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By E S. Souza, H Delboni Jr, M F. Calixto

This paper aims at presenting the results of laboratory, pilot plant and simulation studies for the design of the grinding circuit for the beneficiation of compact itabirites from the Conceitpo mine. Two alternatives were investigated, both utilising the current crushing circuit up to tertiary crushing. Under alternative #1, quaternary crushing was considered to produce the feed of the ball mill; under alternative #2, high pressure grinding rolls were selected to prepare the ball mill circuit feed. Pilot scale studies pointed towards the use of high pressure grinding rolls (HPGR). The circuit design was based on a throughput of 720 t/h, representing a nominal solids flow rate of 600 t/h, considering a design factor of 1.2, and P80 of 95 ¦m.

Jan 1, 2007

By L. Xu, R. Bhaskar

While a NIOSH accepted procedure exists for determination of quartz in the respirable dust samples from coal mines, no specific procedure has been defined for quartz determination in bulk samples. In this study, the effect of particle size on the estimation of quartz using the infrared technique was evaluated. Several laboratory tests were performed to determine the dependence of the infrared absorbance peak height on the different sizes of quartz particles. The significant dependence observed between quartz particle size and the measured peak height indicates the potential for erroneous interpretation of the quartz in bulk samples depending on how the samples are prepared. A procedure to reduce the effect of size in the determination of the quartz content is suggested.

Jan 1, 1994

By Marcela Gotelip Barbosa

Pellets are the main iron input to the blast furnace at ArcelorMittal Lazaro Cardenas iron and steel making facility in Mexico. Pellets are made at this facility using the concentrates generated and shipped from their captive mines viz., Las Truchas, Pena Colorada, Volcan Sonora. The concentrating plants, after grinding the ore to the liberation size, use magnetic separation and flotation to reject the silica, sulphur and phosphorous impurities. At Volcan Sonora Mines, the ore is contaminated with phosphorous minerals, and hence, after magnetic separation, the phosphate minerals are floated using anionic carboxylate collector (sodium oleate). Apart from floating the phosphate minerals, the sodium oleate also has some tendency to smear on the iron bearing mineral surfaces leaving a hydrophobic surface, which is expected to reduce the green pellet strength due to absorption of ultrafine sized air bubbles on these surfaces, and further generate higher levels of dust during the induration process. In order to alleviate this industrial problem, comparative studies were carried out on the concentrates from magnetic separation using reagents from synthetic sarcosinate and carboxylate family collectors. Results have indicated that the sarcosinate family members not only were found as replacement to carboxylate collectors, but also reduce the phosphorous content below the values achieved with oleate, thus have considerable benefits in the downstream steel making process. Based on the results, plant runs are being taken up at Volcan Sonora. In this article, the laboratory results obtained on iron grades and recoveries, and phosphorous rejection using both the reagents are presented.

Aug 1, 2018

By Ariti J

The mineralogy and extractive metallurgy of platinum and palladium in ores and residues is examined and the relative reactivity of Pt, Pd, PtS and PdS in cyanide and chloride media at 20¦C is discussed. Electrochemical measurements establish that Pd is readily leached in chloride media but more slowly in cyanide media due to a passivating PdO film. The passivating oxide film on Pt prevents leaching in either system at ambient temperatures. The results of leaching Au, Pd and Pt from an iron oxide residue obtained from the Sherritt Gordon Process using CN/air and Cl-/H202 are compared. It appears that passivation is overcome either by roasting at ?600¦ or by leaching at >_100¦C.

Jan 1, 1991

By R. N. Chakravorty

Early detection of spontaneous combustion is of utmost importance in underground coal mining to prevent major disruptions of production and to ensure a safer working environment. This paper presents the work done in developing a suitable system for the early detection of heating in a hydraulic coal mine. Laboratory studies on the products of oxidation for Balmer 10 seam coal showed that a significant amount of carbon monoxide is produced during the early stages of heating and that detection methods based on the analysis of other gases, such as hydrogen, ethane or ethylene, are not a better alternative for this coal. The four-point carbon monoxide monitoring system recently installed at the hydraulic mine is discussed in this paper. It is believed that by studying the trend of carbon monoxide concentration in the mine air, it will be possible to detect heating at an early stage. Field tests carried out so far have indicated that infra-red technology will prove to be a powerful tool in the hydraulic mine, particularly for locating hidden oxidation or fire in cracks, fissures, underground workings and coal outcrop areas before it spreads extensively. The project is jointly sponsored by EMR, CANMET, Mining Research Laboratories and Kaiser Resources Ltd.

Jan 1, 1978

By G E. Smith, G N. Lye

Wall control blasting practices are necessary to reduce the impact of blasting on mine faces but can also have a significant negative impact on mine productivity and operating costs. The conventional practice in deep open pit mines is to use so-called trim blasts adjacent to pit walls. To provide burden relief these trim blasts have fewer rows than full production blasts and are fired to a cleared free-face; hence they are termed æunchokedÆ. This practice leads to scheduling constraints on the pit operations and can cause ore dilution due to excessive muckpile movement. The use of such trim blasts stems from the perception that increased wall damage results from æchokedÆ blasts. These concerns are based on the unproven assumptions that blast vibration levels and explosive gas penetration increase with increased blast burden and face confinement. This paper describes work undertaken as part of a major investigation into wall control blasting at the KCGM Fimiston Mine, Kalgoorlie, Western Australia. It details a study to assess damage effects due to blast burden. Borehole air pressure measurements and borehole video camera inspections were done behind a series of single blastholes drilled with varying burden distances, as well as behind a dedicated trim blast and a full production blast. It was found that the measured damage effects, including visible rock cracking, dilation, and the limited extent of gas penetration behind the blastholes, did not vary significantly with burden or blast type for the cases tested. This result was in complete agreement with detailed vibration measurements conducted by Blair and Armstrong (2001) during the study, which found that vibration was independent of blast burden. As a result of these investigations, changes to the blasting practices at the mine were implemented. Dedicated trim blasts and free-face blasting have been replaced by modified production blasts and the practice of æchokingÆ blasts has been introduced. This has resulted in a significant improvement in productivity and cost savings without compromising pit wall integrity.

Jan 1, 2001

By T. C. Rao, D. D. Patil

The fishhook effect, wherein the recovery of fine particles in the underflow increases with decreasing particle size, has been observed in hydrocyclone classification. A systematic study was carried out to determine the factors affecting the recovery of very fine particles to the underflow. Attempts were made to identify factors, i.e., design and operating variables, that affect the size at which this phenomenon occurs. Experimental results show that the sizes at which the fishhook effect occurs is mainly a function of feed size distribution and solids concentration and is less dependent on the design variables.

Jan 1, 2002

By D. Hongjun

In this paper, the flotation rule and behaviors of kyanite-group polymerphous minerals were studied in modified Hallimond tube in detail. Furthermore, the energy change of collector/mineral systems before and after adsorption and the net charge densities of the atoms on the minerals surfaces were calculated by use of quantum chemistry. The flotabilities in minerals were successfully explained.

Jan 1, 1995

By Maurício L. Torem, Isabella A. Scorzelli

Taboca Mining is one of the largest producers of tin in the world. In its pilot plant, significant amounts of a middling of 90% xenotime (YPO4) and 10% zircon (ZrSi04) are produced. Until now, these minerals of this ore body could not be separated successfully. This paper presents some aspects of the fundamentals of xenotime and zircon flotation with anionic (fatty acids) and cationic (amine acetate) collector, as well as the influence of the superficial leaching of the minerals with cold HCI and HNO3 on the floatability. The mineralogical studies showed that both minerals are optically liberated in -212+106 µm size fraction. Surprisingly, SEM analysis indicated that both xenotime and zircon contain very small inclusions (1-5 µm) of thorite (ThSiO4). On the other hand, zircon is fairly metamictizated giving rise to malacon. Zeta potential tests showed that the isoelectric points of xenotime and zircon correspond to a pH value of 4.5 and 4.7, respectively.The pretreatment with HCI and HNO3 displaced the isoeletric point (IEP) of the minerals to the left. The microflotation tests indicated that the floatability of both untreated and treated minerals are quite similar in the presence of the collectors studied in this work. Adsorption mechanisms are also suggested.

Jan 1, 1995

By Hosking JW, Muir DM, Ruane M, Smith I. Hinchliffe WD

Maintaining carbon activity is critical to the satisfactory recovery of gold in the Carbon-in-Pulp (C.I.P.) process. Reduced activity can lead to gold losses in tails and lower tonnage throughput.Carbons from a number of W.A. C.I.P. circuits have been examined for the extent of fouling by inorganics such as calcium, magnesium, copper, nickel and silicon. Many of these carbons have exceedingly low activity leadingto low gold loading and excessive contact times. The relative importance of these fouling agents and cyanide levels on carbon activity is discussed. Mathematical modelling shows that relatively small improvements in kineticactivity lead to much lower tank volume require-ments and carbon residence times.

Jan 1, 1984

By Kyle J. H, Misra V. N

The most recent development in gold processing is the increasing use of heap leaching for the extraction of gold from low grade ore, and old tailings dumps. The reason for this trend is mainly to do with economics. The advantage of heap leaching is the considerable saving in both capital and operating costs. However, not all ores are amenable to heap leaching. It is only applicable to well oxidized ores that have suitable permeability char- acteristics, and the gold recovery is poorer than by conventional process. In this study, an attempt has ben made to ascertain the heap leaching characteristics of Western Australian gold ores on the bench scale using multiple, appropriately sized leach columns. The influence of particle size, flow rate, column depth and leaching time on the rate of gold extraction was determined. The percolation rate of cyanide leaching solution was deter- mined with and without gypsum additions. Efforts were also made to minimise particle segregation, fines migration and solution channelling during leaching, so as to improve solution percolation, gold extraction rate and recovery.

Jan 1, 1991

By Ting Ren, Jon Roberts, Zhongbei Li, Ming Qiao, Jianming Wu

Spontaneous heating of coal continues to present a health and safety hazard in underground coal mines. The influence of seam gas composition on gas flow dynamics and distribution characteristics in the active longwall goaf has not been studied in-depth, and corresponding effective proactive goaf inertization strategies for preventing potential spontaneous heating from occurring have limited investigation. To advance this knowledge, an 80-m-height goaf model was constructed and developed based on specific conditions of an Australian underground coal mine, and onsite gas monitoring data was collated to verify base model results, which allowed for various scenarios of seam gas composition to be simulated and investigated with confidence. This study involved modeling five different gas composition scenarios for the goaf atmosphere, namely, 100% CO2 (case 1), 80% CO2 and 20% CH4 (case 2), 50% CO2 and 50% CH4 (case 3), 20% CO2 and 80% CH4 (case 4), and 100% CH4 (case 5). Simulation results show that O2 is primarily distributed at the middle and upper part of the CO2- dominant goaf model, while it is mainly layered at the floor level of the CH4- dominant goaf model. N2 is superior to CO2 in the goaf inertization for the CO2- dominant goaf model, whereas CO2 performs better than N2 for the CH4- dominant goaf model. The optimal inert gas flowrates for case 1 to case 5 are 1.5, 1.75, 0.75, 0.5, and 1.0 m3/ s, and the oxidation zone area is reduced by 55.76%, 67.21%, 58.04%, 78.17%, and 81.82%, respectively. The simulation results allow for increased insight and understanding of the gas distribution patterns in the active goaf with different seam gas composition and the development of corresponding proactive goaf inertization practices, thus minimizing potential spontaneous-heating-related hazards and improving mining safety.

Sep 26, 2023

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By D. K. Bose, C. K. Gupta, K. U. Nair

A new approach to processing an indigenously available low made molysulfide concentrate by chlorination with elemental chlorine in presence of oxygen is reported. Recovery of nickel and copper values associated with the sulfide concentrate by suitably treating the residue obtained after chlorination is also reported.

Jan 3, 1978

By D. K. Bose, C. K. Gupta, K. U. Nair

A new approach to processing an indigenously available low grade molysulfide concentrate by chlorination with elemental chlorine in presence of oxygen is reported. Recovery of nickel and copper values associated with the sulfide concentrate by suitably treating the residue obtained after chlorination is also reported. In the chlorination process, a gaseous mixture of chlorine and oxygen in the volume ratio bf 2:5 has been passed at 1.66 x 10- 5 m3/s for 1800 s over a 0.01 kg batch of molysulfide concentrate at a temperature of 573°K. Most of the molybdenum has been volatilized as molybdenum oxychloride which has subsequently been extracted in water. The molybdenum value from the aqueous solution has been recovered in the form of calcium molybdate (CaO.MoO3) by treatment with calcium chloride (CaCI2). In an alternative processing scheme, the molybdenum rich solution has been treated with an oxidizing agent (K2S20f.J) and allowed to boil to recover a major portion of the molybdenum value in the form of molybdic oxide (MOOS). The spent charge obtained after molysulfide chlorination has been mixed with about 1 wt % sodium chloride and heated at 773K under an oxygen atmosphere. The reacted mass has been water-leached to yield a nickel-copper bearing solution with limited iron. The process liquor appears to be well suited for further processing by known hydrometallurgical recovery processes for nickel and copper. In the conventional process of molybdenum extraction, the molysulfide concentrate (-59% Mo) is first subjected to roasting to produce molybdic oxide. The oxide is then further processed in sequential steps involving vacuum distillation, ammonia leaching, and calcination to higher purity prior to hydrogen reduction to metal. In India there is at present some small tonnage production of molysulfide concentrate from a byproduct recovery plant of the M/s. Uranium Corp. of India Ltd. (M/s UCIL), Bihar. Efforts are being made at this laboratory to process the low grade fraction of the concentrate which contains sulfides of copper, nickel, and iron; quartz; and chlorites. Here, the conventional routes involving roasting and vacuum distillation appear unsuitable to produce an acceptable quality of molybdic oxide at high recoveries. Formation during roasting molybdates of some of the impurities present in the sulfide concentrate make subsequent vacuum distillation less efficient. In view of these problems, in earlier work reported from this laboratory the low grade concentrate has been processed hydrometallurgically to P. produce calcium molybdate. Starting from this molybdenum intermediate, processes have also been developed for the production of molybdenum and ferromolybdenum. Chlorination as an alternative to roasting for metal sulfides has been drawing considerable interest. The high reactivity of chlorine, the relatively low temperature of operation, the suitability of application to low grade resources, the convenience of recovering sulfur in non-polluting form, and the purity of chlorides which are separated by distillation all favor chlorination. In recent years, considerable work has been reported on the chlorination of common metal sulfides. In the field of molybdenum extraction from its sulfide resource, use of chlorination technology has been rather limited. Senderoff and Labrie3 were the first to chlorinate molysulfide concentrate with elemental chlorine at about 823°K to molybdenum pentachloride for use in the electrolytic preparation of molybdenum. The only other reported work, by Haver, Uchida and Wong, involved reaction between molysulfide and chlorine at 673°K to recover sulfur. The reaction products were, however, identified as molybdenum pentachloride and sulfur monochloride.

Jan 1, 1979

By Chan Min Yoo, Kiseong Hyeong, Inah Seo

INTRODUCTION One of the major concerns for deep seabed mining is its environmental impact, from the disturbance of benthic communities due to the mining activity to the disposal of mine tailings back to the ocean. Yet a significant amount of waste materials would be produced from the on-deck processing on the mining platform, all the materials that produced on the mining platform are to be shipped to the land unless the related regulation and guidelines are developed by IMO and ISA (ISA, 2018). Still, ecotoxicology data for the deep seabed minerals from case studies in deep-sea tailings disposal (DSTD) and submarine tailings disposal (STD) sites are lacking and all other related aspects are also largely unknown. This year, the Republic of Korea has started a research project for the more comprehensive understanding of chemical and physical properties of mine tailings from the on-deck processing and the possible environmental impacts on the marine organisms after its disposal. Based on the scientific data collected from this project, Korea would be able to make recommendations for the methods and technical standards for the deep seabed mining discharges. The subjects of this project are threefold: to understand the physical/chemical properties of the tailings, to model the dispersion of particulates after the disposal, and to assess its impact on the marine ecology. Laboratory Experiments Producing Mine Tailings First, the possible waste materials are produced by mimicking the collecting and dressing processes at sea. The polymetallic nodules (PN) would be mined by using a collector lifting the crushed nodules out of the bottom sediment, and the bottom water, accompanying sediment, and the fine nodule particles which are too small to be recovered would be discharged to the ocean and thus are considered as tailings (Schriever and Thiel, 2013). In the laboratory, PN is crushed into the fragments smaller than 2 cm, abraded in the water using the rock mill, and then sieved to obtain the fine particles to be disposed.

Jan 1, 2018

By Jie Li, Shu Yang, Zhongliang Tian, Xun Hu, Yanqing Lai

The purity of the electrolyte has an important influence on the content of the impurities in electrodeposited silicon. In this paper, effects of electrolysis temperature, current density and the time on the concentrations of two important impurities: phosphorus and iron in the electrolyte were investigated during the purification of Na3AlF6-10%K2SiF6-AlF3 melt. It was observed that the concentrations of P and Fe in the electrolyte decreased with the electrolysis temperature, current density and the electrolysis time increasing. X-ray fluorescence (XRF) of the electrolyte shows that the concentrations of P and Fe decrease from 4.2ppmw to 1.3ppmw and 204.0ppmw to 42.6ppmw, respectively. The removal rates of P and Fe are 69.08% and 79.12% when the electrolysis was performed for the duration of 3 hours and at a current density of 20mA·cm-2 while the operating temperature was 1225K.

Jan 1, 2015

By J. Sjöblom

New copper and nickel processes, flash converting and DON, direct high-grade nickel matte smelting, have been developed in order to replace the conventional and not so environmentally friendly PS-converting process. With a laboratory scale laminar-flow furnace the combustion reactions of sulfidic feed particles can be investigated under simulated flash smelting conditions. In the present study, finely ground and screened feed fractions of a copper matte and a nickel matte were flash oxidized in a laminar-flow furnace. The experiments were carried out using 20, 21 vol% and 75 vol% O2 in nitrogen, at temperatures 1100 and 1300 °C and reaction zone length of 7.5-16 cm. The samples were quenched in a water film after a specified reaction time. The matte particle reactions were stopped after short residence time intervals in order to obtain a better understanding of the reaction mechanisms. Chemical analysis was used to determine oxidation degree, and optical and scanning electron microscope combined with energy dispersive analysis was used for characterization of the reacted particles. On the basis of the experimental results the reactivity of the mattes is discussed and possible reaction and dust formation mechanisms are considered.

Jan 1, 1999

By L. Alagha, O. Molatlhegi, S. Khatibi

"In the present study, the effect of organic/inorganic (hybrid) polyacrylamide polymer on fine coal flotation was investigated. Raw coal samples contain about 37% of ash-forming mineral at a feed size of -75 + 38 um were subjected to flotation tests in the presence of in-house synthesized hybrid Al(OH)3-PAM at different polymer dosages and pH values. Results show a significant improvement in both combustible recovery and ash rejection at 1 ppm polymer dosage. Further improvement of combustible recovery was obtained when flotation was performed at pH 5. Interfacial properties of coal particles before and after flotation were examined through electrokinetic (zeta potential) measurements of coal/water slurries. Zeta potential vs. pH curve were established and compared. In the case of raw coal/water slurry, zeta potential-pH curve resembles the ash-forming minerals (silica and clays) more than coal. After Al(OH)3-PAM-assisted flotation, the zeta potential of froth/water slurry shifted to more positive values point which strongly indicates significant removal of ash-forming minerals from coal by Al(OH)3-PAM. INTRODUCTION Coal has been a major commodity in meeting the world energy demand during the past several decades (Milici et al., 2013). According to the international energy agency, global coal demand will continue to increase for the coming decades. With increasing world population, the global electricity demand would also increase as more people would get access to basic electricity especially in developing countries (Maggio & Cacciola, 2012). Due to this increase in energy consumption, operations in coal mining and beneficiation processes have been highly mechanized to meet the demands. This mechanization has increased the quantity of raw fine coal particles produced which contain high amount of ash-forming mineral matter (slimes). Aplan et al., have reported that the major constituents of ash-forming minerals in U.S.A coal are clay minerals such as kaolinite, montmorillonite and illite (Aplan, 1997). Conventional froth flotation for fine coal cleaning suffers mainly from two major problems: 1) Low recovery of ultrafine coal particles due to slime coating by ash-forming minerals, and 2) The lack of selectivity, which results in the flotation of middlings and entrainment of mineral fines in the froth (Polat et al., 2003). Slime coating on both valuable and air bubbles have been proposed to explain the observed reduction in flotation recovery especially when fine grinding is required. In this case mineral matter may be degraded to extremely fine or colloidal sizes thereby creating difficulty in the water clarification process such as flotation. Slimes inhibit bubble-particle attachment, and increases reagent consumption due to the increase in solid/liquid interfacial area, resulting in low coal recovery."

Jan 1, 2015