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By David Deglon, Martin Harris, Mehdi Safari

"This study investigates the effect of energy/power input on the flotation of a platinum ore in a pilot-scale oscillating grid flotation cell. Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Secondary rougher feed and primary cleaner tail streams were floated in a pilot-scale oscillating grid flotation cell at power inputs from 0 to 2.5 W/kg, using 0.50 and 1.50 mm bubbles. From this study one may conclude that the effect of energy/power input on the flotation rate is strongly dependent on the particle and bubble size. Flotation rates generally increase with increasing particle size and decreasing bubble size. Increasing energy input generally leads to an increase in the flotation rate for finer particles and an optimum flotation rate for intermediate & coarse particles. Optimum conditions for intermediate/coarse platinum ore particles are using small bubbles at low energy inputs, or large bubbles at higher energy inputs. These results suggest that higher energy inputs are generally beneficial for the flotation of platinum ores as these consist predominantly of finer particles (-75 µm) and most industrial flotation applications operate with larger bubbles (1.0-2.0 mm).INTRODUCTIONThere is a considerable body of experimental and theoretical evidence to suggest that energy/power input plays an important role in flotation kinetics, particularly in the finer particle sizes where flotation efficiency is poor (Deglon, 2005). A number of excellent studies into the effect of energy on flotation kinetics have been carried out in impeller stirred cells (Ahmed and Jameson, 1985; Deglon, 2002; Pyke et al., 2003; Newell and Grano, 2006). Investigations using this type of cell have a number of limitations. The impeller influences particle suspension, bubble break-up and agitation in the cell. In addition, turbulence is highly inhomogeneous and anisotropic, with power intensities near the impeller orders of magnitude higher than those found elsewhere in the cell (Deglon, 1998; Koh and Schwarz, 2003; Schubert, 1999, 2008). These limitations have resulted in the development of novel cells for the investigation of energy input."

Jan 1, 2016

By S. K. Utimurd, D. C. R. Espinosa, J. A. S. Tenório

"Waste Electrical and Electronic Equipment (WEEE) has become an environmental issue due to technological advance and waste plastic is one of the main polluters. The excessive discard of these plastics result in a difficult to dispose it to landfill and need further separation with technique in order to produce high added value plastics. There are many kinds of plastics in extensive use at the present time and the co=on are the acrylonitrile-butadiene-styrene (ABS) and high impact polystyrene (HIPS) used in the production of electric appliances. These plastics are difficult to separate because they have similar densities. Flotation of plastics is one possible separation technique and using selective wetting agents. The separation may be possible given close control at particle size and the concentration of the reagent. The process was able to produce a concentrate of HIPS with at least of 93% purity and a concentrate of ABS with 99% purity.IntroductionThe current situation of municipal solid waste (MSW) management especially in emerging economies like Brazil, the growing population and economic activity will result in a significant increase in the generation of waste in the coming decades. It is worthwhile to review and update the sources, amounts and recovery technologies of specific materials from waste, particularly from municipal solid waste (MSW).The growing impact of the current waste management practices stresses the need for a change in how waste is handled. The 2012 survey and the Brazilian Association of Public Cleaning and Special Waste Disposal Companies (ABRELPE) reports the generation of 62 Mt urban MSW in that year, which is an increase of 13% compared to 2011. It has been reported that in Brazil about 90.17% of the generated MSW is currently collected, which indicates an increase in the coverage of collection services compared to 2011 [ l]."

Jan 1, 2014

By Majid Sadeghi, Ali Naghi Dehghan, Kaveh Ahangari, Seyed Mahdi Pourhashemi

"Instrumentation and monitoring of ground deformations in tunneling is a principal means for selecting and controlling the excavation and support methods among those foreseen in the design, for ensuring safety during tunnel construction (including personnel safety inside the tunnel and safety of structures located at ground surface) and, finally, for ensuring construction quality management. In this paper, the effect of Hakim Tunnel excavation on the behavior of the surrounding ground was investigated based on the geotechnical instrumentation. This tunnel with 1080 m length, 18 m width and 12.6 m height is being constructed using the SEM/NATM along the Hakim Highway in Tehran. The results which are obtained from recorded displacements by geodetic pins (on the tunnel wall and roof), extensometers and settlements pins (at the ground surface) demonstrate the tunnel stability during the various stages of excavation. However, it is concluded that the rate of excavation in different sequences could have a major role on stability of tunnel. In this case the surface and underground openings were monitored as well as needed for controlling the face probably collapse. INTRODUCTION Tunneling is increasingly being used world-wide to provide the infrastructure required for sustainable urban areas. The high demand for space and the disturbance of existing infrastructures by construction measures increasingly forces future infrastructure projects to be conducted underground. One of the important purposes of tunneling projects in urban area is not only to minimize displacements but also to control them during the construction (Pourhashemi et al., 2015). Normal method of tunnel stability analysis is not able to evaluate the real rock and soil mass behavior. Hence, instrumentation is a practical method to monitor displacements, to evaluate the stability of underground openings, and also to determine the rock and soil mass properties (Dehghan et al., 2012. Dehghan, 2013). Rocks and soils are materials with properties that can change instantly and significantly from one point to the next. Some complications may often happen due to uncertainties in the loads that the new facility must withstand during construction and operation. Instrumentation and monitoring provide quantitative information on actual behavior of ground and adjacent structures. A lot of deformation monitoring studies for determining and analyzing different kinds of engineering structures such as tunnels, bridges, high-rise buildings and dams are implemented. Considering the type of the structure, its environmental"

Jan 1, 2016

By Mark S. Stagg, Rolfe E. Otterness, Stephen A. Rholl

The Bureau of Mines fired seven test blasts in a 22-ft bench of limestone, screening the material to investigate the influence of explosive type and between row delays on fragmentation. Four 4-hole, single-row test shots were conducted evaluating dynamite, ANFO, emulsion, and a 60-40 emulsion-ANFO mix. Three 12-hole shots, with three rows of 4-holes, evaluated delays between rows of 24, 36, and 120 ms. Accurate in-hole electronic delays were used, firing within 1.5-ms of the nominal delay. All seven shots had a 6- to 7-ft burden, 10-ft spacing, with a hole diameter of 3-1/2 in fired on a 12-ms delay between holes in the row. The tests were instrumented with strain gauges grouted in the burden region examining stress wave and gas pressure effects. Fiber optic probes were used to confirm timing and to obtain detonation velocities.

Jan 1, 1989

By Nicholas J. Welham

"The effect of extended ball milling has been studied for two industrial processes: (1) the processing of metal sulphide concentrates; and (2) the carbothermic reduction of ilmenite to synthetic rutile. The plant concentrates were a gold ore with 128 g/t Au of which 8% was non-refractory and a zinc concentrate with copper impurities.The gold concentrate showed complete dissolution of the gold bearing minerals after milling giving almost complete gold liberation. The zinc concentrate showed almost all of the sulphides had solubilized leaving the gangue and elemental sulphur. A study of pure pyrite and arsenopyrite shows that selective dissolution should be possible by a simple leaching process directly after milling.The milling of ilmenite and coal together results in a temperature decrease of 150°C in the subsequent carbothermic reduction of ilmenite, in addition to improving both the rate of reaction and the selectivity of reduction to rutile. IntroductionAlmost all mineral processing plants use mills for the size reduction of particles prior to physical and chemical processing. When continuing beyond size reduction the energy transferred causes deformation, breakage and realloying of particles giving a steady-state particle size. The breaking also causes increasing damage to the crystal structure by formation of smaller grains giving an increasing number of grain boundaries and increasing crystalline defects due to deformation. The increasing number of grain boundaries and defects leads to increased reactivity, which can be seen directly by a reaction within the mill, or indirectly, via a decrease in the subsequent annealing temperature required for reaction."

Jan 1, 1997

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By James M. Fragomeni

"The mechanical behavior of an Al-Li alloy was studied and related to the extrusion processing parameters, the plastic metal flow during defonnation, the anisotropy, and the microstructure. The extrusion temperatures, strain rates, extrusion ratios, billet temperatures, and extrusion geometries were varied during processing and correlated with the microstructure and properties. The extrusion processing variables were related to the mechariicar behavior, anisotropy, and microstructure through the ZenerHollomon parameter i.e., the temperature compensated strain rate. Based on optical and electron microscopy studies it was found that regardless of the extrusion conditions, the various microstructures for the most part were unrecrystallized for both the as-extruded and the solution heat-treated conditions. Smaller grain sizes were correlated to larger Zener-Hollomon parameters. The extrusion temperature and ratio did not significantly affect the strength or ductility as did the section geometry, which had a large affect on these mechanical properties. The anisotropy of the properties varied substantially when comparing the extruded longitudinal versus transverse grain orientations.IntroductionThe extrusion process also has a substantial influence on: the microsfructure and mechanical properties of a material that is Athens, Ohio, 45701 fonned The plastic defonnation that occurs during the extrusion process alters the grain size, crystallographic texture, anisotropy, subgrain size, dislocation density and various other microstructural features. Often the material being extruded is not homogeneous, therefore variations in the microstructure and properties occur across the cross-section of the final extruded product. The mechanical properties and microstructure can also vary with length since it is hard to maintain a constant temperature throughout the extrusion process. The extrusion temperature often varies from the heat generated during the extrusion process. The demonstration material that was extruded for this .study was an aluminum alloy containing 2.6wt, % lithium and 0.09wt.% zirconium. This alloy was strengthened by heat treatment causing nucleation, growth, and coarsening of coherent metastable o' (Al3Li) precipitates in the microstructure. The ? precipitates which are a consequence 9f artificially aging the AlLi alloy, are spherical, ordered, and coherent with the aluminum matrix and impede the dislocation glide inotion during plastic defonnation. Theo particles grow homogeneously in the matrix, and have the Cu3Au (L 12)"" superlattice crystal structure. Aluminum-lithium alloys are used primarily for aerospace structural applications since they have attractive properties such as a lower density and higher elastic modulus than conventional 2XXX and 7XXX alloys."

Jan 1, 2000

By Keith G. Wallace

The effect of face resistance on ventilation air leakage through stoppings was measured in a twin development heading. Face resistance was varied by alternately tightening or loosening the face line brattice to change the line brattice leakage. Results indicated that tight brattice lines are necessary to maintain acceptable airflow at the face but result in higher leakage throughout the entire system, reduced overall ventilation efficiency, and higher operating costs. Conversely, a low face resistance which simulated an auxiliary fan/duct system gave reduced stopping leakage losses, higher quantities of air at the last open cross-cut and greater entire system efficiencies

Jan 1, 1984

By Enver Alan, MerkeziYapı

People are migrating because of economic, social, natural and political reasons. These natural and humane factors effects the distribution of populations. The need for tunnels has grown in order to provide a comfortable life and reduce losses such as waste of time, labor, energy, efficiency and so on. It is inevitable to carry out excavations in rock tunnels (shears, platforms, lines, connections, wastewater, distribution, energy, transportation etc.), that will be built by excavating with conventional method, by controlled blasting regarding with constrains. In this study of applied explosives engineering the blasting applications are evaluated, which were carried out for research and development purposes at Yenisahra Station tunnels in Kartal Formation which was built with the aim of solving İstanbul's transportation problem within the framework of the Kadıköy-Kartal Metro Project. Twenty-four shots were made by using explosives in 60 blastholes that were drilled in the tunnel faces, which were located between and outside of two different faults. Six microphones were used to measure the air shock and eight geophones were used to measure the parameter values of the vibrations (particle velocity, frequency, displacement, acceleration, amplitude, wavelength etc.), which were placed at predetermined points of the surface, occurred during the blasting applications. Data from the geophone and microphones were recorded on six seismographs. The coordinates and the distances between the shot points and the measurement stations are determined by an electronic theodolite. The total number of seismic records, recorded in seismographs, is 118. The number of records of vibrations that crossed the faults is 42 and the number of records of vibrations that did not cross the fault is 76. The particle velocity, frequency, amplitude, acceleration, displacement and wavelength were measured in transverse, longitudinal and vertical directions. The total number of measurements is 354. By evaluating all seismic records, the effect of delay intervals, faults and scaled distances on the particle velocity, frequency, amplitude, displacement, acceleration, wavelength and air shock were investigated. When the vibrations formed during the Research & Development (R&D) blasts were examined, it was determined that the parameter values of vibrations that crossed the faults are lower than the ones that did not cross the faults. In addition, when the particle velocity values of all vibrations are examined according to the present circumstances, it is determined that the waves did not cross the fault in all delay intervals are superposed in all directions, and that the least superposing occurred in the 50 ms delay range.

By Enver Alan

In this study of applied explosives engineering the blasting applications are evaluated, which were carried out for research and development purposes at Yenisahra Station tunnels in Kartal Formation which was built with the aim of solving İstanbul's transportation problem within the framework of the Kadıköy-Kartal Metro Project. Twenty-four shots were made by using explosives in 60 blastholes that were drilled in the tunnel faces, which were located between and outside of two different faults. S

Feb 1, 2020

By Takeshi Yoshikawa, Kazuki Morita, Yuichi Kato

"A composite composed of carbon fiber and a Cu-Si alloy is a promising candidate for next generation brake disc materials used in high-speed trains. The composite can be prepared by vacuum infiltration of the Cu-Si alloy into the fibrous carbon matrix. The activity of Si in the alloy plays an important role in controlling the formation of SiC; this formation is attributed to the reaction between the Si in the alloy and the carbon fiber during the infiltration process. Because Fe has strong affinity with Si, the addition of Fe is expected to decrease the activity of Si in the alloy. In the present work, the variation in the activity of Si in the alloy with the addition of Fe has been investigated by equilibrating a Cu-Fe-Si alloy with solid SiO2 and graphite under controlled CO partial pressure. The first-order and second-order interaction parameter of Fe on Si in molten Cu was determined to be -16 and 160, respectively. The negative value of the first-order interaction parameter clarified the addition of Fe to the Cu-Si alloy is effective in decreasing the activity of Si in the alloy.IntroductionIron-based materials have been commonly used for brake discs in high-speed trains. It becomes critical for brake disc materials to withstand high thermal loads with an increase in the maximum speed of high-speed trains. The fabrication of high heat-resistant, light-weight brake disc materials is then crucial for their use in next-generation high-speed trains. Carbon fiber is known to be a light-weight, high-strength material, and is considered to be a promising matrix material for use in brake discs. The Cu-Si alloy exhibits high thermal conductivity. The composite in which the Cu-Si alloy is added to the carbon fiber matrix is expected to be a high performance material for brake discs. The composite can be prepared by the infiltration of the Cu-Si alloy into the carbon fiber matrix at a temperature higher than 1700 K."

Jan 1, 2012

By H. Bradley Johnson

A number of Federal laws affecting safety and health in the mining industry has been enacted and revised over a period of many years. We have tended to classify these laws and their applicability into three categories: 1) coal mines, 2) metal and nonmetallic mines, and 3) mines with Federal supply contracts. With the growing attention which is being given to mine safety by the Federal government, the entire mining industry should keep aware of all developments in the administration of each of these laws.

Jan 1, 1970

By Jr. Raleigh

Three run-of-mine bituminous coals, which ranged in rank from low volatile to high volatile A, were floated at nominal -28 mesh (590 µ m), -100 mesh (150 µ m), and -400 mesh (37 µ m) feed particle sizes with selected pyrite depressants and a dispersant. For the coals tested, pyrite and ash-forming minerals were usually rejected best at a -100 mesh feed particle size. Depressant additions tended to improve flotation selectivity between pyrite and coal. When joint dispersant-depressant systems were used at -100 mesh (150 µ m) feed particle sizes, the total sulfur content of the clean coal decreased further. For a comparable coal yield, less fuel oil collector was required for the flotation of -100 mesh coal than was required for the flotation of either -28 or -400 mesh feed.

Jan 1, 1990

By M. Misra

The processing strategy for the effective separation of bitumen from low grade (< 10 weight percent bitumen) Utah tar sands by a hot water process differs significantly from that used for the processing of high grade (> 10 weight percent bitumen) Utah tar sands. Excellent separations (coefficient of separation = 0.9) can be achieved for high grade Utah tar sands by intense hot water digestion followed by a modified froth flotation step. Such a technique is ineffective for low grade tar sands. In order to change the characteristics of the low grade tar sand an attempt was made to enrich the bitumen content of the feed to greater than 10 weight percent by recycle of bitumen concentrate to the digestion stage. However the quality of the separation was not improved under these circumstances. Similarly feed enrichment by heat treating the low grade feed with recycled concentrate prior to digestion did not improve the separation. More successful separations of low grade Utah tar sands were finally achieved by modification of the viscosity of the low grade bitumen with controlled addition of diluent. These results of the hot water separation tests and variations in the quality of separation are interpreted in terms of the physical properties of the bitumen and the surface bonding forces operative at the bitumen-sand interface.

Jan 1, 1979

By J. D. Miller, M. Misra

The processing strategy for the effective separation of bitumen from low grade (<l0 weight percent bitumen) Utah tar sands by a hot water process differs significantly from that used for the processing of high grade (> 10 weight percent bitumen) Utah tar sands. Excellent separations (coefficient of separation = 0.9) can be achieved for high grade Utah tar sands by intense hot water digestion followed by a modified froth flotation step. Such a technique is ineffective for low grade tar sands. In order to change the characteristics of the low grade tar sand an attempt was made to enrich the bitumen content of the feed to greater than 10 weight percent by recycle of bitumen concentrate to the digestion stage. However, the quality of the separation was not improved under these circumstances. Similarly feed enrichment by heat treating the low grade feed with recycled concentrate prior to digestion did not improve the separation. More successful separations of low grade Utah tar sands were finally achieved by modification of the viscosity of the low grade bitumen with controlled addition of diluent. These results of the hot water separation tests and variations in the quality of separation are interpreted in terms of the physical properties of the bitumen and the surface bonding forces operative at the bitumen-sand interface.

Jan 1, 1981

By Y. M. Zhao

The separating performance of a pilot dry beneficiation system using a gas-solid fluidized bed was investigated with coal from South Africa. The coal used for the study has a low inherent moisture content, a moderate ash content, a moderate volatile content, a low sulphur content and a high calorific value. Its washability is moderate. Experimental results show that the separating quality of the fluidized bed drops gradually as the feed-coal particle size decreases. The probable error, E, values for 50?25mm, 25?13 mm and 13?6 mm coals were 0.04 g/cm3, 0.06 g/cm3 and 0.09 g/cm3, respectively. The cause of the differences in separating characteristics was analysed by particle dynamics and numerical modelling. Furthermore, the pilot fluidized bed was employed to separate 50-6mm coal. In this experiment the coal ash content was reduced from 23.74% to 11.79%, with a probable error, E, value of 0.07 g/cm3and a recovery efficiency of 98.26%. This indicates that the fluidized bed is applicable to the separation of coal from South Africa and has good separating performance and wide applicability. Keywords: feed-coal particle size; gas-solid fluidized bed; dry coal beneficiation; numerical simulation.

Jan 1, 2010

By R A. Anand, N N. Viswanathan, M M. Pande

Slags are the most voluminous solid by-products generated in pyrometallurgical operations, and, as such, finding an application for these oxidic materials is pertinent to maintaining resource efficiency. In particular, pyrometallurgical copper production is associated with high slag rates, typically ranging from 2.2 to 3.0 tons of slag per ton produced copper, which necessitates slag valourisation. A possible application for these iron silicate slags is as supplementary cementitious materials (SCMs), which effectively lowers the CO2 emissions per ton of cementitious material. Although utilising iron silicate slags as SCMs has been studied in previous work, the scientific literature has limited data on the effect of composition on the inherent reactivity in cementitious systems. More specifically, no reports on the impact of FeO/SiO2 ratio have been presented in previous publications. Therefore, the present study aimed to isolate this parameter in a synthetic FeO-SiO2-Al2O3-CaO-MgO-Cr2O3 system. Since the amorphous content is a pertinent parameter for SCMs, a high-temperature confocal laser scanning microscope (HT-CLSM) was utilised to assess the crystallisation behaviour at continuous cooling conditions. Furthermore, high-temperature rheological experiments were conducted to measure the viscosities of the slags in relation to the crystallisation behaviour. The experiments showed that depolymerising the slag by increasing the FeO/SiO2 ratio generated a less viscous slag, which showed higher tendencies for crystallisation. Furthermore, experiments assessing the inherent reactivity as an SCM showed that depolymerising the slag by increasing the FeO/SiO2 ratio as the sole independent parameter generated an initially more reactive slag. However, replacing SiO2 with FeO was found to negatively affect the reactivity as measured over seven days within the tested compositional range.

Jun 19, 2024

By Ken Rahal, Chris Braun

As head grades of mines around the world decline, generation of tailings is increasing. Along with the increased tailings generation, reduction in water availability, and recent tailings dame failures, are causing mining companies to look at different disposal methods. One of the methods that is gaining traction is filtered tailings. Filtered Tailings currently provides the greatest water recovery and the smallest footprint among all the tailings disposal methods. This paper will present two case studies that analyze the filter and air compressor costs associated with a change in the final cake moisture target (i.e. a change from 17-wt% to 15-wt% cake moisture), for a base metal mine and gold mine.

Sep 30, 2022

By C. B. Webber, W. A. Grell

"Sherritt Gordon's Ruttan Mine is a copper-zinc operation located approximately 600 miles north-west of Winnipeg. Open pit mining began in 1973 at 10,000 Tpd., with a change over to underground mining in 1981 producing 7,500 Tpd. Ore is crushed to -3/4"" followed by rod and ball mill grinding (two ball mills in series), differential copper-zinc flotation, and dewatering. The copper and zinc concentrates are trucked 75 miles to Lynn Lake, where they are shipped by rail to the HBM&S smelter at Flin Flon.This paper describes a method used to predict the effect of grind particle size on metallurgical performance, as well as details on the copper and zinc metallurgical performance due to fine grinding in actual plant operation.Initial statistical studies on historical data (including ore source, head gr3de, grind, etc.) indicated that copper and zinc recoveries increased with fineness of grind, in the range of 50 to 65% -200 mesh.In order to extrapolate beyond 65% -200 mesh, and to develop expected nonlinear relations between grind, Cu concentrate grade, and recovery, the assays of screen fractions of copper concentrate and tailing were used to determin8 the relation between net smelter return (a function of grade and recovery) and grinding cost. The optimum economic grind would be that grind at which the net smelter return less grinding cost reached a maximum."

Jan 1, 1982

By Douglas W. Reeve, Hoc Nghia Tran, David Barham

"In kraft pulp mills, the spent pulping liquor is concentrated and used as fuel in the recovery boiler. Extensive deposits are formed in the upper section of the boiler due to the very high ash content of the fuel and the volatite nature of the ash. Deposits are composed of Na2S04, Na2C03 NaCI, some potassium salts and reduced sulphur compounds. Chloride and potassium salts are enriched in the deposits compared to the smelt due to their greater volatility.Severe corrosion of the superheater tubes in a recovery boiler has been traced to three factors: a non-uniform temperature profile in the flue gas, relatively high operating steam temperatures and high chIoride and potassium concentrations in the fireside deposits.The role of chIoride and potassium in superheater corrosion has been explained by increased Iiquid phase in deposits. Together with corrosion studies, this information has shown that kraft recovery boiler superheater corrosion due to the chloride and potassium enriched deposits can be avoided by proper boiler operation and by judicious superheater and furnace design.IntroductionThis investigation of recovery boiler superheater corrosion was initiated by the discovery of severe corrosion of the final stage superheater in a Canadian closed cycle kraft pulp mill(1,2). Metal wastage leading to tube failure was believed to be due to three major causes : the relatively high operating steam temperatures, the uneven distribution of flue gas temperature across the boiler which created a "" hot spot"" and the high chloride and potassium concentrations in the superheater fire side deposit. The mill responded to the problem by i) lowering the superheater steam temperature from 475°C to 380°C, ii) minimizing the chloride content in the spent pulping liquor, by controlling the NaCI input with recovered bleach plant effluent, and iii) changing metallurgy of a portion of the bottom section of the final stage superheater platens from ferritic steel T-22 (2.25% Cr, 1% Mo) to austenitic steel Incoloy 800H (21% Cr, 32% Ni, 46% Fe, 1.5% Mn, 1% Si, 0.6% Al) (Fig. 1). Details of the superheater corrosion experienced in the closed cycle mil! have been reported in previous papers(l ·2,) ."

Jan 1, 1984