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By Bayard Morrow

THE copper-bearing ores concentrated at the Anaconda plant of the Anaconda Copper Mining Co. are principally a mixture of copper and iron sulfides associated in a gangue consisting of quartz, lightly altered granite and feldspars, with sphalerite and galena and more rarely barite and hubnerite as accessory minerals. The predominant sulfide is pyrite. The copper minerals present are: chalcocite, bornite (Erubescite), enargite, chalcopyrite, covellite, tetrahedrite and some tennantite. Normal concentrator practice removes a slime prior to ball-mill grinding. The deslimed ore is ground to approximately 10 per cent plus 65 mesh for flotation. Two selective flotation circuits are used, one for deslimed ore and one for slime. The metallurgical results obtained are shown in Table 1.

Jan 1, 1933

By Moorrees C

The end uses of magnesia are determined by both its chemical and its physical proper- ties. There is seen to be an increasing need for products of high chemical purity. Prod- ucts containing 90-95 per cent MgO can be routinely produced by physical beneficiation and calcination of most magnesite ores, the dominant source of magnesia. However, pro- duction of grades containing more than 98 per cent MgO with low impurity levels is not readily achieved physically. Such products can only be readily produced by chemical processing techniques. This presentation outlines the types of impurities present in magnesite deposits and the general concepts that are involved in chemically upgrading them. Of the potential leachants, only hydrochloric acid and aqueous carbon dioxide appear to be commercially attractive.

Jan 1, 1987

A sinter plant baghouse dust has been treated as a hazardous solid waste, and disposed at a very high price. A series of leaching tests were conducted to examine the possibility to produce high grade potassium chloride from the solid waste. It is found that around 40% of the solid wastes can dissolve into water, and a deposit with more than 90% KCl can be produced after simply drying the solution.

Jan 1, 2009

By Gerald W. Elger

A new process under development by the U.S. Bureau of Mines for producing synthetic rutile from ilmenite is described. Rutile formation is based on oxidation and fluxing of titania slag produced by electric furnacing of ilmenite. Laboratory tests show that phosphorus pentoxide flux additions to oxidized slag enhance conversion to rutile by forming a phosphate-based glass matrix. This matrix contains most of the major impurities, including the oxides of iron, aluminum, magnesium, manganese, and silicon. Rutile crystals of 5 to 150 microns in size were formed in slags heated to temperatures of 800° to 1,550° C. The synthetic rutile crystals were liberated from ground slag by treating with phosphoric acid to weaken the glass matrix, followed by attrition scrubbing. Rutile fractions analyzed as high as 94 percent titania content. In several instances, more than 90 percent of the titanium in the shag was recovered to yield combined rutile fractions containing 90.2 to 92.6 percent titania.

Jan 1, 1971

By Arndt C. R

The Ispat Mexicana SA de CV (IMEXSA) pelletising plant is located at Lazaro Cardenas on the west coast of Mexico. It is the primary source of feed stock for the adjacent direct reduction (DR) plants and steelmaking facilities. The initial design of the pellet plant began in 1981 for 3 Mtpa of DR grade pellets using local concentrate received by pipeline.' Several construction delays, an ownership change, and a decision to use imported concentrates delivered in 60 000 to 90 000 tonnes ship cargoes required flowsheet modifications and additions. The design concepts are described for the plant which includes concentrate regrind to final pelletising particle size.

Jan 1, 1999

By A. S. Gendron

A brief description of Inco's ORC copper refinery tankhouse and the electrowinning tankhouse is followed by a comparison of the requirements for the production of the high-quality copper in both systems. The description will focus on both tankhouses, with emphasis on experience to date in the electrowinning tankhouse. Particular attention will be paid to sensitivities of each tankhouse to process upsets which can. significantly afject the quality of the product cathodes.

Jan 1, 1977

By A. An. Mushketov, A. Al. Mushketov, N. A. Sopina

"INTRIDUCTION At present, more and more metallized raw materials with a metallization degree of not less than 80% are used in the smelting of steel. The main quantity of this raw material is produced in furnaces of mine type. Advantages of this type of raw materials for metallurgical processing are low levels of harmful and slag-forming impurities and a high content of metallic iron. At the same time, the cost of smelting raw materials and obtaining high-quality steels are reduced. In addition to the undoubted merits of metallized raw materials, there are high requirements for the quality of iron concentrates, which are the starting material for metallization: the mass fraction of acidic oxides should not exceed 3%; The mass fraction of iron should not be less than 69%, mass fractions of harmful impurities (phosphorus, arsenic, sulfur, copper, etc.) should not exceed 0.02%. These requirements are dictated by the fact that the recovery of burned pellets is carried out by gas in a solid phase. In this case, the empty rock and harmful impurities from the metal are not separated and sent to the steelmaking unit, increasing the heat consumption for heating and worsening the quality of the steel. The combined production of high-quality concentrate and metallized raw materials requires a large capital outlay from the enterprise, which in the future can be compensated for by increased profit from the sale of more expensive marketable products. At present, in the territory of Russia and the CIS countries Lebedinsky mining-and-processing integrated works is the only enterprise that carries out the entire chain of operations for the production of metallized raw materials, starting with the production of high-quality magnetite concentrate with a mass fraction of iron of 69.5% and ending with the production of a metallized product in the form of hot briquetted gland. JSC «SSGPO» is the largest iron-processing enterprise in Kazakhstan, which processes about 40 million tons of ore per year and receives 16 million tons of concentrate per year with a mass fraction of iron 66.0-66.5%. The technological scheme existing at the concentrator of JSC ""SSGPO"" includes the crushing of the feed ore to the size of 20-0 mm; dry magnetic separation operation; three reduction stages to a fineness of 90-95% kl-0.071 mm; operation of desliming, wet magnetic separation and filtration of the concentrate. Dry magnetic separation of the feed ore makes it possible to remove from the process of 19.6% of the tailings with a mass fraction of the total iron 12.5%, of magnetite 2.2%. The first reduction stage is carried out in rod mills with the volume of 40 m3 to a size of -1.6 + 0.0 mm. The first stage of wet magnetic separation is carried out in counterflow magnetic separators PBM-P-150/200L. The magnetic product of the first stage of WMS is classified in hydrocyclones; sands enter the second reduction stage into central discharge ball mill 3600 × 5000. Runoff of mills enter on the second enrichment stage in counterflow magnetic separators PBM-P-150/200L. The magnetic product enters the classification of the second stage, forming a closed cycle. Mass fraction of the class -0.071 + 0 mm in classifications runoff of the second stage is 70-75%. The second stage classifications runoff is transported toWMS-III operation in semi-counter separators PBM-PP-120/300. The magnetic product of the third stage enters the classification of the third stage. Granular residue are transported to the reduction of the third stage into central discharge ball mill 3600 × 5000. The mill runoff enters the third stage of classification, forming a closed cycle. Classifications runoff of the third stage enters on deslimation. Deslimed product is sent for fine screening to the crasher «Derrick» 2SG48-60W-5STK with a cell size of 0.1 mm. Top size of crasher is sent to regrinding. Undersize with a mass fraction of the class -0.071 + 0 mm 90-95% is fed to the wet magnetic separation of WMS-"

Jan 1, 2018

By Y K. Ji, B J. Chung

In recent years, the utilisation of ultra-fine ore in ironmaking has gradually increased due to the depletion of high-quality iron ore. The use of ultra-fine ore in the ironmaking process is typically energy intensive and leads to high CO2 emissions. The improvement of sinter reducibility is one of the methods used to reduce the environmental impact of using fine ore.In this study, a high-strength and high-reducibility sinter manufacturing process was investigated by controlling the sintering reaction. The key technology used in this method is the manufacture of mini-pellets by selective granulation equipment. The mini-pellets consist of iron ore, limestone and burnt lime and are designed to melt at temperatures below 1200°C. The molar ratio of CaO to Fe2O3 of the mini-pellets is 0.25~0.75. The 2~5 mm diameter mini-pellets are manufactured with burnt lime as the binding material.During the sintering of mini-pellets, goethite, which has relatively high reducibility, should be retained as residual ore in the sinter cake. The strength of the sinter cake was kept by the bonding reaction of the mini-pellets, which have a low melting temperature. This is the main principle of the reaction-controlled sintering method.The reaction-controlled sintering method manufactures a high-strength and high-reducibility sinter cake and increases sinter productivity by around 15 per cent using ultra-fine iron ore.CITATION:Chung, B J and Ji, Y K, 2015. Production of high-quality sinter by controlling the sintering reaction, in Proceedings Iron Ore 2015, pp 21–28 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Robert Kinzie

WHEN Mr. Cameron, the President of the Santa Cruz Portland Cement Co., returned from Europe in 1929, he brought first-hand infor-mation about a very versatile type of hydraulic cement. It was not a new cement, many articles having been written about it in foreign journals, but in this country the record of this type of cement had been either neglected or minimized. Using local materials, and applying the information brought back by Mr. Cameron together with many data in numerous publications, the Santa Cruz Portland Cement Co. developed the Santa Cruz high-silica cement. This cement is manufactured by grinding with portland cement clinker a properly calcined mixture of siliceous material and lime. It has all the utility of portland cement, together with an increased resistance to the destructive action of many aggressive solutions. To explain the necessity for the development of a cement having these characteristics, the history of hydraulic binding materials may be reviewed briefly. The materials used as binding media by primitive people were mud, lime, gypsum and bitumin. Due to its utility, ease of preparation, and its common occurrence, lime was the most widely used. Fat lime, when used by itself or with an inert sand, hardened only on the outside surface, where the carbonate was formed by absorption of carbon dioxide from the air, while, the interior of the mortar remained soft. It was quite early discovered that the incorporation of proper siliceous material with the lime increased its ability to harden, and for this purpose various natural siliceous powders were used, such as puzzo-lana in Italy, trass in what is now Germany, and santorin in Greece. These powders reacted with the lime forming a permanent cement and rendered unnecessary the access of carbon dioxide to the mortar.

Jan 1, 1934

By Hammenm R., J. Hammen, C. Hammen

"The production of salable Rare Earth Element (REE) products necessitates a sequence of chemical separation steps between the mine and market commodities. The effectiveness of the chemical separations that purify REE salts is critical to the success of the producer, as the purity of REE salt products affects their market price. This is due to the fact that impurities in REE salts, even at low levels, can be deleterious to the function and usability of the end product. The purification of REE by removal of low levels of contaminant has been referred to as "product polishing". The technologies commonly in use for product polishing, solvent extraction (SX) and ion exchange (IEX) are challenged by the availability of separation chemistries to separate the contaminant from the desired REE salt. In simple terms, if a product specification is 99.9% purity, the SX or IEX separation reagents need to have at least a 999:1 selectivity ratio. Significant testing has been carried out on the use of solid phase extraction (SPE) columns to extract low-level impurities such as aluminum or zinc from REE product streams. The SPE columns are nano-composite materials that have rapid equilibration kinetics with the solutes being processed by the columns. The SPE matrices have been modified with chelating ion exchange ligands that bind the contaminating ion with great selectivity in residence times of a few seconds. Thus, REE streams with 1 to 2% of contaminating aluminum ions, have been polished to >99.99% purity. In this paper, results are presented on the removal of aluminum impurity from a didymium (neodymium+praseodymium) product stream using SPE technology. The selection of the SPE medium and the process steps to treat the feed solution for aluminum removal and ultimate stripping and recycle of the solid phase extractant are discussed."

Jan 1, 2014

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Morgana Rosset, Bárbara da Rocha Pereira

High-purity alumina finds application in various electronic industry sectors, with approximately 100 million tons of this compound being produced worldwide. Alumina is acquired through the mining process of bauxite, a rock composed of a mixture of minerals such as gibbsite, kaolinite, hematite, and either anatase or rutile. In 2020, both bauxite and alumina were included in the list of critical raw materials. Due to the demand for high-purity alumina production, the development of a methodology to remove impurities present in the leach liquor from bauxite processing by solvent extraction (SX) followed by precipitation has been widely studied. This work aims to obtain high-purity alumina from bauxite by a solvent extraction process followed by a precipitation step from the sulfur leach liquor obtained by the thorough dissolution of Al and Fe from bauxite. Different parameters were evaluated in the SX step, such as extractant type, pH, temperature, and volume-to-volume ratio. The results indicated that using Alamine 336 as an extractant at pH 0 and room temperature led to an extraction of 90% of Fe and 15% of Al. Aluminum sulfate was completely precipitated as aluminum hydroxide and 55% of Fe using NH4OH. After the calcination procedure, obtaining a 99.9% pure alumina was possible without generating a red mud-similar residue.

Dec 28, 2023

By O. Kangal

Flame retardant materials can be incorporated or applied to products, including plastics and textiles, to increase their resistance to fire. Incorporating a flame retardant in combustible materials and plastics is a common procedure to reduce the risk of fires. Flame retardant applications include interior and exterior woods, structural steel columns, fabrics, open and closed cell foam, pressure treated wood, Formica and all types of fabrics for use in commercial applications as well as residential applications where their fire protection products can save lives and valuables. Huntite and hydromagnesite are amongst the most important flame retardant additives materials. Although various areas of the world have potential huntite and hydromagnesite deposits, their place in industry is not well known, and a detailed field search for their deposits has not yet been conducted. They are active during the starting phase of a fire, in that they prevent the spread of an inner or exterior source of ignition to the flame-retarded material, thereby, preventing, delaying or inhibiting the spread of a fire. Flame-retardants are, therefore, just one element among many in a concept for preventive fire safety. To obtain huntite and hydromagnesite concentrates that are more than 95% pure, which are used in flame retardant industry, flotation tests were conducted on low-quality huntite and hydromagnesite ores.

Jan 1, 2009

No phase of the steel industry is more typical of its remark- able progress than is the evolution and development of the modern American blast furnace. The founding of the Institute in 1871 also marked the beginning of a new era in the pig-iron industry. The rapidly expanding westward development of the country, with its seemingly unlimited markets, gave rise to unprecedented demands for blast-furnace products. The manner in which the iron industry responded provides a fascinating chapter in the history of industrial development. Prior to this period, the iron industry of the United States, largely concentrated in the East, was based upon the consumption of local iron ores and local fuels, the latter predominately charcoal and anthracite. Small, isolated furnaces were located near scattered ore and fuel sources, and the completely integrated ironworks and steelworks were yet to be developed. In about 1860 exploitation of the newly discovered rich ore deposits in Michigan and the successful adaptation of blast furnaces to coke produced from coal of the great Pittsburgh seam in western Pennsylvania proved to be major factors in firmly establishing the general westward shift of the industry. But these were largely economic in character, and it was not until about 1870 that the aggressive, individualistic nature of the ironmaster asserted itself in no uncertain manner. No longer limited by relatively inadequate equipment and inferior raw materials, and spurred as well as encouraged by those who supplied capital for these new enterprises, furnacemen began to establish unheard of records in iron production. It is not surprising that Pittsburgh was the center of this new activity. Its tenor is best indicated by the following account :l

Jan 1, 1948

Statistics compiled by the United States Geological Survey show that the iron ore mined in the United States in 1917 reached a total of 75,288,851 gross tons, exceeding the former record output of 1916 by 121,179 tons. The shipments from the mines in 1917 were 75, 573,181 gross tons, valued at $238,260,333, a decrease in quantity of 2,297,372 tons, or 2.95 per cent., and an increase in value of $56,358,056, or 30.98 per cent., over the shipments in 1916. The average value per ton at the mines for all grades of ore in 1917 was $3.15 as against $2.34 in 1916. Stocks of iron ore at mines, mainly in Minnesota and Michigan, amounted at the close of 1917 to 10,628,908 gross tons, compared with 10,876,352 gross tons in 1916. The quantity of pig iron, exclusive of ferro-alloys, sold or used in 1917, according to reports of producers to the United States Geological Survey, amounted to 38,612,546 gross tons, valued at $1,053,785,975; compared with 39,126,324 gross tons, valued at $663,478,118 in 1916, a decrease of 1.32 per cent. in quantity and an increase of 59 per cent. in value. The average price per ton at furnaces in 1917, as reported to the Survey, was $27.29, compared with $16.96 in 1916, an increase of 61 per cent. The production of pig iron, including ferro-alloys, was 38,647,397 gross tons in 1917, compared with 39,434,797 gross tons in 1916, a decrease of 4.5 per cent., according to figures published by the American Iron and Steel Institute, March 18, 1918.

Jan 12, 1918

By Masami Taguchi

"It is found that lead monoxide, PbO, has an ionic conductivity, and the all solid-state electrochemical cell using this oxide as an electrolyte has attracted the attention of battery researchers. In this study, thin film PbO2/PbO/Pb solid cells were produced on glass substrates and their discharge properties were investigated. The acti.ve material for the positive electrode, PbO2, was obtained by reactive sputtering of a Pb target in oxygen plasma. The PbO electrolyte and the active material for the negative electrode, Pb, were vacuum evaporated from /3 -PbO powder and a Pb block, respectively. The open-circuit voltage of the cell agreed with the theoretical value based on the thermodynamic data, and the close-circuit voltage was improved by the addition of a univalent impurity such as sodium or potassium to the PbO electrolyte. The connection of the cells in series and in parallel produced a higher electromotive force and a larger capacity. Also, the charge-discharge cycling test revealed that the cell could be charged and function as a storage battery.IntroductionGenerally, the ionic conductivity of a solid-state electrolyte is lower than that of a liquid electrolyte near room temperature. This has been a serious obstacle to using such electrolytes in an electrochemical cell. However, some solid-state electrolytes, which can preferentially pass a specified ion and have high ionic conductivity, have been found. Lead monoxide, PbO, which is an oxygen ion conductor, is such an example (1)(2). If a solid-state electrolyte is adopted for use in an electrochemical cell the problem associated with a liquid electrolyte such as leakage can be alleviated. The cell structure also can be simplified, because the electrolyte plays the role of separator to prevent the active materials from mixing. Thus, physical vapor deposition technology may make it possible to develop a very thin film cell, which consists of only solid phases (3)(4). In this study, the thin film PbO2/PbO/Pb solid cell with a thickness· of only a few micrometers, in which all the constituents were systematically deposited on a glass substrate by reactive sputtering and vacuum evaporation, has been produced and the charge-discharge properties were investigated. An attempt was made to improve the discharge properties by doping impurities such as Na2CO3 and Sb2O3 into the PbO electrolyte. Moreover, the connection of the cells in series and in parallel to get a higher electromotive force and a larger capacity, and the charge-discharge cycling test to determine its use as a storage battery were carried out."

Jan 1, 2000

By M. H. Weinecke, B. P. Faulkner

This paper discusses the process for making lightweight aggregate, the waste materials that make good lightweight aggregate, the chemistry of making lightweight aggregate and the commercial prospects for making lightweight aggregate from wastes. Svedala Industries has been making lightweight aggregate (LWA) from waste materials for the last 10 years. Many claylike materials, such as coal fired boiler ash and washings from a granite quarry, can be used alone or with additional waste materials to produce commercially salable LWA.

Jan 1, 2003

By M. H. Weinecke, B. P. Faulkner

This paper will discuss the process for making lightweight aggregate, the waste materials that make good lightweight aggregate, the chemistry of making lightweight aggregate and finally a discussion of the commercial prospects for making lightweight aggregate from wastes. Svedala Industries has been making lightweight aggregate (LWA) from waste materials for the last ten years. Many clay-like materials, such as coal-fired boiler ash and washings from a granite quarry, can be used alone or with additional waste materials to produce a commercially saleable LWA.

Jan 1, 2001

By Wojciech Kasprzak, Guoxian Liang, Michel Gauthier, Mickael Dolle, Yulong Liu, Xueliang Sun, Hernando Villazon Amaris, Majid Talebi-Esfandarani, Pierre Sauriol, Thomas Bibienne, Gregory S. Patience, Delin Li, Steeve Rousselot

In the 1990s, LiFePO4 (LFP) was discovered as a cathode material for lithium ion batteries and was successfully used in the variety of devices such as power tools, E-bikes and grid accumulators. New challenges associated with use of lithium ion batteries for automotive applications demand higher performance and operating requirements, yet these requirements need to be achieved at affordable cost and without compromising vehicle safety. The advantages of LFP as a cathode material include thermal stability, limited environmental impact and potential of low cost as compared to the cathode chemistries containing cobalt. Currently, solid state and hydrothermal processes are used to synthesize LFP at the industrial scale. However, they require multiple, time-consuming steps and costly precursors. Recently, a melting-casting process to produce LFP cathode material was investigated. The motivation behind this new process is the great flexibility of raw materials including chemical makeup and particle size, and the use of lower cost, commodity chemicals, with the benefits of increased kinetics in the molten state and energy efficiencies leading to overall process cost savings. Also, if successful this process could represent a novel application of conventional casting. Melting lithium-, iron- and phosphorus-bearing precursors in near stoichiometric ratios and casting LFP material that forms around 1000 °C requires fewer processing steps.

Mar 1, 2018

By D. W. Horsfall

The washability of South African coals is described and the problems encountered in washing at low densities, to make premium products, are enumerated. The measures taken to overcome those problems, when low density separations became a commercial necessity, are described in detail. The descriptions of processes are with specific reference to the three sizes commonly treated separately in coal preparation namely coarse coal, small coal, and fine coal. Some information is given on the performance characteristics of the plants erected to meet market requirements.

Jan 1, 1995

By C. H. Tiernon

"This paper was' prepared to emphasize the part that coal washing tables can play in the development of many of the reserves of coking coals in Western Canada_ It covers a brief history of the development of the coal washing table through the present third-generation unit, which suspends from overhead steel beams and is driven by a counter-rotating gear mechanism. The design and operation of this unique table are covered in detail.An analysis of actual operating data is included, with explicit statistical breakdowns of the table products. The data used were actually produced by operating coal companies, and also produced by the United States Bureau of Mines while gathering data for a research investigation. Table feed capacity is discussed, as well as performance criteria and the parameters of relative table performance. Several typical table flowsheets are described, emphasizing the specific reasons for their use. The paper covers the past and present value of the table to the United States coal industry, and makes mention of the newest addition to the family of suspended, multiple-deck, counter-rotating, gear-driven, coal washing tables, the CONCENCO ""88"" Deister table."

Jan 1, 1973