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By Olivier Lacroix, Dubé Mathieu, Guylaine Laforest

The reduction behavior of iron ore pellets in gas-based DR shaft processes has been studied at COREM since the late 80s. At that time, a new DR characterization test called COREM R180 was developped in collaboration with ArcelorMittal Mines Canada (former Quebec Cartier Mining) and ArcelorMittal Long Products Canada (former ISPAT Sidbec Inc.). This paper describes COREM’s approach to improve its understanding of the relations between iron ore pellet microstructure and pellet quality. The differences between the DR90 and the R180 tests are discussed. The evolution of the microstructure during reduction of both tests is also described. The reduction steps during the two tests are put forward as an important factor impacting the microstructural changes as well as the test results.

Oct 1, 2019

By Adrian E. Scheidegger

"AbstractThe possibilities of deriving pertinent information about fractures in an oil pay from data obtained by core analysis are investigated. It is shown that it is possible to obtain an estimate of the fractured area per unit volume of the pay, and that the size of the fractures can be estimated if their shape is known. A suggestion of a routine procedure for the analysis of fractures is given.1.-IntroductionMany oil fields are producing essentially from cracks or fractures. Where this is the case, it is important to be able to obtain a knowledge of the size and distribution of those fractures in the oil pay. This knowledge has to be derived from the analysis of cores taken from the fields, as it is generally impossible to follow a fracture through the pay by direct means. The necessity of using statistical methods to extrapolate the meagre information obtained from the cores of the wells is therefore indicated.It is known that the fractures are much bigger than the diameter of the cores; thus, if they strike a core, the latter will generally fall into two pieces. The angle of the fracture with the vertical can be measured and, if oriented cores are taken, the exact position of the surface element representing the intersection of the fracture with the drill stem can be determined. Sometimes the edge of a fracture can be seen in a core. The number of •Cores that show such an edge can be noted. Of course, one has to be careful to distinguish between original fractures in the pay and fractures in the core caused by drilling operations. Only the former are relevant."

Jan 1, 1955

By William E. Ford, Edward Salisbury Dana

IN the representation of crystals by figures it is customary to draw their edges as if they were projected upon some definite plane. Two sorts of projection are use8; the ah- graphic in which the lines of projection fell at right angles and the chirographic where they fall at oblique angles upon the plane of projection. The second of these projections is the more important, and must be tr2atcd here in some detail. Two points are to be noted in regard to it. In the first place, in the drawings of crystals the point of view is supposed to be at an infinite distance, and it follows from this that all lines which are parallel on the crystal appear parallel in the drawing. In the second place, in all ordinary cases, it is the complete ideal crystal which is represented, that is, the crystal with its full geometrical symmetry as explained on pp. 10 to 13 (cf. note on p. 13). In general, drawings of crystals are made, either by constructing the figure upon a projection of its crystal axes, using the intercepts of the different faces upon the axes in order to determine the directions of the edges or by constructing the figure from the gnomonic (or stereographic) projection of the crystal forms. Both of these methods have their advantages and disadvantages. By drawing the crystal figure by the aid of a projection of its crystal axes the symmetry of the crystal and the relations of its faces to the axes are emphasized. In many cases, however, drawing from a projection of the poles of the crystal faces is simpler and takes less time. The student should be able to use both methods and consequently both are described below.

Jan 1, 1922

By J. Laskowski, J. Lekki

"The mechanism of joint action of a frother (alpha-terpineol) and a collector (ethyl xanthate) in the flotation of chalcocite has been examined. In order to study the dynamic effects of frother and collector in bubble-particle collisions, the following aspects were investigated : determination of zeta-potential. Measurements of the thickness of fluid film on the surface of chalcocite and adsorption of xanthate, as influenced by alpha-terpineol, induction time and flotation versus concentration of alpha-terpineol and ethyl xanthate.The mechanism of the adsorption-desorption phenomenon on chalcocite with regard to non-ionic molecules, e.g. a-terpineol, has been considered, and the influence of this on the stage and thickness of the intervening wet layer between a bubble and a particle, changing the probability of collision and attachment, is suggested."

Dec 1, 1971

By T. N. Patra, Sanjeeva Latchireddi, B. K. Mishra, Sravan K. Prathy

The motion of grinding balls has been the subject of study since 191 9 when Davis published the first treatise on this subject. Subsequently came the notion that knowing mill power draft, using Bond equation or others, is sufficient to do an analysis of grinding. Next, population balance models provided accurate scale-up from small laboratory size mills to very large plant size mills. However, this success was not repeated when dealing with semiautogenous grinding mill. The study of charge motion with the discrete element method provides support and answers to such issues. Besides providing an accurate picture of charge motion in large mills, the method begs the investigator to study grate and pulp lifter equally critically with fluid dynamic principles. Hence, in recent years, the field of comminution in grinding mills is advancing on a firm footing.

Jan 1, 2005

By Michael L. Wayman

Archaeological and ethnographic work during the last century has shown clearly that metals have played a small but important role in prehistoric Arctic cultures. For at least the past several millenia both iron and copper have been used in the North, primarily for blades, projectile points, knives, awls, engraving tools, fishhooks, scrapers and axes. In addition they were used for joining purposes as staples and rivets. It is of great interest to enquire into the origins of these metals. In this connection one begins with the observation that to date there has been no clear evidence for the smelting or melting of metals in the Arctic prior to the arrival of Europeans. This can be explained partly by the absence of traditional pyrotechnologies such as the high-temperature firing of ceramics and the heat treatment of bone and wood. Another factor which surely inhibited the development of smelting/ melting operations is the relative absence of wood in the region. The production of charcoal for smelting requires large quantities of wood, to the extent that the desertification of a number of areas in the Old World is believed by some to have been at least partly caused by charcoal production. In the North this was obviously not possible. Thus the Arctic peoples were restricted to using native (naturally occurring) metals and metals obtained by various direct and indirect forms of contact with areas of the world where smelting was practiced. Both of these sources were important in the case of iron; we know that meteoritic iron, telluric (native) iron and smelted wrought iron were all used in the Arctic. These three types of iron will be considered in tum.

Jan 1, 1999

By James C. Burrows, Frances Kramer Mesher

Tungsten-containing ores are mined on all continents of the world. China is the world's largest producer and controls the world's largest reserves. The USSR, itself a sizeable producer, is estimated to be the world's largest consumer. The major use for tungsten in the noncommunist world is in production of cemented tungsten carbides for cutting, drilling, and wear parts. Other major uses include lamp wires, steels for tools, and armaments. Real tungsten prices have been in a general decline since 1977-1979 as the tungsten market undergoes basic and lasting structural changes.

Jan 1, 1986

The impulsive loading tests under confining pressure were performed to investigate the dynamic fracture properties of rocks in a triaxial stress state. The apparatus in this study consists of the Split Hopkinson pressure bar, a pressure vessel and hydraulic actuator. Magnetite-quartzite and limestone were selected for the test. The stress-strain curves and fracture strength under confining pressure obtaind in the tests were compared with those of the conventional triaxial tests. Finally it is concluded that on the effect of dynamic that on the effect of dynamic compressive strength of rock, dynamic elastic coefficient of rock and confining pressure etc. on the blasting result

Jan 1, 1990

By Bruno Michaux, Markus Reuter, Martin Rudolph

"It is relatively well-established in the literature that the flotation of calcium minerals using fatty acids as collector is very sensitive to the process water composition. In particular, hard waters have often been reported to strongly reduce the target mineral recoveries due to the formation of insoluble compounds such as calcium and / or magnesium dioleate, thus reducing the amount of collector available for adsorption onto the mineral surface. In this study, the flotation of a fluorite pre-concentrate was performed with tall oil, an industrial collector essentially containing fatty acids. The tests were performed in a variety of synthetic waters to simulate multiple degrees of water hardness, and to differentiate the role of magnesium and calcium ions on the flotation performance. The flotation tests revealed that, under the studied conditions, a significant difference between flotation in calcium-rich and magnesium-rich waters was observed, suggesting strong ion-specific effects in the system. Specifically, calcium-rich waters slightly improved the fluorite recovery, whereas magnesium-rich waters caused a decrease in recovery by as much as 20%. This paper is focused on the flotation kinetics aspect of the system. This approach highlighted the interesting finding that calcium ions did not simply increase the fluorite recovery, but also significantly increased its flotation kinetics. The magnesium ions, on the other hand, had the exact opposite effect.INTRODUCTIONAs the mining industry is facing an increasing number of issues related to its fresh water consumption, the idea of using alternative water sources for mineral beneficiation is gaining significant momentum. As a result, a proper understanding of the role of water chemistry in flotation is becoming more and more urgent, leading to an increasing number of studies on this topic."

Jan 1, 2018

Precast prestressed concrete piles designed to be end-bearing in a sand stratum at Drax Power Station met with extremely variable resistance during driving. Some piles came to virtual refusal almost immediately on entering the sand whereas others were driven to considerable penetration with very low resistance. Redriving and load tests on piles experiencing low resistance on initial drive showed that take up in strength occurred over a relatively short period of time. Investigations involving the use of pneumatic piezometers revealed the development of significant excess pore pressures during driving. Samples from boreholes showed that piles met the least resistance when the sand had a high silt content. Comparison with the original site investigation data demonstrated the difficulties in predicting detailed pile behaviour. The varied behaviour could not be related to the original borehole logs or to SPT or static cone penetrometer results. The factors controlling pile driving behaviour were essentially geological and could only be explained with reference to local soil grading.

Jan 1, 1989

By Morris Cohen

This paper deals with the calculation of the composition of the infinitesimal trace of alloy that transfers from the liquid to the solid state at each temperature during the equilibrium solidification of a binary solid solution, and which thereby enables the compositions of the coexisting liquid and solid phases to follow along the liquidus and solidus lines respectively during the cooling. A general expression for the composition (S) of the liquid-to-solid transfer at each temperature has been derived S - ZLXL(XL - P) + Zsxs(P - XS) ZL(xL - P) + Zs(P - XS) where ZL and Zs are the slopes of the liquidus and solidus lines at the given temperature, XL and xs are the composi-tions of the stable liquid and solid phases at the same temperature, and P is the composition of the alloy under considera-tion. The S equation is valid for the process of equilibrium heating as well as cooling, and may be applied to vapor-to-liquid, vapor-to-solid, liquid-to-liquid, and solid-to-solid transfers if the corresponding equilibrium diagrams are known.

Jan 1, 1940

By Morris Cohen

This paper deals with the calculation of the composition of the infinitesimal trace of alloy that transfers from the liquid to the solid state at each temperature during the equilibrium solidification of a binary solid solution, and which thereby enables the compositions of the coexisting liquid and solid phases to follow along the liquidus and solidus lines respectively during the cooling. A general expression for the composition (d) of the liquid-to-solid transfer at each temperature has been derived: d = ZLXL(XL - P) + Zsxs(P- ZL(XL - P) + Zs(P - Xs) where ZL and Zs are the slopes of the liquidus and solidus lines at the given temperature, XL and xs are the composi-tions of the stable liquid and solid phases at the same temperature, and P is the composition of the alloy under considera-tion. The d equation is valid for the process of equilibrium heating as well as cooling, and may be applied to vapor-to-liquid, vapor-to-solid, liquid-to-liquid, and solid-to-solid transfers if the corresponding equilibrium diagrams are known. The d -versus-temperature curves for two alloys Pl and P2 are shown in Fig. I. In each case, the liquid-to-solid transfer has the same composition as the stable solid FIG. I.-GENERAL SOLID SOLUTION DIAGRAM SHOWING S CURVES FOR ALLOYS P1 AND P2. phase only at the temperature of the be-ginning of solidification, and has the same composition as the stable liquid phase only at the temperature of the completion of solidification. At each intermediate tem-perature, the composition of the liquid-to-solid transfer differs by a finite amount from those of the two coexisting phases. Therefore, during equilibrium cooling, the transfers must merge into the solid phase from the liquid without forming a transition phase; otherwise the condition of equilibrium would be violated. At any given temperature during solidification, the composition of the liquid-to-solid

Jan 1, 1940

By Youn-Bae Kang

Evaporation mechanism of S from liquid Fe–C–S alloys at 1873 K was proposed by analyzing available experimental data. It has been known that increasing C content in liquid alloy increases activity coefficient of S ðfSÞ, and it could raise driving force for the evaporation reaction S = S(g). However, experimental data of the evaporation of S in the Fe–C–S alloys could not be accounted for only by considering the increases of fS. In the present study, formation of carbosulfides, CS(g) and CS2(g), was additionally taken into account in order to explain role of C for the accelerated S evaporation. Surface adsorption of S was also taken into account, which retards the evaporation rate of S. An evaporation model equation was formulated. It can be applied to calculate the evaporation rate of S over wider C content (from zero to its saturation to liquid alloy).

By A. Ismail

"The paper takes its material from three peat mining and power project feasibility studies sponsored by CANMET and conducted by Montreal Engineering Company Ltd. in the years 1976 to 1980. The role which peat may play in the Canadian energy prospectus is outlined, estimated and measured fuel peat resources are tabulated, and the economic and technical feasibility of mining peat for power generation is reviewed Recommendations are made for future work, and construction and disbursement schedules are developed for a combined peat mining and power generation project. The relationship between the mining of moss and fuel peat is discussed.IntroductionWhereas moss peat has long been produced in Canada, and exported for horticultural use , the underlying fuel peat has received little attention until fairly recently.In the seventies, however, the deepening oil crisis spurred Canadian interest in Irish, Finnish and Russian experiences in the utilization of fuel peat. Among others, Energy, Mines and Resources Canada had long been alive to the possibilities which indigenous peat offers, and in 1976 the Canada Centre for Mineral and Energy Technology (CANMET encouraged a proposal from Monenco to carry out a preliminary study and submit a report on the "" Assessment of Canadian Peat as an Alternative Fuel for Power Generation"". The report was submitted in April 1977. This was the first of a series of studies, and the authors of this paper were involved in its preparation.The escalating price of oil and the increasing problem of relying on its availability have combined to make alternative fuels more attractive. Peat, like other fuels previously uneconomic because oil was cheap, is now progressively gaining in viability. In addition to these factors, the utilization of peat has the following advantages: improvement in the country's balance of payments, by virtue of burning an indigenous fuel;creation of local employment for the mining of peat; improvement in land utilization;peat is a relatively clean-burning fuel, with low sulphur and ash contents."

Jan 1, 1980

By K. Verghese, R. W. Rousseau, R. P. Gardner

A radioactive tracer method and a size-discretized, mass balance model are formulated and demonstrated in a feasibility experiment for the determination of crystal growth rates in MSMPR crystallizers. The system studied is aqueous KN03 with K-42 as the radioactive tracer. The results indicate that the method should prove to be very valuable for this application, particularly when systems exhibiting size-dependent growth rates are of interest. An indicated refinement to the tracer method is the simultaneous use of an additional tracer in the liquid to determine the amount of radioactivity from the liquid that is adsorbed on the samples of filtered crystals.

Jan 1, 1980

By P. Barnes

THE complete and accurate filtration of water (if the word ,accurate may be thus used) for the feeding of boilers, and for many similar industrial purposes, although somewhat practiced both at home and abroad, has been by no means common. Even if the exact line cannot be defined at which filtration begins to be called for, and will be found profitable, it is certain that in a large number of cases it may be employed with real advantage in the economy of fuel, and also in. the greater durability of the boiler or other form of apparatus in

Jan 1, 1882

By H Allday

The mining industry’s attention has shifted over the last decade with the recovery from the downturn resulting in greater development of innovation and new work methods in a bid to remain competitive and deliver higher productivity. The emphasis on cost reduction to improve profit margins has primarily been the focus of the “work smarter” campaigns embraced within the industry. But is this strategy holistically the best-for-business, or does it place a ceiling on revenue opportunities and inhibit mining companies from truly maximising value? Businesses need to maintain a balance between active cost management and revenue generation often resulting in cost reduction strategies at site level. These strategies have merit, assessing areas of cost wastage across operations and creating space for opportunity. However, this potentially can create distractions from the goal of enabling growth and lead to the sacrifice of quality and delivery. Focusing too heavily on cost reductions without addressing revenue generation is an unprofitable lens to look through, and the relationships between cost, revenue, quality and profit margin can often be overlooked resulting in missed opportunity to maximise value. How these relationships are effectively employed by mining companies to reap the rewards from an overarching corporate perspective down to site level remains a fluid concept depending on the nature, operating market and strategy of the business. A common directive from businesses to their operations is to strive for greater profitability and productivity. The quantification of these requirements, and the nature of the cascading message delivered, impacts the methods employed by the operational team to meet the expectations of the business. Cascaded strategies, if not delivered with appropriate participation and buy-in can often be perceived to be knee-jerk and create frustration for operations who are squeezed to deliver on expectations by slashing site costs. This squeezing is not only felt by the mining operation but at the individual level and can result in increased team stresses. In some cases, this may also steer behaviours towards activities that result in corner cutting and an elevation of operational risk, potentially increasing associated incidents and injury. Driving down costs by any means can create an unhealthy tunnel vision where value is no-longer assessed for best-forbusiness results. By flipping the viewpoint to a value-based approach revenue opportunity may be realised and potentially exceeded, however this opportunity may be missed if value is over shadowed by a cost heavy focus. By analysing a selection of real operational cases (ranging from mining contractors through to in-house mining giants), it becomes apparent that practical revenue maximisation strategies are not only key to an increase in value and cash flow but to a stronger understanding of business drivers for sites and operators alike. In the cases evaluated additional revenue opportunities are foregone in favour of cost reduction strategies resulting in negative impacts on the associated operations and wider businesses. Alignment towards value generation is king. If strategies are not implemented focusing towards value and revenue maximisation, the opportunity loss experienced by mining operations could continue be great and the question should be posed; when the next up-turn hits will operations be ready to reap the rewards or still have a glass ceiling above their heads?

Mar 15, 2021

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By N. S. Dalal, X. Shi

"It has been recently suggested that the exceptionally high antitumor and antibacterial activity of natural fredericamycin A (FMA) is related to its ability to spontaneously generate the superoxide anion (02-) and hydroxyl (""OH) radicals in aerobic solutions [Hilton, B. D., Misra, R., & Zweier, J. L. (1986) Biochemistry 25, 5533]. With a view to understand the mechanistic details, attempts were made to reproduce earlier electron spin resonance (ESR) evidence for the oxygenated free radical formation in well-aerated solutions of natural FMA in dimethyl sulfoxide and dilute H 20 2• Little or no evidence was obtained for the formation of the 0 2- and methoxy (""OCH3) radicals, while the detected formation of the 'OH and methyl ('CH3) radicals was attributable largely to mechanisms not involving FMA. These results thus reopen the T question regarding the mechanism of its exceptionally high tumoricidal-bacteriocidal activity. This paper reports on an electron spin resonance (ESR) investigation of the formation of oxygenated free radicals in solutions of natural fredericamycin A (abbreviated as FMA) which has recently been reported to be a highly potent anti¬tumor antibiotic (Pandey et al., 1981; Warnick-Pickle et al., 1981). The impetus for this undertaking was provided by recent reports (Hilton et al., 1986; Stinson, 1986) suggesting that the strong tumoricidal activity with high therapeutic—toxic index of FMA was related to its ability for the spontaneous generation of superoxide anion (02-) and hydroxyl (OH) radicals. For example, the suggested mechanism for the formation of 02- by FMA was (Hilton et al., 1986)FMA-OH + O2 FMA-O + H+ + 02-Here FMA—OH is simply the FMA molecule emphasizing the —OH moiety which becomes FMA-O, the free radical rep¬resenting the oxidized form of the drug. While some other highly effective anticancer drugs in current clinical application, such as bleomycin, are also thought to exert their antitumor effects via the formation of reactive drug-based or oxygenated free radicals (Carmichael et al., 1985; Gianni et al., 1983), FMA was considered unique in that only in this case the free radical formation was thought to be spontaneous, rather than through a metal- or an enzyme-activated process (Hilton et al., 1986; Stinson, 1986). Thus it was suggested (Hilton et al., 1986; Stinson, 1986) that FMA could be the forerunner of a new class of anticancer drugs. However, we noted that while the hypothesis seemed plausible, the reported ESR spectral evidence appeared to be ambiguous. Because of the high significance of the earlier conclusions (Stinson, 1986), we undertook a systematic ESR study of the radical formation in FMA solutions, and as discussed below, our conclusions disagree with those reported earlier."

Jan 1, 1989

By Takasaki Y, Ohzeki S, Hotta H

TO measure high temperature properties of blast furnace burdens ( the change of gas permeability accompanied by contraction, soft- ening and melting ) which govern the gas flow and its distribution, a series of experiments were carried out under simulated blast furnace conditions, using sinter, acid pellets and self -fluxing pellets. 1) The high temperature properties are affected by the ore's reducibility ( up to 1000 -1200¦C ), and the composition, and volume of gangue before reduction. Generally, the burde- ns with high basicity ( Ca0/Si02 ), high reduc- ibility and low volume of gangue have good high temperature properties. Good high temperature properties are : a high temperature at which the gas permeability rapidly decreases, a high melting point and a low maximum pressure drop. 2) Using acid pellets, slow-down of red- uction rate occurs around 1000¦C because the pellet forms a dense metallic shell, while its slag core, resulting from a FeO, Si02 and A1203 reaction, has a lower melting point. 3) The addition of MgO sources improves high temperature properties both of sinter and Pellets.

Jan 1, 1980