Search Documents

By Robert W. Freedman

Vacutainers are employed by the Bureau of Mines and the Mining Enforcement and Safety Administration for sampling mine air and other atmospheres containing fixed gases, low-molecular-weight hydrocarbons, and products of combustion. Tests were conducted to study shelf life of evacuated samplers prior to sampling and also to check the stability of sampled gases prior to analysis. An unexplained phenomenon, slow accumulation of carbon monoxide in evacuated samplers, occurred after a few weeks' storage; levels were low but increased with time and could pose a problem for critical applications. Accordingly, attempts to halt CO release by additional means of treatment were made, and storage at low temperature was found to be effective.

Jan 1, 1978

By D. E. Traut

A fluidized, countercurrent ion-exchange system was developed, operated, and evaluated by the Bureau of Mines in support of its objective to help assure an adequate uranium supply for future national needs. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows are continuous, except for short periods when resin increments are withdrawn. The exchange of uranyl sulfate between a simulated acid-leach-uranium solution and a strong-base, ion-exchange resin was studied, together with subsequent elution using an acidified sodium chloride solution. The effects of the number of compartments, compartment height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. Also examined were the kinetic and equilibrium relationships for the absorption and elution steps. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The columns system was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By Welby G. Courtney

The Bureau of Mines conducted a field test program in the Pittsburgh coal seam to investigate the effect of water sprays in the suppression of respirable dust being formed while cutting with a continuous-mining machine. Emphasis was given to the location of spray nozzles on the top and bottom of the cutting boom. Results showed that (1) sumping caused about 60 percent of the dust escaping the face area, and shearing and loading caused the other 40 percent; (2) during sumping, top and bottom sprays were equally effective in dust suppression and reduced dust ~13 percent; (3) during shearing and loading, bottom sprays reduced dust 61 percent and were about 50 percent more effective than top sprays; (4) the combination of top and bottom sprays was slightly more effective than the separate systems, but water consumption increased 60 percent; and (5) inclusion of throat sprays decreased dust reduction by removing some of the water from top and bottom sprays where it was more effective.

Jan 1, 1978

By D. L. Paulson

Electric furnace smelting of blister copper directly from copper precipitates (cement copper) was investigated by the Federal Bureau of Mines. Copper concentrations in five different lots of cement copper in the investigation ranged from 62.5 to 82.5 wt-pct. Laboratory-scale smelting tests were made in a 50-kva electric-arc furnace to establish the reductant and flux requirements. Best recoveries were realized by adding 60 pct of the carbon required to combine with the contained oxygen in the cement copper. Operating parameters established during the laboratory-scale smelting tests were used successfully in smelting 20 tons of cement copper during 12 pilot-scale tests in an 800-kva electric-arc furnace. Over 98 pct of the contained copper was recovered as blister-grade metal. The projected energy consumption for a commercial-size furnace was 380 kwhr per ton of cold charge.

Jan 1, 1978

By B. T. Brady

Recent theoretical, experimental, and field studies conducted by the Bureau of Mines suggest that rock failures may be predicted and, in some instances, controlled. Theoretical studies that were later corroborated by laboratory and field studies predict that a seismic anomaly will precede rock bursts and/or roof falls in mines. The seismic anomaly is predicted to consist of an increase in the number of seismic events occurring in the immediate vicinity where the failure 1s nucleated. This increase will then be followed by a dramatic decrease of seismicity in a broad region that surrounds the location of the impending failure. The dimensions of this region allow a preliminary estimate of the time to failure (measured from the time the seismicity increase began) as well as an estimate of the energy that will be released at the instant of failure. Field observations indicating that this predicted behavior does precede rock bursts and a roof fall are presented in this report. Implications of results to the problem of failure control in mines that experience massive rock failures are discussed.

Jan 1, 1978

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By Donald I. Kurth

This Bureau of Mines report describes the development and application of a computer model of aquifer hydrology associated with in situ leaching of uranium. The model provides uranium resource developers with a simulation of leachant flow characteristics in a preproduction or pilot five-spot leaching operation. Various types of aquifers are modeled using closed form solutions of the partial differential equations describing the change in fluid head (pressure) as the leaching operation is carried out. User-supplied descriptive input consists of aquifer, well, and leachant flow characteristics. Numeric and graphic outputs such as isopressure, iso-velocity, and isotime contours are available. A typical application is shown.

Jan 1, 1978

By D. Montagna

This Bureau of Mines report describes a salt-free, fluxless method for reclaiming metallic aluminum from aluminum dross. The dross is smelted under argon, nitrogen, or carbon dioxide, instead of a salt flux, in an externally heated pot furnace. Aluminum recovery, using argon, is equal to recoveries reported from commercial smelters that process dross in rotary-type furnaces This salt-free method could offer a reduction in air pollution, lower energy requirements by elimination of salts, and the production of up to 60 percent less solid waste for disposal than the salt method.

Jan 1, 1978

By E. F. Divers

This Bureau of Mines report describes the results of a program to develop small, rugged mechanical dust collectors (scrubbers) with high dust collection efficiency and low energy comsumption for controlling dust in coal mining operations. All of the scrubbers described are similar in configuration and are powered by 6-hp, 2,000-ft3/min vane axial fans. Air pressure differential is less than 6 inches water column. Height of the scrubbers? including fan is less than 14 inches, width is less than 16 inches, and length is less than 45 inches. The flooded fibrous-bed scrubber achieved respirable (less than approximatey 7 µm) dust collection efficiencies of 95 percent. The small-diameter-cyclone scrubbers showed about 92 percent efficiency and can be best where excess water is a problem. The wetted brush scrubber showed 88 percent efficiency at low cost, and the wetted fan scrubber showed a slightly lower efficiency (87 percent) but offered the smallest size and cost. A suitable water droplet eliminator is described.

Jan 1, 1978

By B. J. Scheiner

A ferrous chloride-oxygen leaching system was investigated by the Federal Bureau of Mines to determine its effectiveness for recovering copper and silver from a tetrahedrite concentrate that had been pretreated to remove a majority of the antimony. The pretreated concentrate contained coppers, silver, lead, zinc, antimony, and arsenic. Parameters affecting metal extraction (such as temperature, pressure, amount of ferrous chloride, and initial hydro-gen ion concentration) were studied. Copper extraction of 98 pct was achieved by leaching 4 hours at 40 pounds per square inch gage (psig) and 100° C. Copper was recovered from leach solutions by cementation with iron, and the resulting ferrous chloride was recycled. Leaching the residue with cyanide followed by electrowinning recovered 99.7 pct of the silver. Iron, antimony, arsenic, and sulfur reported to the tailings.

Jan 1, 1978

By Raymond M. Stateham

Climatic conditions are compared with roof fall occurrence from April 1, 1972, to December 31, 1975, by the Bureau of Mines. These comparisons indicate that humidity has a strong influence on roof fall occurrence rates. Cubic regression techniques are used to develop best fit curves. Statistical analysis of these curves indicate that both are sinusoidal and exhibit positive correlation with each other. The sine waves have a period of 1 year with maximum and minimum inflection points in August and February.

Jan 1, 1978

By H. W. Kilau

The Bureau of Mines used a high-temperature rotational viscometer to test basic oxygen furnace slags to determine fluorspar requirements and to evaluate colemanite and fused boric acid as substitute fluidizers. A continuous technique of viscosity measurement was adapted to better determine the viscosity-temperature profiles of volatile fluorspar slags. Criteria used for estimating slag fluidizer effectiveness were (1) the apparent solidification temperature, and (2) the temperature range of slag crystallization. Colemanite and fused boric acid in high-basicity slag were superior fluidizers to fluorspar when compared on the basis of boron versus fluorine concentration. Fused boric acid was nearly equivalent to ceramic-grade fluorspar when compared on a simple weight basis, while colemanite was inferior to fluorspar. Fluorspar slags volatilized fluorine during viscosity testing. Colemanite and fused boric acid slags were stable, no boron losses being detected. A fluidizing limit was found for fluorspar at 2.9 percent fluorine concentration; higher concentrations impaired viscosity and caused foaming and crusting of slag. Concentrations of boron up to 4.4 percent resulted in very fluid slags with no fluidizing limit.

Jan 1, 1978

By Benjamin W. Haynes

This research was conducted as part of the U.S. Department of the Interior, Bureau of Mines program to recover metals, glass, and a combustible fraction from municipal solid waste (MSW). The objective of this analytical study was to determine the concentration of antimony, arsenic, and mercury in samples taken from various sampling areas in the Bureau of Mines raw refuse recycling plant and to compare these values with those for coals used in the generation of electricity. To provide the necessary analytical data, sensitive reproducible ashing-chemical digestion-atomic absorption procedures were adapted from published procedures. It was determined that antimony and mercury concentrations in the combustible fraction of MSW are approximately an order of magnitude higher than those found in coals presently used for power generation;' the arsenic concentration is similar in both fuels.

Jan 1, 1978

By I. Liebman

The Bureau of Mines conducted research to develop triggered barrier systems for protection against gas explosions that can occur in underground coal mines during the use of continuous miners. Several extinguishing agents were tested in barriers at a simulated mine face. Water, powered by pressurized nitrogen, was found to be efficient in stopping fully developed gas explosions, but it had little effect against the explosion during its incipient stage. Hybrid combinations of currently known extinguishants, however, were successful against incipient explosions. Three hybrids that were developed and tested consisted of Halon 1301, combined with either an aqueous foam solution, water, or a dry chemical powder. The three hybrids were found to be more efficient than any constituent alone. Results of the tests point to a synergism between the hybrid components, and indicate that the Halon aids in dispersing its constituent and also converts the aqueous foam solution into a stable fine foam and the water into fine drops.

Jan 1, 1978

By Stephen W. Lambert, Michael A. Trevits

The Bureau of Mines examined the wellbore of a vertical gas drainage well in the Mary Lee coalbed to determine the results of specific completion procedures in coal. A jet-slotting tool was used to cut four vertical slots through the casing about 1 ft below the coalbed. Even though stimulation treatment pressure was excessive, hydraulically induced channels were contained entirely within the target coal zone. Sand-filled, induced channels were horizontal, inclined, and vertical, and were propagated in directions similar to bedding planes, rock joint, and coal cleat directions measured in the mine. Variable gas flow rates, recorded during the productive life of the well, were attributed to chronic downhole pump malfunction and the slotted casing below the production zone.

Jan 1, 1978

By Stephen W. Lambert

The Bureau of Mines examined the wellbore of a vertical gas drainage well in the Mary Lee coalbed to determine the results of specific completion procedures in coal. A jet-slotting tool was used to cut four vertical slots through the casing about 1 ft below the coalbed. Even though stimulation treatment pressure was excessive, hydraulically induced channels were contained entirely within the target coal zone. Sand-filled, induced channels were horizontal, inclined, and vertical, and were propagated in directions similar to bedding planes, rock joint, and coal cleat directions measured in the mine. Variable gas flow rates, recorded during the productive life of the well, were attributed to chronic downhole pump malfunction and the slotted casing below the production zone.

Jan 1, 1978

By V. R. Miller

The Bureau of Mines developed and evaluated a detecting and sorting device to separate the copper-bearing portion from the barren portion of Michigan native copper ore in the minus 4- plus 1-inch size range. Small-scale sorting tests were also conducted on minus 1- plus 1/2-inch material from the Centennial No. 6 mine, using a previously developed system that was modified to increase sensitivity. Results showed that, with the added sensitivity, 85 to 90 pct of the copper in the minus 1- plus 1/2-inch material could be recovered in about 50 to 60 pct of the fraction. Sorting tests on minus 4- plus 2-inch and minus 2- plus 1-inch fractions from the Centennial mine were conducted with the large sorting system. Results showed that 86 to 93 pct of the copper was recovered in 43 to 64 wt-pct of the sorted fractions. Combining of concentrates from the two fractions resulted in a recovery of 90 pct of the Popper in 55 pct of the weight. The composite concentrate contained 2.40 pct copper, and the tailing analyzed 0.33 pct Cu; the head sample assayed 1.46 pct Cu.

Jan 1, 1978

By Frank G. Horino

Drill cores from 18 exploratory holes that were drilled into the unleached saline beds were tested for mechanical properties by the Bureau of Mines. Test cores were primarily selected from zones L4B, R4B, L3, and R3A in the Piceance Creek Basin, Rio Blanco County, Colo. Regression analysis techniques were tried in an attempt to relate kerogen yield or apparent specific gravity to the parameters compressive strength, Young's modulus, and Poisson's ratio. Correlation coefficients were very poor, indicating that this type of analysis was not amenable to these data. Analysis of variance techniques were tried using a division of either greater than or less than 10% nahcolite together with the requirement of less than 3% dawsonite. Results showed that a larger percentage of nahcolite tended to lower the compressive strength and to increase Young's modulus. A second analysis was made using a division of less than 3% dawsonite and greater than 3% dawsonite together with the requirement of less than 1% nahcolite. For this analysis, a larger per-centage of dawsonite tended to increase compressive strength, Young's modulus, and Poisson's ratio. Mean compressive strength values were determined for the mining horizons of interest. Average physical properties for design purposes were also determined for the horizons of interest and for a proposed adit based only on logged geologic depths to these horizons. No consideration was given to percentages of nahcolite and dawsonite. Creep data obtained from nahcolite-and dawsonite-rich oil shales provides a best fit to a modified power equation.

Jan 1, 1978

By Daryl E. Radcliffe

The Bureau of Mines studied the displacement of the roof in a portion of the Bear coal mine near Somerset, Colo, Horizontal-and vertical-displacement gages were installed in a five-entry section during normal room-and-pillar mining procedures. Monitoring of the roof continued until this section was mined out. Displacement measurements in combination with known time lapses between mining and bolting operations indicate that once support is achieved, the length of unsupported time does not appear to affect long-term roof stability in the mine under investigation.

Jan 1, 1978