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By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980.s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão - GO), Bunge (Cajati - SP), Fosfértil (Tapira - MG) and Copebrás (Catalão - GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By Charles Hart

THE art of electric smelting came with the turn of the present century and owes its existence to the introduction of alter-nating current, which found its first wide use in the establishment of the great power plants at Niagara Falls, N, Y. Prior to that time current was largely direct. The fur-naces were electrolytic in nature and found their first metallurgical use in the produc-tion of aluminum, and this process still prevails. The normal production of pig iron up to that time was carried on in blast furnaces in which charcoal, coke and anthracite were used as the fuel. This new electric process called for sufficient carbonaceous material to reduce the oxides and impregnate the pig iron with sufficient carbon, but the remainder of the energy was to be supplied by electric power. The chemical reactions are essentially the same in electric smelting as obtains in the older blast furnace. All of these data are so well known in both methods as to need no discussion at this time, for they can be found in scientific publications and books written during the first two decades of this century.

Jan 1, 1940

By A F. Kravic

Carbonyl nickel powders of irregular particle shape and low a11parent density are used extensively in the production of porous nickel electrodes for nickel-cadmium storage batteries and hydrogen-oxygen fuel cells employing alkaline electrolytes. Such porous nickel matrices are at-tractive for these intended applications as they are relatively inexpensive, are corrosion resistant, have good electrical conductivity, can be welded to form electrical contacts, have a long life (as demonstrated in alkaline storage batteries), and are rugged and vibration and shock resistant. This paper describes a feasibility study concerning the production of porous multi-layer nickel electrodes by the pressing and sintering of stacked layers of green-powder rolled nickel sheet. Background H AUSNER (1) conveniently listed nine different powder compaction processes used for forming metal powders into useful shapes. These are shown in Table I. There are additional powder metallurgy processes; however, most of these are combinations of two or more processes listed in the Table. A study of the literature revealed that every powder compacting process, with the exception of isostatic pressing and explosive forming, has been evaluated or is being used for the manufacture of porous metal electrodes.

Jan 1, 1965

By R. Q. Honaker, D. P. Patil, A. Sirkeci

Because of increasing production of fine coal during mining over the past century and because of inefficient fine-coal recovery technologies, a vast reserve of high-quality coal now exists in refuse ponds. A novel finecoal circuit, consisting of a hindered-bed classifier, an enhanced gravity concentrator and a flotation column, was evaluated for the recovery of fine coal from refuse ponds. The treatment of a pond derived from Pittsburgh No. 8 seam coal resulted in the production of a premium fuel containing less than 5% ash and a calorific value of about 30,170 kJ/kg with 60% mass yield. Results from the treatment of two refuse pond materials are presented in this paper.

Jan 1, 2002

By R. Q. Honaker, D. P. Patil, A. Sirkeci

Due to increased production of fine coal during mining during this century and inefficient fine coal recovery technologies, a vast reserve of high quality coal currently exists in refuse ponds. A novel fine coal circuit consisting of a hindered-bed classifier, an enhanced gravity concentrator and a flotation column has been evaluated for the recovery of fine coal from refuse ponds. The treatment of a pond derived from Pittsburgh No. 8 seam coal resulted in the production of a premium fuel containing less than 5% ash and a calorific value of about 30,173kJ/kg with 60% mass yield. The results from the treatment of two refuse pond materials will be presented in this publication.

Jan 1, 2000

By R. Hammen

Processes are needed to rapidly and cost-effectively produce highly pure lithium salts for the rechargeable battery sector. Lithium purification is a chemical engineering challenge, due to the low concentration of lithium compared to sodium, potassium, magnesium, calcium, and transition metal ions commonly occurring in lithium brine resources. We describe a Solid Phase Extraction (SPE) process that rejects sodium and potassium, while binding lithium and other higher valent ions. Lithium is then harvested by selective displacement from the SPE column. The rapid equilibration kinetics of SPE composites enables these ion separations to occur in a small SPE column and in one column stage. The chemical parameters of the process are described.

By Yavuz Ali Topkaya

Rare earth ferrosilicide is a versatile alloy mainly used to control the detrimental effects of sulfur in steel and to modify graphite structures in cast iron. The aim of this study was to determine the optimum conditions to make rare earth ferrosilicon alloy using a preconcentrate produced from a bastnasite type of ore present in the Beylikahir-Eskisehir region of Turkey. This concentrate contained 23.5%REO, 41.37% CaF2, 10.69% BaSO4, 8.50% CaCO3, 4.18%Fe2O3, 2.83% Al2O3, 2.74% SiO2, 1.20% P2O5 and small amount of other oxides. The initial metallothermic reduction of this concentrate using ferrosilicon and aluminum in a graphite crucible placed in a muffle furnace gave very low recoveries due to the difficulties encountered in adjusting the slag composition, temperature and amount of additives. Therefore, two batches of rare earth oxide concentrate containing 61.1% and 81.7% cerium oxide, respectively, that were procured from a Turkish glass producer, were used to optimize with respect to temperature, duration, slag-making additives and amount of reducers. In these experiments, smelting and reduction was done in an induction furnace with graphite crucible, and, ferrosilicon and aluminum were added after melting the charge. As a result, there was no difficulty in obtaining a rare earth ferrosilicon alloy containing 35-55% RE, 5-25% Fe and 20-40% Si, with about 80% metal recovery. When the optimum conditions were applied to the preconcentrate, alloys of similar compositions were obtained with 70-80% recovery. Experiments were also done with mixtures of preconcentrate and rich concentrate, and, recoveries as high as 95% were obtained. Only in this case, to increase the recovery, mixtures had to be charged to the empty graphite crucible after heating the crucible to the required temperature.

Jan 1, 2006

By P. S. Seryogin

R & D works supported by industrial-scale tests, which were carried out by joint efforts of the OAO Gipronickel Institute and MMC ?Kola? engineers, have accomplished with the production of 90?95% metallized nickel powder in tube furnaces (NPTF), with its ?active fraction? (AF) to be further used for decopperization of nickel electrolyte by cementation. Consistently positive results obtained in the course of the lab and industrial experiments have allowed the Severonickel Combine management to effectively replace all activated nickel powder (ANP), which was then employed for cementation, with the AF, having activity over 80%, and eventually shut down the entire operation of gaseous reduction. Ever since the developed technology has been implemented, its annual economic effect exceeds 2 ml. dollars.

Jan 1, 2006

By Jorge A. S. Tenorio, Girley F. Rodrigues, Joner O. Alves, Denise C. R. Espinosa

"Rock wools are mineral fibers composed of amorphous silicates, due to their thermo-acoustic characteristics this material has a broad consumer market in the construction, automotive, and electric-electronics industries. This work studied the recovery of wastes from ornamental rocks (granite and marble) as partial raw materials in the production of rock wools. Residues from granite and marble cuttings are industrial wastes with considerable production and limited applications. These wastes should be appropriately managed because when discharged in rivers or lakes can cause siltation, and also they can cause serious human health problems, such as silicosis. Samples of produced materials with thickness smaller than 500µm were characterized by chemical analyses, XRD, and DTA. Results showed that the rock wools produced using granite or marble wastes have important properties, especially the melting point. This process decreases the extraction of mineral resources and provides a profitable destination for the ornamental rock wastes.IntroductionThe ornamental rocks industry is a sector with large production of wastes. During the granite and marble extraction processes and specifically during the rocks cutting (see Figure 1), approximately 35 tons of powdered rock per month can be produced. These residues should be appropriately managed, because when discharged in rivers, lakes or watersheds, they can cause siltation. Also, these wastes can cause serious human health problems, such as silicosis [1].Currently, the granite and marble wastes are mainly used in civil construction to produce materials in the form of mortar, bricks and tiles. However, due the current produced volumes and the average growth of world production estimated at 6% per year, new applications for these wastes are necessary [2]."

Jan 1, 2011

By L. A. Nemchinova, M. A. Arustamian

"For a long time tailings piles of mining and smelting complexes have met the eye being a prospecting feedstock source for many industries. Nowadays, 6.5 million tons of copper and cooper-zinc processing tailings are stockpiled in the Urals annually, as there is no technology of its processing to provide a full and complex metal extraction within mining and processing operations. In spite of large volumes of mining wastes, not more than 20% of annual overburden, approx. 10% of processing wastes, approx. 40% slags (1) are involved into processing.Based on today’s complex of economic, environmental and social challenges of ore processing, waste processing technology using existing capacities is a burning issue. Mining wastes characteristics (including fine dissemination, variability of physical and chemical properties of mineral surfaces under impact of oxidizing, leaching, etc.) predetermine challenges arising out of its involving into processing and justify high capital intensity of new construction or reconstruction projects followed by replacement of existing processing lines with new ones.In this paper, the authors propose flotation technology for mature tailings of copper, copper-zinc and polymetallic ore processing. The technology developed provides for upgrade of existing process flowsheet diagrams at minimum costs to produce additional saleable products including low-grade copper concentrate, saleable zinc concentrate and gold concentrate thus facilitates sustainable use of depleting minerals and operational efficiency due to cost-efficient processing of already mined materials, being in fact, final semi-products located near existing operations. This is particularly important for operations with standby capacities and not engaged workforce."

Jan 1, 2018

By Masanori Harata

A fundamental study was conducted on a new process for producing scandium (Sc) metal or aluminum-scandium (Al-Sc) alloy by the calciothermic reduction of scandium oxide (Sc2O3). In this study, aluminum (Al) and calcium chloride (CaCl2) were used as the collector metal and flux for the reduction, respectively. A mixture of Sc2O3, Al, and CaCl2 in a tantalum crucible was placed inside a stainless steel reaction container, and the feed mixture was reacted with calcium (Ca) vapor at 1273 K for 6 h. After the reduction experiment, the reaction product (CaO), CaCl2 flux, and excess Ca reductant were removed from the obtained alloy sample by leaching with an aqueous solution. The formation of Al3Sc in the Al matrix phase of the alloy was confirmed by X-ray diffraction (XRD) and electron microprobe analysis (EPMA). This result indicates that Sc2O3 was successfully reduced to metallic Sc and alloyed in situ to form liquid Al-Sc alloy during the reduction. When Al was not used in the reduction experiment, a complex oxide (CaSc2O4) was formed, and the reduction was incomplete. This study demonstrates that the Al-Sc alloy can be directly produced by calciothermic reduction using CaCl2 flux and Al collector metal.

Jan 1, 2006

By Hanaoka K, Ikeda K

Kakogawa Works, Kobe Steel, Ltd. has two pelletizing plants and one sintering plant, and the blast furnaces have been operated with 30 - 50% pellets. At Kakogawa Works, various improvements in pellet quality have been carried out since the beginning of operation of the pelletizing plant. Especially, dolomite-fluxed pellets developed in 1975, have superior high temperature properties. The fuel rate of the large blast furnaces at Kakogawa Works has been reduced to 450 kg/t- hn by using a high percentage of dolomite-flux ed pellets.

Jan 1, 1980

By F. Shigeyoshi

The development of pelletizing during the last ten years has continued, however, self-fluxing pellets have not been regularly and commercially produced for use in blast furnaces, except as Kobe Steel, Ltd., Japan. This paper tells about unique developments for self-fluxing pellets, and their effects when used in Kobe Steel's No. 3 blast furnace at the Nadahama Works (inner volume 1845 Nm3, hearth diameter 9.5 m)., Several phases of the pelletizing process are discussed individually, and also their relation to performance in blast furnace operation. Special emphasis is placed on proper preparation of the limestone added to the raw materials, and indurating at optimum conditions. Means of improving pellet quality by correct control of size distribution of the raw materials used in pelletizing, and indurating temperatures, are also discussed. As basicity (CaO/SiO2) of pellets increased 0. 1, coke consumption decreased 3. 8 to 4. 2 kg per ton of hot metal, when using 70% pellets in the iron burden.

Jan 1, 1969

By K. E. Merklin, F. D. DeVaney

Students of the modern blast furnace seem unanimously agreed that they are observing a major revolution in practice. Rather than changing construction and operation of the furnaces, most of the great advances now under way deal with the raw materials feed. Prepared burdens have gained increasing significance during recent years. Sizing, concentration, and agglomeration have all become bywords to greater production and reduced operating costs. The remarkable results with test furnaces in which self-fluxing sinter makes up part or all of the ore charge foretell even greater improvements. Other investigators have reported many of these advances, and it is enough to predict here that more and more operators will turn to the use of self-fluxing sinter.

Jan 3, 1960

By JiaPeng Xu, Brian Lo, Uday B. Pal, Yihong Jiang, Soumendra N. Basu

"The Solid-Oxide Oxygen-Ion-Conducting Membrane (SOM) electrolysis process has been successfully tested on a laboratory scale, producing silicon directly from silica in a cost-effective and environmentally friendly way. A yttria-stabilized zirconia (YSZ) tube, closed at one end was employed to separate the molten salt containing dissolved silica from a liquid metal anode placed inside the YSZ tube. When the applied electric potential between the liquid tin cathode in the molten salt and the anode exceeds the dissociation potential of silica, oxygen ions are pumped out of the molten salt through the YSZ membrane and oxidized at the anode while the silicon cations in the flux are reduced to silicon at the liquid tin cathode. The presence of high-purity silicon crystals on the surface of liquid tin cathode was confirmed by scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS). Silicon crystals were extracted from tin cathode by chemical etching.IntroductionPhotovoltaics (PV) generate electrical power by using solar cells, and dramatically reduce the emissions of greenhouse gases (GHG). Through 2006 to 2011, it grew the fastest of all renewable technologies with operating capacity increasing an average of 58% annually [l]. However, the cost of manufacturing solar-grade silicon (SoG-Si) for high-efficiency solar energy production represents a major barrier to achieving the industrial goal for solar power of $1/Wp (watt at peak exposure) which would enable widespread grid parity. The current contract price of silicon to PV manufacturers is $50-$60/kg, with the spot market in 2007-2008 showing prices as high as $300/kg [2]. This makes the development of low cost and environmentally friendly manufacturing of high purity silicon very important."

Jan 1, 2013

By Xiang Li, Merete Tangstad

Currently, the main carbonaceous material for Mn-alloys production is solid carbon, i.e. coke, charcoal and petroleum coke, which is produced with large CO2 emissions. Due to the simple purification, high carbon activity and low CO2 emissions, natural gas has some advantages compared with conventional reducing agents. The aim of the present project is to develop a new technology for production of Mn-alloys using natural gas as a source of carbon. Experimental results indicated that injection of CH4 gas directly into melted slag reduced slightly the MnO and SiO2. However, the metal yield was much less than the theoretical value due to a relative low residence time of CH4 in the slag. The alternative approach was to use carbon black as reductant, produced by CH4 decomposition. The preliminary experimental results showed a high reduction rate using carbon black.

Mar 1, 2017

By Katsuya Kase, Kaname Takeya, Keaji Ohmori, Yoshiyuki Asakawa

"The reduction-diffusion process (the R-D process) using Ca as a reducing agent has been practiced in industry in the production of the SmCos type, the Nd-Fe-B type and the 1b-Fe-Co type magnetic materials. The advantages of the R-D process are the generally high yield of rare earth metals and the single-stage conversion of a mixture of oxides and metal powders into a product of rare earth alloy powders. On the other hand, one of its disadvantages is the slightly high contents of oxygen and calcium. This disadvantage is remarkable in the Nd-Fe-B type. Singe-phase Nd2Fe14B alloy powders with low content of 0 and Ca, is obtained by choosing appropriate raw materials and performing the R-D process in a controlled way. These alloy powders are very suitable for the production of Nd-Fe-B sintered magnets and expected higher magnetic properties by adopting advanced magnet production method.IntroductionThe hard magnetic rare earth transition metal intermetallics, especially, have attained considerable technical importance. Examples are the alloys based on the intermetallics SmCo5[1], SmC017[2], NchFet4B[3], or the recently developed alloy SnuFe11Nx[4]. The reduction-diffusion process using Ca as a reducing agent has been well known as an economical method of producing rare earth based magnet materials[5]. The reduction-diffusion process has been practiced in industry in the production of the SmCos type, the Nd-Fe-B type and the 1b-Fe-Co type magnetic materials. The advantages of the reduction-diffusion process are the generally high yield of rare earth metals, the single-stage conversion of a mixture of oxides and metal powders into a product of rare earth alloy powders, the elimination of the crushing process of the alloy ingot, the inessentiality to special equipment, etc. On the other hand, one of its disadvantages is the slightly high content of oxygen and calcium. This disadvantage is remarkable in the Nd-Fe-B type. An outline of basic studies of the reduction-diffusion process was reviewed from the particular viewpoint of the production of magnet materials by Ogawa [6]."

Jan 1, 1998

By T. S. Krishnan

Among the established permanent magnets, SmCo5 magnet occupies the foremost position as it offers a unique combination of high energy product, coercivity and curie temperature. The SmCo5 magnets are thus extensively used for high field applications. These are also best suited for use in environments where high demagnetising field and high temperature are operative. Also, for applications where high performance and miniaturisation are the over-riding considerations, the choice again falls on SmCo 5 magnets. The main deterrent to the widespread use of SmCo5 magnet is its high cost. Both samarium and cobalt metals are high priced, and the magnets prepared from their directly melted alloy are thus naturally very expensive. An alternate process involving calcium reduction of their oxide intermediates has, therefore, been studied and the alloy prepared by this process has been evaluated and found satisfactory for magnet production. The process essentially involves compaction of the charge mix containing samarium oxide, cobalt oxide (or metal) and calcium metal and' reduction of the charge compact at 1000-1300°C in hydrogen atmosphere, followed by water and acid leaching, drying and classification. The calcium reduction process offers three distinct advantages over the conventional melting processes: (i) The oxide intermediates are relatively cheaper and do not pose any handling problems. (ii) The operation temperatures are comparatively lower and hence precise composition control is possible as samarium losses due to volatilisation

Jan 1, 1989

By Jaime Lomelin

The brines from the sub-surface of the Laguna del Rey dry lake are pumped to Química del Rey, S. A. plant, where they are cooled in adiabatic crystallizers precipitating sodium sulphate decahydrate. This salt is dehydrated in multiple effect evaporators and dried in rotary kilns producing high purity anhydrous sodium sulphate. The spent brines from the sodium sulphate operation are concentrated in solar ponds, precipitating astrakanite and leaving a brine with a higher concentration of magnesium ions. This brine is treated with calcium chloride solution to eliminate the remainder of sulphates, leaving a solution of magnesium chloride ready for the manufacture of refractory grade magnesium oxide or periclase. The magnesium chloride is reacted with dolime to produce magnesium hidroxide which is washed, filtered, and calcined to produce soft burned magnesium oxide, which is briquetted and dead burned to produce the periclase.

Jan 1, 1984

By R. H. Matjie, J. R. Bunt, A. C. Collins, J. C. van Dyk, C. A. Strydom

South African coal discards derived from feed coal for thermoprocesses pose human health and environmental problems and incur high disposal costs. These issues need to be resolved. Coal fines and a coal fines/ K2CO3 blend were combusted at 700°C in a laboratory rotary kiln to produce ashes containing metakaolinite (Al2O3.2SiO2) and illite/muscovite/orthoclase amorphous materials. The blend ash and coal fines ash, containing 18% K2O and <1% K2O respectively, were leached with water and with 1 M and 8 M NaOH at 80°C for 4 hours using a solid to liquid ratio of 1:5. The 8 M NaOH leach yielded 17% sodalite (Na8Si6Al6O24(OH)2) formation through SiO32-, Al(OH)4-, and Na+ precipitation in the leached ashes. The 1 M NaOH leach yielded no sodalite. X-ray fluorescence analysis of the original ashes and leached ashes showed low Al and Si dissolution efficiencies due to the sodalite formation. Sequential NaOH leaching resulted in the highest potassium dissolution efficiency of 89% for the ashes of fines/K2CO3 blend and 59% for the fines. It may be possible to increase the ash-derived zeolite concentration by using even higher NaOH concentrations (12–20 M NaOH) during leaching. Sodalite derived from coal ash could possibly be utilized for water purification in industrial applications, or as molecule separators. The potassium-containing liquid could be used in fertilizer manufacture.

Mar 30, 2023