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By Aloísio Simões Ribeiro

Para a preservação e extensão da campanha do Alto-Forno é de fundamental importância o monitoramento, controle e estabilização da temperatura de pontos quentes na parede do cadinho do forno, possíveis de serem gerados durante a sua campanha operacional. Já são bem conhecidas diversas práticas operacionais para controle dos pontos quentes sendo que, uma das mais usuais, é o uso na carga do forno ou injeção via ventaneiras de fontes de óxido de titânio para formar, junto à parede do cadinho, uma camada protetora composta por carbonitreto de titânio. Neste trabalho será apresentado o desenvolvimento de uma nova concepção de massa de tamponamento contendo dióxido de titânio sintético, para auxiliar em problemas de pontos quentes em regiões do cadinho próximas aos furos de corrida.

Aug 16, 2017

By C Laming, P M. Hetherington, F A. Pym, M P. Murphy, K E. Crook

Reconciliation is a powerful tool used by mining operations to compare the mass and grade of ore produced with what was estimated before mining. The primary objective of reconciliation is to verify that the estimated planned metal production is achieved during processing, allowing issues to be identified for which adjustments can be made throughout the mining value chain to improve recovery and maximise efficiency. Traditionally, the mine plan is based on estimated mine grades using sampled exploration drill hole or blasthole grades. Reconciliation discrepancies between the mine plan and mill are common due to such factors as insufficient or non-representative sampling, poorly conceived models, or unrecognised blast movement. MineSense Technologies Limited® (MTL) has developed an X-ray fluorescence (XRF) sensor-based ore classification system that is installed on mining equipment to provide real-time grade estimates of run-of-mine material at bucket, truck, or belt-scale. Bucket level grade estimates provide insights into grade variations at the mine face that were never before available. This data set eliminates some of the leading causes of reconciliation discrepancies and enables tracking of tonnages and grades from the mine face to the processing plant at bucket resolution with confidence. Bucket-by-bucket grades at the mine face enable dynamic optimisation of the mine plan to stabilise the mill feed grade through blending of mine and stockpile loads. Beyond stabilising feed grade, Mine to Mill reconciliation combined with the full XRF spectrum response can generate proxy relationships to ore characteristics like hardness and recovery. These properties can then be predicted at the mine face, enabling further optimisation of the downstream mill feed, not only for grade, but also for power and water consumption, reagent addition, and recovery. This paper presents the benefits of MTL technology for grade reconciliation and mill performance optimisation at a Cu Mine in BC (Canada).

Mar 22, 2022

By P M. Hetherington, M P. Murphy, K E. Crook, F Pym

Resource characterisation is critical for informed decisions in both strategic and operational space. The sources of information for resource characterisation are limited by: direct measurement of resource attributes, such as grades, rock-types, mineralogy, and are available only from sparse locations, ie drill holes; or indirect geophysical measurements such as seismic, gravity or electro[1]magnetic survey. Data collection tools, methods, and processing technologies are constantly improving providing a broad spectrum of options for data collection strategies. The cost of each data survey varies from thousands to millions of dollars with the value of each additional data having diminishing return for a particular business decision. The value of information analysis provides the optimal decision on data collection strategy within a limited available budget. This work presents an example of value of information analysis for new Blast Hole Assay Tool (BHAT) and Reverse Circulation Grade Control (RCGC) data used in addition to the wider spaced exploration data. The value of information is quantified in terms of reduction of grade uncertainty, ore loss and dilution by comparing different combinations of data collection methods. Four different strategies were considered: exploration samples in addition to 50 per cent of blastholes surveyed with BHAT, exploration samples in addition to 33 per cent of blastholes surveyed with BHAT, exploration with wide-spaced RCGC data, and exploration without additional grade control. For each strategy the observed values have been simulated using advanced multivariate geostatistical simulations and compared with simulated ground truth models. The calculated uncertainty, ore loss and dilution informed the optimal data collection strategy. Opportunity to reduce sample density from the nominal 50 per cent of drill holes was evaluated.

Mar 22, 2022

By Klaus-Peter Kinzel

Staves Coolers de cobre proporcionaram uma excelente proteção da carcaça do alto-forno em áreas de alta temperatura. Isso resultou para que os operadores de alto-forno alcançassem alto desempenho em termos de produtividade e taxa de combustível, além de campanhas de mais de 15 anos. No entanto, nos últimos anos, alguns altos-fornos experimentaram um desgaste prematuro nos staves de cobre. Algumas dessas empresas se alinharam com Paul Wurth para investigar a causa fundamental desse fenômeno com base em todos os fatores de influência e, em seguida, propor ações corretivas. Estes resultados são discutidos e apresentados a seguir no trabalho técnico.

Oct 30, 2017

By Rafael Oliveira Sena

A SMS Siemag tem oferecido ao mercado brasileiro novas tecnologias para Lingotamento Contínuo de Placas com objetivo de aumento de desempenho dos equipamentos. A SMS Siemag tem desenvolvido e otimizado o processo de revestimento de placas de cobre do molde que utiliza em conjunto com o processo de eletrodeposição a tecnologia thermal spray que proporciona um produto com alta propriedade de resistência ao desgaste. O revestimento cerâmico, mais conhecido como UniGuardTM, tem obtido resultados excelentes no mercado da América do Norte atingindo valores superiores a 300.000 toneladas. A utilização do revestimento UniGuardTM proporciona um aumento de produtividade e redução dos custos de manutenção do molde bem como redução de aquisição de novas placas de cobre.

Jul 29, 2018

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By G. Kipouros, M. Dadvand, A. Dadvand

"A novel methodology was developed to obtain a 3D porous layer with a high aspect ratio of porosity on a titanium electrode. The porous structure allowed more active material such as hydrous ruthenium oxide to be accommodated during the fabrication of the supercapacitor, resulting in an exceptionally high capacitance per surface area. The electrode demonstrated a remarkably high capacitance of 4,800 mF/cm2. The porous layer was composed of functionalized nanoparticles of TiO2 organized in a perfect 3D hexagonal close-packed array that resulted in a highly porous 3D structure. The layer was used as a template to electrolessly deposit a thin layer of silver prior to the electrodeposition of active material. KEYWORDS Capacitance, Porous, Ruthenium, Silver, Supercapacitor, Titanium RÉSUMÉ Une méthodologie innovante a été mise au point afin d’obtenir une couche poreuse tridimensionnelle (3D) affichant un rapport d’aspect élevé en termes de porosité sur une électrode en titane. La structure poreuse permet d’utiliser une matière plus active telle que l’oxyde de ruthénium hydraté durant la fabrication du supercondensateur, ce qui se traduit par une capacité exceptionnellement élevée par surface active. L’électrode affichait une capacité remarquablement élevée de 4 800 mF/cm2. La couche poreuse était composée de nanoparticules fonctionnalisées de dioxyde de titane (TiO2) organisées dans un arrangement regroupé parfaitement hexagonal en 3D, qui a engendré une structure en 3D hautement poreuse. Cette couche a servi de modèle pour le dépôt autocatalytique d’une fine couche d’argent avant l’électrodéposition de la matière active. MOTS CLÉS argent, capacité, poreux, ruthénium, supercondensateur, titaneINTRODUCTION There is a growing demand for integrating compact energy storage elements into electronic circuits due to the miniaturization of electronic circuits, sensors, and actuators, and the increasing importance of portable and wear-able devices incorporating more advanced electronic technologies that operate in controlled or uncontrolled environments to gather, process, store, and communicate information (Deng, Ji, Chen, & Banks, 2011; Beidaghi & Wang, 2012; Chen, Ramachandran, Mani, & Saraswathi, 2014). The manufacturing of compact energy storage elements needs to be compatible with the electronic circuit microfabrication processes. Recently, interest in integrating miniaturized supercapacitors into electronic circuits has increased due to their high charge–discharge rate and long operating life; however, ultra-high power miniaturized supercapacitors suffer from low energy density, hence requiring significant enhancement in their energy density for various applications (Deng et al., 2011; Beidaghi & Wang, 2012; Chen et al., 2014)."

Jan 1, 2019

A form of wet pelletization is described where the bridging of the individual particles is achieved by a second liquid phase that pref- erentially wets the suspended solid particles. The phenomenon can be used to obtain efficient separation of solids from carrier liquids, to form spheres from finely divided solid materials, and to separate selected constituents from a body of mixed solids. Typical examples of each of these applications are presented.

Jan 1, 1974

By Abhishek Lahiri, Animesh Jha

"A new technique for the selective separation of rare earths and impurities from lower grade titaniferous ores has been developed which will reduce the overall reduction in the energy costs, and therefore the CO2 generation by at least an order of magnitude during the chlorination and waste handling stages of TiO2 to TiCl4 reaction. The process includes roasting the ilmenite ore with alkali followed by water washing step, which removes nearly 80% of oxides of lanthanide and actinide elements present in lower grades of titaniferous minerals. In the context of preferential separation of rare- 3+ + earth and actinide oxides, we have examined the roles of Al and K ions on the lattice structures of ilmenite and complex titanate as the product layer forms during the roasting in air in the presence of potash. The composition of the mixtures of oxides derived from the separation process shows that the mixture of rare-earth oxides m ay be a high-value co-product of the overall beneficiation process.IntroductionWorldwide the production of synthetic rutile is carried out either by the sulphate or the slag-making followed by fluidised bed chlorination of TiO2 enriched slag granules. The chlorinated gas is then re-oxidized to make white pigment grade TiO2. The waste generated by the sulphate process is predominantly iron sulphate, which has limited use in the water treatment plant. The remaining wastes from the sulphate process undergo further treatment using filtration followed by evaporation and thermal decomposition after which it is disposed into deep sea. On the other hand the chloride waste is extremely hazardous and requires special case by neutralisation, followed by impoundment in a managed pond, where it is monitored for long-term for potential contamination to the soil and ground water. Rare-earth and prelanthanide wastes often end up in the pond where they are diluted and irretrievably lost for further use or recycle. Certain parts of the world the chloride process wastes are pumped via deep boreholes into porous geological strata. The present techniques of disposal are not only expensive but also pose continued threat groundwater and soil and marine life in case of sulphate waste [1, 2]."

Jan 1, 2009

By T. Karlkvist, H. R. Kota, F. Andreas, B. I. Pålsson

"Separation of different calcium minerals have long been an interesting and challenging problem. In this investigation calcium mineral separation is examined by: microflotation, zeta potential measurement and adsorption, using novel collectors having two functional groups instead of one. In theory, by varying the distance between the functional groups, it could be possible to preferentially target one calcium mineral by matching the spatial distance between the sites on the mineral surface. In this investigation two new surfactants have been tested to estimate their ability to float apatite and/or calcite. Preliminary findings show that an increase in distance between the functional groups favors one mineral over the other, and this might be due to differences in the mineral surface structure. INTRODUCTION Apatite is a strategically important mineral which has both great value for industrial use as a precursor to phosphoric acid; and in the agricultural industry as an important source of phosphorous in fertilizers. This has led both the European Union and the United States to recognize it as an important resource for the future. Currently there is no lack of apatite in the world, but it is important to develop the beneficiation to ensure future supply. A common problem in apatite flotation is the selectivity towards calcite, which it is commonly associated with. Although calcite is an important industrial mineral its abundance makes it not usually worth to extract from apatite ores unless it is easy to separate1,2. Both apatite and calcite are semi soluble minerals with calcium as one of their constituents. The most common way to separate apatite and calcite is to use flotation. A process that involves making the mineral particles to extract from the system hydrophobic by adsorbing a collector on the mineral surface. One way to study collector adsorption on a mineral surface is by zeta potential measurements. The zeta potential is the charge at a slip plane a short distance from the surface. By measuring the zeta potential with and without the presence of collector it is possible to investigate if the collector is present at the surface or not, a change is indicative of collector adsorption. The zeta potential of fluorite, apatite and calcite without collector can be seen in Figure 1. The small difference in zeta potential between apatite and calcite shows the similarity in their surface properties and gives an indication of their separation difficulty. One additional problem with semi soluble minerals is their tendency to slightly dissolve in the pulp and thereby change the ionic composition of the solution. This makes separation and research problematic as the freed ions may readsorb on the mineral surface and interfere with the collector adsorption on the mineral surfaces3–5."

Jan 1, 2016

By Peter G. Chamberlain

Novel and innovative mining methods are attracting the attention of mining engineers at an unprecedented level. Historically, the US mining industry has responded rather conservatively to new technology. The financial difficulties affecting the domestic mining industry in the early 1980s changed attitudes toward new technology. The market contraction during that period, coupled with an expanding world mine capacity, created a serious oversupply of many raw mineral products. Many mining companies found that retaining a share of world markets while making a profit required drastic cost-cutting measures.

Jan 1, 2008

By M. H. Kotze, V. Yahorava

A gold-selective ion exchange resin, containing tributylamine groups, was developed by Mintek for the recovery of gold from cyanide leach solutions. The Dow Chemical Company and, more recently, Purolite commercialized the production of this gold selective resin for use in the gold mining industry, and it is marketed as Dow XZ-91419.00 and Purolite A194 respectively. A novel application of this resin is the selective recovery and separation of AuCl4 - f rom p latinum group metals (PGMs) in chloride and nitrate solutions. The current paper describes potential benefits of this type of resin for selective recovery and upgrading of gold from low grade chloride or nitrate waste streams, and the possibility of gold separation from PGMs during their refining in chloride media.

Jan 1, 2014

By S. R. S. Sastri, G. V. Rao

Because the nickel contained in lateritic nickel ores does not occur in an identifiable mineral, it is generally accepted that these ores are not amenable to beneficiation. For this reason, such ores are either directly smelted or leached to extract the nickel. In this paper, a process for enriching the nickel content of the lateritic nickel-bearing chromite overburden, normally a waste material generated during chromite mining, is described. In this flotation process, a nickel preconcentrate containing >1.1% Ni was obtained from material containing as little as 0.36% nickel. An empirical relationship was developed to predict the grade of nickel that can be obtained.

Jan 1, 1997

By R. Bhima Rao

Performing a magnetizing roast in a furnace or kiln is a well-established technology. However, the use of microwave heat for the magnetization of hematite in the beneficiation of ferruginous bauxite is a new approach. This paper reports on an investigation of this procedure, which is followed by comminution and magnetic separation. The results of this investigation indicate that a nonmagnetic product containing 80% A1203 and 2.5% Fe203 with a recovery of 80% can be made from a crude bauxite ore containing 55.9% A1203 and 5.6% Fe203. This product is suitable for refractory use. The mechanism is explained by the ability of the microwave radiation to heat specific points within the bauxite. These heat-specific points are at the location of iron minerals. In a reduced atmosphere, the microwaves promote faster conversion of the iron minerals to a magnetic phase, which improves the magnetic-separation process.

Jan 1, 1997

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000

This paper summarizes the results from a project aimed at adapting scroll centrifuges for application to the dewatering of flotation concentrates. The main impetus for the project was to reduce the high cost and footprint size of the technology currently used to dewater fine coal. The technical challenge was to enhance solids capture by incorporating a laser-cut screen into the design of the basket. The project has shown that a pilot-scale scroll centrifuge can be used to dewater froth concentrate. A number of different basket designs were tested, the best results being achieved with a basket comprising a laser-cut screen of aperture 70 µm. The best result on a sample of untreated flotation concentrate, which was taken from the open trough flotation cells at a coal preparation plant (CPP) in NSW was a solids recovery of 82 wt% at a product moisture of 24.3wt%. By comparison the best product achieved with a conventional wedge wire basket was a similar moisture content but solids recovery was only 64 wt%. This could only be achieved after the feed had been artificially thickened. Conditioning of the centrifuge feed with polymer flocculants led to an increase in recovery up to 88 wt% with a moisture content of ca 25 wt%. It is thought that optimizing additive selection and conditioning parameters, as well as screen aperture and open area, could improve performance still further. The results were obtained using centrifuging conditions (centrifugal force, feed solids, feed rate) in the pilot-scale machine which should be possible to translate into conventional designs of commercial scale machines, without downgrading solids throughputs. However only with full-scale trials will it be possible to establish this assertion with certainty.

Jan 1, 2001

By A. Schippers, S. Hedrich

Chalcopyrite represents the most important copper resource and is currently mainly exploited using pyrometallurgy. Bioleaching is an environmental-friendly and economic alternative to conventional mineral processing technologies. The technical feasibility of stirred tank reactor bioleaching of copper ore concentrates using acidophilic iron-/sulfur-oxidising bacteria is proven, however, often incomplete due to inefficient chalcopyrite dissolution. A decoupling of bacterial growth from bioleaching activity in one bioreactor by adjusting appropriate temperatures for both process steps allows for almost complete chalcopyrite dissolution. Separation of copper and recovery of other metals from the PLS was possible by implementation of different biological and chemical techniques. The Ferredox process has been proposed to treat limonitic laterite ores for cobalt and nickel recovery by means of anaerobic reductive dissolution with autotrophic, acidophilic bacteria. As a modification, aerobic reductive dissolution of laterites with acidophilic bacteria has shown economic and environmental advantages over anaerobic reductive dissolution. The reductive bioleaching technology has the potential to increase metal recovery in existing mines, and transform unexploited ores and limonite stockpiles into valuable resources. Keywords: Biomining, bioleaching, chalcopyrite, laterite, Ferredox process

Jan 1, 2020

By R. Trammell, O. Eterigho-Ikelegbe, S. O. Bada

In response to the enormous amounts of coal discard generated during coal mining and preparation, the development of an efficient and sustainable strategic use of this resource is essential. Furthermore, the rising urban population over the next decades is confronted with the depletion of quality raw materials for building components. To this end, this study reports new information on the morphology, water absorption, and flexural strength properties of ceramic composites produced from three different coal discards and polysiloxane pre-ceramic polymer (PCP) resin. In addition, test results relating to the continuous operating temperature, chemical resistance, and efflorescence potential of the composites are presented. The results show that the water absorption and flexural strength of the coal composites, up to 1.94% and 36.46 MPa respectively, exceed the requirements for ceramic and clay roof tiles. The continuous operating temperature of composites is found to be more thermally stable than conventional roofing tiles (concrete and ceramic) between ambient temperature and 600°C. In addition, the excellent chemical resistance of the composites (94.43%−99.98%) compared to conventional roofing tiles (67.82%−99.97%) eliminates the need for additional external coatings. The interesting results documented so far suggest that this technique could be used to produce low-temperature application building products such as bricks, panels, roofing tiles, etc. This new recycling technique offers an excellent opportunity to eliminate enormous volumes of coal discard and to advance the circular economy in the coal industry.

Aug 2, 2022

By David J. Collins

The emergence of activated charcoal adsorption as the most popular recovery method for precious metals, has led to numerous innovations aimed at increasing the efficiency of the process. This article describes a change in traditional charcoal transfer methods which will aid in reducing charcoal attrition losses. Studies have shown that significant charcoal attrition takes place during transfer, be it when using airlifts or centrifugal pumps. Tests conducted at Pinson Mines indicated a 4 to 8% loss to the minus 20 mesh fraction of charcoal after three (3) hours of pumping charcoal. Tests conducted while the author was at Jerritt Canyon indicated that charcoal transfer was a major contributor to charcoal losses; a decrease in the amount of coarse charcoal (plus 12 mesh) and an increase in the amount of finer charcoal (minus 16 plus 20 mesh) was noted as charcoal was moved to the head of the adsorption circuit.

Jan 1, 1998

By Monette J. C, Nulty J. H

High temperatures and pressures are required to obtain acceptable stripping rates. Higher chemically induced stripping rates could reduce the need for higher temperatures which lead to cyanide losses. The higher rates could lead to lower carbon inventories and higher gold production. This paper reports laboratory and continuous test unit data which strongly suggest that the preceding can be achieved. New stripping agents demonstrate efficient stripping under conditions of cyanide depletion such as after carbon acid washing. Stripping times for gold and silver can be reduced by at least half compared to caustic cyanide through the use of these novel substances.

Jan 1, 1991