Search Documents

This geometallurgical study examines the gangue mineral variability at the Bingham Canyon porphyry copper mine in Utah. Understanding an orebody?s mineralogy is important for mine and mill planning because it provides information on the size, texture, and distribution of ore minerals, the relationship between ore and gangue minerals, and the extent and type of alteration. Quantification of the mineralogical variability and properties of an orebody provides valuable input to the ore model and may have a significant effect on recovery optimization. This study was designed to be carried out on an initially detailed scale in order to develop a robust methodology for measuring and quantifying specific parameters, such as the distribution of mineral phases, alteration assemblages and fractures from key ore domains at the Bingham Canyon mine (Figure 1). Details of the methodology are reported below. This technique can be applied to testing the impact of mineralogy on a number of processing parameters. [ ] Figure 1. Ore domain map of Bingham Canyon (Kennecott Utah Copper, 2003) showing the 33 geometallurgical ore domains. The samples for this study were collected from the northwest part of the deposit circled on the map. PROJECT BACKGROUND Geology The Bingham Canyon deposit is a large porphyry Cu-Mo-Au deposit with associated skarn and base-metal replacement deposits mined in an open-pit mine measuring about 2.5 miles across and 4,000 feet deep. The deposit is hosted by the Bingham Stock, a Late Eocene to Mid-Oligocene intrusive complex. The skarn is hosted by the Late Carboniferous-age Bingham Mine Formation, which is comprised of quartzites and basal limestones (Babcock Jr. et al., 1998). The Bingham Stock is a composite intrusive complex that was emplaced over a period of about two million years. The oldest phase is described as a fine-grained equigranular monzonite (MZ), which intruded the country rocks at 39.8 ± 0.4 Ma (U-Pb zircon TIMS age) (Parry et al., 2001). Subsequently, the quartz monzonite porphyry (QMP) was emplaced, followed by intrusion of a latite porphyry (LP). The final intrusive phase, which forms narrow dikes that crosscut the Bingham Stock, is represented by a quartz latite porphyry (QLP), which is dated to 37.5 ± 0.4 Ma by 40Ar/39Ar dating of sanidine (Deino and Keith, 1998). Also present, are a minette dike in contact with a QLP dike (Waite et al., 1998; Deino and Keith, 1998), and a biotite porphyry (BP), a quartz latite porphyry breccia (QLPbx), and a pebble dike (Redmond, 2002). The copper orebody is centered above the Bingham Stock and forms an inverted cup shape with three high-grade copper zones extending to depth. Molybdenite mineralization occurs within and extends below the copper orebody, but is not correlated with copper mineralization. The main sulfide assemblage is chalcopyrite, bornite, molybdenite, and pyrite. Gold is locally intergrown with chalcopyrite and bornite (Babcock Jr. et al., 1998; Phillips et al., 1998). The surrounding country rocks host skarn deposits with three main ore types - garnet skarns, massive sulfides, and iron oxides. The garnet skarns contain chalcopyrite and pyrite with magnetite veins. In the massive sulfides chalcopyrite and pyrite occur either in banded sulfides or in unconsolidated microbreccias. The iron oxides contain disseminated chalcopyrite with minor chalcocite and bornite (Harrison and Reid, 1998). The deposit is overprinted by several stages of alteration. Potassic alteration is concentrated at the center of the deposit. It is surrounded and partially overlapped by a propylitic alteration zone. Both zones are overprinted by sericitic alteration. In the northern part of the deposit evidence for argillic alteration can be found (Bowman et al., 1987). Similarly, the skarn deposit was also overprinted by several stages of alteration: wollastonite, idocrase, and garnet in cherty limestones, and quartz and diopside forming in calcareous quartzites. Distally, diopside was replaced by talc, tremolite, dolomite, secondary calcite, and pyrite, and quartz and sulfide veinlets with biotite and actinolite selvages are present. Andradite garnet, diopside, quartz, magnetite, hematite, and copper sulfides were overprinted by wollastonite (Babcock Jr. et al., 1998). Because the monzonite, quartz monzonite porphyry, latite porphyry, and quartz latite porphyry host the bulk of the mineralization, our research is focused on these lithologic units. Geometallurgy On the basis of geological (lithology, alteration assemblages, fracture density, copper mineralization) and metallurgical properties, the deposit has been divided into 33 ore domains by mine geologists and metallurgists (Figure 1). In map view, these domains cross geologically defined boundaries (MZ, QMP etc.). These domains reflect regions of the deposit that have particular, mapable attributes or properties. They reflect a combination of geological and mineralogical characteristics that combine to impact processing. Alteration, for example, as shown by talc mineralization, is one such key feature. Hardness may reflect the absence of sericitic but presence of potassic alteration. Structural discontinuities such as faulting, fracturing, or development of void

Jan 1, 2009

By W. M. Tuddenham, R. J. P. Lyon

In many areas surrounding the orebodies in mining districts rocks have been bleached and altered by the ore-forming solutions and have been oxidized during later weathering processes. A number of the rock-forming silicates have been broken down to clay, sericitic micas and chlorites have been developed, and pyrite may be found hundreds of feet outside the economic limits of the orebody. These halos of altered ground are prime targets used by geologists in many districts to delineate promising sites for drilling. Both in the field and in the laboratory it is often difficult to map these mineralogical changes in the halos in detail without numerous petrologic examinations. The secondary minerals are generally fine-grained, and since conversion of one mineral to another is often progressive, many alteration processes have not proceeded to completion (feldspars to clay to sericite mica). Qualitative detection of these minerals is difficult; quantitative determination is frequently impossible.

Jan 12, 1959

By M. B. Sizgoric

Quantitative mineralogy is used in a study done on an Inco Metals Company nickel sulfide occurrence from 'the Thompson area in Northern Manitoba. The study included: a) determination of the variations in chemical composition of the ore minerals; b) determination of the liberation of the ore minerals for the various types of ore and for different feed grinds; c) assessment of the preliminary mill test results by comparing the mineral distribution in the different tailings. Preliminary mill test results had outlined three main problem areas: 1) unacceptabiy low grade concentrate with, 2) very high weight recovery and, 3) low pyrrhotite rejection resulting in a high sulfur concentrate. The mineralogical study readily explained these results by showing that: 1) between 20 and 40% of the nickel in the feeds and 55 and 75% of the nickel lost in the tailings is associated with pyrrhotite. This accounts in part for the low grade of the concentrates obtained at high recoveries: 2) hexagonal nonmagnetic pyrrhotite constitutes over 90 percent of pyrrhotite. Since hexagonal pyrrhotite floats more readily than monoclinic pyrrhotite, this could be part of the reason for the undesirable high pyrrhotite recoveries into the concentrates. Further test work to establish both the optimal grind and the best conditions for pyrrhotite rejection is therefore mandatory.

Jan 1, 1981

By R. S. Fitzpatrick, P. Hegarty

"Gravity separation is a key technology in the recovery of a range of mineral ores including coal, tin, tungsten and tantalum. One of the problems associated with gravity concentration is that recovery is traditionally lower than for other separation techniques such as the flotation of base metals. Any improvements in recovery will, therefore, have a significant effect on the economics of operations of this type. More accurate, robust modelling of gravity separators is one means of achieving greater recoveries. Furthermore, better modelling can lead to more informed equipment selection and process design for potential economic deposits.Previous models for gravity separation equipment have typically relied on simple metal mass balances from samples of the separated products. However, with advances in technology there is a ready availability of analytical instruments for the automated quantitative determination of mineralogy. Instruments such as the Mineral Liberation Analyser and QEMSCAN make it possible to estimate particle size and density (related to mineral liberation and association) which are the primary factors in gravity separation. Models produced using quantitative mineralogy of feed streams will be potentially superior to those produced historically.This paper describes test work undertaken on a wet shaking table using a synthetic ore. The objective of this test work was to develop a model to predict the effect of changes in feed ore characteristics on shaking table performance by measuring quantitatively the mineralogy of the feed material. Particles were divided into size/density classes based on the results of QEMSCAN analyses.It was found that it was possible to use data from QEMSCAN to predict the recovery of size/density classes and to predict the effect of changes in the relative abundances of these classes on the separation. This model can potentially be used to adjust operating variables to maximise grade and recovery by monitoring the input feed. Care was needed when utilising QEMSCAN data to ensure representivity."

Jan 1, 2016

By T. Bhambhani, O. Yavuzkan, D. R. Nagaraj

"The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors is the widely used technique. CPS has certain limitations: a) inability to recover certain oxide Cu minerals because they are refractory to sulfidization, b) high consumption of NaSH (or Na2S), and c) potential health and safety hazards associated with NaSH (and Na2S). Flotation of oxide copper minerals using alkyl hydroxamate (AHX) collector has been studied extensively. Investigations using single minerals and laboratory ore flotation have been conducted in the past to demonstrate the efficacy of alkyl hydroxamates. The technology has been used intermittently in plants. One of the main challenges in plant use has been quantifying the true potential for alkyl hydroxamates for recovery of various oxide Cu species in complex and variable ore systems and identifying the most suitable conditions for optimal use. Quantitative mineralogical analysis using QEMSCAN was used in this study to characterize flotation products lab flotation samples. Analysis of concentrates and tails from hydroxamate flotation and CPS flotation stages demonstrated that certain oxide Cu minerals respond exclusively to alkyl hydroxamates and not to CPS. The hierarchy of interaction of AHX with the various oxide Cu minerals could be inferred from these studies. Finally, these studies also allowed quantification of a group of minerals species, which (erroneously) report as part of the Acid-Soluble Cu [ASCu] but cannot be recovered by flotation, thereby facilitating an estimation of the true recovery potential for alkyl hydroxamate.INTRODUCTIONCopper that is economically recoverable occurs in three major types of ores, which are defined by the modal mineralogy of Cu. For sulfide ores, Cu occurs as sulfide minerals and is satisfactorily recovered by flotation using sulfide collectors. Non-sulfide ores, which contain Cu in the form of oxides, phosphates, carbonates and silicates, described in the industry as “oxide” ores (or ores containing “acid-soluble” Cu or ASCu), are currently treated using hydrometallurgy, which involves leaching with dilute sulfuric acid followed by solvent extraction and electrowinning, unless the ores contain acid consuming gangue minerals such as dolomite. For mixed sulfide-oxide ores (i.e. containing both sulfide and oxide Cu minerals) that do not contain acid consuming gangue minerals, Cu values are easily recovered by flotation of sulfide Cu minerals followed by leaching of oxides (only when a leach plant is available). However, when the ore contains acid consuming gangue minerals flotation is required to recover both sulfide and oxide Cu minerals."

Jan 1, 2018

By S. Suzuki, C. Tokoro, S. Owada, T. Sakakibara

Acid mine drainage (AMD) has been actively treated by neutralization from about 80 abandoned or closed mines in Japan. More efficient and cost effective treatment processes has been demanded for AMD due to the government investment of billions of yen every year to protect the environment from these discharges. In this study, quantitative modeling was conducted for actual AMD to predict pH or residual concentration of toxic elements after neutralization/co-precipitation process. Simple chemical equilibrium calculation was not adequate for quantitative prediction of pH after neutralization, because residual concentration of major elements of AMD, such as Fe or Si, could not be quantitatively calculated. When oxidation rate of Fe(II) to Fe(III) and precipitation rate of kaolinite were added to the model, quantitative prediction of pH and Fe or Si concentration was achieved. Surface complexation at the interface between hydroxide such as ferrihydrite or aluminum hydroxide and AMD was the most important mechanism for removal of dilute toxic ions. When surface complexation model at the interface of ferrihydrite was added to the model, residual As (V) and Pb (II) concentration after neutralization/coprecipitation process was successfully calculated. On the other hand, surface complezation model of aluminum hydroxide was also necessary for quantitative prediction of residual Zn(II) concentration after neutralization/co-precipitation process.

Jan 1, 2014

By S. Hobo, M. Yagisawa, T. Uchida, C. Tokoro, T. Kato

In this study, quantitative modeling was carried out for the treatment of simulated waste water containing As(V), Zn(II) and Hg(II) as toxic elements, and Fe(III), Na(I) and sulfate as coaxing ions. The objective was to predict the pH and residual concentrations of all the elements in solution after the neutralization/co-precipitation treatment. To accomplish this, the removal mechanism for As(V) and Hg(II) by ferrihydrite precipitation was first investigated for simulated waste water containing only As(V) or Hg(II). From the experimental results, it was confirmed that the removal mechanism involves not only surface complexation but also surface precipitation. However, surface complexation is the main mechanism for As(V) and Hg(II) removal to meet the target levels regulated in Japan. Next, the surface complexation model was constructed for the removal of As(V) and Hg(II) by ferrihydrite. The specific surface area and site density were determined from reference values proposed by Dzombak and Morel (1990). By comparing the experimental and calculated results, it was confirmed that our constructed model could successfully represent the experimental results. Furthermore, the surface complexation model was coupled with chemical equilibrium calculations and applied to the neutralization of simulated waste water containing As(V), Hg(II), Zn(II), Na(I), Fe(III) and sulfate. The constructed model could successfully represent the pH edge for As(V), Hg(II), Zn(II), Fe(III) and SO42- removal. In addition, the constructed model could represent the ion balance. Thus, our constructed model is useful to estimate the amount of neutralizer that is needed to achieve a target pH.

Jan 1, 2016

By P. C. Lightfoot, J. M. Duke, A. J. Naldrett

"The segregation of magmatic sulphides from mafic and ultramafic silicate magmas, in many circumstances, leaves the magma with a lower-than-normal Ni/MgO ratio, which is characteristic of both lavas erupted from the magma chamber and olivine crystallizing within it. Two end members of the segregation process are discussed; i) batch segregation and ii) fractional segregation.In the former, the critical factor is the magma/sulphide ratio. Computer modelling suggests that where this ratio has been less than 1000, the magma will be recognizable as anomalously low in Ni, due to sulphide segregation, and thus a good target for exploration. In fractional segregation, the critical factors are the proportion of sulphide to silicate being segregated and the degree of fractionation.Samples believed to represent the liquid portion of komatiitic lava f lows from a series of unmineralized sequences in the Abitibi greenstone belt, Canada. Belingwe belt, Zimbabwe, and Barberton Mountainland, South Africa coincide with the sulphide-free fractionation model. They are in marked contrast to samples from the ore-bearing districts of Kambalda and Scotia. Western Australia in which distinct Ni depletion, corresponding to fractionation of olivine plus sulphide in a ratio of between 100 and 200:1 is recognizable. Ni-depleted olivines also mark the sulphide-bearing Dumont intrusion of the Abitibi belt.The Moxie intrusion of northern Maine has distinctly Nidepleted olivines, as does the nearby and petrologically related Katahdin body. In both of these intrusions, the composition of the olivine allows reasonable predictions to be made of the Ni tenors of sulphide showings within them. At Katahdin, the Ni depletion is so widespread that little hope is help out for the presence of economic concentrations of sulphide. At Moxie. the olivine compositions suggest that the best chance of economic sulphides lies in the southern lobe of the intrusion.Ni-depleted olivines also characterize certain rock units within intrusions of the Insizwa complex, Transkei, Southern Africa. Many millions of tonnes of Ni have apparently been removed by sulphides from these rock units, many more than are contained within the single mineralized occurrence so far identified at Waterfall Gorge."

Jan 1, 1984

By James D. Bliss

Evaluation of data for three engineering variables-absorption, bulk specific gravity, and freeze-thaw durability (350 cycles)-was made for quarries in carbon- ate rocks in Oklahoma that supply aggregate. It was found that lower Paleozoic carbonate rocks (Cambrian through Devonian) are likely to make a better quality aggregate than upper Paleozoic (Mississippian to Permian) carbonate rocks. In addition, freeze-thaw durability can be forecast from absorption and is exemplary for lower Paleozoic carbonate rocks.

Jan 1, 1999

By Reynold Q. Shotts

Nitric acid oxidation rate analyses of three coals, previously studied microscopically by the Bureau of Mines, revealed three components. Relative quantities agree with those found for the four components given by the Bureau and results are consistent with current ideas of coal constitution. Possible multi-component composition for bright coal and a reactivity-rank relation are suggested.

Jan 5, 1953

By S Lehane, S Pearce

The characterisation and assessment of waste rock has been the subject of considerable research, and many guidance documents have been published both internationally and within Australia. While these documents provide detailed information on how to characterise waste rock, there is not a great amount of detail on how to determine the optimal waste management options from an operational viewpoint. For example, typical questions that a mine operator would seek answers to include: What placement method should be used (eg end tipping versus paddock dumping)? What is an optimal tip head height for waste placement in a storage facility? How should sulfide grade control be carried out?Defining the contributing factors to waste management and waste material placement and assessing the contribution of each variable directs these assessments towards a semi-qualitative and quantitative methodology. Quantitative methodologies show an increase in the confidence of these assessments by providing logical, measureable assessments.As part of a strategic assessment for waste management at an active mine site, a detailed risk-based investigation of the influence of variables common to waste placement was completed. These variables included placement method, placement height, sulfur grade and material conditioning (eg compaction) on the associated risks of waste material storage. The assessed risks include temperature assessments (potential for thermal take-off as a result of spontaneous combustion), toxic gas production and flow and acid production potential. Applying a numerical modelling approach to the assessment of the different waste material placement strategies allows for the variation in risk to be graphically presented and communicated through risk matrices and histograms.CITATION:Pearce, S and Lehane, S, 2015. Quantitative risk assessment tools to assist with waste management and placement guidelines, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 353–364 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By F. Essrich

A quantitative rockburst hazard assessment procedure was introduced on Elandsrand Gold Mine at the end of 1994. It is currently used to evaluate the seismicity-related risk in production areas on the mine. Six parameters related to seismicity, geology, mining layout, and production are rated and results are used as a planning tool on a regular basis. The applied assessment can be considered successful in that it promotes awareness of the seismic hazard and provides an opportunity to address seismicity-related mining problems. A comparison between high risk panels and those working areas with rockburst incidents showed that high hazard ratings reliably forecast the occurrence of larger events in the following month but they do not necessarily predict those working places with rockburst-related accidents. From this one may conclude that high levels of seismicity do not coincide with high rockburst rates.

Jan 1, 1997

By Lester W. Strock

METALLURGISTS handling lead and zinc ores have long been familiar with the spectrograph as a routine analytical tool, as its earliest regular use by American industry was in controlling impurities of zinc metal and its alloys. This application has been extended to other metal industries on an extensive scale, accompanied by refinements of procedure to such an extent that a large part of some metals produced, especially magnesium, aluminum and steel, are checked only by spectrographic methods for conformity to specifications. The spectrographic analysis of ores and other poorly conducting powdered solids presents difficulties not encountered with metallic samples, which can be arced or sparked as self-electrodes or can be readily dissolved, so that their solutions can be analyzed, as in the American Society for Testing Materials standard methods for zinc and zinc-base alloys. Spectra of powdered solid samples can be prepared by using carbon electrodes provided with a crater of suitable size, into which the sample is packed. Ore samples and many other powdered solid materials usually analyzed in the chemical and metallurgical laboratory are more complex and varied in composition than samples of metals produced in large tonnages. More preliminary work therefore is usually necessary in devising a spectrographic method for analyzing a given type of powdered sample than for analyzing metal samples, in order to use that method with confidence. The knowledge that the standard samples and unknowns produce equivalent line intensities at equal concentration is the fundamental basis of any quantitative spectrographic method. On the other hand, powdered samples have an advantage over metals in that any desired number of chemical compounds can be mixed dry in any desired ratio to produce a synthetic standard. Experience has shown, however, that spectra of elements in finely divided compounds introduced into a standard in preparing a synthetic ore sample do not always behave in the electric arc in a manner that produces spectral line intensities similar to those observed at the same concentration in a natural mineral. In ore samples minor elements frequently are contained in the crystal lattice of larger particles of an abundant ore mineral. Their dissociation and volatilization from the sample into the arc then proceeds differently in the standard and sample, with resultant differences in intensity. During the past 10 years I have devised and applied several quantitative spectrographic methods for determining various elements in rocks and minerals in connection with studies on their geochemistry,1 but the incentive has gradually changed since the summer of 1940 to the specific practical problem of searching for domestic sources of rare and strategic metals. The

Jan 1, 1945

By F. Twyman

PART I.-QUALITATIVE, SPECTRUM ANALYSIS THOSE chemists (they are still greatly in the minority) who use the spectroscope, use it very often, and find it almost indispensable. As a means of detecting minute quantities of the metals it is unrivalled. A metal can be readily distinguished in the presence of any other element, compound, or mixture without the necessity of separation. The qualitative analysis of the metallic constituents of a substance, which, the spectroscope gives so easily, is a sure basis for planning a chemical analysis. As the determination of each element proceeds the purity of precipitates maybe checked as often as desired. If, possessing these advantages; the spectroscope has been neglected in general chemistry, it is not surprising that it was neglected in metallurgical chemistry; for many of the impurities which are of industrial interest, even when they are present in a metal or alloy in small quantities, are not then always easily detected by the examination of their visible spectrum. The history of the development of the art has been given in Bureau of Standards Scientific Paper No. 444.

Jan 1, 1928

By F. Twyman, D. M. Smith

THOSE chemists (they are still greatly in the minority) who use the spectroscope, use it very often, and find it almost indispensable. As a means of detecting minute quantities of the metals it is unrivalled. A metal can be readily distinguished in the presence of any other element, compound, or mixture without the necessity of separation. The qualitative analysis of the metallic constituents of a substance, which the spectroscope gives so easily, is a sure basis for planning a chemical analysis. As the determination of each element proceeds the purity of precipitates may be checked as often as desired. If, possessing these advantages, the spectroscope has been neglected in general chemistry, it is not surprising that it was neglected in metallurgical chemistry; for many of the impurities which are of industrial interest, even when they are present in a metal or alloy in small quantities, are not then always easily detected by the examination of their visible spectrum. The history of the development of the art has been given in Bureau of Standards Scientific Paper No. 444.

Jan 1, 1928

By S Wan, F Zhang, J You, K Tang, X Tang, C Bessada, A Canizarès, Q Zhang, L Lu

Microstructure of CaO-SiO2-based glassy samples with various Al2O3 contents were examined quantitatively by Raman spectroscopy and 27Al MAS NMR (magic-angle spinning nuclear magnetic resonance). Sequence of multiple cluster models of aluminosilicate system modified with Ca2+ and Na+ cations have been designed, and Raman spectra simulation were carried out after geometric optimisation by quantum chemistry (QC) ab initio calculation. The functional relationship between Raman scattering cross-section (RSCS) and stress index of silicon-oxygen tetrahedron (SIT) for aluminosilicates was established, which was applied to the calibration of experimental Raman spectra. Some five-fold coordinated aluminium (AlV, around 5 per cent) and less than 2 per cent sixfold coordinated aluminium (AlVI) were detected by 27Al MAS NMR, while most of aluminium remained in tetrahedral sites (AlIV). The hyperfine quantitative results of Raman spectroscopy and NMR showed a gradually production of AlIV with addition of Al2O3, along with the significant adjustment of Qi species distribution, in which Q1, Q2 reduced and fully polymerised Q4 increased while Q3 showed a non-monotonic variation and obtained the maximum at Al2O3 = 18 mol per cent. Furthermore, the effects of aluminium to bridging oxygen bond types (T-Ob, T = Si, Al) and the degree of polymerisation were also discussed in detail. The evolution of microstructure and its correlation with the viscosity of CaO-SiO2 based melts, incorporating various Al2O3 additives, have been investigated by employing in situ high temperature Raman spectroscopy at 1823 K and viscosity model. These structural features related to composition are essential theoretic foundation to understand their properties. The average Qi evolution culminates in an overall enhancement of the degree of polymerisation. Viscosity was determined utilising a rigorously selected viscosity model, elucidating a consistent upward trajectory as Al2O3 content is incrementally added. Furthermore, a quantitative analysis of the relationship between viscosity and structure was conducted based on the average number of non-bridging oxygen per network-forming tetrahedron (NBO/T). It provides valuable insights for examining and predicting viscosity behaviour of aluminosilicate systems.

Aug 21, 2024

By A. P. I. Popoola

Aluminium AA1200 was laser alloyed with a combination of nickel and titanium diboride using different weight ratios. Chemical reactions took place with the formation of different phases. The characterization of the alloyed surfaces was carried out by x-ray diffraction (XRD), optical and scanning electron microscopes. The alloyed surfaces are composed of the initial phase of Al-Ni dendrites and eutectics of TiB2/Al and TiB2/Ni distributed on the initial phase. Experimental results obtained showed that Al-Ni intermetallics brought about a significant increase in the hardness property of Al; however, these intermetallics are highly brittle and prone to fail by brittle fracture or stress corrosion cracking when put in service. The addition of TiB2 brought about a reduction in the formation of the seintermetallic phases. A microhardness increase of over 10 times the hardness of the substrate was achieved. Keywords Dendrites, intermetallics, metal composite, Nd: YAG laser.

Jan 1, 2011

By John R. Wynnyckyj

Results of correlations between strength-development and sintering shrinkage occurring during induration are presented. A mathematical treatment of the shrinkage kinetics is, next, given and is based on the use of semi-empirical equations. The discussion stresses the significance of kinetic constants and activation energies in the assessment of iron ore concentrates for pelletizing and induration. Next, starting with the assumption that there is a need for parameters to characterize the iron-ore concentrates and relate these parameters to shrinkage-kinetic constants and balling behaviour, results of compaction measurements and pore structure characterization (mercury porosimetry) are presented and discussed.

Jan 1, 1977

By B. K. Bhattacharyya, Morley. L. W.

"The primary purpose of conducting aeromagnetic surveys in mineral areas, and interpreting the data thus obtained, is to aid in the extrapolation of the geology from known to unknown areas-both in a horizontal and vertical direction. This paper describes one of the steps in the process of interpretation which has, in the past, been neglected-that of mathematically or quantitatively treating the data in two-dimensional map form. For this, several techniques are available.These techniques determine the downward and up-ward continuation fields, the second vertical derivatives and the fields reduced to the pole from the total magnetic field data. Second vertical derivatives and downward continuation fields increase the resolution and sharpness in the observed magnetic anomalies and tend to outline the surface traces of causative bodies with a reasonable amount of success in most cases. The 'reduction to the pole' is a mathematical process of calculating the field at the north pole from the observed field so that the un-desirable effects of the dip and declination of the earth's field and of rock magnetization are eliminated.New and accurate means of carrying out these calculations have been developed by the Geological Survey of Canada. In this paper are also presented the results of a method for obtaining the symbol and numerical map of the processed data with the help of the printer associated with the computer. The tedious work of digitizing magnetic field values in a map can be speeded up by the use of a semi-automatic coordinatograph, with the aid of which field values can be accurately transferred to punched cards."

Jan 1, 1966

By R. S. Shoemaker, D. L. Harris

Past investigations into the possibility of concentrating the low-grade iron ores of the Gogebic Range in Wisconsin have been hampered by the complex association of the constituent minerals. In part the problem arises from the fact that the iron occurs essentially as two minerals, hematite and goethite, having nearly the same chemical composition but exhibiting different physical properties. Individual grains of these minerals are usually so small that the ore must be ground to a size finer than 325 mesh if substantial liberation of the minerals is to be secured. Appraisal of beneficiation tests on this iron ore requires, therefore, some method of determining quantitatively the contents of constituent minerals in the various products of the beneficiation. Because of the chemical similarity of the two iron minerals, chemical analyses do not provide a means of differentiation. Although the minerals are different physically, they are both opaque and friable, and as the ore must be ground to a very fine size for liberation to be secured, quantitative microscopic methods of analysis are extremely difficult at best. In an effort to overcome these analytical problems, a quantitative X-ray diffraction analysis method has been developed at the University of Wisconsin for the research program on iron ore beneficiation.

Jan 5, 1955