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By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By Tapio Ahokainen, Asmo Vartiainen

"Outotec's portfolio contains a wide variety of smelting solutions for non-ferrous metals. Some of these include flash smelting for primary copper and nickel, flash converting for copper, Ausmelt technology for primary and secondary copper, nickel, tin, lead, and zinc residues and waste, Kaldo technology for secondary copper, lead, and precious metals recovery. Outotec also offers slag cleaning technologies and much more.Company provides complete process solutions tailored to each customer's individual needs. Decades of experience have resulted in extensive metallurgical know-how that ensures the most profitable process choice and optimal performance. Outotec's life cycle technology partnership with their customers spans from the early stages of process solution design through the supply and commissioning of the entire process chain. They include integrated process control and holistic service and support concepts. Continuous research and development ensures that the customer is provided with the latest advancements in process and equipment solutions.IntroductionOutotec develops and provides technology solutions for the sustainable use of the Earth's natural resources. Solutions are ranging from various processes and special equipment needed for metallurgical extraction and mineral processing of ores to the production of refined metals and minerals. The processes include not only the grinding and physical separation of ores but also the smelting and leaching of base metals and precious metals. The company provides engineering services for whole projects as well as life cycle services on the equipment and products that they supply."

Jan 1, 2012

By Jaana Romppanen, Satu Jyrkönen, Tiina Ranki, Peter Björklund, Markku Lahtinen, Kaj Eklund, Päivi Suikkanen

Outotec is continuously developing our existing process equipment and new equipment solutions to enhance the Flash Smelting process. Thanks to the long operating history of the Outotec Flash Smelting process feedback from the numerous operating references are available and is utilized. The general goals for development work are to improve equipment performance, thus realizing savings in Smelter plant operation costs by increasing the process efficiency and online availability. Digitalization also opens new possibilities for the feeding equipment and furnace operation monitoring. These solutions will improve the safety and performance of the smelter, and provide process and equipment related information which has not been available earlier. INTRODUCTION The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. The Flash Smelting technology, is now owned and developed by Outotec Oyj and the first plant, is now owned by Boliden Harjavalta Oy. The two companies have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a hot theme/topic during the first days of Flash Smelting, it has nevertheless been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. Along with the process technology development, also development of the equipment has taken place over time. Outotec is continuously working on developing our equipment to better suit the changing need of our customers in the continuously changing operational environment. Orebodies are getting more challenging with lower ore grades and more impurities. Achieving high recoveries for all valuable elements becomes more difficult with high slag quantities and with the need to tackle the high impurity concentrations. There is a need for higher capacities in greenfield and brownfield smelters. The role of the Loss-in-Weight Feeder, the Air Slide and Concentrate Burner is to ensure even feed into the reaction shaft of the Flash Smelting Furnace, and to enable controlling the process well, thereby enabling the best performance for the customers smelter. The design of the Flash Smelting Furnace aims for high availability, long campaign and safe operation.

Jan 1, 2019

By Joey Hoang, Robert Johansson, Tapani Keronen, Mikael Jåfs, Jani Jansson, Mikko Korpi

At the Copper 2016 conference in Kobe, Japan, Outotec introduced a vision for the year 2020, wherein smelting would make use of four digital cornerstones: intelligent instruments, advanced process control, improved information management and transparency of and access to data. Since then, this vision coined the phrase “Fully Automated Smelter” with the mission promising a concept where no manual actions from human operators would be needed during normal smelter operations. Replacing repetitive physical work, collection and analysis of everyday production data has a great potential for further automation and will provide productive ways to improve efficiency and safety of smelters in the future. Therefore, a lot of emphasis has been put into developing solutions to automate these tasks and to move people out of harm’s way. A lot of new equipment, systems and optimization tools are under development. In addition, a lot of effort is going into developing dynamic process models and advanced control systems to interface with the plant automation systems. The goal is to integrate all these concepts to meet Outotec’s Fully Automated Smelter vision. This paper will cover these latest achievements toward this vision and introduce the near-future of digital smelting. INTRODUCTION As is well known already, the humankind is currently experiencing a change, extent of which is broadly studied by the governmental, educational and industrial institutions and parties. The wellbeing and quality of life have traditionally been improved alongside the developments in industrial production, which is now about to enter its fourth revolution. Therefore, the current change is often described as fourth industrial revolution, or industry 4.0 (or industrie 4.0, as named by Acatech, 2013) and can be considered anything from small incremental development to a ground-breaking global reset that will affect everyone’s lives. Many seem to agree, that the scale of change will indeed be big, even significantly bigger than the three industrial revolutions before it (Pellini, Weyrauch, Malho & Carden, 2019; Geissbauer, Vedso & Schrauf, 2016; Jansson, Bjorklund, Lahtinen, Heinonen, Jafs & Fagerlund, 2016).

Jan 1, 2019

By Tuomas Hirsi

The world’s first large scale modular solvent extraction plants have been delivered by Outotec. The first of these is now in operation and has proven that the VSF®X technology can deliver the excellent performance of the Outotec VSF® solvent extraction process. Modular delivery allows site work to be minimized and the manufacturing done in a controlled environment, allowing for serial production manufacturing benefits. Container based delivery was found to be a highly efficient way of utilizing the standardized transportation methods on a global scale. Site work with modular units was found to be efficient and highly predictable. In this paper, we present the first successful Outotec VSF®X deliveries and discuss the benefits of the modular delivery and design compared to the standard solvent extraction installation’s delivery. The process performance of the VSF®X is also discussed with experiences from the first industrial reference presented.

By Maureen E. Lipkewich

Education builds long term awareness, acceptance and support for responsible mineral resource development. The MABC Education Program is an award winning education partnership with British Columbia classroom teachers that has helped over 5400 teachers with resources and other learning opportunities. Each year, thousands of students begin, and continue, to learn about our modern mineral industry as a result of this teacher-written program. The CIM network has an integral role in the future of mineral education in today?s classrooms in Canada and programs of this caliber are vital to our future. The industry needs help in raising awareness of the benefits of modern mining and teachers need help in acquiring that information.

May 1, 2002

By Z-Y Pi, B Zhang, S Wen

"The paper introduces the structure and work processes of outside auger hollow claw tipped mechanical sampler for coal. Twenty sets of claw tipped sampler performance tests show that: The design of inner hollow cylinder-type (?180 mm) can ensure to take a coal sample with nominal top size of 60 mm. Built-in self-cleaning piston pusher ensures no adherence and blocking of the sample. The operation practices show that the mechanical sampler can operate in order for taking coal sample with up to 16 per cent of total moisture. Claw closing design can avoid sample leaking or spilling during the claw lifting and ensure the integrity of primary increment. Ultrasonic positioning device makes the sampler capture the materials no less than 10 cm from the bottom of the wagons, basically meeting the requirement taking full depth of the sample. The precision and bias test indicates that the moisture and ash have no relative bias under the sampling process; the sampling precision is in accordance with the requirement in IS013909.At present, the spiral mechanical sampler is widely used for coal sampling but there are many limitations during application, for example: It is difficult to capture a large size sample, so the size range of a coal sample taken is limited. There is easy adhering or blocking for high moisture coal, which will result in the mixture of different increments, wear of sampler and the difficulties for cleaning and maintenance of sampler. It is difficult to capture the coal sample at lower than 30 cm from the bottom of the wagons, in order to avoid damage of the vehicle. It is possible for coal sample loss and spilling during the sampler lifting, due to the unsealed sampler.For the outside auger hollow claw tipped mechanical sampler designed for solving the above problems, the opening distance of the claw is the opening size of the sampler and makes the size range of the coal sample to be taken wide. During sampling, the two pieces of claws open and the sampler rotates vertically downward to capture an adequate coal sample after reaching the specific point. Then the two pieces of claws close tight automatically to ensure there is no coal leaking or spilling. The inner pusher of the sampler will prevent from the adherence and blocking of the coal sample effectively.CITATION:Zhang, B, Pi, Z-Y and Wen, S, 2012. Outside auger hollow claw tipped mechanical sampler for coal, in Proceedings Sampling 2012, pp 41-44 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 21, 2012

My "outside exploration" began in November 1908, only 16 months after I had come to Bisbee as a raw engineer. The well publicized reputations of eminent engineers up to that time, including John Hayes Hammond, Herbert Hoover, James Douglas, D.C. Jack- ling, J. Park Channing, and a few others had been due to new mines they had found or brought to successful operation. And here was I, a mere youngster, given a chance to join the group. I knew there would be disappointments but I had no idea how many of them. In spite of the many prospects that turned out to be worthless I never looked at a new one without the feeling that this one might turn out to be the big success. This confidence, blind as it was, gave every arduous examination a zest and it made me climb every mountain on which the owner said there was something worth seeing, or on which T could see a distant staining that might mean ore. If I looked at every showing the owner suggested he at least would think I was honest and would bring other properties to our attention. This reputation of never refusing to go to see an outcrop, no matter how hot the desert sun or how rough the terrain, was probably one of my best assets. High as my hopes were at the start, they proved not to be exaggerated and if I were given a chance to do it again I would not hesitate, in spite of the jaundice, rheumatic fever, and other maladies that beset some of the expeditions. On the whole the results have equaled all my hopes. Toward the end of my years of active exploration I totaled up the score. Out of the prospects submitted to us about two out of three were eliminated after questioning the owner or prospector, without an examination. This left about a 1000 mines or prospects that seemed worth at least a preliminary look. One out of seven of these was worth a little development and a seventh of this seventh turned out to be a modest success or better. And nine or ten in all, or one out of 1000

Jan 1, 1976

By D J. Clark, R F. Wright, M D. Goodz

The A1 Gold Mine is a Devonian-age narrow vein high-grade gold deposit located 115 km east of Melbourne. The mine operated almost continuously from 1861 to 1992 producing 442 334 ounces of gold (13.8 t) from 530 436 tonnes from primary gold ore tonnes processed at an average recovered grade of 25.9 g/t Au. The A1 dyke was attributed with a yield exceeding 620 000 ounces (19.3 t) of gold (including gold in alluvial and tailings deposits), and was renowned as one of VictoriaÆs premier mines paying considerable dividends. The orebody was principally in a diorite dyke bulge 150 m long, 45 m wide and 700 m deep and was mined via two vertical shafts. The mine site was closed in 1992 and the site was rehabilitated in 1999. In 2008 - 2009, a diamond drilling program identified various extensions to the host dyke lithology and to gold-bearing quartz vein filled fault zones over a 700 m strike length. The outcome of this study was the establishment of a mine geology corridor four times longer in strike length than the original 1970s model. This opens A1 dyke hosted deposit style to exploration outside the historical dyke bulge and provides exploration opportunity for all similar deposits. Construction of the first 3D geological model has developed new insights on the host rock diorite dyke system and identified various extensions to both host stratigraphy and to gold-bearing mineralised structures. Coarse visible gold in quartz vein mineralisation (>30 g/t Au) and medium-grade stockwork mineralisation (8 - 15 g/t Au) has been intersected within 100 m of the surface and up to 300 m along strike of the nearest historical underground workings. At depth it appears that the mineralisation is continuous with the main dyke body with consideration of minor rotation in the strike orientation and limited reverse thrust faulting showing maximum displacement of 10 - 20 m. Along the A1 mine corridor, between two and five parallel dykes are observed at different drill sections. The gold mineralisation is hosted mainly within the dyke rocks, but where the sedimentary rocks are intensely silicified or are xenolith rafts, the gold mineralisation continues across these sedimentary rock blocks. There has been inference to the role of silicified sedimentary rocks as a second ore host and a bounding material for inflections in fault and vein orientations. In the central 150 m long A1 mine dyke bulge, the extremities are demarcated by four to five parallel dyke fingers (referred to as apophyses) going both north and south. These apophyses are clearly observed both vertically and horizontally between levels No 4 and No 9. The dyke fingers entrap sedimentary rock xenoliths and collectively form the A1 dyke æcorridorÆ, which is quite uniform in overall width from the easternmost contact (footwall) to the westernmost contact (hanging wall). Dyke fingers were assumed to coalesce at depth into a single dyke, but recent drilling shows this feature to repeat in several positions with depth and along strike. Key observations are the relationship between gold grade and fracture density, alteration, sulfidation, host rock morphology û relation of contact shape and fault zones. These relationships allow for the classification of prospectivity indicators and geology as a guide to potential extensions of mineralised zones. Mining geology is contributing to the whole-of-mine life planning and development where decline path, stockpile and infrastructure positions are controlled by geology.

Jan 1, 2009

The decision to contract or owner mine should be independent of, and should be made before, definitive estimated cost comparisons could be available. There is substantial potential risk of estimated cost comparisons being flawed due to difficulties in compiling comparable estimates for differing business objectives, errors and omissions or because of significant bias. In the current economic environment, escalating cost pressures potentially lead to increased incidence of disputes in mining contracts. The apparent cost of contractorÆs profit and overheads has tended to become more significant to owners. Economy-driven trends towards higher levels of performance and commercial risk for contractors, and the potential for more adversarial, difficult management; with attendant disputation between contractors and owners, have encouraged development of so-called ærelationship contractsÆ û partnering or project alliance contracts. The paper discusses the issues, circumstances when owner mining or contract mining is favoured and perceived advantages and disadvantages of contract mining. The implications of owner-perceived core business and core skills and outsourcing are also discussed. Techniques of introducing objectivity into the decision to owner or contract mine using matrix analysis or benefit comparisons are described. A disciplined procurement process should deliver a decision to owner or contract mine independent of, and prior to, any definitive comparison of estimated costs. A generic procurement process model is provided as a basis for discussion. Risk is discussed generally and as a significant factor in comparison of estimated operating costs. Consideration of risk and any prudent cost treatment are promoted as necessary pre-requisites to any comparison of estimated costs. The paper develops the concept that the decision to owner or contract mine should be based on real benefits that become obvious in the early stages of the development, particularly the procurement process; and before definitive estimated cost comparison can be available. In the context of this concept estimated cost comparisons tend to be confirmatory. Problems with comparing estimated ownerÆs operating costs with tendered contract prices are also discussed, particularly recovery of capital cost of equipment; and the owner minerÆs trade-off of operating risks for the residual contractorÆs margin attributed to overheads and profit. The paper concludes that sole reliance on a comparison of estimated ownerÆs operating costs with tendered contract prices in deciding to owner or contract mine is questionable and likely driven by a need to satisfy specific in-house customers.

Jan 1, 2003

By Claudio Ballota

Los sistemas de gestión empresarial son importantes -en tanto las estrategias de negocios acompañadas del apoyo de sistemas de información, permiten planificar, ejecutar y controlar el desempeño empresarial. Por ello, la integración de la información en una empresa a través de reportes gerenciales y herramientas de análisis, son fundamentales para cualquier ejecutivo que quiera desempeñarse exitosamente en el mercado moderno. En ese sentido, el presente texto señala la eficiencia del outsourcing de sistemas integrados en la administración de las empresas como un proyecto tecnológico de negocios que está dirigido a todos los empleados de la empresa que interactúan con sistemas para realizar sus tareas operativas diarias y para los gerentes que buscan información para tomar mejores decisiones.

Jul 17, 2000

By C. J. H. Steenkamp

Theoretically, the main driver behind a mining operations? sourcing decision should differ from company to company, and within a company from project to project, but in reality it often relates to cost. Research confirms that there are a number of factors, including cost, to consider when choosing between in-house and outsourced mining. While the literature is rife with factors to consider, little information exists on how to apply these in practice and the relative importance of the different factors to be considered. A study was conducted to determine whether mining is truly a core competency for a mid-tier commodity specialist mining company. Furthermore, a decision-making framework for mining operations sourcing was developed, and the critical success factors that should be adhered to if outsourced mining is chosen were determined. The research showed that owner mining is not a core competency for the mining company investigated. A decision-making framework was developed using the order winner/order qualifier structure, which can be used to facilitate the mining sourcing decision. The most important tools at the disposal of a mine owner?s team to manage a contractor miner are the social and output control mechanisms, according to the critical success factors study.

Jan 1, 2014

By J. R. Shultz, R. J. Lambert

One of the present trends in the mining industry is the increased use of mining contractors. In the past, many project owners have utilized mining contractors for topsoil stripping or overburden removal, usually on a short-term or periodic basis. In recent years, mining contractors have not only removed the overburden, but mined the product as well. Why is this change occurring? A prevalent trend in the mining industry appears to be the outsourcing of non-core and non-strategic functions, allowing producers to focus more on areas of technical expertise where higher incremental value is added—that is the processing, refining, and marketing of the product. As capital allocation becomes more critical, this trend is likely to continue.

Jan 1, 2002

Outsourcing of specialist and non-continuous services is common practice in international mining operations. There is an increasing trend towards this practice in South Africa as a result of the major organisational changes that have taken place in the industry, and as lower revenues and production cost pressures have reduced profit margins. Many specialist functions have been outsourced in the industry for a long time, an example being shaft sinking, which is undertaken by specialist shaft sinking contractors. In the professional services area, some activities have been outsourced, for example the design and construction supervision of tailings dams, but mining related activities such as geology, mine planning and scheduling, engineering, ventilation, and rock engineering, have traditionally been carried out by in-house staff. In this paper some of the industry problems which have led to an increase in outsourcing of professional services are considered. Then the pros and cons of outsourcing are dealt with before outlining the factors which should be taken into account in choosing an outsourcing partner.

Jan 1, 1999

By L. C. Graton

Introduction The Porcupine district of northern Ontario has yielded over $300,000,000 in gold during its twenty-three years of mining operations. It thus ranks among the foremost gold producing areas of the world. Of this $300,000,000 already produced from the District, the Hollinger mine has furnished over 60 per cent and stands as one of the greatest gold mines of all time. In 1929, the Hollinger Directors decided to supplement the current geological and development work by an intensive investigation of the geology of the mine. This special study, begun in June of that year, was completed in October, 1932. An account of the geology of the mine in a degree of detail commensurate with the intensity of the study is in course of preparation. But the widespread interest manifested at the present day in gold occurrence generally, in Canadian gold deposits, and in the specific results of the investigation at Hollinger, appears to justify the immediate presentation of a highly abridged summary of our principal findings, insofar as they relate to the more general and scientific phases of the geological situation. Those conclusions having direct bearing on operating and exploratory policy are not dealt with here. The present preliminary paper, therefore, records chiefly the conclusions reached, with little incorporation of supporting argument or evidence. While intended to give a reasonably balanced perspective of Hollinger geology, the condensed presentation naturally emphasizes those views which are not in complete accord with accounts hitherto published regarding this district.

Jan 1, 1933

By Maciej Korecki

Pyrowear®Alloy 53 steel is an excellent material for the construction of drive transmission components (gears, shafts, etc.) which have to operate in difficult conditions primarily in the aviation industry (Fig. 1.). Among the properties of such items is a high case hardness and abrasion-resistance, while the core remains flexible and is capable of carrying large impact loads. They can work at elevated temperatures with limited lubrication. The thermal treatment of such materials is based on case hardening by means of carburizing. This paper presents the technology of vacuum carburizing of Pyrowear® Alloy 53 steel. It discusses the methods of establishing different profiles of carbon concentration in a layer and their influence on the hardness profile. The effects of sub-zero treatment and tempering on the properties of the hardened case are also considered. It also presents a SimVaC® simulator of vacuum carburizing, designed especially for Pyrowear® Alloy 53 steel, which provides highly accurate predictions of the outcome of the process as the profile of carbon concentration in the layer, or vice versa: establishes the process parameters which will guarantee the required profile.

Aug 16, 2017

By Teresa M. Bodas Freitas, Arianna Lupattelli, Peter J. Bourne-Webb, Diana Salciarini, Martina Zito, Donatella Sterpi

The thermomechanical response of thermally-activated (TA) piles under monotonic thermal loads is quite well understood and the remaining uncertainties relate to the effect of long-term, cyclic loading of individual TA piles and pile groups. Recent studies undertaken by the authors have provided insights into the behaviour of TA pile foundations undergoing cyclic thermal loading. Despite their simplicity, the analyses show that key aspects of the observed response of piles in sand, under cyclic thermal loading can be reproduced, providing confidence in the outcomes of the analyses. The studies examined isolated piles and pile groups, and concluded that irrecoverable thermally-induced settlement may be mitigated through the choice of an appropriate margin of safety on the pile shaft resistance under service mechanical load conditions, and the maximum thermal stress can also be readily estimated. This paper consolidates these works and provides guidance regarding the safe geotechnical and structural design of the piles, then looks towards the remaining issues around the safe provision of thermally-activated pile foundations.

May 1, 2022

By Antonio Augusto Gorni

O posicionamento de bobinas a quente com seu eixo na direção horizontal protege suas bordas, mas restringe sua área de apoio sobre o solo. Logo, é inevitável que a bobina sofra algum grau de ovalização pela ação de seu próprio peso, o qual se torna particularmente acentuado em algumas situações, como no caso de aços com médio e alto teor de carbono após bobinamento sob temperaturas relativamente altas. O objetivo desse trabalho foi identificar as possíveis contramedidas para minimizar o grau de ovalização das bobinas a quente. Foi constatado que a ocorrência desse problema é crítica para bobinas mais finas, com maior peso e com menor tensionamento entre as espiras, bem como quando seu bobinamento termina antes da transformação total da austenita, particularmente no caso de aços com alto carbono equivalente. Por outro lado, o posicionamento das bobinas em berços com ângulos otimizados contribui para minimizar a ovalização. A seleção das medidas a ser adotadas para reduzir esse problema deve ser ponderada caso a caso, pois elas podem eventualmente interferir com as características finais do produto solicitadas pelo cliente.

Jul 30, 2018

By Felix E. Wormser

REGISTRATION started bright and early Monday morning in the Silver Corridor at the Waldorf-Astoria with Mrs. W. H. Bassett as chairman. What a registration-over 200 ladies! Several joined us from as far away as California and Washington State. Apparently they enjoy our meetings so much that present travel inconveniences didn't discourage their coming. At noon the ladies joined the men at the All-Institute Luncheon and Monday evening we had our informal dance, which is separately reported. Tuesday morning was devoted to our annual meeting at which all Section annual reports were read. At noon we were all the guests of the W.A.A.I.M.E. at a luncheon at the Port Arthur Restaurant on Mott St. in Chinatown. Many of us rode down on the old 3d Ave. elevated railway-the last of four. It, too, is soon to be torn down. The luncheon was delightfully unusual, with huge dishes of delicious Chinese food on each table. Our chairman, Mrs. Read, who lived in China in her youth chose our menu, and she chose it well, for most of us indulged so heartily that as we arose from the table we felt we couldn't eat again for 24 hours. Someone donated sherry wine, and boxes of Chinese pencils as favors. We wonder who? All owe a big vote of thanks for this lovely party to Mrs. T. T. Read and Mrs. H. A. Prosser, chairmen, and Mrs. H. W. Hardinge, Mrs. R. Hursh, and Mrs. R. L. Lloyd, vice-chairmen.

Jan 1, 1944

By W. R. Shimer

(New York Meeting, October, 1913.) THE investigation herein described was carried out for the purpose of studying, both by chemical and metal-lographical means, the extent of over-oxidation of steel that can be accomplished by excessive over-blowing in a Bessemer converter. In addition there are appended some results of basic. open hearth and crucible steels. Remarks on Chemical Methods. The test block used was hemispherical in shape, 4.5 in, in diameter and 2 in. thick. Drillings for analysis were obtained by drilling through the entire solid part of the. block, carefully avoiding all cracks anti blow-holes and mixing these drillings thoroughly. Drillings were carefully examined for scale and the finest were gone over with a microscope to be sure all scale from whatever source had been. removed. Oxygen was determined by the well-known method of Ledebur, modified according to Cushman,1 with, however, the removal of the preheating tube, which was found unnecessary. This method has been found to give concordant results. Blanks run from 0.0003 to 0.0006 g. Duplicate determinations varied not more than 0.001 to 0.003 per cent. It seems to be generally supposed that the hydrogen method gives only that oxygen which is combined with iron. Whether this be true or not, the content of oxygen existing as iron oxide no doubt predominates sufficiently, so that the result obtained is sufficient to indicate whether the steel is over-oxidized or not.

Jan 9, 1913