilibrium of the overburden, is theoretically the more logical choice for use in subsidence prediction.

Jan 1, 1987

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By D. Wolfe, K. Reid, T. Nunn

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. In order to minimize front-end rejects, and to allow for high throughput, the ore top size at Aurora has been set at a nominal 125 mm. These relatively large lumps have a significant effect on both pump performance and pipeline pressure gradient. Current design methods underestimate the solids de-rating effect of lumpy slurries in pumps, and do not accurately describe the distribution or magnitude of the lump effect on pipeline pressure gradient. Data from the Aurora hydrotransport systems has been compiled, to quantify the effect of lumps on the pump head ratio and pipeline pressure gradient, and how this effect changes as lump ablation occurs along the length of the pipeline. A model has been built, using a logarithmic curve, which predicts the effect of 125 mm lumps on pipeline pressure gradient as a function of velocity and the distance from the start of a hydrotransport pipeline. This model is applicable only to Aurora hydrotransport operation, but similar models could be developed for other operations using the same methods. Using accurate pipeline pressure gradients and pump head ratios when designing future hydrotransport pipeline systems will help improve their reliability and operability."

Jan 1, 2014

By Woodcock J. T, Millett R. N

It was shown that manganese dioxide could be used as an oxidant in acid thiourea leaching of a gold ore. Manganese dioxide could generate high redox potentials and was as effective as hydrogen peroxide in the leaching process. Results obtained under closely controlled leaching conditions confirmed that high redox potentials enabled faster dissolution of gold to be obtained but led to extremely high reagent consumptions (thiourea, acid, and manganese dioxide). Additions of sodium sulphite solution in an attempt to lower thiourea consumption by reducing formamidine disulphide back to thiourea were only marginally successful. Although thio- urea consumption was slightly decreased, the consumption of acid and manganese dioxide was substantially increased and there was no net benefit in using sulphite. Tests in which a single addition of mangan- ese dioxide was made before addition of thiourea minimized overall reagent consumption and gave only a slightly lower dissolution rate of gold. This is a promising technique for further Investigation.

Jan 1, 1987

By August Wendel

IT is a well-known fact to all Bessemer steel manufacturers using a blooming mill, that ingots show large cracks in the first few passes of the rolls, which, in the following ones, do not always roll up satisfactorily. This deficiency in the quality of the product is generally called " red-shortness," though, in the writer's opinion, mostly unjustly so. Different explanations for the said peculiarity are given by the leading authorities, each works selecting one element as a special scape-goat for the inferior quality of the ingot. The sulphur is generally first charged as being the principal cause of all mischief in this direction ; then, after ascertaining that sulphur is not higher than the average, and sometimes lower in the very worst heats, silicon has to bear its share of abuse. How and why silicon should affect the working qualities of the metal, the writer could never precisely learn, but is convinced that the doctrine of its pernicious influence is an established one with many. In cases where silicon failed to explain everything, resort was taken to calcium, aluminum, and some other known or unknown elements, without settling the difficulty; and lastly, when the skill of the chemist became exhausted, " practical men " came to the same conclusion, which many leading blast-furnace managers had arrived

Jan 1, 1876

By Lyman Fearn

Men and institutions are what they are largely because of inheritance. Out of the past comes experience that enables men to build more wisely than did preceding generations. The field of possibilities has widened as the horizon of men's vision has been extended. The realization of these possibilities has depended largely on the application of men's natural endowments, brain and brawn, to the problems at hand. In the field of mechanized mining, Wyoming has a greater percentage of men with vision, who have a realization of the possibilities of mechanized mining, than any other state in proportion to tonnage production. With the introduction of mechanized mining systems have come problems that have caused the men who are connected with the safety work much thought. Discussions on mechanical drilling, cutting, loading, conveying, haulage, etc., have come in for their share of the debate. There have been a few attempts made to show that mechanical mining is safer than are the more primitive ways of doing underground work by man power. We also have a number of places in the coal producing States of the United States, where the mechanized systems have been abandoned chiefly on account of the safety element involved bringing about condemnation of the system by State inspection forces. Certain types of scraper systems have been condemned, and some have voiced opposition to long faces. This would lead us to believe that the question is still a debatable one as far as the safety element is concerned. It is only fair that we discuss the operations of mechanical systems and from the results obtained take analysis of conditions as they exist, basing our conclusions from the results obtained.

Jan 1, 1928

By J. E. Burke, Y. G. Shiau

SEVERAL attempts have been made to account for the fact that grains in a fully recrystallized metal will coarsen on annealing Two fundamentally different hypotheses have been advanced; with several variations of each. One school considers that the cause of grain growth is the surface energy of the grain boundary The theory of Jeffries1 that grain size and grain size contrast control growth is an example The second school considers the primary cause to be a difference in the lattice energy on either side of the grain boundary The more perfect grains are considered to grow at the expense of their less perfect neighbors, with a decrease in free energy, and a consequent increase in the stability of the system. Burgers2 presents the case for the strain or lattice imperfection theory of grain growth quite completely The latter theory is attractive, since there is no doubt that differences in lattice energy or lattice perfection can cause grain boundary migration A recrystallization nucleus grows for this reason as was beautifully demonstrated by van Arkel and Ploos van Amstel3 Although it is generally stated that grain growth does not precede recrystallization, several workers4,5 have shown that small strains may induce a single crystal in an aggregate to grow, or at least may cause some' grain boundary migration The origin and nature of the imperfections that are considered to be responsible for normal grain growth have never been clearly described, but it is generally agreed that they are a consequence of the difficulty of atomic reorientation in the solid state, and that they do not seriously differ from the type of imperfection that-can be introduced by mechanical deformation An object of the present work was to determine whether the introduction of mechanical deformation would cause grain growth in a specimen which would not otherwise show it under the conditions used It was also planned to determine the effect of such deformation the rate of growth in a specimen which would show - growth in the unstrained condition Recently Maddigan and Blank6 have indicated that slightly strained specimens of alpha brass can undergo considerable growth prior to recrystallization if annealed at low temperatures French7 has reported that at deformations less than 17 pct it is very difficult to detect the beginning of recrystallization in the same material. It was therefore planned to broaden this work to include a complete study of the microscopic behavior of alpha brass under conditions of temperature, time, grain size and deformation such that recrystallization would not occur or would occur to only a small extent EXPERIMENTAL PROCEDURE The brass was prepared by melting cathode copper and commercially pure zinc

Jan 1, 1947

By Prakash Venkatesan, Mehmet Ali Recai Ӧnal, Shaik Saida, Veerendra Singh, Chenna Rao Borra, Manish Kumar Kar

A laboratory-scale investigation of the effect of milling operation and catalyst addition ( K2CO3) on the partial reduction of low-grade pyrolusite ore pellets was carried out using coke as a reductant. Thermogravimetric analysis was used to understand the correlation between milling and catalyst addition parameters with the reduction temperatures. DTG analysis of pyrolusite pellet reduction showed three distinctive peaks associated with a three-step reduction mechanism (i.e., MnO2→ Mn2O3→Mn3O4→MnO). The results showed that the grinding and addition of the catalyst have a significant effect on lowering the MnO2 reduction temperature independently. But maximum reduction temperature drop is obtained when combining grinding and catalyst addition in this work. By 3 h milling and 10 wt% catalyst addition, the reduction temperatures were reduced by more than 200 °C compared to the raw ore pellets. These results obtained from the DTG analysis were further supported by XRD analysis of the reduced samples.

Dec 20, 2022

This paper reviews the historical literature and the author's experience with regard to the effect that the selection of grinding ball size or sizes has on ball mill grinding efficiency. The conclusions presented provide guidelines for single and multi-size charging prac- tices in commercial milling operations.

Jan 1, 1998

By Augustine O. Orumwense

Ball mills are commonly used for regrinding operations in the mineral processing industry. But, in recent times, efforts are being made at the introduction of stirred mills particularly for those instances where very fine grinding is required. Media type (steel shot, glass beads, alumina balls and crushed quartz), media size, mill speed and the number of passes required to obtained the target product size are studied. The product size and energy consumption are used in the evaluation of the test results. The grinding media size, shape, density, filling ratio, mill circumferential speed and grinding time play a distinct role in product size fineness.

Jan 1, 2005

By Zygmunt Sadowski

Problems encountered in barite flotation from various waste materials such as spent drilling muds are likely to be closely connected with the effect of chemical additives and metal ions present either added or present as contaminants, on the flotation. Fuerstenau and Palmer (1976) have studied in detail the adsorption of multivalent cations onto oxide and silicate minerals. It was observed that the adsorption of a multivalent metal species exhibits a sharp pH dependence which is related to the formation of hydroxy complexes of the metal ions in solution. Investigations on the recovery of barite from tailings ponds and mining wastes (Sullivan and Lamot, 1981) have shown that such barite materials can contain large quantities of carbonate and silicate minerals (including clay minerals). Also iron oxide slimes can be present. From these substances cations such as Ca2+, Mg2+, Fe2+ and A13+ can potentially dissolve and be present in the aqueous phase accompanying the various minerals. These ions and their hydrolysis products can have a substantial effect on any subsequent flotation scheme. The present study investigates the effect of the noted ions on both the stability and electrokinetic behavior of barite suspensions.

Jan 1, 1986

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By Weiran Zuo, Emmy Manlapig, Fengnian Shi

The effect of metalliferous grains on electrical comminution efficiency was investigated by comparative experiments using natural rocks and synthetic samples. The result indicated that the existence of metalliferous grains affects the breakage probability and product size distribution of electrical comminution. On average, metalliferous grains increased the breakage probability of particle in the first pulse discharge by 55% and generated finer product at the coarse end. As a result, particles with metalliferous grains exhibited higher energy efficiency than that without metalliferous grain in electrical comminution. A positive linear relation between product fineness and specific energy in electrical comminution was observed. With the assistance of numerical simulation on the electrical field distribution of ore particle, the role of metalliferous grains in electrical comminution is confirmed and the mechanism of metalliferous grains effect is elucidated. Understanding of the effect of metalliferous grains on electrical comminution is important to evaluate the feasibility of applying electrical comminution to ores with different mineral composition, and to understand the breakage behavior in electrical comminution.

Jan 1, 2014

By Lana Alagha, Ashraf Alsafasfeh, Amal Al‑Hanaktah

As freshwater resources are becoming scarce, the use of seawater as replacement of fresh water is appealing in order to make mineral processing operations more sustainable. Since froth stability plays a critical role in determining the performance of flotation operations, there is an urgent need to study the effect of frother dosage and seawater on froth stability. In this study, flotation tests in seawater were conducted to examine the effect of frother’s dosage (MIBC) on the froth stability and flotation performance of low-grade phosphate ore. The stability of the froth layer was assessed by measuring the froth growth velocity and the froth maximum height at equilibrium. Results indicated that the best flotation performance was obtained at 75 g/ton of MIBC where ~ 90% of phosphate minerals were recovered. At this recovery value, the concentrate grade was determined to be ~ 70%. Results from froth stability experiments showed that the stability of the froth layer increased by increasing MIBC dosage. At MIBC dosage of 75g/ton, the calculated values of dynamic froth stability and the froth height were ~ 0.4 cm/sec and 16 cm, respectively.

Jan 17, 2024