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By T. D. Mailula

Paper written on project work carried out in partial fulfilment of M.Sc.(Chemical Engineering) degree Chromite and talc are two major gangue minerals in platinum bearing UG2 ore processed from the Bushveld Complex in South Africa. During flotation, talc is effectively depressed by the addition of depressants. Chromite, on the other hand, is considered to be hydrophilic, its recovery is believed to follow water recovery and therefore recovered by entrainment only. In certain cases it has been shown that chromite can be activated by the reagent suite and hence is made amenable to true flotation. The aim of the work was to investigate the effect of the addition of copper sulphate as an activator and the effect of the depressant type and dosage on the recovery of chromite. The results of these experiments showed that copper sulphate, at higher dosages, activated the chromite. Low dosages of copper sulphate resulted in no chromite activation. This was observed at low depressant dosages of both IMP4 (guar gum) and KU5 (carboxymethyl cellulose (CMC)). When the depressant dosages were increased, at higher copper sulphate dosages, it was observed that the activated chromite was depressed by IMP4, but that the activation was still significant with the use of KU5. The activation of the chromite is attributed to the form of the copper species present in the solution and on the mineral surfaces at pH = 9 enhancing collector adsorption and thereby increasing hydrophobicity. These species were not measured directly and it is recommended that this should be further investigated using surface mineral techniques. Keywords: flotation; depressants; chromite; copper sulphate

Jan 1, 2003

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using sodium dodecyl sulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).In order to investigate the effect of the initial concentration of Fe3+ on As removal, sets of experiments were performed with a concentration of Fe3+ in the proper range of pH (5,0 – 6,0) previously observed in the coprecipitation tests. As removal improves significantly as the concentration of the coprecipitant agent increases from 60 mg.L-1 (77,4%) to 80 mg.L-1 (99,7%). This is probably due to the higher concentration of ferric hydroxide (Fe(OH)3) which provides a larger surface area available for adsorption of As. From the initial coprecipitant concentration of 80 mg.L-1, As removal has shown to be rather high (? 99,7%), with the maximum being (99,9%) by using a Fe3+ concentration of 160 mg.L-1. Therefore, for a maximum As removal, under these test conditions, the optimum concentration of Fe3+ is 160mg.L-1.This paper also shows the effect of the initial concentration of Al3+ on As removal at a suitable range of pH (7,0 – 8,0). A very significant increase on As removal was found to occur as the initial concentration of coprecipitant was increased from 60 mg.L-1 (35,7%) to 80 mg.L-1 (97,7%) and a decrease in As floatability (43,7% - 54,5%) was found to occur from that Al3+ concentration amount. Based upon those results, the optimum Al3+ concentration so as to remove As under these test conditions is 80 mg.L-1."

Jan 1, 2003

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using Sodium Dodecylsulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).By comparing the coprecipitant type and concentration studies it could be concluded that As5+ removal in the presence of Fe3+ (160 mg.L-1) alone, or a Fe3+ (80 mg.L-1) and Al3+ (40 mg.L-1) mixture, is equivalently effective (99,9%) and greater than in the presence of Al3+ (80 mg.L-1) alone (97,7%).Through SEM/EDS analyses, it was possible to observe that both morphology and composition of the precipitate produced in the solution and retained in the foam depend on the physico-chemical conditions of the system, that is, on the species present in the solution."

Jan 1, 2003

Some crystal chemical properties of several apatites from Brazilian deposits and occurrences were determined; the samples had different origins (igneous, metamorphic and sedimentary). The aim was to establish relationships to their froth flotabilities behaviour. Detailed X-ray diffraction studies were carried out, to determine precisely the unit cell parameters and the degrees of crystallinity of the apatite samples. A thorough chemical analysis of these minerals was also conducted. Microflotation studies were carried out, using sodium oleate and dodecylammonium chloride as collectors. The crystallinity levels were determined for all samples studied, with the establishment of a crystallinity index, which varied from 10.0 to 4.5, on a normalised scale. A marked dependence was observed between this crystallinity sequence and flotability; for both collectors, flotability dropped drastically for crystallinity indices lower than 8.0. Also, the low crystallinity apatites showed a decrease in floatability, for longer conditioning times.

Jan 1, 1993

By M. Kermani

This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill has an alkali activator such as sodium silicate in its materials in addition to primary materials of cemented mine backfill which are deslimed tailings, water and binders. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. Initially, the influence of sodium silicate concentration on the mechanical properties of samples was evaluated using the unconfined compressive strength (UCS) test. Consequently, the effect of curing temperature on CHF and Gelfill samples cured in various curing temperatures ranging from 5?50 °C was studied using the UCS test. Microstructure of selected samples was studied wirth the mercury intrusion porosimetry (MIP) technique. This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Curing temperature strongly influences the mechanical and microstructural properties of CHF and Gelfill samples. (iv) The microstructure analysis revealed that the addition of sodium silicate can modify the pore size distribution and total porosity of Gelfill which can contribute to the better mechanical properties of Gelfill. (v) The MIP tests suggested the microstructure of specimens were changed by adding sodium silicate in a way that the Gelfill samples had a higher percentage of fine pores than CHF samples.

Aug 1, 2013

By P. G. Coombs

The kinetics of the cyclic oxidation and reduction processes for palladium powder were examined in the temperature range 848 to 923 K. The changes in oxidation behavior due to cycling are shown to result from the decrease in surface area. Sintering is found to occur only during the reduction process. Oxidation kinetics were found to follow a cubic law with time and yield a relation for the oxidation rate constant of k x = (1.05) 106 exp P74.0). 103 / RT] The kinetics of reduction are demonstrated to be first-order with the rate constant described by the expression: kr = (7.69) 1012 exp [-(208.0) 103 / RT] . In both expressions R is in J.mo1-1.K-1.

Jan 1, 1984

By S. Kok, D. Delport, J. Calitz

Altering the microstructure in order to improve the tensile properties of bow shackles resulted in inconsistency in the fatigue performance. This raises the question whether the inconsistency in fatigue life can be attributed to microstructural changes along the profile of the shackle or to decarburization at the surface. Bow shackles forged from 080M40 (EN8) material were subjected to different heat treatments in order to alter the microstructure. The shackles were subjected to five different fatigue load cases, which represented typical loads experienced at termination points for an overhead power line with a span length of 400 m, with changes in conductor type, configuration, wind, and ice loading. Although the change in microstructure does improve both the tensile and fatigue performance, we found that the depth of the decarburization layer has a greater effect on the high cycle fatigue life of bow shackles than the non-homogeneous microstructure.

Oct 1, 2021

The effects of changes in sintering bed height, coke fuel, suction and basicity on sinter productivity, physical strength and mineralogy were determined. It was found that, for a given iron ore, there is a narrow -coke range which maximises sinter strength, irrespective of bed height (in the range 300 to 500 mm) or basicity (in the range 1.2 to 2.2). Increases in bed height, at a constant coke level, improved the physical strength of the sinter. Productivity increases were obtained by increasing the sintering suction but, at coke levels other than the optimum, these *ere somewhat offset by the decrease in sinter physical strength. At basicities higher than 1.2 (i.e. 1.6, 1.8 and 2.2) there was a narrowing of'the size range of product sinter, with a decrease in the percentage of top size material, and a decrease in the amount of fines produced. Changes in coke, bed height and basicity exert major effects on sinter mineralogy, while the Nagoya index was mainly influenced by cote and bed height Changes.

Jan 1, 1975

By O Omidi, P D. Katsabanis

The effect of delay time on fragmentation has been discussed for a long period but rarely in a satisfactory and unbiased way. Despite the efforts of many researchers, delay selection for fragmentation improvement or optimisation remains a controversial issue. Large-scale tests have been plagued with scarcity and scatter of observations, while small-scale tests have been associated with boundary effects and energy losses. Theoretical work is often used to produce explanations for available measurements or tries to simplify wave propagation and wave interaction to guide observation and practical work. The present work analyses results obtained from a relatively large number of small-scale experiments in blocks made of grout, and re-analyses results of previous experiments, to conclude on the effect of delay on fragmentation. It is shown that the main contribution of the delay is found in the fragmentation of the larger fragments of the blast, while the small fractions show almost no effect. Samples, where copper liners were used to inhibit penetration of detonation products in the rock mass, showed effect of delay only when short times were used and steady but poor fragmentation when long delays were used. Based on small-scale experiments, it appears that the fragmentation is optimised when a hole fires prior to the radial cracks, produced by the previous hole, reach the free face of the blast. Gas penetration may result in the development of few more fractures that affect the fragmentation of the largest particles of the blast.CITATION:Katsabanis, P D and Omidi, O, 2015. The effect of delay time on fragmentation distribution through small- and medium-scale testing and analysis, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 715–720 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Y. B. He

The effect of the stability and rheological properties of magnetite dense medium on the separation performance of a 6" dense medium cyclone (DMC) is studied with the use of fine density tracers. The tests in which different size fractions of magnetite are used to prepare the dense media reveal that at low medium densities (<1.5 s.g.), the best separation is achieved when using the magnetite with intermediate particle sizes (du3.2=18 11m). At medium densities above 1.5 s.g., however, it is beneficial to use coarser magnetite. With the fine magnetite dense medium, an increase in medium density results in a decrease in separation efficiency. With the coarse magnetite, an opposite trend is observed; the separation efficiency is improved with increasing medium density. An accurate cutpoint control is critical in gravity separation. The cutpoint shift for coarse feed particles is found to decrease with increasing medium stability (density). It assumes values close to zero in a highly stable fine dense medium. When the size of the treated particles is small (<0.5 mm), the cutpoint shift is mainly determined by medium rheology. With increasing medium density, a continuous increase in cutpoint shift is observed.

Jan 1, 1993

By Herty, C. H.

The effect of temperature on the physical properties of structural materials has been the subject of many investigations during the past decade. The literature on the effect of elevated temperatures. is voluminous, and during the last four years a great deal of experimental work has been carried out on the effect of low temperatures on the impact properties of steel. For many engineering purposes it is important to know the shock resistance of steels at low atmospheric temperatures, and with the ever-developing field of refrigeration and separation of materials at low temperatures, the normal limits of atmospheric temperature have been exceeded in practice. Iron and its alloys in the unnotched condition have a high impact strength at low temperatures, but in practice variations in type of notches result either from design or accidentally through scratches and surface or internal defects. A study of notched bar impact tests is, therefore, highly important to the engineer. A survey of the literature on low temperature impact testing indicates that chemical composition, heat treatment and method of testing have been the variables which have been considered in most previous work. In only a few instances has any mention of the steel- making method been mentioned and in these the comparison was between steel-making processes and not between steel-making methods on the same process. In view of the wide variations in impact properties at room temperature, in quench and strain ageing and in grain growth of steels of identical chemical composition, (by this is meant the usual five element analysis reported), it was felt

Jan 1, 1957

This paper discusses how the link between design software tools and recycling models can be established in order to predict the recyclability of the car during the design phase, as well as to be able to apply design for recycling on a solid technological basis. Due to the complexity of the design of the car, optimisation of recycling can only be realised based on a sound technological basis, in which the dynamic and statistically distributed parameters affecting the recycling rate are described and understood. This paper gives a brief overview of the dynamic and recycling models, which are developed for optimisation of the recycling of the car and the calculation of recycling rates of the car in the design phase in view of EU legislation. Moreover the possibilities for modelling of shredding and liberation within the recycling system are discussed. The performance of experiments on a fundamental basis in order to collect statistically correct industrial data, supported by a closing mass balance, is referred to on the basis of a large scale industrial recycling experiment. It will be shown how design for recycling and environment can be supported by the sophisticated models as developed by the authors.

Jan 1, 2005

The effects of detonation of downlines and downline-booster systems on lodse-poured charges of 94% porous prilled ammonium nitrate/6% fuel oil (AN/FO) were determined. Detonation stability was indicated by the initiation-failure pattern of detonating fuse witness lines located at intervals along the charge. Steel tubing was used as the confining medium. Charge diameters (d) varied between 2-21/32 and 8.1/8 in. and specific charge weights (w) of downlines between 4.0 and 93.2gr/ft. The axes of charge and downline were colinear. The minimum value of w required to cause initiation of AN/FO increased with d. When initiated by a downline only, the charge&apos;underwentlowòorder detonation. When downline-booster systems are used, the detonation wave in the downline cuts all equatorial planes in the charge before the detonation wave in the surrounding AN/FO. If the downline itself does not cause initiation, therefore, the explosive ahead of the main detonation wave is crushed, and hence desensitised, by the radially-expanding compression wave and gases generated by the downline. In a given equatorial plane, the fraction gftharge undergoing detonation decreases with an increase in the booster-plane distance. The longitudinal limit of nation increases significantly with d, but surprisingly little with a decrease in w. In the presence of a downline, the blasting performance of AN/FO charged _

Jan 1, 1970

By Kerr I. D, Kennedy M

Flash X-radiographs were obtained of commercial electric No 6 and No 8* strength aluminium tube detonators in small-diameter cartridges of emulsion explosive at various times after fusehead operation. The trigger system for the radiography was based on the detection of light following fusehead firing via optical fibres inserted into the fusehead cavity during detonator assembly. These experiments were simulated using a finite element hydrocode with realistic treatment of the non-ideal reaction kinetics. Excellent agreement was demonstrated for the shape and position of the shock waves. In both cases, initiation of the emulsion was predominantly forward from the detonator. For the No 8* strength detonator, this initiation resulted from the shockwave delivered through the sides of the detonator, while for the No 6 strength detonator, initiation was the result of a complex interaction between shockwaves originating both from the sides and from the endcap. In the reverse direction (towards the crimped end of the detonators), initiation was only weakly dependent on detonator strength, being controlled mainly by the competing processes of rarefaction from the cartridge boundaries and comer turning of the detonation wave from the forward initiation. The consequences for field performance of small-diameter emulsions will be discussed.

Jan 1, 1990

By John Manka

Emulsion manufactures often spot buy the diesel fuel used in their fuel phases from various sources. Because their diesel source changes, there can be large fuel variation which may affect the quality of the resulting emulsions. This paper shows that the diesel fuel used in manufacturing emulsion explosives has a significant impact on emulsion stability and that the fuel additives dosed into the diesel fuel as it is made also have an impact on the emulsion characteristics and stability. We found that fuels with higher distillation ranges improve emulsion stability. We also found that while none of the diesel fuel additives affected the initial formation of the emulsion, some fuel additives did affect the characteristics and stability of the emulsions as measured by emulsion viscosity, droplet size, high and low shear testing, bin storage testing and freeze thaw cycling.

Jan 1, 2002

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By Kyeong Woo Chung, Rina Kim, Ho‑Seok Jeon, Yeongjin Ahn, Byunghun Go, Min‑seuk Kim, Hong‑In Kim, Sujeong Lee, Yuik Eom

The study focused on the recovery of vanadium from a Korean vanadium-bearing titaniferous magnetite (VTM) ore, examining the behaviors of magnetic separation and Na2CO3 roasting-water leaching. Two concentrates were prepared using single-stage dry magnetic separation and three-step wet magnetic separation, resulting in V2O5 grades of 0.8% and 1.0% and major gangue mineral SiO2 contents of 6.5% and 1.7%, respectively. These concentrates were subsequently roasted at 1050 °C with the addition of Na2CO3 and then water-leached at 25 °C. Various stoichiometric ratios of V2O5 to Na2CO3 were tested, ranging from 1:1 to 1:40 of the theoretically required amount. As the amount of Na2CO3 increased, the vanadium leaching efficiency showed fluctuations between 4 and 35% for ratios of 1:1 to 1:10, while it linearly increased from 4 to 82% for ratios of 1:10 to 1:40 in the leaching of the low-grade concentrate. In contrast, the leaching efficiency increased from 47 to 74% for ratios of 1:1 to 1:8 and then sharply rose to 84% at a ratio of 1:10 in the leaching of the high-grade concentrate. Subsequently, it reached a plateau of 92 to 94% for ratios of 1:20 to 1:40. The difference in leaching efficiency was primarily due to the reaction of gangue minerals with Na2CO3, which hindered vanadium leaching from the VTM concentrates. This hindrance was notably more pronounced in the low-grade concentrate with the lower salt ratio, as the gangue minerals exhibited a preference for consuming Na2CO3 over vanadium. The mineral formation was analyzed in detail using XRD and MLA to shed light on the mechanism of different vanadium leaching behavior depending on the concentrate grade and vanadium to salt ratio. Based on the results of this study, it is evident that applying a proper magnetic separation procedure is significant to achieving satisfactory vanadium recovery with less salt amount by removing gangue minerals ahead.

Mar 15, 2024

By Rolf A. Knopp

This paper discusses how design differences in FLP diesel equipment in underground coal mines came about. "Design standards" tend to create differences between countries while fostering uniformity among products of competing manufacturers. "Performance requirements," on the other hand, tend to eliminate differences between countries while encouraging competitive development of better products. Examples of regulations from the U.S., Canada. Great Britain. Australia. South Africa, etc., are used to illustrate differences in the design and certification of diesel equipment for underground coal mines.

Jan 1, 1978

By T. W. Wlodek

In this paper the relative merits of shot peening, induction surface hardening, spiral-rolling, and the combination of these surface treatments, are evaluated on the basis of their capacity to increase the fatigue strength of drill steel. The S-N relations for plain car-bon steel (SAE 1080) and Ni-Cr-Mo drill steels in the as-rolled condition were determined previously, using the new Canadian method of testing drill steel introduced at the annual meeting of the Institute in Toronto in 1950 (19). S-N curves have now been determined by this method for these two drill steels in the following conditions: shot-peened and drawn, induction hardened, induction hardened and shot-peened, and spiral-rolled. ( S.R.) . The ratios of the fatigue strengths of these steels after surface treatment, to their fatigue strengths in the as-rolled condition, are compared and the most beneficial treatments are thereby pointed out. The expected range of stresses and their distribution during actual drilling operations are estimated from data available, and the mechanism of failure of drill steel in the as-rolled and surface-treated conditions is analyzed. The magnitude of the surface compression stresses and their effect on ?fatigue strength are discussed.

Jan 1, 1958

By Nikzad Oraee, Parham Khajehpour, Kazam Oraee, Arash Goodarzi

"Rock fall related accidents continue to occur in coal mines, although artificial support mechanisms have been used extensively [1]. Roof stability is primarily determined in many underground mines by a limited number of methods that often resort to subjective criteria. It is argued in this paper that stability conditions of mine roof strata, as a key factor in coal mines, must be determined by a survey which proactively investigates fundamental aspects.Failure of rock around the opening happens as a result of both high rock stress conditions and the presence of structural discontinuities. The properties of such discontinuities affect the engineering behavior of rock masses causing wedges or blocks to fall from the roof or slide out of the walls [2]. A practical rule based approach to assess the risk of a roof fall is proposed in the paper. The method is based on the analysis of structural data and the geometry and stability of wedges in underground coal mines. In this regard, an accident causing a huge collapse in a coal mine leading to four fatalities is illustrated by way of a case study. A comprehensive investigation of the hanging wall has been gathered through a systematic collection of evidence. The investigation results are then analyzed, and an interpretation of the evidence gathered is provided.For this purpose, horizontal and vertical profiles are prepared by geophysical methods to define the falling zone and its boundaries. The collapse is then modeled by the use of sophisticated computer programs in order to identify the causes of the accident and hence recommend corrective actions to prevent or minimize reoccurrence probability of similar accidents. The corrective measures are placed into a rule-based framework for the benefit of the mine operators.INTRODUCTIONRoof rock failure has generally been the most dangerous hazard for underground coal mining in the world. Failure of rock around shallow coal mine openings often results from loosening of blocks of rock on the weakened planes under the influence of gravity. This condition is not typically seen in large deep coal mines. There are a number of differences between large mechanized mines and small mines related to ground control [3]."

Jan 1, 2015