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By A. Dale Wunderlich

Introduction Loss prevention programs have become absolutely necessary at any precious metals producing property. In the past eight years, one security company, specializing in precious metals mine, mill, and refinery security, has been involved in investigations at gold and silver properties that have resulted in 62 criminal convictions. Of those, all but five were employees, former employees, contract employees, or vendors for the company. Several of the cases involved losses of more than $1 million. The largest number of employees prosecuted from one investigation was 17. A recent case resulted in 12 criminal prosecutions and, several years ago, one involved an additional 12 criminal prosecutions. The most serious theft problem facing precious metals mines is employee theft. Is is estimated that 95% of the dollar losses from precious metals thefts can be attributed to employees. This does not mean there is no robbery or burglary exposure. There have been successful robberies, burglaries, and extortion cases. Most mining companies, though, provide better protection against external theft than from internal theft. That is one reason employee theft has reached epidemic proportions. Any product can be stolen No product is immune to theft. Precious metals investigations have involved the theft of high grade ore, dore, bullion, concentrates, precipitates, loaded steel wool, loaded carbon, and sump cleanup. Over a period of several years, this author's security agency has documented the theft of more than 22.5 t (25 st) of load carbon. Most mining companies do not protect the number one adsorption tank or the loaded carbon screens, which frequently leads to losses. Precipitates, electrowinning tank sludge, sump material, and concentrates are usually afforded lit¬tle protection because mine management believes it is too difficult to process. There are custom mills throughout the United States that will process any form of precious metals with no questions asked. This has become a particular problem since the certificate of ownership requirement has been eliminated by most states. Due to the large number of gold mines coming on line, many mine managers are being recruited from base metal mines, where primary security problems involve the theft of tools and company property. These managers do not understand the unique security problems associated with precious metals production. Consequently, they usually forego many security needs in the interest of economy. Unfortunately, numerous cases are on file where mining companies have suffered large losses because their physical security and their security procedures were not adequately addressed when the property was in its planning stages. Properly designed and appropriate equipment The most economical time to plan alarm/closed-circuit televi-

Jan 4, 1988

By J. Geisler

When addressing Germany’s resource supplies, we need to distinguish between those domestically available and imported ones. Resource extraction ostensibly competes with the designation of protection areas. However, the parallel existence of wildlife and plant life, and operations in the areas used for resource extractions is continually underestimated. The European Commission has compiled guidance documents facilitating the extraction of resources from protected areas. With regard to resource productivity, the market appears to be the appropriate instrument for minimising resource consumption. Policy makers are now called upon to create a legal framework leading to a consensus accepted by society.

Jan 1, 2011

By Charles F. Herbert

In February of this year at the Washington, D.C., hearings of the Interior Department on the Alaska pipeline, the author was amazed to hear speaker after speaker oppose not only pipline construction but any development whatsoever in the State of Alaska. In one case, a man objected to development in Alaska because his neighbor in Maryland had cut down some shade trees. Another man recited at length from the poems of Robert W. Service. While it seemed inconceivable that such thoughtless opposition should have any effect, a check with the offices of some congressmen showed that mail was largely against any development of Alaska. In the barrage of words and redundant phrases directed against Alaska, it is difficult to find a thought worthy of study. Fortunately, there is a statutory guide towards resolution of the problem of development versus non- development. This law, the Environ- mental Protection Act of 1969, has indeed given much of industry the jitters; copper smelters see no way to comply with the new sulfur- emission standards, the Alaska Department of Highways estimates that the Act has nearly doubled the cost of planning and engineering for highway construction. In spite of these and many other troubles and costs, the Act provides a sound legal basis for defeating nihilistic emotions and, since Alaska is relatively undeveloped, adoption of environmental safeguards will be simpler than correcting longstanding abuses.

Jan 1, 1971

By E. M. Hillary, D. F. Sangster

"Abstract - As a contribution to the World Minerals Geoscience Database Project, an index-level database comprising information on 142 SEDEX Pb-Zn deposits and occurrences was constructed in Microsoft Access 95 format. Although consisting of only basic information, the compilation, with full referencing of all data, is possibly the largest non-corporate SEDEX Pb-Zn database in the world. It thus provides an opportunity to make geoscience queries of SEDEX Pb-Zn deposits on a scale not previously available. This report provides a summary of the results of a few such queries both as a contribution to a better understanding of SEDEX lead-zinc deposits and as a demonstration of what even such a simple database can offer.During the compilation process, it became apparent that SEDEX Pb-Zn deposits could be assigned to one of the following three sub-types: Type 1 (53.5% of total) in which sulfide minerals are the only exhalative components; Type 2 (33.1%) in which the exhalative components are sulfides plus chert, siderite/ankerite, and/or barite; Type 3 (13.4%) which contains any components of Types 1 and 2 plus abundant iron-oxide minerals (commonly magnetite) and/or is associated with iron oxide-rich sedimentary rocks.Highlights of systematic queries of the database reveal that:1. a majority (84%) of the world’s SEDEX Pb-Zn deposits are not underlain by a discordant footwall feeder zone or vent complex;2. 63.6% of deposits occur in Proterozoic strata followed by a second peak in the Devonian (16.8%). Of those in the Proterozoic, 83% of Type 3 deposits occur in the Gondwanaland supercontinent, whereas only 42% of Type 2 and 39% of Type 1 are located in this large paleo-landmass;3. median (Pb+Zn) grades in Types 1 and 2 fall between 9% and 10% with a majority clustering within this range. Type 3 grades, however, range from ~1% to ~20% (Pb+Zn) with a median of 5%; 4. median size of Type 3 deposits is ~33 Mt, whereas Type 1 and 2 median sizes are ~7 Mt and ~8 Mt, respectively.The report concludes with a brief discussion of how an index-level database such as this can be used in conjunction with other, similar databases to reveal interesting and instructive relationships for guiding both research and exploration."

Jan 1, 1998

By Ronald D. Hill, Elmore C. Grim

Sediment is one of America's greatest pollutants. More than a billion tons of sediment reach the major streams of the United States annually(l). Damages are reflected in the reduced carrying capacity of streams, clogged reservoirs, destroyed habitat for fish and other aquatic life, filled navigation channels, increased flood crests, degraded facilities for water-based recreation, increased industrial and domestic water treatment costs, premature aging of lakes by enrichment of the water with silt-carried fertilizer that promotes algae growth, destroy crops, and reduce productivity of flood plain soils. Erosion and sedimentation are natural processes that are usually gentle actions releasing controlled amounts of silt from watersheds to receiving streams. Surface mining activities accelerate these natural processes and short duration, high intensity storms can become a violent force moving thousands of tons of soil in a brief period of time. Cover is a very important factor. With the removal of ground cover, water moves across the denuded area on its own terms picking up soil particles as it flows and leaving gullies behind. The susceptibility of strip-mined land to erosion depends on: 1.Physical characteristics of the overburden 2. Degree of slope 3. Length of slope 4. Climate 5. Amount and rate of rainfall 6. Type and percent of vegetative ground cover. By development of erosion and sedimentation control plans before disturbance of the area, many of the detrimental effects of strip mining can be prevented.

Jan 1, 1974

By R. Hogg, P. Bunnaul

Sedimentation in highly, flocculated suspensions of fine particles, such as clays, occurs through individual settling units (flocs) that have very open structures and correspondingly low densities (typically less than 5% solids by volume). Such settling processes rapidly lead to the buildup of a bed of flocs that are essentially close-packed, with an inter-floc porosity of perhaps 50%. However, the overall solids content is no more than about 2% to 3% by volume. Consequently, the thickening process is dominated by the bed consolidation rather than by the simple settling of the individual flocs. Experimental measurements of sediment consolidation in flocculated clay suspensions indicate, for a given system, that consolidation rates are essentially determined by the solids concentration and can be evaluated using the classical Kynch treatment. However, these rates are strongly dependent on the physical, as well as the chemical, conditions of the flocculation process. Furthermore, the extent to which gravity consolidation proceeds depends on the total weight of the sediment (i.e., on the bed height and the solids concentration). The implications with respect to thickener operation and the requirements for the laboratory testing for thickener design are discussed.

Jan 1, 1993

By R. Hogg

Sedimentation in highly flocculated suspensions of fine particles such as clays occurs through individual settling units (flocs) which have very open structures and correspondingly low density -typically less than 5% solids by volume. It follows that such settling processes rapidly lead to the build-up of a bed of flocs which are essentially close-packed, with inter-floc porosity of perhaps 50%, but with an overall solids content of no more than about 2-3 percent by volume. An important consequence is that the thickening process is dominated by the consolidation of this bed rather than by simple settling of the individual flocs. Experimental measurements of sediment consolidation in flocculated clay suspensions indicate that for a given system, consolidation rates are essentially determined by solids concentration and can be evaluated using the classical Kynch treatment. However, these rates are strongly dependent on the physical as well as chemical conditions of the flocculation process. Furthermore the extent to which gravity consolidation proceeds depends on the total weight of sediment (i.e. on both height and solids concentration). The implications with respect to thickener operation and the requirements for laboratory testing for thickener design are discussed.

Jan 1, 1992

The chemical composition of the nodules varies with the type of manganese minerals and the size and characteristics of their nucleus, but those who have an economic interest have the following composition: Mn 29%, Fe 6% Si 5%, Al 3%, Ni 1.4%, Cu 1.3%, Co 0.25%, Na 1.5%, Ca 1.5%, Mg 0.5%, K 0.5%, Ti 0.2 0.2% and Ba 0.2% (Morgan, 2000; ISA, 2002). The Pacific Rim is an area of abundant occurrence of polymetallic nodules (Glasby et al., 1980; Morgan, 2000). According to these authors, the Pacific sea floor of the Clarion-Clipperton Zone (CCZ) is one of the most interesting areas in regard to the genesis of polymetallic nodules. Their abundance in the ocean floor is very variable, as there are places where they cover more than 70% of the ocean floor. The nodules can be found at any depth, but the highest concentrations are between 4000 and 6000m (Morgan et al., 1993). In studies conducted in the EEZ of the Mexican Pacific are those made within the project "Research on the origin, process and distribution of minerals in the Pacific ocean floor in the Exclusive Economic Zone of Mexico". Within this project Rosales (1989) conducted studies on the origin, process and distribution of polymetallic nodules, finding that a number of processes give origin to nodules, being diagenesis one of the main mechanisms of elements that contribute to the nodules. Besides hydrothermal processes that are carried near the East Pacific Rise at 21° N, inputs are contributing to the nodules metallic elements and sediments, especially in regions close to the dorsal, as a greater influence hydrogenetic processes occurs westward (Rosales and Carranza, 1990). In 1993, after cruise MIMAR II, Carranza and Rosales refer that metals such as Cu, Co, Ni, Sn, Fe, Mg, Pb, Zn and Ba may have a relationship with the East Pacific hydrothermal activity and sea currents carry these metals in solution to the Clarion-Clipperton fracture area, where there are hydrogenic metals sources (Al, Fe and Mn). As result of chemical analysis of Mn, Cu, Ni and Co, polymetallic nodules observed in part of the EEZ of Mexico are possible of potential economic interest (Rosales and Carranza, 1990, 2001; Carranza and Rosales, 2003).

Sep 14, 2011

The chemical composition of the nodules varies with the type of manganese minerals and the size and characteristics of their nucleus but those who have an economic interest have nucleus, generally : Mn> Fe> 6> Si> Al> Ba> Ni> Cu > Co. The Pacific Rim is an area of abundant occurrence of polymetallic nodules and the Pacific sea floor of the Clarion-Clipperton Zone (CCZ) is one of the most interesting areas in regard to the genesis of polymetallic nodules. Their abundance in the ocean floor is very variable, as there are places where they cover more than 70% of the ocean floor. The nodules can be found at any depth, but the highest concentrations are between 4000 and 6000. Hydrothermal processes that occurs near the East Pacific Rise at 21° N, may inputs metallic elements to nodules and to pelagic sediments, especially in regions close to the dorsal, as a greater influence hydrogenetic processes are present westward Metals such as Cu, Co, Ni, Sn, Fe, Mg, Pb, Zn and Ba show a relationship with the East Pacific hydrothermal activity and sea currents carry these metals in solution to the Clarion-Clipperton fracture area, where there are hydrogenic metals sources (Al, Fe and Mn).

Sep 14, 2011

The chemical composition of the nodules varies with the type of manganese minerals and the size and characteristics of their nucleus, but those who have an economic interest have the following composition: Mn 29%, Fe 6% Si 5%, Al 3%, Ni 1.4%, Cu 1.3%, Co 0.25%, Na 1.5%, Ca 1.5%, Mg 0.5%, K 0.5%, Ti 0.2 0.2% and Ba 0.2% (Morgan, 2000; ISA, 2002). The Pacific Rim is an area of abundant occurrence of polymetallic nodules (Glasby et al., 1980; Morgan, 2000). According to these authors, the Pacific sea floor of the Clarion-Clipperton Zone (CCZ) is one of the most interesting areas in regard to the genesis of polymetallic nodules. Their abundance in the ocean floor is very variable, as there are places where they cover more than 70% of the ocean floor. The nodules can be found at any depth, but the highest concentrations are between 4000 and 6000m (Morgan et al., 1993). In studies conducted in the EEZ of the Mexican Pacific are those made within the project "Research on the origin, process and distribution of minerals in the Pacific ocean floor in the Exclusive Economic Zone of Mexico". Within this project Rosales (1989) conducted studies on the origin, process and distribution of polymetallic nodules, finding that a number of processes give origin to nodules, being diagenesis one of the main mechanisms of elements that contribute to the nodules. Besides hydrothermal processes that are carried near the East Pacific Rise at 21° N, inputs are contributing to the nodules metallic elements and sediments, especially in regions close to the dorsal, as a greater influence hydrogenetic processes occurs westward (Rosales and Carranza, 1990). In 1993, after cruise MIMAR II, Carranza and Rosales refer that metals such as Cu, Co, Ni, Sn, Fe, Mg, Pb, Zn and Ba may have a relationship with the East Pacific hydrothermal activity and sea currents carry these metals in solution to the Clarion-Clipperton fracture area, where there are hydrogenic metals sources (Al, Fe and Mn).

Jan 1, 2011

By G. Wheeler

Epithermal gold exploration in the last decade has developed useful models for exploring new ore districts in Oregon. In Eastern Oregon, disseminated gold occurs in epithermal deposits that have been pervasively silicified and brecciated. Many gold prospects staked since 1980 are in fluvial and lacustrine sandstone and conglomerate deposits. Clay alteration products and disseminated pyrite may be present. Vein filling calcite and thin to thick quartz veins are common. Late stage quartz forms pseudomorphs after calcite in many deposits. Arsenic, mercury and gold are geochemically anomolous but silver is usually not. The epithermal deposits are located in part of the Deer Butte Formation or equivalent units. Exploration criteria include the presence of Deer Butte Formation or correlative units and NW structures cut by N-S basin and range structures.

Jan 1, 1987

By Brian D?Olier

Much of the aggregate that is being exploited at present from these areas is a ?relic? deposit. It was originally eroded from primary source rocks and transported to a depositional centre by processes that are now either greatly reduced in effectiveness or are largely absent at the present time. Following the retreat of the Devensian ice sheet, the subsequent rise of sealevel and the drowning of large areas of the continental shelf along with the lower reaches of many rivers, a fresh sequence of sediment sources, pathways and sinks now exist. Sediment is being eroded from several, pre-existing source areas and transported along different, well - defined pathways to a number of new depositional sinks. Some of the present, licenced, aggregate dredging areas lie close to these sources, pathways and sinks with the consequent dredging activity being perceived by some as interfering with the ?natural process? that links the offshore and the coastal / littoral zones. With this perception in mind, the principal, sources, pathways and sinks between Flamborough Head and Beachy Head will be highlighted and the relationship of dredging activity upon them, evaluated. It will be demonstrated that offshore dredging activity has no effect upon supplies of sediment to coastal beaches.

Jan 1, 2004

By C. J. R. Braithwaite, Giancarlo Rizzi

"Abstract-The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. The Stackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grainstone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is confined to the Meath Formation. The linear dolomite body, trending NE-SW, has a flattened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing fluids initially rose vertically, cross-cutting stratigraphic and sedimentological boundaries, although fluid flow was subsequently controlled by these features. Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL), oxygen isotopes, and fluid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and fluid inclusion data suggest growth of successive stages from waters which became progressively hotter (60°-160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages 1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage 3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore field may point toward unrecognized zinc-lead prospects."

Jan 1, 1997

By C. J. R. Braithwaite, Giancarlo Rizzi

"The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. TheStackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grain-stone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is con?ned to the Meath Formation. The linear dolomite body,trending NE-SW, has a ?attened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing ?uids initially rose vertically, cross-cutting stratigraphic and sedimentological bound-aries, although ?uid ?ow was subsequently controlled by these features.Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL),oxygen isotopes, and ?uid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and ?uid inclusion data suggest growth of successive stages from waters which became progressively hotter(60°–160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore ?eld may point toward unrecognized zinc-lead prospects."

Jan 1, 1997

By J. T. Pardee

INTRODUCTION PLACER is a Spanish word, the definitions of which include "an extensive bank of sand or gravel" and "a place where currents of water deposit particles of gold."l The term, probably first used in the western hemisphere by Spanish or Mexican gold miners, is now generally applied to all detrital deposits that yield valuable minerals by washing. In the Western States placer products other than gold, including the silver alloyed with it, are chiefly sapphires, produced in Montana, and platinum alloys recovered in California and Oregon. During the war tungsten ore (scheelite) was obtained from placers in the Atolia district, California, and a number of diamonds have been found in the Sierra Nevada gold belt. Small amounts of stream tin have been produced in the Black Hills of South Dakota and a little monazite sand in the Boise Basin. Idaho. Magnetite, chromite, ilmenite, zircon, and other useful minerals are more or less abundant in the beach placers of the Pacific coast and in the heavy residues of placer mining elsewhere, but the problems of profitably separating and marketing them remain to be solved. Minerals of lead, quicksilver and other metals occur in many of the placers and although not plentiful enough as a rule to be worth recover-ng, their presence has, in several instances, led to the discovery of valuable lodes, notably at Leadville, Colorado. Historical summary.-In New Mesico, Arizona, and Southern California, placer gold was mined by Mexicans and Spanish priests in the first half of the 19th century or earlier. With these exceptions history of placer mining in the Western States begins with Marshall's discovery of gold in northern California in 1848. During the next twenty years placers were found in all of the principal mining districts that are known today. The richer deposits were soon mined out but a relatively large production was maintained from the leaner deposits chiefly by hydraulic

Jan 1, 1933

By R. C. Carne, R. J. Cathro

"Most of the recent large discoveries of zinc, lead and silver in Western Canada are Paleozoic-aged stratiform deposits that occur within the limits of the tectonic sub-province of the Canadian Cordillera known as Selwyn Basin. Bounded on either side by coeval carbonate platforms. Selwyn Basin trends northwest for 1300 km from northeast British Columbia to Alaska. Paleozoic rocks of Selwyn Basin consist primarily of chert, shale and coarser-grained clastic sedimentary rocks with minor volcanic rocks.The Selwyn Basin deposits have few counterparts elsewhere in Canada, but have a close similarity in geological setting, mineralogy and morphology to well-known deposits such as McArthur (HYC) in Australia, Meggen and Rammelsberg in West Germany, and Sullivan in British Columbia. Recent studies of these deposits have led to an emerging, but now generally accepted, model of ore deposition in which stratabound zinc-lead-silver shale-hosted or ""sedimentary-exhalative"" (sedex) deposits are precipitated in active tectonic environments from metalliferous geothermal brines that rise to the sea floor along deep-seated fault zones. Although their mineralogy and ore metal zoning can be similar to that of volcanogenic massive sulphide deposits, most sedex deposits have only a weak genetic link with volcanism.Sedex mineralization in Selwyn Basin has been identified within three separate ages of shale or its metamorphosed equivalent. The lower Cambrian-age Anvil Camp in central Yukon Territory contains the only producing mine (Faro). Important lower Silurian-age zinc-lead mineralization is at Howards Pass along the Yukon - Northwest Territories border. Barite and zinc-lead-barite mineralization of upper Devonian age occurs across Selwyn Basin. Potentially economic deposits have been found at Macmillan Pass, along the Yukon - Northwest Territories border and in the Gataga District of northeastern British Columbia."

Jan 1, 1982

By Robert L. Bates

The natural separation of one element or compound from others in the earth's crust is a rare geological phenomenon; accumulation of large quantities of a separated substance forms mineral deposits of value. Although igneous and metamorphic processes are effective at times, by far the most significant fractionation is sedimentary. High-silica sandstone, high-purity limestone and dolomite, salt, and anhydrite-gypsum occur in very large deposits and are termed first-order fractionates. The marine diatomite of California, the trona of Wyoming, and the kaolin of Georgia and South Carolina are in deposits of comparable purity but smaller size, and are designated second-order fractionates. The paper considers the various processes and environments in which such industrially valuable deposits were formed.

Jan 1, 1972

By John Finch

IN AUGUST, 1927, the writer examined certain copper deposits in New Mexico, which occur in beds of sandstones and shale, and in connection therewith reviewed the literature upon deposits of this type. Such deposits are known and have been reported upon at various points in Texas, Oklahoma, Arizona, Colorado, Wyoming and Utah, but in New Mexico they have been given more development than elsewhere and apparently occur there more conspicuously than in the other states. Some 25 years ago the writer examined deposits of similar origin in northern Arizona and more recently other deposits in western and southwestern Colorado, and these examinations have led him to realize how widely scattered are the deposits and how generally non-commercial they are. On superficial development, to one without a comprehension of their geologic nature, they are alluring on account of occasional small amounts of high-grade ore and much misplaced capital has been expended upon them. This paper, therefore, aims to present briefly certain theories of genesis, some details of which may possibly be new, and to lead up to practical conclusions which may be useful to other geologists and engineers. A bibliography of the more important literature upon such deposits is given below.2 Coffin's Bulletin upon the Radium, Uranium and Vanadium Deposits of Colorado, published in 1921, is a particularly clear discussion. The most comprehensive recent statement is Butler's. He describes a large number of occurrences in Utah and connects them up genetically with deposits in other states.

Jan 1, 1928

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Grégoire

Abstract -A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (2:3 cm thick), which seems to have been developed over the entire sedimentary basin of >80 km2, consists of pyrite, vaesite (NiSi), and sphalerite. The average grade of the mineralization is about 5.3% Ni, 0.73% Zn, ?770 ppb (PGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE +Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrient­ rich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic­ matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained S04 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich 1arninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesite­ pyrite assemblage crystallized at approximately 138°C. The ?34:S values range from -14.7 o/oo to-10.0 o/oo and are up to 34 o/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The ?13:C values of calcite in the footwall of the mineralized unit ( -12 o/00 to -6 o/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Gregoire

A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (=3 cm thick), which seems to have been developed over the entire sedimentary basin of > 80 km2, consists of pyrite, vaesite (NiSz), and sphalerite. The average grade of the mineralization is about 5.30/0 Ni, 0.73% Zn, =770 ppb (pGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE + Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrientrich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained 804 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich larninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesitepyrite assemblage crystallized at approximately 138°C. The 034S values range from -14.7 0/00 to -10.00/00 and are up to 340/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The Ol3C values of calcite in the footwall of the mineralized unit (- 12 0/00 to -6 0/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992