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By Richard C. Neavel

Among the many compositional parameters used to judge the quality of a steam coal is the fouling factor of Attig and Duzy1 [% base in ash % acid in ash X % Na20] in ash. The higher the fouling factor, the more likely the heat transfer surfaces of the boiler will acquire a deleterious deposit of sintered ash. While examining the elemental composition of ash from various size and gravity fractions of coals from Illinois, we noticed that variations in the fouling factor were attributable mostly to variations in the sodium content. Further, sodium content was essentially the same in all sink-float fractions from a given coal. In other words, sodium was related neither to the ash nor to the organic material. We therefore concluded that the sodium was most likely in the pore water, which was approximately a constant proportion of all fractions. This led to the supposition that the sodium might be removable through water extraction. This supposition tended to confirm the observations of Daybell,2 Daybell and Gillham,3 and Gluskoter and Ruch4 that much of the sodium in coals existed as water soluble sodium ions. In passing, it should be noted that most sodium in Western U.S. coals (i.e., Wyoming, North Dakota, Montana) is not water soluble, but rather is fairly strongly held in association with the organic material (ion-exchanged).5 Because data reported in the literature were not very conclusive about the typical proportions of sodium that might be removed by water extraction, and because there were few data indicating extraction rates, and finally, because our calculations showed a favorable economic incentive to lower sodium contents, we initiated an experimental program to investigate water extraction of sodium from Illinois coals.

Jan 1, 1976

By Kwang K. Koh, Nicholas C. Nahas, Richard C. Neavel

Sodium, a relatively abundant element in Illinois coal, is reported to cause fouling of utility boiler heat exchange surfaces. Distilled water extraction of 22 Illinois coal samples resulted in average removal of more than 50% of their included sodium. Chlorine was the dominant anion. Extraction rate conformed to Fick's law of diffusion. Extraction with hot water increased both the rate and maximum amount removed. A commercial-scale countercurrent staged process can be envisioned as technically feasible.

Jan 1, 1978

By Thomas D. Boyce

Minewater from many western U.S. uranium mines often contains radioisotopes in concentrations higher than permissible for discharge to unrestricted areas. .Radium 226 has the lowest permissible concentrations of all radioisotopes and usually greatly exceeds this limit in untreated effluents. This radionuclide is derived from the natural radioactive decay of uranium: [ ] The treating of minewater effluents has been studied previously (1) and the classical removal method for radium has been adsorption on barytes or freshly precipitated barium sulfate. This paper describes the removal of radium from minewater by utilizing a selective complexer based on a crosslinked organic polymer matrix.

Jan 1, 1982

By J. H. Field

The sulfur dioxide emitted in low concentrations in flue gases from the combustion of sulfur-containing coals and fuel oils is a significant factor in contamination of the atmosphere with sulfur dioxide. A review of methods for treating gases containing high concentrations of sulfur dioxide shows that they are seldom satisfactory for purifying flue gases. Processes developed specifically for treating flue gases using liquid absorbents are costly and may cause localized pollution, because the cooled flue gases can settle in the vicinity of the stack. Bench-scale research is being conducted to investigate the use of dry absorbents for sulfur dioxide removal at temperature levels of about 250°- 300° F. and 600°-650° F. Alkalized alumina has been found effective for treating simulated flue gas and Is regenerable by hydrogen, carbon monoxide, or producer gas. Other metallic oxides have been tested as absorbents also. Chemically impregnated activated carbons removed sulfur dioxide from the gas at 265° F. Vanadium pentoxide is effective as a catalyst for oxidizing of sulfur dioxide in the simulated flue gas at temperatures lower than have been used commercially for gases with higher concentrations of sulfur dioxide. Conversions of sulfur dioxide to trioxide wore studied as a function of temp- erature over a range of about 570° to 750° F.

Jan 1, 1959

By James S. Browning

The Mineral Resources Institute of The University of Alabama conducted research on the removal of sulfur from coal using a combination of gravity concentration and flotation methods. The research utilized the gravity and centrifugal force capabilities of the Humphreys spiral to remove part of the pyritic sulfur and ash. Flotation of the Humphreys spiral coal concentrate removed additional sulfur and ash to yield products that conform to Federal air quality standards for sulfur oxide emissions. The clean coal products recovered by the combined process contained 7.7 to 8.0 percent ash, 0.12 to 0.16 percent pyritic sulfur, and 0.78 to 0.96 percent total sulfur. Pyritic sulfur rejection by the process was about 95 percent. In addition to obtaining good recoveries of high quality coal the tests demonstrated that the pyrite in the wastes could be isolated as enriched flotation products by the combined gravity - flotation apporach. Pyrite concentrates analyzing 25 to 33 percent sulfur were recovered. Potential benefits of the pyrite flotation step are recovery of a product of possible market value and the elimination of the pyrite from the waste ash which could be a potential acid water problem when impounded.

Jan 1, 1981

By Dachun Liu, Xutao Guo, Wenlong Jiang, Baoqiang Xu, Bin Yang, Yong Deng, Heng Xiong

Typical copper dross, the byproduct of lead bullion pyrometallurgical refining for copper removal, mainly contains Pb, Cu, S, As, Sb and Sn etc. In traditional treatment process, copper dross is transformed to be copper matte by smelting with iron scarp and iron pyrite. Here, a new treatment process of converting-vacuum distillation (CVD) was proposed and investigated. Based on this concept, the converting process was tentatively investigated in this paper. The results of element distribution of converting samples showed the sample has three layers. The upper layer is mainly sulfides of lead and copper, the middle layer is mainly copper arsenide, and the lower layer is lead arsenide and crude lead. On the condition of oxygen flow rate 400 ml/min, the converting temperature 1000 °C, the holding time 1 h, the converting time 10 min, the lead copper alloy containing 0.17% S was obtained.

Mar 1, 2018

By W. W. Odell

THE sulfur content of coal is perhaps more important in the manufacture of illuminating gas than in any other coal-using industry. Whether the gas is made by the distillation of coal in retorts or ovens or by steaming incandescent coal or coke in the water-gas process, a portion of the sulfur present in the fuel always passes into the crude gas. Practically all the sulfur that remains in the finished gas is transformed into sulfur dioxide (SO2) when the gas is burned. Sulfur dioxide is a pungent suffocating gas and, if present in the air in any perceptible amount, is deleterious to health and comfort and damaging to house furnishings. So universally is this recognized that laws regulating the amount of sulfur that may be permitted to remain in the gas are very generally in force. The capacity of a plant to purify gas frequently limits the selection of coal for gas making. This condition may arise from different causes. Some plants were originally designed to handle a certain grade of low-sulfur gas coal, and very little leeway was allowed for growth or for the use of inferior coals. Other plants, when built, had ample capacity to purify gas from relatively higher sulfur coals, but their output has grown so rapidly that their purifying capacity is now limited and only- the low-sulfur coals can be handled. There is a great quantity of coal in the United States that would satisfy the requirements of the gas manufacturer, were it not for the high sulfur content. The coals containing less than 1 per cent. sulfur are becoming scarcer year by year and, in time, the gas industry will probably be compelled to use coals that are now considered out of the question.

Jan 9, 1919

By B. K. Parekh, W. M. Goldberger

A novel process is proposed for continuous removal of ash and unreacted solids which become suspended in the oils obtained during coal liquefaction. The proposed method uses water in direct contact with the oil under conditions which cause the suspended residue solids to transfer from the oil to the water phase. Separation of the phases yields a product oil essentially free of suspended solids. The water is cooled, clarified or filtered by conventional low-cost systems, and recirculated. The paper describes experimental work leading to development of the novel concept and includes the result of batch experiments that establish the feasibility of the process.

Jan 1, 1980

By Omero Alonso-Gonzalez, Sergio Haro-Rodriguez, Ricardo Solis-Rodriguez, Francisco Alvarado-Hernandez, Juan Antonio Gonzalez-Anaya, Héctor Rene Vega-Carrillo

"Precious metals are currently associated with refractory minerals such as telluride (Calaverite, Sylvanite, etc.) and selenium (Naumannite Ag2Se), which are difficult to dissolve through traditional methods, therefore it is necessary to perform a pretreatment (oxidative or roasting) preceding the process of leaching by cyanidation. In this preliminary work the aim was to study the use of solvent extraction to remove tellurium and selenium ions from a synthetic cyanidation effluent, with the purpose of recycling the cyanide back to the process. For the extraction of these anions, TeO32- and SeO42-, tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (Amine F) were studied as extractants, using nonylphenol as a modifier in the organic phase (trimethylpentane). The results show that it is possible to recover 82% of selenium and 10% of tellurium from synthetic solutions containing either 20 mg/L Se or 20 mg/L of Te, respectively The Se or Te mole ratio to cyanide was 1:4.INTRODUCTION In relation to extraction of precious metals, the cyanidation process has been in use for over a century and despite environmental and toxicological problems it remains the most widely used and economical process available. In the late 90s, there were great efforts to recover gold and silver from refractory ores, which is difficult to do by simple cyanidation. To improve gold recovery from tellurides and selenides that occurs in some new mines, the ores are pretreated by roasting. This is one of the most effective ways of rendering refractory gold ores leachable as well as being a fast pretreatment process compared with bio-oxidation or pressure leaching (Aylmore, 2001). The most important tellurides minerals are Calaverite (AuTe2) and, Silvanite (Au, Ag)2Te4). In the case of selenides, minerals include Naumannite (Ag2Se) and Aguilarite (Ag4SeS) (Ostroumov et al., 1989). Examples of deposits containing telluride include La Bambolla Mine (Sonora, Mexico), Cripple Greek (Colorado, USA), and Kalgoorlie (Western Australia) (Aguayo et al., 1996). The main purpose of this work was to explore the feasibility of using quaternary ammonium salts such as: tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (amine F) to extract tellurium and selenium anions from aqueous synthetic cyanidation effluents, so that the cyanide solution could be recycled back to leaching process. The tests were performed on synthetic solutions similar to those found in a mine: 20 mg/L Te as TeO32-, 20 mg/L Se as SeO42- and mole ratio to cyanide was 1:4. using an alkaline medium with pH ranging from 8 to 12. Two aspects are evaluated in this paper:"

Jan 1, 2017

By Daniel Chen, Jewel Andrew Gomes, Venkata Palla, Sadia Afrin Jame, David Cocke, Paul Bemazzani

"Textile industries use various kinds of chemicals including dyestuffs and pigments during dyeing and finishing processes. The effluent from these processes includes suspended particles, strong color, high pH and high chemical oxygen demand (COD) that are extremely toxic and make environmental hazard. Although physical, chemical, photochemical, and biological methods are available for treating such wastewater, the electrochemical technique, electrocoagulation (EC), has emerged as an efficient, simple, and cost-effective technology in the last few decades. In this study we present the applicability of EC technique for removing dye, such as direct red dye using iron electrodes, and the optimized conditions such as dye concentration, current density and pH. The degradation of dye molecules was investigated using UV-visible spectroscopy. The EC-floe was also characterized using SEM/EDS, XRD and FTIR.IntroductionWastewaters generated by textile industries contain large amounts of toxic aromatic compounds, especially azo dyes. Azo dyes and their degradation products, such as aromatic amines, are highly carcinogenic. These effluents are also responsible for causing high levels of color. The colored wastewater released into the environment is also a source for disruption of aquatic life and aesthetic pollution as well [1].In most textile industries, dyeing and finishing are the two important processes which are generally applied. These two common processes generate significant amount of wastewater, which may contain, suspended particles, high pH, strong color and high chemical oxygen demand (COD) concentration [2]. Low pH and high temperature are other polluting factors from the waste water. Textile industries make use of about 10,000 dyes and pigments [3]. Disposal of these colored wastewaters poses a major problem for the industries as well as a threat to the environment. In textile industries, because of the low efficiency (60-90%) of dye fixing on textile fibers, substantial amounts of unfixed dyes are released in waste waters. The conventional method for treatment of textile wastewater was a combination of biological, physical and chemical methods [2]."

Jan 1, 2011

By Catherine Williams-Beam

Thallium is more toxic to humans than mercury, cadmium, lead, copper or zinc. Its chemical behavior resembles the alkali metals (K, Rb, Cs). It occurs almost exclusively in natural waters the monovalent thallous cation. The solubilities of thallous compounds are relatively high so that monovalent thallium is readily transported through aqueous routes into the environment. The major sources of thallium are the base metal sulfides and precious metal bearing sulfides. Therefore, it is often present as a contaminant constituent in waters emanating from heavy metal sulfide bearing deposits. Thallium can be effectively removed from wastewater to <2 µg/L by reductive precipitation of thallium sulfide. Effective thallium sulfide precipitation requires a controlled solution potential/pH combination. The required potential can be effectively achieved by utilizing a particulate iron slurry or packed column environment. Experimental results will be presented and discussed.

Jan 1, 2003

By Michael Gebman, Jack Gerwick

"With the opening of the new San Francisco-Oakland Bay Bridge East Span, the former bridge and its caisson foundations are being demolished. Caisson foundations are in the path of a future shipping channel and therefore need removal down to the mudline 50 ft below water (MLLW). For the first caisson to be removed (E3) a mechanical demolition was performed above the waterline and an implosion was done for the remaining caisson down to mudline. Mechanical demolition consisted of excavators operating from either on top of the caisson, from work platforms or from barges. The demolition was implemented on a trial basis with a successful implosion on November 14, 2015. The work was conducted in an environmentally sensitive area, with measures taken to protect fish, marine mammals and birds. This demolition technique was cost effective, faster to execute, and had a better environmental impact then an alternative option. The demolition, measures implemented to protect the environment, outcome, and lessons learned are presented.INTRODUCTIONThe California Department of Transportation needed a cost effective and environmentally friendly solution for removal of the remaining San Francisco-Oakland Bay Bridge (former East Span) caisson foundations, starting with caisson E3. This was necessary to clear a future shipping channel. One option was to construct a steel cofferdam around the caisson to allow demolition in the dry down to the mudline. This option would take years to complete, be cost prohibitive, and its noise would disrupt aquatic life and birds throughout the cofferdam construction and demolition. An alternative option was implemented on a trial basis to conduct a mechanical demolition of the caisson above waterline along with an implosion of the remaining caisson down to mudline. This had the clear advantage as a cofferdam was not needed, and the demolition project duration would be approximately 6 months, instead of several years for the cofferdam option. The potential impact on aquatic life and birds from the implosion was a concern, as the location is environmentally sensitive; however, measures were implemented to minimize these impacts. As presented in this paper, this demolition option was implemented on a trial basis for Caisson E3. The technique succeeded and will now be used on the remaining caissons.BACKGROUND INFO ON CAISSON E3The reinforced concrete Caisson E3 is the largest caisson which supported the former East Span of the Bay Bridge. It was constructed in 1934, with the Bay Bridge opening in 1936. Figure 1 shows the project location. The caisson had a cell arrangement of 7 x 2 above the mudline. Below mudline, the caisson had a cell arrangement of 9 x 4. A structural transition was made between the 7 x 2 and 9 x 4 cell arrangements with buttress walls. All cells were flooded, as underwater openings were included in the original caisson walls to equalize the hydrostatic pressure. Figure 2 shows the caisson layout with limits for mechanical demolition and for the implosion."

Jan 1, 2016

By Nieves Iglesias

The removal of the refractoriness of a gold bearing pyrite- arsenopyrite ore is studied. Flotation concentrates were prepared and leached with a dilute acidic ferric sulfate solution. The elemental sulfur film which forms on arsenopyrite in the oxidation process is not responsible for the low rate of the arsenic dissolution observed. A positive effect on the leaching rate is observed when Ag&apos; is added. This pretreatment eliminates the refractory nature of concentrates.

Jan 1, 1993

By Chuck Kliche, Bill Clements

This project involved the removal of the top of an old water supply reservoir tank for the City of Lead, SD by explosives. The general contract called for the removal of the concrete top without damaging the sides or floor of the reservoir. The option of a rock hammer was eliminated, due to the possibility of an unpredictable collapse damaging the sides or floor of the reservoir. Different blasting options were discussed between the primary contractor and the blasting contractor, along with the pros and cons of each. The primary contractor settled on the option of drilling the structure for blasting versus using shaped charges

Jan 1, 2007

Removal of Thiocyanate from Solutions by Precipitation

Sep 13, 2010

Physical and chemical methods were investigated to tower thorium levels in Eneabba Ilmenite from the natural levels of 180-500 ppm to give Becher Process synthetic rutile with less than 100 ppm thorium. Chemlcal treatments, but not physical separations were successful. A pilot plant trial of a sodium hydroxide leach (25M NaOH at 75°C and 40 wt% solids for Ih) followed by a sulphuric acid leach (3M H2S04 at 90°C and 60 wt% solids for 211) confirmed that thorium could be removed to below 100 ppm. However, the activity of the ilmenite was not lowered to the same extent

Jan 1, 1996

By Kandipati Sreenivasarao

Ion flotation is a promising separation process for continuously removing toxic metal ions from dilute process effluents. After treating the effluent with appropriate surfactant(s), the metal- bearing species adsorb onto the surface of rising gas bubbles and can be collected as foams. Suitable collectors have been identified for most of the elements of the periodic table. However, a better understanding of the thermodynamic, kinetic and engineering principles that determine the performance of ion flotation systems would facilitate commercial utilization of this technology. A model system of sodium dodecylsulfate-ethanol has been studied for the removal of Cu (11) from dilute solutions, using laboratory-scale flotation columns. This paper reports the effects of the air flow rate, solution height, foam drainage zone height and col1ector:metal ion ratio on the flotation kinetics, ultimate recovery of metal, flotation product grade, foam losses and effluent quality. Preliminary results for Pb (11) removal are also reported.

Jan 1, 1993

The removal of tritium from tritiated water (-0.5 µCiIL) was studied by metallothermic reduction using aluminum. The influence of the three variables namely the aluminum powder amount, the NaOH concentration and the reaction time has been studied on the tritium activity reduction. The experimental results and statistical analysis showed that more than 85% of tritium can be removed from the tritiated water. Further work on the tritium recovery as well as efforts to totally decontaminate water by incorporating a cryogenic concept is currently pursued.

Jan 1, 1998

By N. I. Um

The coal bottom ash generated from coal-fired power plant accounted for approximately 5 mil-lion tons in Korea. Almost all of coal bottom ash was treated as reclamation of the landfill because of the content of unburned carbon. For recycling of coal bottom ash, effective removal of that is required. So, in this study, the removal of unburned carbon by flotation was studied with respect to adsorption ability in surface of a bubble in order to consider its application to recycle the coal bottom ash. The sample A, B and C were that the coal bottom ash contained 2.73%, 7.01% and 10.49% of the unburned carbon (UC) respectively. The column flotation was carried out for each time as the artificial injection of air at 10.0L/min flow rate and the reagents of 500g/ton kerosene and 80g/ton MIBC were used. The samples per water of 1.3 liters were from 0.5% to 4% (w/w.%). In the result of this study, the kinetic curves of unburned carbon adsorption from injected air bubbles were in-creased rapidly as equilibrium was approached; only 5 sec was needed from the sample A and B and 10 sec was from sample C. And the equilibrium isotherms of unburned carbon adsorbed by the infected air bubble from the sample B and C could appear the BET adsorption isotherm; MT = KMEEO/(EO-E)[EO+(K-1)E](K: adsorption affinity), but not the sample A that was not enough to express the adsorption curve.

Jan 1, 2014

By S. K. Kawatra

The fly ash from coal combustion often has a high unburned-carbon content. This can make it unusable as a cement admixture, which is the major fly ash utilization market. As a result, high-carbon fly ashes currently disposed of by landfilling, at sometimes considerable expense. In this paper, the use of froth flotation to remove the unburned carbon from fly ash is described. Three different fly ashes were studied, which had Loss-on-Ignition (LOI) values of 6.79, 6.90, and 11.11 %. It was found that the use of an alkanolamide/oil mixture as a froth-conditioning reagent could greatly reduce the amount of collector needed, by increasing the affinity of the collector for oxidized carbonaceous surfaces. For each of the three fly ashes, froth flotation reduced the LOI of the ash to less than 2% which is well below the ASTM specification of no &apos; more than 6.0% LOI for Class F fly ash. Increasing carbon content of the ash tended to increase the quantities of reagents needed in flotation.

Jan 1, 1996