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By L. de Florez

The successful control of any operation, whether industrial, military, or purely physical, is fundamentally dependent upon the same elements: (I) The securing of accurate and pertinent information concerning the factors involved in the operation; (2) Correct interpretation of their relationship as affecting future results; (3) Efficient means for effecting changes in the factors governing the operation to shape the result. The analogy which exists in the control of operations in these widely differing fields of action is of utmost interest, and in considering the physical control of a process, the realization of its existence permits a clearer conception of the steps required to achieve results and aids in formulating the problems to be met. Let us imagine, for instance, the requirements for successfully conducting a business. It is evident that the first requisite lies in obtaining continuous and reliable information concerning the functioning of its various branches and in detecting, with the least possible delay, any tendency of change in their functions; next, in correctly analyzing this information by comparison with past records, showing the relation of the particular business to general conditions in the trade; and finally, in employing means for counteracting any unfavorable change in general conditions, or compensating for its effects by an appropriate action. Likewise, in military operations, the success in carrying out a plan lies primarily in the maintenance of proper intelligence and communication service, which furnishes information as to the disposition of forces; in correct analysis of the ascertained position, guided by fundamental knowledge of tactics; and finally, on the efficient carrying out of orders and effecting corrective movements. In the physical operation of a process, such as for example in cracking, our information is obtained by pressure and temperature instruments, etc., which permit us to visualize existing conditions under which the operation is being carried out. The information at hand is then analyzed and certain conclusions arrived at as to the results which will be obtained under the observed conditions. If this analysis should indicate, in the

Jan 1, 1928

By E. B. Phillips, A. E. Miller

The title assigned to this paper permits a discussion of one of the most interesting chapters in the history of the American petroleum industry. Nature was kind to man when she prepared crude oil for him in commercial quantities in the hills of Northwestern Pennsylvania. Most of the refining operations we are now accustomed to apply were either not needed or had been carried out by earth processes ages ago. Such technology as was applied dealt with the physical separation of the valuable components in the crude oil and intermediate products and did not need more than mild refining treatments to bring them to marketable quality. • The pioneer refiners were concerned principally with distilling, dewax-ing and decolorizing operations. The products produced were limited in number and the uses to which they could be put were few. Natural products from the very high grade crudes, then plentiful, supplied the domestic demand and no other markets were open. As time passed, other producing fields were discovered and crude oils of lower natural quality were made available. To refine these grades to a quality expected by buyers, refinery practice had to be changed and new methods found. At the same time the accidental discovery that crude residues could be cracked by dry distillation at atmospheric pressure to produce a much larger amount of lamp oil than had been customary, opened a new vista for the industry. Export kerosene soon became the leading revenue product for all refiners and considerable new technic was added to refinery practice. High sulfur crude oils from Ohio next made their appearance, causing the development of the first commercial desulfurizing process, the sodium plumbite treating method for "sour" lamp oil stocks and the application of fine earth for the removal of "flock." Some improvements in methods of handling lubricating oils and cylinder stock fractions of crude were worked out, but in general, it can be said that the closing decade of the last century found the industry in a stabilized condition. Typical refinery operations of 1900 were simple and were conducted with the single purpose of producing as much export kerosene as possible Light naphthas and fuel oils were a drug on the market and every means

Jan 1, 1928

By Robins R. G

The dissolution of metallic copper powder in aqueous solutions of cupric sulphate under the influence of ethylene gas was investigated. The dissolution reaction stoichiometry obtained was: Cue+(aq) + Cu(s) + 2C2H4(g) = 2(CuC2H4)+(aq) The rate of formation of the copper (I)-ethylene complex in the above reaction was studied in a laboratory autoclave and the effect pH, temperature, ethylene partial pressure and initial concentration on the dissolution rate was measured experimentally and expressed theoretically in terms of several simple conceptual kinetic models. The results led to the selection of optimum conditions for the reaction and the suggestion of an "ion-molecule reaction" mechanism to explain the very low activation energies for the reaction system. The area of application of this reaction lies in the direction of refining impure copper such as cement copper. Several experiments were performed in which an acidified solution of cupric sulphate under ethylene pressure was used to dissolve copper from the cement copper powder in the form of the copper (I)-ethylene complex, followed by the release of gas pressure to disproportionate the complex and precipitate a purer metallic copper.

Jan 1, 1987

By R. G. Robins

The dissolution of metallic copper powder in aqueous solutions of cupric sulfate with ethylene under low pressure was investigated. The reaction stoichiometry obtained was:

Jan 1, 1988

By R. R. Rogers

ABSTRACT The experiments described demonstrate that crude commercial lithium containing in the order of 0.5 per cent sodium can be refined, the resulting metal containing as low as 0.001 per cent sodium. During the process, the metal is vaporized and condensed at a gauge pressure of less than 0.04 micron. Considerable operating data and a detailed description of the experimental equipment are included. INTRODUCTION DUE TO THE unusual properties of lithium metal, its use is likely to increase considerably during the next few years (1, 2). This is of particular interest to Canadians because there are important deposits of lithium-containing minerals, especially spodumene, in Canada and it is hoped that lithium compounds and lithium metal will be produced from these deposits in the fairly near future. In order to assist in the development of this industry, the Mines Branch of the Department of Mines and Technical Surveys has initiated a programme of research in lithium metallurgy. In 1948, a paper (4) was published on methods of producing lithium metal and its alloys. Data on the corrosion resistance of some lithium alloys were included. In 1949, a paper (3) was published which showed that the addition of a small percentage of lithium to zinc anodes used for cathodic protection will improve their usefulness under certain circumstances.

Jan 1, 1951

ecent work on decoppering lead is reviewed; CuS is formed rapidly even from dilute solutions of copper in lead. he mechanism of decoppering is discussed, and an explanation for the retention of metals such as silver in lead is dvanced. As decoppering tin appears to be an analogous process, the Cu-Sn-S system is studied at 300¦C. CuS, hich is not, an equilibrium product, is found in decoppering drosses. In the removal of nickel from lead, Ni3pb2S2 formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by tirring in sulphur. Decoppering bismuth is thermodynamically favoured, but is complicated by the occurrence of uBiS2. The Cu-Pb-S system is the only one of the four studied where the equilibrium can be calculated simply, as ' resence of ternary sulphide or other phases invalidates calculations based on binary data.

Jan 1, 1970

Recent work on decoppering lead is reviewed CUS is formed rapidly even from dilute solutions of copper in lead. The mechanism of decoppering is discussed and an explanation for the retention of metals such as silver in lead is advanced. As decoppering tin appears to be an analogous process, the, Cu-Sn-S system is studied at 300°C.. CuS, which is not an equilibrium product, is found m decoppermg drosses. In the removal of nickel from lead, Ni3Pb2S2 is formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by stirring in sulphur. Decoppering bIsmuth IS thermodynamically favoured, but is complicated by the occurrence of CuBiS2 The Cu-Pb-S system IS the only one of the four studied where the equilibrium can be calculated simply, as the presence of ternary sulphIde or other phases invalidates calculations based on binary data.

Jan 1, 1971

By Ali Unal, Ali I. Kahveci

Alcoa developed a fractional crystallization process some 30 years ago as a method to purify aluminum. Depending on the purity of feed metal, it has been commercially used to make 3N7-6N purity aluminum. As an extension of this technology, Alcoa has experimented with purifying various aluminum alloy scrap for the purpose of recycling. Purified aluminum alloy scrap can be reused for making the same alloy. This presentation will discuss Alcoa fractional crystallization technology and its application to alloy scrap processing. Process capabilities and the partitioning of eutectic and peritectic impurities during fractional crystallization will be discussed for the alloy systems investigated.

Jan 1, 2000

By Rees D. Groves

Cement copper is ordinarily converted to marketable metal by processing in a conventional smelter and refinery. Because of rapidly increasing cement copper production and limited excess smelting capacity, other techniques were investigated for preparing marketable copper products. One route was to make copper powder for industrial use. The process scheme employed flotation for rejecting the bulk of the impurities, acid leaching to remove residual iron and aluminum, reduction sintering to eliminate oxygen, and grinding to obtain powder. Another route was to sinter the floated and leached copper into the form of anodes and electrolyze these to yield refined copper cathodes. At a current density of 30 amperes per square foot, power consumption for electrorefining was 185 kwhr per ton of copper. The feasibility of preparing commercial-size anodes by sintering is still to be assessed.

Jan 1, 1970

By C. -J. Rick

By implementing a converter downstream of the reduction furnace it is possible to broaden the product range significantly. The converter can also successfully be used to strip furnace slag from chromium oxide. Some process alternatives and their economical, practical and environmental implications are studied using process models developed based on UHT?s long experience in stainless steelmaking, stainless steel process control and charge chrome refining. Keywords Charge chrome, converter refining, ferrochromium products, process design.

Jan 1, 2010

By Senanayake G

A sample of crude copper powder produced by the CLEAR Process was refined by dissolution and recovery in sulfate media using the Parker Process. The Parker Process offers an alternative method of copper recovery to electrorefining and allows a range of Eh and pH conditions to be used to provide further discrimination of impurities. High purity copper powder was recovered by the Parker Process even in the presence of added impurities when the Eh and pH was maintained near constant throughout the refining step.

Jan 1, 1984

By P. Fossi

This report describes a pilot-scale study of a hydrometallurgical process to treat high-grade nickel matte or a nickel-cobalt sulphide precipitate to produce high-purity electrolytic nickel. The first step of the process is the oxidative leaching of the nickel-bearing material by nitric acid; the nitrous gases generated during leaching are reconverted to nitric acid. The crude nickel sulphate nitrate solution is purified and is then subjected to a denitrification step. Nitrate separation is effected either by the crystallization of nickel sulphate or by precipitation of basic nickel carbonate. The electrolyte is prepared from the nitrate-free material and nickel is then recovered by electrolysis of the sulphate solution using insoluble anodes. Some technical and economic problems encountered with this processing route are discussed and the method is compared to the "all-chloride" process developed by Société Le Nickel.

Jan 1, 1977

By Alexandr I. Volkhin

It is practically useful to separate copper from nickel at the fire refining stage of blister copper by transferring nickel in electrochemical inert silicides which are being concentrated further into the tank-house slimes. The treatment of copper melt by silicon-containing reagents is resulted in lowering the interfacial tension of the melt, its deoxidizing, selective siliconizing of in-melt nickel and forming a by-product with fluxing properties. Si-containing reagents have positive influence on results of fire and electrolytic refining, and further pulverizing of copper in plant conditions.

Jan 1, 2006

By Kajioka H, Nakamura Y

Na2CO3 is a powerful flux for both dephosphorization and desulphurization in oxidizing atmospheres. In order to study refining with Na2CO3 and the nature of the Na2CO3 slag itself, hot metal (4Kg) was melted in Al203 crucibles in a high frequency induction furnace and oxidised with oxygen under Na2CO3 slag. The behaviour of Na2CO3 at high temperature was observed by thermobalance. It was found that dephosphorization ceases in a few minutes and [,P] after refining is easily lowered to less than 0.010%. [%P] after refining is affected by [Si], [P] of hot metal, the refining temperature and the consumption of Na2CO3. Desulphurization also ceases in a few minutes but it shows curious behaviour, increase of [S], decrease of (S) and increase in sulphur lost, during the latter half of run. [%S] after refining is also affected by [P] of hot metal, the refining temperature and the consumption of Na2C03o

Jan 1, 1980

By R. F. Pearce

The paper in based on laboratory and pilot plant investigations which led to the development of a series of processes for production of high purity metals from nickel-copper-cobalt mattes of a wide range of composition. The selection of ammonia pressure leaching or acid pressure leaching for various mattes is discussed. This is followed by discussion of various methods for leach solution purification and metal separation. The metals of high purity are produced by reduction with hydrogen from purified solutions. Examples are given of complete flowsheets for a number of mattes. Drawing upon those examples, general principles for the selection of the most suitable treatment process for particular material are outlined. Under certain circumstances, those processes may replace part of the pyrometallurgical treatment and all of the electrolytic refining steps which are customary in the treatment of nickel-copper-cobalt mattes.

Jan 1, 1959

By G. P. Demopoulos

"The recovery and separation of platinum-group metals (PGM) from primary and secondary materials currently attracts a lot of interest due to the high value of the metals and their increasing demand for high-tech applications. Thus, the traditional refining processes are gradually replaced by newer more efficient separation techniques such as solvent extraction and ion exchange. In this paper the classical and modern refining techniques are reviewed and the pertinent solution chemistry dictating proper processing strategies in each case is discussed. The technological advantages of the modern separation methods are emphasized and reference to the recovery of PGM from primary as well as secondary materials is given. INTRODUCTIONDue to their outstanding physicochemical properties, such as catalytic activity, conductivity and corrosion/oxidation resistance, precious metals now find extensive usage outside of the traditional jewellery and investment industries. The increasing use of precious metals in such areas as electronics and catalysis, as well as their increasing high value, has led to a growing interest in their recovery and separation from primary and secondary materials.Quantitatively the demand of platinum metals in the western world by area of application is described in Table I. Platinum and palladium represent 90% of the total demand, Rh and Ru 8% and the remaining is taken by Ir and Os. In terms of value the following were the average prices (US$/oz) of the metals in the second half of 1986: 500 Pt, 125 Pd, 1200 Rh, 650 Os, 400 Ir and 80 Ru. Due to these prices, exploration, mining, reclamation and refining activity were very high in South Africa, the biggest producer of Pt metals in the world, as well as in other areas: United States (Stilwater deposit), Canada (Sudbury, Marathon and Lac des Isles, Ontario; Kenly Lake, Quebec, etc.), Australia, Europe and elsewhere"

Jan 1, 1989

By Harold L. Hinds

The refining of precious metals from steel wool cathoodes is completed by one of two methods: 1) By direct fire smelting or: 2) Acid treatment of the cathodes to dissolve the steel wool and then followed by fire smelting. To further the refining of the cathodes, the Miller Process and the Wohlwill Process are used.

Jan 1, 1981

By H. L. Hinds, L. L. Trautman

The refining of precious metals from steel wool cathodes is completed by direct fire smelting or acid treatment of the cathodes to dissolve the steel wool followed by fire smelting. To further the refining of the cathodes, the Miller process and the Wohlwill process are used.

Jan 1, 1984

Discussion of the paper of DR. L. EDELEANU, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin No. 93, September, 1914, pp. 2313 to 2332. F. W. BUSHONG,* Pittsburgh, Pa.-This process of extraction is particularly advantageous in the case of Roumanian oil, on account of its high aromatic content. I have prepared a paper, which will appear probably next month in the Journal of Industrial and Engineering Chemistry, describing a series of two-degree fractions of oil from the Nowata field in Oklahoma. I have made extractions with liquid sulphur dioxide in accordance with Dr. Edeleanu's method, and found that the Oklahoma oils, for instance the kerosene fractions, are purified in this way, although the quantity taken out does not at all compare with that taken out of the Roumanian oil. I have made careful analyses of separate fractions, before and after extraction, and they show a very distinct fractional separation-. I like the distinction, brought out by Dr. Day in previous discussions, in regard to oils, rather than oil, and his beautiful illustration of fractionation. Just as fuller's earth, and other clays, will enable us to obtain lower-boiling fractional portions of the oils, and eventually retain a residuum which is hard to get rid of, or to remove, so there is an advantage to be gained by the use of a reagent which begins at the other end by taking out these last constituents first, namely, ozone. I have also analyzed the ozonides and they are derivatives of hydrocarbons very much poorer. in hydrogen than we have heretofore supposed. Similar results have been obtained with Roumanian, Russian, and Italian petroleums. Furthermore, I have prepared ozonides from a fraction of Oklahoma oils, both before and after ex-' traction with liquid sulphur dioxide, and found that the ozonide obtained from the extract is the same as that precipitated out of the original oils. In other words, the residual substance, which the fuller's earth retains, is the one first thrown down by the use of ozone, but it may also be extracted by liquid sulphur dioxide- and be thus separated in apparently unaltered condition. The analysis of this extract corresponds to the formula C15H20, which is surprising, since it is lower in hydrogen content than we have been in the habit of considering among the constituents of our oils. The extract was probably contaminated with other hydro-carbons, but I think it is unquestionable that we must look for hydro-carbons in petroleum which correspond to a formula at least -as low in hydrogen as C15H2o, and possibly even as low as C15H16.

Jan 4, 1915

By L. Edeleanu

Crude petroleum is a mixture of various groups of hydrocarbons and some bodies containing oxygen or sulphur.

Jan 1, 1915