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By H. W. Turner

THE axis of the middle portion of the Ural mountains is made up chiefly of highly compressed igneous and sedimentary schists, considered of Devonian age by the Russian geologists, with large areas of serpentine (peridotite originally) gabbro, etc., intrusive in the schist series. In addition there are large areas of probably older granitic and gneissic .rocks. The nickel deposits referred to in this paper are found in the Devonian schists and their associated igneous rocks. The gabbro-peridotite intrusions probably took place in late Devonian or early Permian time, inasmuch as the Permian and Carboniferous beds lie at gentle angles on the Devonian series on the west slope of the Urals. Perhaps the first attempt to work a nickel deposit in the Urals was made about 1866 in the Revdinsk district, which is situated southwest of Ekaterinburg. I was informed by a Russian that a wet method of extracting the nickel was tried but was not a commercial success. This deposit has been described by Müller,1 Foullon,2 and Karpinski.3 Beck4 gives an abstract of these papers.

Jan 2, 1914

By F. E. Senftle

Preliminary geophysical surveys for nickel deposits are usually carried out by airborne magnetometer and surface electrical methods. Once an anomaly is discovered by these techniques, one must resort to chemistry to identify nickel and determine its concentration. Consequently, a method to determine nickel quickly and quantitatively at the exploration site could help guide detailed sampling and provide analytical data that might otherwise be delayed at distant laboratories. In addition, borehole probes capable of indicating nickel in the rock adjacent to the hole, should prove attractive to the exploration geologist. With these needs in mind, preliminary investigations have been made to demonstrate an in situ analytical technique which appears feasible for nickel exploration. The method depends on the very high energy gamma rays emitted when nickel absorbs a thermal or low energy neutron. These neutron capture gamma rays should be distinguished from the lower energy gamma rays emitted during decay of radioactive nuclides as in conventional activation analysis.

Jan 1, 1971

By Paul Queneau

Some years from now, perusal of the unfolding saga of the nickel family will show that the year 1968 was the herald of change-both in the geography of its endeavors and in its technology. No one should doubt any longer that oxide ores of nickel have come of lusty age-their heavyweight stature in the Caribbean area and in the Western Pacific can be shrunk only by immersion in the politics of unhappiness. The sulfide branch of the family has been augmented afar off by substantial ore deposits in western Australia-right across the globe from Sudbury-and in southern Africa, 9000 miles from the nickel hub. The Foreword of the 1961 AIME volume, dealing with the extractive metallurgy of copper and nickel, noted that "the dead hands of nitrogen" had been lifted from oxidation reactions utilizing air and that the industry was on the threshold of under- standing this fact. Here, at least, nonferrous industry had led its ferrous counterpart in the commercial use of tonnage oxygen in liquid phase pyrometallurgy-the reference is to oxygen flash smelting. Today large oxygen-producing plants are blossoming everywhere and the fruits which will follow are many and varied. Among them is Inco's forthcoming use of the top-blown oxygen converter for sulfide melts. The bell tolls for those "pyro- metallurgical dinosaurs" which still stalk smelter aisles the world around. Silicate oxide nickel ores will rejoice in the glow of modern elevated temperature chemical metallurgy in its various manifestations, vindicating the bulldog spirit of that ancient of clans, the hot metal men-including the renovator of Le Nickel's Doniambo Works.

Jan 10, 1968

By Fathi Habashi

In the past five years Cuba has been attempting to more than double its nickel production by constructing two new ammonia leaching plants. No metals are yet produced on commercial scale but a variety of oxides and sulfides. This report updates the Cuban nickel industry as a result of two visits : one at the invitation of the Cuban Ministry of Basic Industries in 1987 and the other as a consultant to the United Nations for the Cuban Laterite Project in 1989.

Jan 1, 1993

By Gen-ichi Nakazawa, Masamichi Fujimori, Ichiro Doi

INTRODUCTION The major products of nickel industry in Japan are the electrolytic nickel (E-Ni), the ferro-nickel (Fe-Ni) and the nickel oxide sinter (NOS), totaling in production to 90 - 100 X 103 tons/year in terms of pure nickel content, and sharing approximately 20% for E-Ni, 10% or less for NOS, and the rest for Fe-Ni. The raw materials to be used for these products depend totally upon the imports from abroad; matte, the raw material used in the production of E-Ni, is from Australia and Indonesia; matte for the NOS is from Indonesia and New Caledonia; and garnierite, the raw material for Fe-Ni, is imported in bulk from New Caledonia, Indonesia and the Philippines. This report describes the acquisition of these raw materials, the production processes, trend of supply-demand, problem areas and the measures taken, and so forth, in connection with the nickel industry in Japan. ELECTROLYTIC NICKEL 1. History The nickel industry in Japan began in 1939 by the Sumitomo Metal Mining Co., Ltd. (SMM) with 150 tons E-Ni/month under the blast furnace smelting and the metal anode electrolysis. This was temporarily suspended after the end of last World War II, but resumed in 1952 with garnierite of New Caledonia as a raw material. Since then, the production capacity has been expanded incidentally to the increase of demand. However, since the smelting of garnierite contained about 2% nickel was very costly, the smelting process had been changed to smelt the briquettes of the mixture of garnierite and nickel sulfide concentrate imported from Canada and Australia. In 1975, this smelter was closed, and SMM's nickel refinery used matte from Western Mining Corp. (WMC) of Australia as a raw material. The refining process had been the metal anode one. The crude nickel oxide derived from roasting the high grade nickel matte had been melted and reduced with coke in the electric furnace and cast into anode. In 1970, a new refinery was constructed to produce 1,000 tons Ni/month under the matte anode process, and further, in 1976, the old refinery was converted into the matte anode process, thus resulting in the total production capacity of 1,690 tons Ni/ month today under the matte anode process. Shimura Kako Co., Ltd. began in 1951 to produce a little of E-Ni, and in 1955, they constructed a shaft furnace smelter with New Caledonian garnierite as a raw material to begin the E-Ni production under the matte anode process. Its monthly production reached 400 tons in 1957, but it discontinued its smeltering in 1963 to convert to the matte import from S. Le Nickel, WMC and INCO. In 1979, it changed the source of matte supply from the above to Soroako of Indonesia, discontinued the E-Ni production in 1979, and arranged for a total toll contract with Sumitomo. Meanwhile, SMM has developed a very distingished process for nickel-cobalt separation and refining by a solvent extraction method from nickel and cobalt mixed sulfide generated as a by-product in the nickel recovering process from laterite under the Nicaro process. Nippon Mining Co., Ltd. (NMC) also developed its own process. The plants under these processes were constructed in 1975, with the monthly production capacity of 230 tons of nickel and 130 tons of cobalt by SMM, and 300 tons of nickel and 110 tons of cobalt by NMC. SMM imports the raw material from the Marinduque Mining and Industrial Corp. of the Philippines, while NMC from Queensland Nickel Pty. Ltd. of Australia. 2. Production Status 2.1 Producers and materials Today, SMM holds the monthly E-Ni production capacity of 1,920 tons, of which 1,690 tons are from the matte anode process, and the remaining 230 tons are from the mixed sulfide as a raw material. NMC also uses the mixed sulfide as a raw material for a production of 300 tons/month. [ ] Most of SMM's raw material, nickel matte, is imported from WMC of Australia, partly using the Soroako matte from Indonesia. An example of material analysis is given in Table 1. Matte is a raw material for E-Ni and NOS, and the major sources of matte supply at present are Australian WMC and Indonesian Soroako, occupying ap-

Jan 1, 1982

By M. J. Virnig, B. D. Boley, G. A. Wolfe, J. M. W. Mackenzie

A flowsheet for the recovery of nickel and cobalt from laterite ores was developed. The flowsheet involves acid leaching followed by hydroxide precipitation of the metal values and then releaching of the hydroxide cake with ammonia. Investigations of the chemistry of extraction of nickel by LIX® 84-I and a developmental reagent, XI-84-IT, along with the physical properties of the organic phases are described. Based on these investigations, suggestions with regard to design of a solvent-extraction plant and operating conditions were made.

Jan 1, 2002

By M. J. Virnig

A flowsheet for the recovery of nickel and cobalt from laterite ores has been developed which involves acid leaching followed by hydroxide precipitation of the metal values and then releaching of the hydroxide cake with ammonia. Investigations of the chemistry of extraction of nickel by LIX® 84-1 and a developmental reagent, XI-84-IT, along with the physical properties of the organic phases are described. Based on these investigations, suggestions with regard to design of a solvent extraction plant and operating conditions are made.

Jan 1, 1999

By M. J. Virnig, B. D. Boley, G. A. Wolfe, J. M. W. Mackenzie

A flowsheet for the recovery of nickel and cobalt from laterite ores has been developed which involves acid leaching followed by hydroxide precipitation of the metal values and then releaching of the hydroxide cake with ammonia. Investigations of the chemistry of extraction of nickel by LIX® 84-I and a developmental reagent, XI-84-IT, along with the physical properties of the organic phases are described. Based on these investigations, suggestions with regard to design of a solvent extraction plant and operating conditions are made.

Jan 1, 1999

By N. L. Hayward, V. H. Ness

In the past decade Australia has seen the development, construction and commissioning of three complex processing plants for the treatment of lateritic nickel ores. These have all been based on high pressure acid leaching (HPAL) for extraction of nickel and cobalt into solution, followed by solid liquid separation in a CCD circuit. However, flowsheets for separation and purification of the nickel and cobalt diverge markedly. The existing plants have been commissioned with varying degrees of success, with a variety of problems ranging from materials of construction to inadequate design. While the process problems are not insurmountable, there is much room for improvement. Currently there are several new HPAL plants at the feasibility or financing stage. All of these have adopted one of the existing flowsheets. Most of the enhancements have focused on increasing autoclave size. It is now time to assess the success and failures of the three existing plants and incorporate this experience in a design for productivity, efficiency and reliability. Towards this end, this paper discusses aspects of flowsheet optimization, materials of construction and engineering design.

Jan 1, 2001

By C. Walker

Since the 1950's, production of ferronickel from laterites has predominantly been achieved using the Rotary Kiln -Electric Furnace (RKEF) process. The productivities of kilns and furnaces have increased steadily over the years and metallurgical smelters can now rely on a smaller number of high-powered, reliable units to meet production objectives at much lower capital and operating costs per tonne of production. Modem RKEF plants are characterized by one or more process lines consisting of one large kiln feeding one large furnace. The current benchmark is one RKEF line with a high capacity kiln feeding an 80 MW furnace to process approximately 1.3 million tonnes per year of new laterite ore. It is proposed that a single RKEF line comprising one kiln producing 240 t/h of calcine feeding a 120 MW furnace could process 2 million tonnes per year of dry new ore which, for an ore grade of 2% nickel, is equivalent to 36,000 t/y of nickel per line. The plant could also be twinned to double the capacity to 72,000 t/y of nickel. This paper reviews recent developments in kiln and furnace technology, which enable substantial increase in productivity of an RKEF plant. The reduction in the capital and operating costs of a single-line, 2 million tonne of ore per year nickel laterite facility, and accompanying improvement in energy efficiency and environmental performance compared to existing operations, are also highlighted.

Jan 1, 2009

By John K. Wright

The segregation process involves heating oxide-type ores with a halide salt in the presence of a solid reductant. By a complex series of cyclic vapour-phase reactions, the desired metal is extracted from its original position in the ore and segregated to the vicinity of the reductant. In this form it is then amenable to concentration by physical methods. In this work the segregation behaviour or eight different nickel laterite ores has been examined using a laboratory rotary kiln. It was found that the silicate (serpentine) ores responded better to the segregation conditions used than did the limonitic ores. An examination of the segregated metal particles showed that they consisted of ferro-nickel. The concentration of nickel in the metallics was sensitive to the ore types and the segregation roasting conditions.

Jan 1, 1994

By E. W. Lithgow

Commercial volumes of nickeliferous laterite ores overlie part of a 90 km long belt of peridotites in central Dominican Republic. Protores are serpentinized harzburgites and dunites, with lesser serpentinite. The ore mineralogy consists mostly of goethite, serpentine-group minerals, quartz and poorly crystallized, x- ray amorphous materials. Minor constituents are hematite, gibbsite, olivine and enstatite. In the Ore Dressing plant the mine feed is subjected initially to proper sizing and blending to produce a homogenized mix. Subsequent drying and upgrading, by selective crushing and screening of rock fragments through a Barmac circuit, complete preparation of the ore for pyrometallurgical processing.

Jan 1, 1993

By J. H. Corrigan

A series of six papers describing the Falconbridge Dominicana Ferronickel project were presented at the International Laterite Symposium held as a joint project of TMS-AIME in February 1979 at New Orleans. A review of the ore mineralogy, as well as. the processing and environmental practices as they exist today at Falcondo with emphasis on modifications put into practice since 1979 are presented in two papers: Part I.- Mineralogy and Ore Dressing E.W. Lithgow - General Superintendent ? Mines Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Commercial volumes of nickeliferous laterite ores overlie part of a 90 km long belt of peridotites in central Dominican Republic. Protores are serpentinized harzburgites and dunites, with lesser serpentinite. The ore mineralogy consists mostly of goethite, serpentine-group minerals, quartz and poorly crystallized, X- ray amorphous materials. Minor constituents are hematite, gibsite, olivine and enstatite. In the Ore Dressing plant, the mine feed is subjected initially to proper sizing and blending to produce a homogenized mix. Subsequent drying and upgrading, by selective crushing and screening of rock kagments through a Barmac circuit, complete preparation of the ore for pyrometallurgical processing. Part II.- Pyrometallurgy, Fuel and Power Generation J.H. Comgan - Manager ? Production Falconbridge Dominicana, C. por A. Bonao, Dominican Republic Falcondo's energy requirements are based on oil which is refined on site to provide distillate to carry out drying and selective reduction of the nickeliferous ore in the shaft furnaces, plus bunker oil to produce electrical power for process melting, refining and ancillary use. The dryer product at 1.68% Ni is briquetted and passed counter current to hot reducing gas in 12 vertical shaft furnaces. The hot calcine discharge is melted in two high power electric furnaces at very high secondary voltage. The crude ferronickel is ladle refined and cast as 15 kg ingots or 125 gm ferrocones.

Jan 1, 1993

By Santo Ranieri

We will briefly review the nickel market in 2003 and look forward to the supply demand balance for the next few years focusing in on the key factors influencing future price dynamics. On the supply side we will examine slated brownfield and greenfield expansions including the Norilsk factor and the small to mid-range 'supply creep'. We will also review the cost side of the industry and what to expect going forward. On the demand side, we will discuss the stainless steel and non-stainless demand, the China factor and the stainless steel scrap supply cycle. We will conclude by pinpinting where the market is on the current price cycle, and where we believe the mid-term direction is headed.

Jan 1, 2004

The mineralogy and microstructure of mattes from the nickel flash smelter at Kalgoorlie, Western Australia, have been studied. The flash furnace matte consisted mainly of an intimate mixture of pentlandite and heazlewoodite with some nickel metal. The electric furnace matte was mainly an iron-nickel alloy with subsidiary pentlandite while the converter matte consisted mainly of heazlewoodite with crystals of nickel metal.

Jan 1, 1977

By Johnson G. D

Confidence in Yakabindie becoming a truly cost competitive nickel project has risen recently because of: ò the emergence of an economically effective contract mining climate; ò the delivery of cheaper energy via the Goldfields Gas Pipeline; and ò the development of the Yakabindie Process for production of nickel cathode and cobalt by-product directly from sulphide concentrates at site, dramatically cutting capital and operating costs compared to the conventional route. Development of the Yakabindie Process was a result of 'necessity being the mother of invention'. Yakabindie can now break out of the trap of relying on existing downstream processors to treat an intermediate, and instead the project can gain direct market access. The very attractive cost advantages demonstrate that hydrometallurgical processing of sulphide concentrates is a worthy prize. Improved cobalt recoveries, and tolerance of higher levels of magnesium and arsenic than allowable by smelters, are further advantages of this approach. Leach residues are combined with much larger quantities of naturally alkaline flotation tailings and remain at site. As a result the process is more environmentally sensitive than the conventional smelt/refine route, with no sulphur dioxide gas emissions and 'metal only out the gate'.

Jan 1, 1996

By C. T. Wiliams, John B. Bush, John Lamb

"THE TOWN OF HEDLEY is in the valley of the Similkameen River, about 200 miles east of Vancouver and 25 miles north of the International Boundary between British Columbia and the State of Washington. The main ore deposits are located on Nickel Plate Mountain, northeast of the town.The outcrop of the Nickel Plate system of orebodies is at an elevation of 5,900 feet. It was discovered in 1898 by prospectors and sold in the following year to the Marcus Daly interests of Butte, Montana. Production commenced in 1904 under the name of Daly Reduction Company. In 1909 control passed into the hands of the Hedley Gold Mining Company. Operation of the mine continued until 1930, when exhaustion of known ore reserves forced it to close. Upon the recommendation of Paul Billingsley (3) the mine was optioned by the 1. W. Mercer Exploration Company in 1932. Production began once more in 1934 under the name of Kelowna Exploration Company Limited, and was practically continuous until August 1955, when the mine was again shut down. The name of the latter company was changed in 1951 to Kelowna Mines Hedley Limited.The Mascot Fraction, a small wedge-shaped claim lying astride the Nickel Plate orebodies, was mined by Hedley Mascot Gold Mines Limited between 1935 and 1949. The geological setting and structural control of ore are essentially the same as in the adjoining Nickel Plate Mine.Total production from all operations on Nickel Plate Mountain to the end of 1954 was approximately 3,800,000 tons of gold ore, with a gross value in excess of $48,000,000.General GeologyNickel Plate Mountain occupies the gentle westerly dipping limb of an asymmetrical anticline, the axis of which trends northeasterly. The rocks are composed of a thick pile of Triassic limestone, limy argillite, and quartzite, -resting on a flattish floor of granodiorite near the base of the mountain. Associated with these sediments is a host of porphyritic sills and dykes of gabbro-diorite composition. In the mine area east-west brown soda-rhyolite dykes and north-south black andesite dykes crosscut all the other formations and the ore, probably following steep later fractures."

Jan 1, 1949

By R. A. Bergman

"Process descriptions are provided for the following ten plants that treat high-magnesia lateritic nickel ores (saprolite) by pyrometallurgical means: PT Aneka Tambang; Cerro Matoso S.A.; Falconbridge Dominicana C. por A.; Hyuga Smelting Company Ltd.; Larco (Societé Minière & Métallurgique de Larymna); Loma de Niquel; Le Nickel, SLN-Eramet; Nippon Yakin Kogyo Company Ltd.; Pacific Metals Company Ltd.; and PT Inco Indonesia.Flowsheets, equipment information,chemistry and production data have been compiledfor plants based on both information providedby the companies and on calculated massand energy balances.IntroductionNickel is of vital importance to modern society. Without it, we would not be able to enjoy many of the things that we take for granted, such as computers, airplanes and stainless steel appliances in our homes and workplaces, to mention a few.Nickel occurs in nature both as sulphide and oxide ores. Approximately 36% of the nickel reserves in the Western World occur as sulphide and 64% as oxide ores. Sulphide ores respond to concentration processes, whereas, oxide ores do not. Sulphide ores mined at 1% nickel can be readily concentrated to 10% nickel, whereas, oxide ores cannot be concentrated and therefore have to be processed as mined.Laterite ores are normally classified intotwo groups:1. The high-magnesia ores, saprolites or serpentines, are, as a rule, processed by smelting. The main reason for this is that the nickel replaces magnesium in the magnesium-silicate lattice. To be able to recover nickel, the lattice has to be destroyed. This can be achieved by smelting under reducing conditions.Acid leaching is also possible, but in this case, large amounts of MgSO4 or MgCl2 will be produced making it costly to regenerate the acid.2. The high-iron, low-magnesia ores are known as limonite. The nickel is relatively loosely bonded to goethite and hence can be recovered by selective reduction followed by ammonium-ammonium carbonate leaching. In recently developed processes, these ores are also being extracted by acid pressure leaching, with high Ni and Co recoveries.This paper focusses on the production of ferronickel and nickel matte from the highmagnesia ores."

Jan 1, 2003

By Donald I. Bleiwas

World primary nickel production in 1987 is projected to be 770,000 mt, slightly higher than that in 1986. Market economy country (MEC) production in 1987 is projected to be about 524,000 mt, an increase of almost 5 pct over 1986 production. Production cutbacks and closures at Japanese ferronickel plants in 1987 resulted primarily from the strong yen and higher energy prices. Cutbacks also caused reductions in ore production from Indonesia, New Caledonia, and the Philippines. Technical problems affected production, to varying degrees, in Botswana, Indonesia, and Yugoslavia. World primary nickel production for 1988 is projected to be 787,000 mt, of which 536,000 mt will be produced in MECs. Increased production is projected from Botswana, Canada, Cuba, and possibly Greece and Yugoslavia, while slight production decreases are projected for Indonesia, New Caledonia, the Philippines, and Zimbabwe. .. South African nickel production in 1988 could be severly curtailed by social strife. In the early 1990's Brazil and China could be major economic competitors to Western nickel producers.

Jan 1, 1988

By R. G. Whittemore, R. Derry

Nickel metal, in powder form, has been produced by pressure reduction, with hydrogen gas, of slurries of nickel hydroxide at temperatures up to 250°C. The nickel hydroxide was obtained by precipitation from nickel chloride and nickel sulphate solutions, using both magnesium oxide and calcium oxide. Rates of reduction and yields were determined as a function of temperature, hydrogen overpressure, seed addition, and the amount of alkali used. The mechanism of reduction of slurries obtained from the sulphate system was studied, and major differences between the sulphate system and the previously examined chloride system investigated. Specifically, in the sulphate system, contra the chloride system, no seeding was necessary, plating and densification were virtually absent and only short induction periods occurred. Grades of product are given and the use of this process in the recovery of nickel from laterites is discussed. The selective reduction of nickel from mixed hydroxide slurries and effluent treatment plant sludge has also been examined.

Jan 1, 1973