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Recovery of Precious Metals from Chloride Solution by Magnetite The development of environmental-friendly lixiviants as alternatives to cyanide and the increasing recycling activities to recover precious metals from waste materials have prompted researchers to find efficient methods and alternative sorbents to recover precious metals, such as Au and Pt, from aqueous solutions. This study explored the use of magnetite (Fe3O4) as a sorbent to recover Au and Pt from chloride solutions. Magnetite is a semiconductor and has the capability of transferring electrons both within the solid state and across the solid-liquid interface and has the ability to reduce metal species on its surface. The sorption of AuCl4- and PtCl62- from NaCl solution on commercial grade magnetite powder was investigated by batch-sorption experiments. The effects of pH, contact time, NaCl concentration and precious metal concentration on the recovery were studied. Sorption experiments revealed that magnetite exhibited selectivity towards other metals with the strongest affinity for Au. Both Au and Pt recoveries showed similar pH dependence curves, with peaks at pH 6 - 7. At this pH range, a maximum of 4.4 ¦mol Au/g Fe3O4 and 3.0 ¦mol Pt/g Fe3O4 were recovered after 24 h at an initial metal concentration of 0.05 mol/m3. Increasing the initial precious metal concentration increased the Au and Pt uptake amount by magnetite. It was also observed that the recovery decreased with high NaCl concentrations. The SEM images of the magnetite particles after the treatment showed that gold, which was confirmed by the EDX analysis, agglomerated and were deposited on Fe3O4 surface.

Sep 13, 2010

By C. R. Palmer

The Bureau of Mines investigated the use of ion-exchange technology for the recovery of precious metals from cyanide leach and spent electrolytic solutions. This research included adsorption of gold and silver on both weak-and strong-base anion-exchange resins. The effects of nickel, mercury. and iron on precious metal loading of strong-base resins were also determined. Due to the nonselectlvity of strong-base resins, selective elution also was investigated. Both commercially available and experimental weak-base anion-exchange resins were tested. None of the commercial weak-base resins tested were suitable for a caustic-cyanide system owing to their low recovery of precious metals at pH 10 or above; however, three experimental resins have possible application. Continuous tests conducted with mill cyanide solution in a multicompartmented ion-exchange column using strong-base anion-exchange resins adsorbed nearly 100 pct of the precious metals as well as the iron and nickel. During the elution of this loaded resin the iron was first removed with NaCI plus NaOH; then nickel with dilute H2S04 or HCl; finally gold and silver with thiourea in dilute HCl.

Jan 1, 1988

By Roberto Giovanardi, Isabella Lancellotti, Luisa Barbieri, Ercole Soragni, Fernanda Andreola

"Recovery of precious metals (PMs) is a present topic, as they are used almost in every electronicelectric device. Gold is the second PM in order of consumption (following silver) and it is almost ubiquitary in electronics where it mainly finds application to produce bonding wires in integrated circuits and as a coating for contacts and connectors. Given this, discontinued electronic and, with a minor role, electric devices may represent a primary source of PMs as gold mines or jewelery wastes.At present the recovery of gold from such waste is generally accomplished by two strategies: by oxidative thermal treatment followed by metallurgical or chemical processes or by cyanide chemical etching; both techniques do not represent the optimum as the first one deserves a great amount of energy and non-combustible pollutant slag and fumes are produced, while the second procedure comports the use of a highly pollutant agent as cyanide.The aim of this work is the characterization of different electronics scraps to evaluate the gold concentration, and the selective recovery of this metal using enviromentally-friendly techniques. In particular, a new process was developed in order to overcome such environmental and efficiency issues. The process reaches the goal of detach the gold film from the substrate by selective leaching of the supporting metal.IntroductionThe treatment of waste from electrical and electronic equipments is a current topic as their role in modern life is increasing. The disposal of such waste represents both an environmental and an economical concern due to the vast amount of both precious and non precious metals.The use of precious metals (PM) in this field is of primary importance given PM’s unique properties, which give to each of them a specific and irreplaceable role. Silver is the most used, with a demand of over 5000 tonnes per year, mainly for switches and contacts in electric appliances. Gold is the second PM in order of consumption (over 250 tonnes per year and 8% of the total demand) and it is almost ubiquitous in electronics where it finds application to produce bonding wires in integrated circuits and as a coating for contacts and connectors. It is also used as solder in integrated circuits (in alloy with tin) or for wide coatings where it ensures protection against corrosion. Palladium, platinum, rhodium and iridium follow in order of consumption [1- 3]."

Jan 1, 2008

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By T. Wajima

Recovery of precious metals from hydrochloric solution using sulfur-impregnated carbonaceous adsorbent was examined. Sulfur-impregnated adsorbent with adsorption abilities of precious metals can be prepared from activated carbon using pyrolysis at 600 oC under 10 % H2S gas flow, and the adsorbed Au and Pd were precipitated as metal phase on the surface of the adsorbent. The adsorbents after precious metals adsorption were burned at 700 oC to obtain the residue mainly containing precious metals. The adsorbent was found to be highly efficient and selective for the uptake of precious metals, especially Au, in the presence of excess base metal ions from simulated spent automotive catalyst eluted solution using a column pack test. Keywords: Gold, platinum, palladium, reduction precipitation

Jan 1, 2020

By Andries Van Wyk, Steven Bradshaw, Guven Akdogan, Jacques Eksteen, Cornelius Snyders, Cleophace Mpinga

"In order to exploit lower grade and complex platinum group metal resources, cheaper and more efficient alternatives to the conventional mill-float-smelt-refine route are being sought, particularly for resources’ in areas that are water-scarce and where electrification is costly and problematic. Leaching with cyanide is a promising process option and although recoveries are lower than in the conventional process routes, progress into the understanding of cyanide leaching of PGM containing ore and concentrate has been made. Research regarding the feasibility of upgrading the pregnant PGM leach solution using activated carbon has, however, been lacking and hence forms the focus of this paper. Bottle roll adsorption tests for dilute PGM solutions (0.15ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) onto granular activated carbon showed high rates within the first 60 minutes (giving more than 90% recovery of precious metals). Comparison of the Pt isotherm to Au isotherms from literature indicated a similar loading capacity, while that of Pd was found to be significantly lower. The effects of solution pH, temperature, base metal concentration, free cyanide concentration, thiocyanate concentration, initial PGM concentration and activated carbon concentration were investigated and are discussed. Elution of the Pt and Pd, with the AARL elution process, was found to be effective with recoveries of 95% after 5 bed volumes of eluant at the optimum pre-treatment concentrations and a temperature of 80°C. Temperature, NaCN and NaOH pre-treatment concentration and the ionic strength of the eluant were found to be the most important factors affecting elution while base metals concentration, acid-pre-treatment, carbon loading and thiocyanate concentrations to a lesser extent. Simplified combined flow sheets are suggested and the corresponding mass balances are compared."

Jan 1, 2014

By S. K. Kawatra, T. C. Eisele

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. To reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, because different measures are required for reducing entrainment, locked particle flotation or true hydrophobic flotation. In this paper, evidence is presented that suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite; instead, the bulk of the recovered pyrite results either from simple entrainment or from being physically locked with floatable coal particles.

Jan 1, 1993

By S. K. Kawatra

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. In order to reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite, and that the bulk of the recovered pyrite is there either as a result of simple entrainment or by being physically locked with floatable coal particles.

Jan 1, 1991

By Harold L. Lovell

The current interest in sulfur recovery from coal measures is indicated by a recent report prepared for the Public Health Service (1) It was noted that the concentration of pyrites to a product containing 42-48 percent sulfur should be relatively easy with present equipment. It was also pointed out that a utility potential exists for the high-grade iron concentrate which results as a by-product of the consumption of pyrites in the acid-making process. However, economics, marketing characteristics, location, transportation, pyrite levels and coal characteristics all strongly influence the feasibility of fostering industrial development of such processes. The extent of pyrite recovery and product quality is intimately related to pyrite particle size and its degree of liberation, a consideration usually given greater emphasis in metal ore preparation than in processing coals. Consequently, fine crushing to nearly 20 mesh probably will be essential for maximum practical processing. It appears that any process separating pyrites from a coal must involve a reprocessing of the normal preparation plant refuse, although some yields can be attained from certain existing operations as products from, a shaking table or a jig. Further, the existence of millions of tons of coal refuse cannot be ignored as a mined source of raw materials. The recovery of saleable products from such wastes, although untried on a large scale under current conditions, not only offers a realistic source of sulfur but also would achieve a secondary refuse with the minimal contents of substances which incite and propagate the burning of organic and inorganic combustibles. These silicate materials, thus beneficiated, also offer some potential for economic utilization. Some significant tonnages of pyrites have been produced from coal measures in the past, but the experience was, in general, not consistent with current coal preparation practice. The processes involved did not include cyclones and heavy media; nor were they carries out under the sociological environment concerned with pollution as exists today.

Jan 1, 1967

By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018

By J. Karonen, M. Tiihonen, J. Guentner, L. Haavanlammi, Outotec GmbH, E. Kolehmainen

"Rare earth elements have obtained significant attention during the last few years due to predicted increase in their demand. Several projects worldwide are at pre-feasibility or feasibility stage aiming to commence production. Deposits of rare earth elements are typically complex and multi-metallic of nature. This means that production processes are often also complex and therefore, various metallurgical unit processes are needed. Outotec’s equipment and technology portfolio is very comprehensive and includes hydrometallurgical and pyrometallurgical apparatus and processes applicable to the efficient exploitation of rare earth deposits. Outotec has gained useful experience relevant to the processing of rare earths through several assignments including those for Alkane Resources Ltd. (Dubbo Zirconia Project), Greenland Minerals and Energy Ltd (Kvanefjeld Project), Frontier Rare Earths Limited (Zandkopsdrift project), Tantalus Rare Earths AG (Madagascar), Quest Rare Metals (Strange Lake project) and Orbite Aluminae Inc. (HPA project). The hydrometallurgical test work of two process flowsheets is presented in the paper. A roasting or acid baking step is common to several proposed rare earth projects. In the past, rotary kilns have been used, but Outotec has developed a new process concept to handle the rare earth material in fluid bed reactors. The basis for this development is long experience in fluid bed technology of Outotec in Germany. One advantage of fluid bed roasting is the higher throughput per unit. In combination with the roasting and baking, Outotec offers the gas cleaning and acid plant and provides a complete and closed concept.INTRODUCTIONRecovery of rare earth elements (REE) has obtained significant attention during recent years. It has been estimated that their demand will be boosted because of their need in many technology areas. REE can be utilized in magnets, batteries, displays, catalysts, optical devices etc. (Jordens, Cheng, & Waters, 2013; Zhang & Edwards, 2013). The production of REE is focused in China, which means that production outside of China is very scarce. However, there are multiple active development projects worldwide working towards production of REE containing products outside of China (Chen, 2011)."

Jan 1, 2016

By Shuqiang Guo, Xionggang Lu, Yuyang Bian, Weizhong Ding, Lan Jiang, Kai Tang, Changyuan Lu

For recovery of rare earth elements from the NdFeB based permanent magnet scraps, a high temperature process was used. Permanent magnets scraps were firstly oxidized in air. The optimal oxidation conditions under air are at temperature of 700oC holding for 30min. After the oxidation process, the oxides were reduced by graphite crucible at 1500oC under Ar atmosphere. By this way, the rare earth elements were recovered in the form of oxides, and Fe was separated to the metal phase. Boron distributed in both the rare earth oxides (REO) containing slag and the metal phase. In order to reduce the boron contents in the rare earth oxides, the carbon saturated iron bath and NdFeB added carbon saturated iron bath were used to refine the slag. By this process, the rare earth oxides with a comparatively high purity of 98.2% were gotten.

Jan 1, 2015

By Vinay Kumar, Manis Kumar Jha, J. Rajesh Kumar, Archana Kumari, Rekha Panda, Jin Young Lee

Rare earth metals (REMs) play a significant role in the manufacture of permanent magnets, fluorescent lamps, catalysts, medicines, super alloys etc. Recently, China, which controls 97% of world trade in REMs, imposed restriction on its export. Consequently, the global demand of REMs is escalating and is expected to exceed the supply by 40,000 tonnes annually. Present review paper reports the flow-sheets of commercial processes based on pyro-hydro and hybrid techniques as well as systematic research for process development to recover REMs from primary and secondary resources. This review paper also reports the recommendation and future prospective to fulfill its demand and supply gap keeping in view environmental prospective.

Jan 1, 2014

By Tatsuki Uzawa, Takashi Nagai

The consumption of Nd and Dy is increasing dramatically because of an exceptionally high demand for Nd-Fe-B-(Dy) magnets and a significant amount of the magnets are wasted. It is important to develop a recycle process the elements from the wasted magnets. In this study, Nd and Dy were extracted from the magnets by silver at high temperature. Nd can be extracted more than 70 % by silver. However, Dy is extracted only 25 % in the same experimental condition.

Jan 1, 2014

By D. DePaoli, P. Zhang

"Phosphate ore is one of the most significant secondary resources for rare earth elements (REEs), and Florida phosphate is of particular interest due to its much higher ratio of heavy REEs, especially yttrium. Analyses of numerous samples from different phosphate processing streams in Florida showed that heavy REEs account for about 50% of the total REEs in Florida phosphate with yttrium accounting for approximately 30%. It was estimated that the amount of yttrium from US phosphate processing could meet the world demand for this critical element. This research aimed at recovering both REEs and phosphorus from a phosphate flotation tails. This tails is composed of mainly silica and phosphate with a small fraction of heavy minerals including monazite and xenotime. Since the specific gravity of silica is 2.6 versus 3.2 for phosphate and 4.5-5 for rare earth minerals, pre-concentration of the minerals of interest by gravity separation was investigated first. A pilot scale shaking table was used in this study. One pass gravity concentration achieved a shaking table concentrate analyzing over 600 ppm REEs at about 40% recovery. Flotation of the shaking table concentrate resulted in a product containing 1809 ppm REEs and 26.37% P2O5 with corresponding recoveries of 73% and 82%. Sulfuric acid leaching at 75oC could recover over 60% REE and nearly all the P2O5. Higher REEs (>90%) recovery was achieved by conducting leaching at higher temperature with concentrated sulfuric acid. The phosphoric acid from leaching of the flotation concentrate is of superior quality compared with that generated from regular phosphate rock.INTRODUCTION Rare earths are a group of 17 elements including those of the lanthanum series, as well as the non-lanthanides, yttrium and scandium. These elements have very specific critical uses in a multitude of markets. For example, lanthanum is used as a catalyst in breaking down crude oil to produce gasoline, diesel and jet fuel and neodymium is the core magnetic component in high-strength magnets for electric car batteries, wind turbines and hard disk drives. Rare earths are also essential for many military applications. Many of these applications have no substitute materials and the move to green technologies has dramatically increased their demand."

Jan 1, 2018

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By Jae-Chun Lee, Jinki Jeong, Manis Kumar Jha, Divika Gupta, Pankaj Kumar Choubey

Rare metal indium (In) is mostly used as electroluminescent material in liquid crystal displays (LCD) monitors. Present paper describes leaching studies for the recovery of In from waste LCD monitors in presence of different other impurities. The leaching studies showed that more than 85% of In was leached out using 20% sulfuric acid at 60oC in mixing time 30 min at fixed pulp density 25 g/L. The solution could be purified using SX/IX and from the pure solution metal/ salt could be produced by evaporation, precipitation, electrolysis, crystallization processes.

Jan 1, 2014

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By B. J. Jody

Each year, about 11 million tons of metals (ferrous and nonferrous) are recovered in the U.S. from about 10 million discarded automobiles. The recovered metals account for about 75% of the total weight of the discarded vehicles. The balance of the material or shredder residue, which amounts to about 3 million tons annually, is currently landfilled. The residue contains a diversity of potentially recyclable materials, including polyurethane foams, iron oxides, and certain thermoplastics. This paper discusses a process under development at Argonne National Laboratory to separate and recover the recyclable materials from this waste stream. The process consists essentially of two- stages. First, a physical separation is used to recover the foams and the metal oxides, followed by a chemical process to extract certain thermoplastics. The status of the technology is discussed, and the process economics are reviewed.

Jan 1, 1994