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By J. M. Davidson

The potassium mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H20) found in large deposits in western Texas and southeastern New Mexico is associated with varying amounts of halite (sodium chloride, NaCl) and anhydrite (calcium sulphate, CaSO4). Although the anhydrite, because of its low solubility and slow rate of solution, is relatively inert, the halite is dissolved immediately in any process solution with which the polyhalite comes in contact. Limited quantities of sodium chloride in the liquors used for the hot extraction of polyhalite materially improve the results obtained,4 but only a very small sodium chloride content may be desired in the entering polyhalite in other procedures, such as Bureau of Mines process 75. In. all of the processes suggested for the recovery of potassium sulphate from polyhalite the control of the sodium chloride content will be desirable, if not absolutely essential to efficient operation. OCCURRENCE OF HALITE IN POLYHALITE A preliminary estimate of the amount of halite associated with typical deposits of polyhalite may be derived from drill cores, although it should be remembered that only 50 or 60 core tests have been made in the many hundreds of square miles of the Permian basin. From a mineralogical study of 41 of these cores, Schaller and Henderson6 state: In many of the sections of core that seem when viewed by the unaided eye to consist essentially of polyhalite, both halite and anhydrite are present in greatly varying quantities - with very minor quantities of clay and magnesite.

Jan 1, 1934

By J. M. Davidson

The potassium mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H2O) found in large deposits in western Texas and southeastern New Mexico is associated with varying amounts of halite (sodium, chloride, NaCl) and anhydrite (calcium sulphate, CaSO4). Although the anhydrite, because of its low solubility and slow rate of solution, is relatively inert, the halite is dissolved immediately in any process solution with which the polyhalite comes in contact. Limited quantities of sodium chloride in the liquors used for the hot extraction of polyhalite materially improve the results obtained, but only a very small sodium chloride content may be desired in the entering polyhalite in other procedures, such as Bureau of Mines process. In all of the processes suggested for the recovery-of potassium sulphate from polyhalite the control of the sodium chloride content will be desirable, if not absolutely essential to efficient operation.

Jan 1, 1934

By Sam S. Taylor

In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas produced with the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production must be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a as supply is not available, often air is used. Although air is a cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, sortie fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case. The Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla., has been interested in problems connected with air-repressuring for a number of years. Some time was spent in studying the so-called "bad gas"--return mixture of low fuel value. However, it appeared impossible to attack the problem successfully from this angle, and an approach was made through a laboratory-scale study of direct oxidation of crude oil.

Jan 1, 1934

By Sam S. Taylor, H. M. Smith

"INTRODUCTION In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas Produced with the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production must be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used.Although P.ir is a Cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case. The Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla., has been interested in problems connected with air-repressuring for a number of years. Some time was spent in studying the so-called ""bad gas""--return,mixture of low fuel value. However, it appeared impossible to attack the problem successfully from this angle, and an approach was made through a laboratory--scale study of direct oxidation of crude oil."

May 1, 1934

By Sam S. Taylor

In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas produced With the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production nest be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used. Although air is a cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case.

Jan 1, 1934

By W. H. Coghill

Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with so many "inflection points" and "counterflexures" that they obscure the issue. Some of the investigators have neglected the very essence of the problem, namely the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration. Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.

Jan 1, 1934

By W. H. Goghill

Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with so many "inflection points" and "counterflexures" that they obscure the issue. Some of the investigators have neglected the very essence of the problem, namely the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration. Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.

Jan 1, 1934

By W. H. Coghill, F. D. DeVaney

"Introduction Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with no many ""inflection points"" and ""counterflexures"" that they obscure the issue.Some of the investigators have neglected the very essence of the problem, namely, the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration.Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.Grindability Characteristics When the ores are being studied the information sought is grindability characteristics (grain-size distribution) and the grindability (work required to produce new surface) of a group of ores.When the study is of the machines, several machines are used for a given ore or given types of ores, and the grinding performances of the machines are compared by a grain-size study.Table 1 gives the grindability characteristics and grindability of six substances, one of which is coal. The substances are arranged from left to right in progressing order of tons per horsepower-hour. Curves and graphs are not needed for elucidation. The secret of the ease of interpretation is the order mentioned and the similarity of the sizing analyses. Power records must be complete in grinding studies.The grinding device was a ball, plunger, and mortar called the drop weight.' It may be used to advantage when the amount of material to be tested is too small for the orthodox machines.The upper part of table 1 shows the grindability characteristics by the cumulative-sizing analyses. Note how closely the percentage weights agree for a given sieve size. The lower part shows the grindability in terms defined elsewhere. The present paper should be read in conjunction with that paper."

Jun 1, 1934

By T. L. Joseph

"IntroductionThe efficiency of ore reduction in the blast furnace and fuel requirements depend upon the degree of uniformity with which reducing gases can be distributed through the stock column and upon the permeability of individual pieces of ore and sinter. If the ore is fine, the major problem in reduction is to get the ascending gas stream to the surface of the ore-Hard, dense ores of low permeability, mined in coarse sizes, tend to improve the permeability of the bed, but unless they are crushed to the proper size they reach the hearth unreduced.Surveys by the Bureau of Mines have shown conclusively that the gas distribution in the upper three fourths of the furnace is far from ideal. Furnace lines, top design, and methods of charging are important, but more thorough size preparation of the ore is necessary to eliminate size segregation at the stock line, which inevitably leads to non-uniformities in gas distribution.Because of the quantity of sinter now produced close study of the characteristics which determine its behavior in smelting is warranted. As the use of concentrates increases agglomeration will become more of a necessity. Improvements in the physical character of the ore burden are particularly important to plants using coke of poor physical quality. In addition to aiding reduction, improved physical properties of the ore burden will permit the use of higher blast heats, which is equally important.Reduction Tests on Fine Sizes of SinterPrevious reduction tests on minus 0.742— plus 0.525--inch pieces of commercial sinters revealed large differences in porosity and reducibility. The results have been published in a former report. 3 Although the physical properties of the sinter, particularly porosity, were found to be of major importance in determining the rate of deoxidization, it appeared that certain chemical properties of the sinter appreciably retarded the reduction of sinters high in silica. This was attributed to the presence of fayalite, which has been identified by Schwartz and by Luyken and Kraeber4 as an important constituent of sinter. Although furnace operators and metallurgists have assumed that iron silicate is more difficult to reduce than hematite or magnetite, definite data on the reduction characteristics of this material were not available. Tests were undertaken, therefore, to develop a method for de-termining the amount of iron silicate present in sinters so that its effect upon reduction could be observed."

Jun 1, 1934

By T. W. Johnson

The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past several years the flow of natural gas through high-pressure pipe lines. This report deals with that part of the study involving the design off pipe-line systems consisting of lines laid parallel to each other. The lines are referred to as the original line and the parallel line. The paralleling line may or may not extend the entire length of the original line; however, the parallel line is connected at its two ends to the original line. As a result of the large expansion of the natural-gas industry almost all markets within economic distance from the developed gas fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future

Jan 1, 1934

By W. B. Berwald, T. W. Johnson

"The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past several years the flow of natural as through high-pressure pipe lines. 4 This report deals with that part of the study involving the design of pipe-line systems consisting of lines laid parallel to each other. The lines are referred to as the original line and the parallel line. The paralleling lire may or may not extend the entire length &f the original line; however, the parallel line is connected at its two ends to the original line.As a result of the large expansion of the natural-gas industry almost all markets within economic distance, from the developed as fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural-gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future expansion in the natural—gas industry will consist of paralleling the present lines. The several formulas given in this report have been developed to aid in the design of such systems. Curves and tables were prepared from these formulas to simplify the calculations materially and to facilitate determination of the sizes of pine to be used in paralleling various diameter lines to give the most economical design. The formulas are presented without detailed derivations, as a complete report on the flow of natural gas through pipe lines is being prepared which will contain the derivations of these formulas. Examples included here show the detail of application of the several formulas to problems of design of parallel lines."

Jun 1, 1934

By T. W. Johnson

The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past-several years the flow of natural bas through high--pressure pipe lines.4 This report deals with that part of the study involving the design of pipe-line, systems consisting of lines laid parallel to each other. The lines are deferred to as the original line and the parallel line. The paralleling line may or may not extend the entire length of the original line; however, the parallel line is, connected at its two ends to the original line. As a result of the large expansion of the natural-gas industry almost all markets within economic distance from the developed gas fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future

Jan 1, 1934

By G. L. Oldright, Virgil Miller

"INTRODUCTION The first ten papers of the series on smelting in the lead blast furnace described the operation at the custom smelter of the International Smelting Co., Tooele, Utah, and at the plant of the Bunker Hill Smelting Co., Kellogg, Idaho, which handled a very rich lead concentrate. These previous papers may be considered a picture of the traditional lead smelter treating custom ores and of the smelter that will treat the type of product likely to be made in the future - lead concentrates of an increasingly rich grade.The great plant at Trail is of special interest to those smelting lead products containing much zinc and faced with the necessity of transforming all of their byproducts into commodities which may be sold profitably. The plant is equipped to produce electrolytic zinc, lead, copper, silver, bismuth, and cadmium. Part of the sulphur evolved from treating the ores is converted into sulphuric acid. Complete fertilizers for agricultural purposes are also produced.The smelter of lead ores has long considered that zinc is one of the most difficult ingredients that he has to handle. Even with the gretat improvement in flotation practice today, the residues from electrolytic zinc plants leaching zinc concentrates must still be smelted for their lead content. Of the total gangue material not separated from the lead concentrate sent to the smelter, zinc is still one of the most notable in percentage. The most successful way of coordinating the over-all operations of a concentrator, an electrolytic zinc plant, and a smelter provided with a plant for re-treating the blast-furnace slag for its lead and zinc content must be of interest to many treating complex ores.ACKNOWLEDGMENTThe data in this paper were collected in cooperation with the Consolidated Mining & Smelting Co. of Canada, Limited, and its entire technical staff. Detailed acknowledgments of assistance received are given in the papers from which this one is briefed."

Sep 1, 1934

By G. L. Oldright

The studies previously made on Smelting in the Lead Blast Furnace have dealt with the custom smelter of the International Smelting Co. at Tooele, Utah,4 and on the smelter of the Bunker Hill & Sullivan Mining & Smelting Co.5 at Kellogg, Idaho. The International plant may be considered representative of the traditional custom smelter. The lead smelter of the future seemingly will have to treat increasingly richer lead charges. This feature was then stressed in describing the Bunker Hill plant.

Jan 1, 1934

By G. L. Oldright

The studies previously made on Smelting in the Lead Blast Furnace have dealt with the custom smelter of the International Smelting Co. at Tooele, Utah, and on the smelter of the Bunker Hill & Sullivan Mining & Smelting Co. at Kellogg, Idaho. The International plant may be considered representative of the traditional custom smelter. The lead smelter of the future seemingly will have to treat increasingly richer lead charges. This feature was then stressed in describing the Bunker Hill plant.

Jan 1, 1934

By G. L. Oldright

The data presented in this paper were collected et the smelter of the Consolidated Mining A Smelting Co. of Canada, Limited, Trail (Tadanac), British Columbia, through the courtesy of S. G. Blaylock, vice president and general manager; James Buchanan, smelter superintendent, George Murray, assistant smelter superintendent; and the staff members listed in Paper XI, Report of Investigations 3243. INTRODUCTION This paper is the twelfth of a series on smelting in the lead blast furnace and the fifth4 dealing with blast-furnace gases.

Jan 1, 1934

By G. L. Oldright

This paper is the twelfth of a series on smelting in the lead blast furnace and the fifth dealing with blast-furnace gases. It was noted in Report of Investigations 2957 that the gases evolved from the top of the lead blast furnace at Tooele were similar in composition to those from the top of an iron blast furnace. It was noted in Report of Investigations 3095 that at Kellogg, where a smaller percentage of coke on charge and shorter stock column were employed, the gases evolved were much less reducing. At times there was a considerable amount of oxygen in the top gases at the second plant. More SO2 was also evolved from sulphides in the charge. Then operations were conducted as at Kellogg, the gases were alternately reducing and oxidizing. This paper deals with the gases evolved in smelting a charge containing more zinc than at either of the other two plants with about the same amount of coke as was used at Kellogg,: To compare other factors influencing the composition of the gases, it may be noted that at Tooele the approximate height of the charge column was 15 feet, at Kellogg 9 feet and at Trail 13 feet. The furnaces have about the -same cross-sectional area- tog. The furnaces at Tooele are about 6 inches wider at the tuyeres, being 54 inches wide against 48 for the other two plants. At Tooele and Kellogg the furnaces are fed at the top from bottom-dump cars. At Trail the charges are dumped from Decauville cars (bottom cars which dump when tilted), which run on tracks placed on both sides of the blast furnaces. The hoods through which the waste gases are conducted are directly above the shafts of the furnaces. The flues for removing the effluent gases lead off from under the charge floor at Tooele and Kellogg. (Charging and distribution of the feed in the furnace covered later in a rate paper of series.)

Jan 1, 1934

By G. L. Oldright

The data in this paper were collected at the Trail smelter of the Consolidated Mining & Smelting Co. of Canada, Limited, through the courtesy of S. G. Blaylock, vice president and general manager; James Buchanan, smelter superintendent; George Murray, assistant smelter superintendent; and the staff members given in Paper XI, Report of Investigations 3243. INTRODUCTION This paper is the thirteenth of the series on Smelting in the Lead Blast Furnace, and the third of the series on Handling Zinciferous Charges. Tyro other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By G. L. Oldright

This paper is the thirteenth of the series on Smelting in the Lead Blast furnace, and the third of the series on Handling Zinciferous Charges. Two other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By G. L. Oldwright, Virgil Miller

"The data presented in this paper were collected at the smelter of the Consolidated Mining & Smelting Co. of Canada Limited, Trail (Tadanac), Brithish Columbia. The authors are greatly indicated to S.G. Blayrock, vice president and general manager; James Buchman, smelter superintendent; and the staff members mentioned in Report of Investigation 3243. The authors are exceedingly grateful to George Murray, assistant smelter superintendent, for his keen interest, suggestions, and help in carrying out this investigation.INTRODUCTIONThe methods of charign the blast furnaces at Toole and Kelloggs were noted in Report of Investigations 2957 and 3094 respectively. Report of Investigations 2957 cited (4 to 9 inclusive) Hofman's Metallurgy of Lead (p. 226) and the work of A.S. Dwight, Thompson and Sicka, the staff of the Engineering and Mining Journal, and L.D. Anderson, N.F. Collins, in The Metallurgy of Lead (Chas. Griffin, London, 1910) also gives (pp. 247 254) the principles that he believes govern the successful charging of the blast furnace."

Dec 1, 1934