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By T. H. Udayashankara

Soil pollution, a very serious environmental problem, has been attracting considerable attention in recent years. It is now generally recognized that land as a component of the environment deserves the same attention and protection as water and air. This recognition has arisen perhaps because of increased incidents of land pollution, the scarcity of land, and increased awareness and concern about long-term effects of land pollution on terrestrial and aquatic eco-systems and on ground water quality. Contamination of land results from a wide range of human activities, including industrial discharge process, disposal of wastewater and agriculture. The environmental impact of exploration, production and refining of crude oil is a major concern in developed and developing countries. Because of the known adverse effects of petroleum hydrocarbons on soil ecology and fertility there has been growing interest in the development of efficient technologies for the remediation of contaminated land, with a view toward making it available for further use. Crude oil is a natural product and as such is susceptible to degradation by naturally occurring micro flora. Bioremediation has become an important method for the restoration of oil-polluted environments. A bench scale study was conducted to evaluate the bioremediation technique in treating soil contaminated with transformer oil. The steps involved in this study are: (1) Preparation of contaminated soil, (2) Extraction of PAHs and PCBs from contaminated soil, (3) Treatment of contaminated soil in slurry batch reactor, and (4) Analysis of PAHs and PCBs by gas chromatography technique. The performance of reactor was assessed by measuring parameters like COD, PAHs and PCBs. The study was con-ducted for six different pulp densities ranging from 20% to 40%. The maximum removal of PAHs and PCBs was observed for 20% pulp density.

Jan 1, 2008

By Joo Hyun Park, Soo Sang Park

The distribution behavior of Pb between molten copper and FetO-SiO2 (-CaO, Al2O3) slags was investigated at 1473 K (1200 oC) and p(O2)=10-10 atm in view of the reaction mechanism of Pb dissolution into the slag. The distribution ratio of Pb (LPb) decreases with increasing CaO content (~6 mass pct) irrespective of Fe/SiO2 ratio (1.4~1.7). However, the addition of alumina into a slag with Fe/SiO2=1.5 linearly decreases the LPb, whereas a minimum value is observed at about 4 mass pct Al2O3 at Fe/SiO2=1.3. The log LPb continuously decreases with increasing Fe/SiO2 ratio, and the addition of Al2O3 (5 to 15 mass pct) into the silica-saturated iron silicate slag (Fe/SiO2 < 1.0) yields the highest Pb distribution ratio. The log LPb linearly decreases by increasing the log (Fe3+/Fe2+) value. The Pb distribution ratio increases and the excess free energy of PbO decreases with increasing Cu2O content in the slag. However, from the viewpoint of copper loss into the slag, the silica-saturated system containing small amounts of alumina is strongly recommended to stabilize PbO in the slag phase at a low Cu2O content.

Jan 1, 2014

By Bo Jiang, Lianyun Liu, Hongmin Zhu, Kai Huang

"Watermelon peel is selected as a novel adsorbent to remove Pb(II) from aqueous solution. A simple saponification process is proposed to modify the peel and the adsorbent is characterized by SEM and FTIR. The effects of pH, contact time, initial concentration of Pb(ll), biosorbent dosage and temperature on adsorption of Pb(II) are investigated. Different models are used to fit experimental data. These models indicate that the adsorption process follows the Langmuir model and pseudo-second-order model. The maximum adsorption capacity obtained from Langmuir model is 1.05mol kg-1 for the prepared sorbent. Equilibrium time is attained in 5-10 min for the studied concentrations. The watermelon peel can be used as an effective and low-cost biosorbent for removal of Pb(ll) from aqueous solution.IntroductionRecently, removal of heavy metal ions from industrial effluents by biosorption has become a very attractive topic, since the more serious pollution issues caused by heavy metals emerge frequently, and more strict requirements for its control are called upon by society [1,2]. In this case, most conventional purification technologies are not suitable due to poor cost-effectiveness [3]. For example, chemical precipitation by alkaline reagents usually can not decrease the metal ion concentration below the permissive levels, and also it will produce a large amount of sludge containing toxic metals. Membrane separation techniques can realize deep purification of wastewater easily, although its operating cost is usually high. Thus, considering the high effectiveness, low cost and free-sludge operation, bisorption has become a promising technique in water treatment [4]. The most important thing for this technology is the synthesis of a suitable biosorbent, whose adsorption properties will determine the removal efficiency and economic cost for the whole process. Watermelon is one of the most popular fruits for mankind for its delicious flavor. Usually, the watermelon is consumed mainly for its edible pulp, and its peel is discarded or only used as feed for livestock. Considering the pectin contained in the watermelon peel, just like that in orange wastes in the reported literatures [3], the idea of using it as the raw material to prepare the biosorbents for heavy metal ions removal from the aqueous solution was evaluated in this study."

Jan 1, 2012

By Qingzhu Li

The adsorption process of Pb2+ from aqueous solutions by spent grains modified with Imol/L NaCI solution was investigated. The effects of solution pH, contact time, adsorbent concentration, initial Pb2+ concentration, particle size on Pb2+removal were also studied. The initial adsorption process was rapid and 90.35% of Pb2+ adsorption occurred within 30 min. The absorption equilibrium was obtained at 4h. When pH was 5.5, Pb2+ concentration in aqueous solutions decreased from the initial content of 20 mg/L to 0.0 I mg/L after 5 hours by application of IOg/L adsorbent at 25?C, Pb2+ removal efficiency reached up to 99.95% and the Pb2+ remaining in aqueous solutions was under China Sanitary Standard for Drinking Water (GB5749-85). Adsorption data fitted well with Lanf+muir and Freundlich models. However,Langmuir isotherm model was better to descnbe Pb- adsorplion than Freundhch model, mdlcatmg that the applicability of monolayer coverage of Pb2+ on the surface of adsorbent.

Jan 1, 2008

By C I. Edwards

Phosphorous is typically present in iron ore either in the mineral apatite, Ca5(PO4)3OH, or associated with the goethitic fraction of the ore. In this paper, we present results that show that phosphorous associated with the goethitic fraction can be removed with a heating pretreatment around 300 176;C for 1 h, followed by a caustic leach with 1 - 5 M NaOH, or a leach with sulfuric acid at pH 0.5. The heating pretreatment is considered to dehydroxylate the goethite to form a haematite intermediate phase, ‘protohaematite’, that reacts during the leach making the phosphorous accessible to the leachant. In the acid leach, ten to 15 per cent of the sample was dissolved to obtain a leach product with 0.08 per cent P. In the caustic leach, as no weight loss occurs, it is proposed that iron species associated with the protohaematite have either not dissolved or have reprecipitated at the high pH values of the leach.For an ore containing apatite as the source of phosphorous, a leach with sulfuric acid dissolved the apatite, lowering the phosphorous levels in the sample. The sample treated contained carbonate minerals (including siderite) that also reacted with the acid, and in practice a balance between the dissolution of the apatite and the carbonate minerals may be needed to minimise acid consumption.

Jul 11, 2011

By A Batnasan, K Haga, A Shibayama, K Higuchi, H Takeuchi

High silica (SiO2), alumina (Al2O3), and phosphorus (P) contents in iron ore adversely affect the quality of iron products. The removal of those impurities from iron ore is an essential point in further iron ore processing. In this paper, the removal of P, SiO2 and Al2O3 impurities from iron ore by alkaline drying followed by reverse cationic flotation is discussed. The reverse cationic flotation experiments are performed using the iron ore samples without and with alkaline drying pretreatment. All other flotation conditions except pulp pH (4–12) and particle size distributions (-45 to -250 μm) are held constant. A typical collector and frother, such as dodecylamine acetate (DAA) and methylisobutylcarbinol (MIBC), are used in the flotation experiments. Alkaline treatment is conducted before flotation using sodium hydroxide at fixed conditions. The impact of alkaline drying on the performance of iron ore flotation is evaluated based on the removal rates of P and SiO2 + Al2O3, iron grade, and iron recovery compared with the iron ore flotation without alkaline drying (direct flotation). X-ray diffraction (XRD) analysis indicates hematite and goethite are the main minerals in the iron ore, which assays 62.8 mass per cent Fe, 0.232 mass per cent P, 7.1 mass per cent SiO2 + Al2O3 (total) determined by X-ray fluorescence analysis (XRF). Results indicate that a combined approach is more effective for removing P and SiO2 + Al2O3 impurities from iron ore than the direct processing technique because the maximum removal rates of P and SiO2 + Al2O3 are 48.2 per cent and 66.5 per cent from the alkaline dried iron ore when 8.4 per cent and 13.1 per cent from the non-alkaline dried iron ore.

Sep 18, 2023

By Harold R. Kokal

Lisakovsky is a 3-billion ton oolitic iron ore deposit in north-central Kazakhstan operated by Orken LLP, a subsidiary of Ispat Karmet and the LNM Group. The iron oxide minerals are goethite and limonite. The gangue occurs as discrete quartz grains and an unidentified form of colloidal silica-alumina. The concentrate produced contains about 49.5 percent iron (Fe) and 0.6-0.8 percent phosphorus (P) or 10-20 times the acceptable phosphorus level. The phosphorus is intimately associated with the iron oxide and colloidal gangue, no discrete phosphorus minerals are found, and beneficiation is not possible. Therefore, to reduce the phosphorus, a hydrometallurgical process that includes roasting followed by leaching in dilute sulfuric acid has been developed. Phosphorus extraction is 70-90 percent, with only a minor loss of iron. The process has been tested in the laboratory and in a pilot plant at 50-300 kg/h. Construction of a 900,000 t/y demonstration plant is underway.

Jan 1, 2003

The present study is devoted to improvement of the leaching efficiency during phosphorous removal from high phosphorous gravity-magnetic concentrate. Before leaching the concentrate has been subjected to roasting with the addition of either Ca(OH)2 or CaO. The oolitic iron ore is roasted at 900°C for one hour. This reflects in reaction between alkaline earth additive and quartz, aluminosilicates, phosphorus, and some other minor components of the gangue minerals. The application of leaching, physical separation, and wash out of salts has resulted in the decrease of phosphorus from 0.7 to 0.15 % and it is established that the major influencing factor is the concentration of acid and to a less extent duration of the leaching process. About two third of the phosphorus can be removed by roasting with 3 % CaO to hematite, coarse grinding to d50 0.3 mm, dry high intensity magnetic separation and leaching of the magnetic fraction with hydro-chloric or nitric acid.

Sep 1, 2012

By Andrew J. Gaber

Beginning in 1961 the Coal Research Bureau of the West Virginia University School of Mines began a program of research to investigate the potential of the magnetic separation process to remove sulfur of the pyritic form from pulverized coal. Using a so-called isodynamic magnetic separator (1) it was demonstrated that significant quantities of pyritic sulfur could be removed from coal. Pulverized coal samples representing several different coal seams were individually screened into sizes in the 48 mesh by 200 mesh (297 to 74 microns) range, and untreated and steam-air treated samples of each were processed by the magnetic separator. The results of the investigations to magnetically remove pyrite from coal were published in two separate reports issued by the Coal Research Bureau (2,3), The isodynamic magnetic separator was designed about 30 years ago for use in geological and mineralogical laboratories (1,4,5) to isolate one or more minerals exhibiting only small differences in their magnetic propertiese Specifically, to accomplish this, the air gap of the unit was designed to provide a nearly constant magnetic gradient both laterally and longitudinally in the separating zone. It is reported that mineral concentrates of 99.5 percent purity can-be produced on closely-sized fractions after several cleanings through the unit. The isodynamic magnetic separator, therefore, was not expected to process coal containing sizes smaller than 200 mesh, or to demonstrate commercial capability to process pulverized coal. The primary purpose of the Coal Research Bureau in using the unit was that of determining if the magnetic process could remove pyrite from coal, and thereby encourage further research directed toward development of acceptable full-scale processing equipment.

Jan 1, 1969

By Stanojevic R, McGlinn PJ, Day RA, Levins DM

This paper reports the results of a number of studies that Ansto has carried out for mineral sands companies concerned about low-levels of naturally-occurring radioactivity in their products. Where measured levels of radioactivity have exceeded allowable levels, Ansto has used specialised techniques to identify the source and distribution of the radioactivity and investigated processing strategies to remove the Contamination.

Jan 1, 1993

By D. Raicevic

The presence of residual uranium and other radionuclides in the uranium mill tailings are posing a continuous health concern to the surrounding environment. The slow generation of sulphuric acid from residual sulphide minerals is the cause of persistant dissolution and discharge of many metallic components of the tailings. The most effective long term solution to these problems would seem to be to produce chemically stable tailings. This paper describes two possible answers to the objective: (1) Removal of radionuclides and pyrite from tailings by mineral dressing techniques; some 60 - 68% of the residual uranium, 70 - 75% of the radium, 60 - 65% of the thorium and 95 - 98% of the pyrite have been rejected from the Elliot Lake tailings. The decontaminated tailings contained 0.003% uranium, 50 - 60 pCi/g radium226, 0.01% thorium and less than 0.1% sulphur as pyrite. (2) Preconcentration of radionuclides and pyrite by beneficiation from Elliot Lake ores prior to leaching; applying this approach about 97% of the uranium, 95% of the radium, 92% of the thorium and 98.5% of the sulphides were concentrated in a radionuclide and pyrite concentrates comprising 25% and 8% of the ore, respectively. The preconcentration tailings (waste) produced contained 0.004% uranium, 20 - 25 pCi/g radium226, 0.005% thorium and less than 0.1% sulphur as pyrite. Economic and environmental advantages of both approaches and the leaching of the concentrates are also discussed.

Jan 1, 1980

By Ralph B. S

Bacterial leaching of low grade quartz felspar porphyry copper ore was studied in large-scale laboratory percolation leaching columns.Limitations in the release of soluble copper showed up before fifty per cent recovery, due to occluding precipitates of iron oxides and hydroxides. Precipitates were removed by increasing the acidity of irrigation feed four-fold with respect to sulphuric acid. However, irrigation at low pH (pH 1.5) inhibited copper leaching. Resumption of bacterial leaching at pH2 was achieved by introducing a period of non-irrigation. The results suggest a &apos;direct&apos; attack by bacteria on the chalcopyrite substrate rather than an &apos;indirect&apos; ferric-leach mechanism.

Jan 1, 1981

By Arcy R., D&apos George

Removal of S02 from smelter gases is being investigated, using an innovative technique that results in the almost simultaneous recovery and production of elemental sulfur. S02 is removed from the gas stream by scrubbing with suitable aqueous salt solutions or high-boiling organic fluids. The S02-laden liquor is then reacted with H2S Crystalline, high-purity sulfur is instantly precipitated and, after filtration, the regenerated liquor is recycled. The H2S required for the process is produced by reacting a portion of the recovered sulfur with hydrogen or with methane and steam. The chemistry and results of preliminary laboratory research are discussed.

Jan 1, 1969

By K. T. Dreher, J. A. Brierley, C. L. Brierley

Water from underground uranium mines located in the Ambrosia Lake district near Grants, New Mexico, U.S.A., is treated to reduce levels of uranium, selenium, radium and molybdenum. The treatment system consists of a series of ponds and an ion exchange plant. Bacterial and algal populations present in the pond system are considered agents which actively assist in removal of the pollutants present in the water. Pondbottom sediments maintain a reducing zone and a large population of sulfate-reducing bacteria of the genera [Desulfovibrio] and [Desulfotomaculum]. Uranium, molybdenum, and selenium accumulate in the pond sediment. Stimulation of the microbial sulfate-reducing activity resulted in a decrease of soluble concentrations of these elements in laboratory systems. Predominant components of the treatment ponds’ algal flora are the filamentous [Spirogyra] and benthic [Chara]. Laboratory study indicates that [Spirogyra] is more active than [Chara] in removal of uranium and molybdenum from solution. However field-collected algal samples of both of the genera contain uranium and molybdenum. Laboratory studies indicate that death and decay of the algae in association with pond sediment does not result in return of cellbound uranium and molybdenum to the water. The algae appear to act as bio-filters for accumulation of particulate pollutants and agents for adsorption and/or absorption of soluble pollutants.

Jan 1, 1980

By M. De Ladurantaye-Noël, M. Laliberte

Selenium is widely present in the environment at usually low concentration. It is mostly present in the environment at higher oxidation states, i.e., as selenites and selenates (+4 and +6 oxidation states respectively). It is rarely present as selenides (-2 oxidation state) and almost never found as the element (0 oxidation state). Selenites and selenates are generally soluble in water, as such they cannot easily be removed from water by precipitation. Selenites can form insoluble surface complexes with metal oxides such as ferric hydrous oxide and manganese hydroxide, and can therefore be removed that way. However, it is not so common to find selenites in natural environments as it will quickly oxidize to selenate in aerobic conditions. Elemental selenium can also be produced from selenites or selenates by using a reduction process; the end product is a colloid that can be destabilized to be removed from water using the right chemistry. Because of their toxicity, selenides need to be handled with care, and if present, it can form insoluble metal salts or, at low pH, be emitted as H2Se, a noxious and highly toxic gas. The most favorable selenium forms for its removal are therefore selenite and elemental selenium. Organo-selenium species play a crucial part in understanding selenium toxicity. There are a great number of these species. Basically, any organic species that contains sulfur has an equivalent that contains selenium. Of particular interest is the substitution of sulfur by selenium in the two sulfur-bearing amino acids, cysteine and methionine, resulting in selenocysteine and selenomethionine. Methylseleninic acid (CH3SeO2H) is another organo-selenium specie which has been detected in water treated by biological processes and which is biologically active.

Feb 1, 2023

By J. R. Batista, J. C. Young

Leachates from gold heap-leaching mines may contain selenium concentrations as high as 2 mg/L. Previous studies report satisfactory selenium adsorption by activated alumina from relatively "clean" drinking waters. However, the findings of these studies cannot be directly applied to the treatment of mine leachate where other ions compete for the alumina adsorption sites. This study evaluated the adsorption of selenium from a mine leachate to develop design parameters for a full-scale activated alumina process. The study revealed that 68% of the selenium in the leachate could be removed by alumina at pH levels greater than 5.0. At pH levels less than 4, silica was poorly adsorbed by alumina, and selenium adsorption was improved. Silica adversely affected the selenium adsorption capacity.

Jan 1, 1998

By J. R. Batista

Leachates from gold heap-leaching mines contain selenium concentrations as high as 2 mg/L. Previous studies report satisfactory selenium adsorption by activated alumina when using relatively "clean" drinking waters. However, the findings of these studies cannot be directly applied to the treatment of mine leachate where other ions compete for the alumina adsorption sites. This study evaluated the adsorption of selenium from a mine leachate to develop design parameters for full-scale activated alumina processes. The study revealed that 68% of the selenium in the leachate could be removed by alumina at pH > 5.0. Silica adversely affected the selenium adsorption capacity. At pH values < 4, silica was poorly adsorbed by alumina and selenium adsorption was improved.

Jan 1, 1994

By Helen Joyce, Larry Twidwell, Jay McCloskey, Eric Dahlgren, Andy Hadden

The reduction of dissolved selenium oxyanions from mine wastewater utilizing an elemental iron cementation technology on been studied on a laboratory scale at Montana Tech of The University of Montana and on a pilot scale at MSE-Technology Applications as a water treatment process potentially capable of removing dissolved selenium to GO WL. Laboratory and pilot scale studies using elemental iron have demonstrated effective removal of dissolved selenium. Enhanced selenium reduction rates have been demonstrated when galvanically coupled iron/copper and iron/ nickel are utilized. The laboratory and pilot scale results are presented and discussed.

Jan 1, 2005

By T. Ono, B. Altansukh, S. Kawamura, K. Haga, A. Shibayama, Y. Takasaki

In recent years, the grade of silica in zinc concentrate has increased due to the degradation of zinc content and the increase in impurity content in natural ores. It implies that the development of silica removal technology from zinc concentrate is necessary to solve problems in the smelting process caused by the high content of silica in zinc concentrate. In this paper, the authors investigated the silica removal processes from silica-rich zinc concentrate by mineral processing approaches such as re-grinding and flotation. This study focused on the pulverisation process as a pretreatment for the investigation of individual minerals' liberation from the silica-rich zinc concentrates using different kinds of pulverisers. Flotation experiments were performed to separate silica and zinc concentrate from the pulverizsd feed sample using a pH regulator (NaOH), activator (CuSO4), collecting agent (PAX), and foaming agent (DOW froth 250). Results showed that the liberation rate of silica (SiO2) was reached 75% from 13% by pulverisation in an attritor with a 2 mm ball in diameter, while silica accumulated in a fraction over 20 mm in size. Flotation experiments indicated that silica removal efficiency was achieved by 44% from + 20 mm fraction obtained from pulverisation whereas the grade of silica in froth reached 1.85 mass% from 4.5 mass%. Results indicate that silica could selectively separate from silica-rich zinc concentrate, and 99.8 % zinc recovery is achieved under the studied conditions. Keywords: Zinc concentrate, silica, pulverisation, liberation, sieving, flotation

Jan 1, 2020

By Jiangtao Li, Zhongwei Zhao, Xingyu Chen, Xuheng Liu

In order to produce good quality ammonium paratungstate, Sn needs be removed efficiently from the tungstate processing solution. The nascent hydrous ferric oxide has excellent adsorption ability and is often used as an adsorbent to remove metal ions from aqueous solution. In this paper, nascent hydrous ferric oxide is used to remove Sn from tungstate solution. Through experimental, the effects of pH value, reagent amount of adsorbent, reaction temperature and reaction time on the Sn removal are investigated. The study shows that 98% of Sn can be removed effectively from sodium tungstate solution and only 2% of W is lost during process under the conditions of pH 9~12, reagent amount of Fe addition 40 times Sn amount, reaction time 30min and room temperature. As the Fe addition reaches 90 times of Sn concentration in the ammonium tungstate solution, 99% of Sn is removed and APT with zero level purity national standard is obtained.

Jan 1, 2014