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By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By O. G. Yeremin

The Joint Venture "Inter-S" jointly with the Gintsvetmet Institute have developed a technology for manufacturing of sulphoconcrete and sulphoasphalt. The sulphoconcrete manufacturing technology comprises preliminary production of modified sulphur, which is blended in liquid form at a temperature of 120°C with an inert material preheated to the same temperature. The second promising area for the use of sulphur is partial substitution of modified sulphur for more expensive bitumen. The sulphoasphalt manufacturing process comprises preliminary production of a sulphur and bitumen mixture with a sulphur content of 30% to 40%, which is then blended with inert materials using conventional techniques. Sulphoasphalt manufactured at a full-scale plant meets all requirements set to its strength properties for road paving. Technology has been developed for production of high-purity sulphur based on rectification of liquid sulphur in a packed column. A commercial-scale plant with a capacity of up to 15 tonnes per year for production of sulphur with an impurities level of about 110-6 % by mass has been put into operation.

Jan 1, 2006

By T. N. Alexandrova

Results of mineralogical-technological research of carbonaceous rocks of Kimkansky precious metal occurrence are presented, on their basis new typemorphic natural and technological microelement associations were revealed using mathematical statistics methods. Keywords: carbonaceous rocks, processing, microelements, flotation, statistical criteria

Sep 1, 2012

By M Sampara, W Comeau

The introduction of large-diameter holes to underground mining has made possible the development of new mining methods such as the Vertical Crater Retreat (V.C.R.) method. It is not only the safest underground excavation system but also provides mass production at a lower cost than any conventional mining method (1, 2, 3, 4, 5).

Jan 1, 1981

By Arthur F. Taggart

Tins paper proposes two units (believed to be new) for designating, respectively, capacity and efficiency for primary and intermediate crushers. CAPACITY Operators know that the tonnage of rock that can be put through a particular crusher in a give time depends primarily upon the crusher setting (open setting for jaw and primary gyratory types; closed setting for cones and rolls), and secondarily on the lithological character of the feed, its maximum size, the amount of fines that it carries, its moisture content, and the method of feeding. The proposed capacity formula states a relationship between all of these factors in one empirical equation, as follows: TR = TR80KK'K" [I] in which Ts, called "reduction tons per hour" is the new capacity unit; T = tons of feed per hour requiring crushing; R80 = "80-per cent reduction ratio"; and K, K', and K" are constants that approximate quantitatively lithological character, moisture content and method of feeding, respectively. T is the hourly weight of material in the feed that is coarser than the coarsest discharge of the crusher. (For marked departures from the normal specific gravity range - 2.5 to 2.7 - T should. be adjusted to corresponding volumes.) In the crushers under consideration, discharge from the crushing zone is limited by the minimum dimension of a particle. Passage of the particle through a square-mesh screen is limited by its intermediate dimension. Sheppard1 has shown that the ratio of maximum: intermediate: minimum average dimensions of broken rock fragments may be taken as about 1.5 : 1 : 0.6 for nonslabby rocks such as are normally crushed, while for slabby rocks, such as thin-bedded sedimentaries, foliated schists and gneisses, and the blocky metamorphics, the ratio is of the average order I.3:I:0.3, with the possibility of an even smaller relative value for the thickness. Gaudin2 finds the corresponding ratio for 150 + 200-mesh pyrite to be 1.4: 1 : 0.6. The hourly tonnage of crusher-plant feed, therefore, should be diminished by the amount thereof that would pass a square-mesh screen of which the aperture is S times the crusher setting, where S is a shape factor with the value 1.7 for rocks that break exceptionally cubic; 2 for ores and rocks that exhibit no appreciable tendency to slabbiness; and 2.5 to 3, or, in exceptional cases, even larger, when the tendency to slabbiness is marked. R80 is the quotient of the theoretical square-mesh aperture that would pass 80 per cent of the feed, divided by the aperture that would pass 80 per cent of the product. It is best determined from screen tests.

Jan 1, 1941

By Arthur F. Taggart

THIS paper proposes two units (believed to be new) for designating, respectively, capacity and efficiency for primary and intermediate crushers. CAPACITY Operators know that the tonnage of rock that can be put through a particular crusher in a given time depends primarily upon the crusher setting (open setting for jaw and primary gyratory types; closed setting for cones and rolls), and secondarily on the lithological character of the feed, its maximum size, the amount of fines that it carries, its moisture content, and the method of feeding. The proposed capacity formula states a relationship between all of these factors in one empirical equation, as follows: TR = TR80KK'K" [I] in which TR, called "reduction tons per hour" is the new capacity unit; T = tons of feed per hour requiring crushing; R50 = "80-per cent reduction ratio"; and K, K', and K" are constants that approximate quantitatively lithological character, moisture content and method of feeding, respectively. T is the hourly weight of material in the feed that is coarser than the coarsest discharge of the crusher. (For marked departures from the normal specific-gravity range-2.5 to 2.7-T should be adjusted to corresponding volumes.) In the crushers under consideration, discharge from the crushing zone is limited by the minimum dimension of a particle. Passage of the particle through a square-mesh screen is limited by its intermediate dimension. Sheppard' has shown that the ratio of maximum: intermediate: minimum average dimensions of broken rock fragments may be taken as about I.5: I: 0.6 for nonslabby rocks such as are normally crushed, while for slabby rocks, such as thin-bedded sedimentaries, foliated schists and gneisses, and the blocky metamorphics, the ratio is of the average order I.3:I:0.3, with the possibility of an even smaller relative value for the thickness. Gaudin2 finds the corresponding ratio for -150 + 200-mesh pyrite to be I.4: I : 0.6. The hourly tonnage of crusher-plant feed, therefore, should be diminished by the amount thereof that would pass a square-mesh screen of which the aperture is S times the crusher setting, where S is a shape factor with the value I.7 for rocks that break exceptionally cubic; 2 for ores and rocks that exhibit no appreciable tendency to slabbiness; and 2.5 to 3, or, in exceptional cases, even larger, when the tendency to slabbiness is marked. R80 is the quotient of the theoretical square-mesh aperture that would pass 8o per cent of the feed, divided by the aperture that would pass S0 per cent of the product. It is best determined from screen tests.

Jan 1, 1941

By R. S. Dean

REQUIREMENTS for war materials have led to large scale experimentation upon metallurgical innovations. It is of interest to inquire what this may contribute of permanent value to our existing technology, as innovations adopted during war are apt to be discarded promptly at its end. This is because utilization of substandard ores usually requires a new technology for ore treatment, and a new use-pattern for employment of the products. Thus two very different problems are involved: first, devising a process; then, adopting its products by industry, with readjustments of the use-pattern if necessary. A new process may be as good or better than an old one, but the readjustments required for use of its products may prevent its general adoption if this implies scrapping existing plants and investing much additional capital. Metallurgical innovations are of three kinds: I. The use of substandard material in processes already established; 2. The grading-up of substandard material to render it more suitable for established processes; 3. The adjustment of technology and use-pattern to the raw materials that we have.

Jan 1, 1945

By Paul M. Keyser, Donald G. Foot, Jeffrey D. Mckay

In the past 30 years, there have been tremendous advancements in the uses and applications of column flotation. From their first use as final cleaners that could produce excellent grades at the cost of recoveries, columns are now being used in every stage of the flotation circuit as well as is SX-EW. Columns as roughers, final scavengers and even at the end of CIL circuits, are finding their way into the marketplace. Operational results of these new uses are presented. INTRODUCTION Flotation columns have been in use since the early 1950's in the U.S. (Hollingsworth, 1952) and the early 1960's in Canada (Trembley, Boutin, Wheeler, 1963). Application of column flotation has been somewhat diverse. In the early years, columns were used predominately for molybdenum cleaning in Canada and for phosphate flotation in the United States. Unfortunately, results met with skepticism and disdain as the columns were hard to operate, temperamental and although producing high grades, could not achieve acceptable recoveries. Since the inception of column flotation technology, the degree of knowledge for design and operation of columns has vastly improved. Despite improvements in the technology, there is still some reluctance by mineral producers to investigate the use of column flotation cells for processing stages other than cleaner flotation. This characterization is in part due to the proven advantage of flotation columns in reducing gangue entrainment in the froth product which results in higher grade products and/or fewer processing stages. Also, during the development of column technology, different types of spargers have been used with varying degrees of success. Furthermore, the general knowledge base of parameters affecting column flotation design and operation have advanced tremendously. Inefficient, or primitive, sparger design, coupled with the lack of column design and operating knowledge and experience, resulted in poor metallurgical and mechanical performance in many cases. Unfortunately, this lack of knowledge caused many column installations to be characterized as failures. The industry felt that columns could not achieve high recoveries, especially when dealing with coarse particles. Therefore, columns were characterized as cleaners, where low recoveries could be tolerated as recirculating loads rather than direct losses and froth cleaning advantages of the quiescent column flotation regime could be realized. Fortunately for the minerals industry, some producers have stood at the forefront of technology and allowed the column to be utilized for new applications. In the last decade, column flotation applications have expanded to virtually every mineral system and plant location throughout the world. The expanded application of columns has generated a new wave of interest for processing various streams. One of the most notable is in the use of columns as rougher cells. This is of particular interest to "green-field" plants and plants where expansions are taking place. Here, metallurgical superiority can be combined with maximum capital and operating cost advantages for a rapid return on investment. The superior results experienced to date, have generated a cohesive vision of the future in mineral processing where flotation columns function as single stage primary separation devices (roughers) with a single stage cleaner, if necessary. The advantages of column flotation go far beyond their original uses. We now have seen columns used as final tail scavengers, in SX-EW plants and even at the end of CIL circuits. Some of these cases will be reviewed. CASE STUDIES In an attempt to show the diversification of column flotation to many facets of the mineral processing plant, a variety of case studies will be discussed. Some of these were designed by the authors while others have been provided by plant sources. It is important to note that in each successful case, the columns were designed using the author's design and scale-up approach. This method assures that the columns are designed correctly for their particular application. For successful

Jan 1, 1993

By Edwin A. Zink, Gerald P. Zink, John E. Wolgamott

Recent advances in high-pressure water technology can be effectively employed in underground mining. The new equipment is based on standard industrial water cleaning hardware and is compatible with conventional mining techniques. Three viable applications are addressed: rock drilling, hole notching, and rock bolting. Highlights of test results are presented that were obtained in several underground mines during the last two years of development work.

Jan 1, 1982

By M Matheson

Increasingly, owners and operators of underground mines that have a long history are realising the economic and practical advantages of capturing historic mining records and converting hand drafted plans of underground mine workings into an electronic collection of attributed 3D wireframes that can be used for mine planning and exploration purposes. This case study looks at the conversion of historic data to 3D models, with examples from three historic mining operations where this task has been undertaken: West Wits gold projects in South Africa, Northern MiningÆs Radzimowice gold mine in Poland and Avalon ResourcesÆ Viscaria copper mine in Sweden. West Wits Mining Limited holds leases in the West Rand Goldfield of the Witwatersrand Basin, which has significant gold and uranium resources that have been mined since the 1890s. The Radzimowice Gold mine, Poland, hosts Au-Cu-As-Ag mineralisation that has been exploited since the 15th to 16th centuries. The Viscaria Copper mine is located in northern Sweden and was operational during a 15 year mining period to 1997. The process of data collection, management and modelling is inherently challenging for these mines; specifically, collation of historical information, organising this data into logical arrangements that could be validated and sequentially creating 3D models using geo-spatial computer software. Despite the challenges and costs involved in creating a digital 3D model, the conversion has added significant value to each project through identifying areas of potential new resources, aiding planning and presentation to stakeholders. This paper outlines the processes involved in conversion from paper records to a 3D model, the challenges encountered and how these can be overcome, and importantly, the practical and economic advantages of undertaking such a task for explorers, miners and investors.

Jan 1, 2009

By Rafael Tadeu Pinto e Moura, Giorgio De Tomi, Jacopo Seccatore

This paper describes a research and development project in an open-cast mine with the goal to achieve an average P80 of 300 mm (11,8”) in the run-of-mine (ROM) product without altering the existing budget. The project included several variables in the blast design that were not previously taken into account, such as the orientation of natural joint sets in the rock mass, specific energy of the explosive and firing sequence. The new blast design method considered the directions of natural joint sets and determined the drilling pattern and the firing sequence accordingly to favor the movement of the blasted rock along its preferential direction, to reduce its confinement. At the end of the project, it was achieved an average P80 of 304 mm (12”) in the ROM, 50% lower than the one at the beginning of the project. The final blast of the project showed a reduction of 3% of the drill and blast cost, employing the same powder factor and the same drill pattern size used at the beginning of the project. The results achieved show how rock fragmentation is related to variables that are not contemplated in the most common fragmentation models: the firing sequence and the direction of movement in the blast.

Jan 1, 2015

By Edgar Rickard

E UGAR RICKARD comes of a long line of mining men and was born at Pontgibaud, France, in 1874, where his father was then in the course of his professional work. Later his father came to California and was until his death prominently connected with milling in that state and Nevada. Edgar Rickard grew up at Berkeley, attended the University of California, graduated in 1895 from the mechanical engineering course, and remained a year longer for post-graduate work in the College of Mining. His first job was as assarer for the Mountain Copper Co., Keswick, Cal., in 1896. The following year he was assayer and surveyor for the Cornucopia Mines, Oregon. In 1898, he joined the staff of the Venture Corporation, London, and for two years made examinations for them in various parts of the world. He served as mine manager at Cripple Creek and at the Briseis tin mine, in Tasmania. From 1901 to 1905, he was general manager of the Progress Mining Co. in Lower California, but when his cousin, T. A. Rickard, bought the Mining and Scientific Press he was persuaded to come to San Francisco as business manager of that periodical. A few years later the two cousins went to London and started the Mining Magewine there as a joint venture, Edgar being the business manager. In 1915, he took over control, T. A. Rickard returning to California to devote his time to the Mining u.rbd Scientific Press. In 1917 Edgar Rickard sold out to his British associates and came home to serve in the Food Administration through the war. Rickard was one of the first of the American engineers called to his staff when Herbert Hoover began his relief work by helping stranded Americans home at the be- ginning of the war and he has been with him constantly since in the Commission for Relief in Belgium, the

Jan 1, 1929

By AIME AIME

FEW mining engineers-noted as the profession is for migratory predilections.--can point to as varied a record as Scott Turner, director of the U. S. Bureau of Mines and newly elected vice-president of the Institute. His record as printed shows that from the time of his graduation from the Michigan College of Mines in 1904 until he went to the Bureau in 1925, he worked for 21 different companies. Geographically the record is no less imposing, although one reason for this is the fact that he was field engineer for several exploration companies. Virtually every important mining state in the Union is represented in addition to Canada, Alaska, Panama, and several countries each in South America and Europe. In addition to all of the common metals he has mined tin and coal. He opened and operated for five years a group of coal mines in 73" 13' S. Lat., on the Island of Spitzbergen. This was 825 miles north of the Arctic Circle on No Man's Land, where Mr. Turner claimed and maintained pos- session under the American flag of an area of 600 square miles. Incidentally, he was a survivor of the ill-fated Lusitania, sunk by a submarine in May, 1915.

Jan 1, 1930

By P. W. Bridgman

THE thesis of this article is that the age of Newton is now coming to a close, and that recent scientific discoveries have in store an even greater revolution in our entire outlook than the revolution effected by the discovery of universal gravitation by Newton. The revolution that now confronts us, arises from the recent discovery of new facts, the only interpretation of which is that our conviction that nature is understandable and subject to law arose from the narrowness of our horizons, and that if we sufficiently extend our range we shall find that nature is intrinsically and in its elements neither understandable nor subject to law. The new experimental facts are in the realm of quantum phenomena. Comparatively little has been written for popular consumption about this new realm which has opened in the last fifteen years. The man in the street has been much more interested in relativity, which to him has seemed extremely interesting and revolutionary. Occasionally, however, there has filtered down to him the news that nearly all the theoretical physicists are occupied with a new order of phenomena which they find very much more exciting and revolutionary than any in the realm of relativity. For after all is said and done, the practical effects of relativity, measured in ,dollars and' cents or in centimeters and grams, are exceedingly small, and require specially de- signed experiments executed by men of the highest skill to show their existence at all. The phenomena with which quantum theory deals, on the other hand, are of the greatest practical importance and involve the simplest aspects of everyday life. For example, before the advent of the quantum theory no one could explain why a tea kettle of water boiling on the stove should not give out enough light in virtue of its temperature to be visible in the dark; the accepted theories of optics demanded that it should be visible, but every burned child knew that it was not.

Jan 1, 1929

By K. C. Lahiri, H. P. Das, G. G. Sarkar

"The petrographic components of any particular rank of coal often show some distinct physical and chemical characteristics. Therefore, their pro-portionate distribution in a coal greatly influences the technological behaviour of the coal.In any size or gravity separation of a coal, the petrographic constituents become segregated to different degrees in some preferred size or specific gravity range. Therefore, a knowledge of the petrographic nature of the washed and/or screened fractions is often considered essential in selecting the most efficient method for coal preparation and in exploring the proper evenues for its utilization.A graphical method is described in this paper to indicate the mineral-matter content and the petrographic components of the washed fractions of a coal at different ash levels of separation in the form of a new washability diagram. This diagram can be conveniently used to assess or predict the petrographic composition of clean coal or sinks corresponding to any desired ash level in the cleans. With the help of this diagram, it is also possible to locate the yield level of cleans at which maximum enrichment of vitrinites and exinites occurs with the least amount of mineral-matter content."

Jan 1, 1971

To clean coal mine air by developing a low-cost scrubber suitable for belt transfer and similar applications. Approach Design a scrubber operated by water only, with no moving parts. Use conventional water spray nozzles located within a duct to both move and clean the air. Use a droplet eliminator to get the water droplets and mist back out of the airstream. How It Works Conventional scrubbers require a mechanical fan driven by either an electric or a hydraulic motor. They also require water sprays and some type of scrubbing mechanism. The water powered scrubber, however, offers higher reliability over conventional scrubbers since it utilizes the water sprays to both move the air and scrub the particulate from the air. Conventional water spray nozzles are placed near one end of a rectangular duct open at both ends. The sprays are directed towards the far end of the duct where a stationary wave blade water droplet eliminator is located. Movement of the water spray droplets coming from the nozzles generates (by momentum transfer) an air movement In the same direction as the sprays. The volume of air moved Is primarily a function of the duct cross-section size, water pressure and water

Jan 1, 1981

To cool hot working environments in deep mines more efficiently, while substantially reducing the maintenance required by presently used cooling coil heat exchangers. Approach A mine's chilled water supply cools fresh air enroute to hot working areas, in an improved, direct-mixing heat exchanger. How It Works Warm, fresh ventilation air traveling through the mine's ventilation tubing enters the lower portion of the cooler heat exchanger through a large round opening designed to accept the ventilation duct. This air flow is turned upward and evenly distributed by egg-crate lattice and pair guide vans at the bottom of the cooler. On the diagram, warm air enters at the bottom left. As the air moves upward through the cooler, it passes through a plastic or wire mesh pad which is arranged so that it offers the most resistance to upward airflow immediately above the cooler inlet: this more or less equalizes the upward air flow along the length of the cooler. The air next moves through the cold water sprays, and then through a wire-mesh demister pad before exiting from the cooler at the top right. Cooling of the air is accomplished in several stages. As the incoming air passes through the lower plastic or wire mesh pad, it is exposed to water flowing downward through the pad to the water sump. This is water that has fallen from the sprays or dripped from the upper wire-mesh mist eliminator. This water is slightly warmer than the spray water since it has already done some cooling,

Jan 1, 1981

By Ingunn Opland, Silje M. Tinderholt

Drill and blast project in Norway’s capital. The contract consists of 7 rock caverns (350–950 m2), 9.2 km tunnels, and four shafts. With 110 blue-collar and 31 white-collar, the project produces an average of 16–21,000 m3 hard rock per week, with a total of 19 tunnel faces. Weekly, nine grouting rounds for water control, 800 m3 shotcrete, and 1,200 bolts are required, and 60 trucks leave the site pr. day. Challenges include blasting in densely populated areas, planning and coordination to maintain high production, obtaining a CEEQUAL certification of very good, and transporting rock on Oslo’s main highway.

Jun 13, 2023

By Andrew Hall

Many Latin American countries are facing a scarcity of water. As such, infrastructure decisions are quite different from those made in parts of the world that experience a positive water balance. In the latter case, the water treatment approach tends to be ?treat and discharge.? For Latin American regions facing the challenges that go with a negative water balance, the focus is on resource optimization and reuse. Historically, the water challenge has had a significant impact on economic development in Latin America, especially in sectors such as mining, where water usage is high. At the same time, countries such as Chile and Brazil are major development targets for mining and oil and gas operations. Given the water supply challenge, industry is increasingly turning to technologies and processes that maximize water recovery and reuse. With sulfide precipitation and ion exchange water treatment processes for example, it is possible to treat and recover more than 99 percent of water for reuse onsite. These technologies have been applied successfully in other regions of the world where water conservation practices are essential to economic survival.

Jan 1, 2012

By B. T. Stanley

Traditional methods of creating a water tight shaft liner involve the use of segmented or welded steel. When shafts are located in ground that exhibits extremely difficult conditions of high water inflow and hydraulic pressure, composite liners are often combined with ground freezing during construction. The authors were searching for a cost effective and more flexible solution to hydrostatic liners design than the traditional concrete/steel composite design used so far. Searching through new technologies developed for tunneling applications, sprayed on membranes systems seemed very promising but were not developed for the specific circumstances encountered in shaft sinking applications where ground freezing is involved. Even though freezing is a very effective technique, it creates adverse temperature conditions for the application of spray on membranes. In addition, application and hydrating cure times for those membranes products ranged between six to twenty-four hours under ideal conditions (usually temperatures well above freezing point), which eliminated them from consideration in a shaft sinking cycle. While researching different spray on membrane materials, it was discovered that Stirling Lloyd Polychem Ltd. has developed and proven a different membrane material for waterproofing liners in different tunneling applications. The characteristics of the membrane exceeds the pressure parameters encountered in frozen shaft sinking operations, and the chemical cure times were reduced to one hour per layer which worked well into the shaft sinking cycle times. More over their system included a quality control procedure that allowed insuring integrity of the membrane at application time, a very desirable feature for shaft liner construction. However, the frozen rock surface still presented an unknown in the cure time and stability equation. As all membrane products a shotcrete substrate is usually required prior to application. The hypothesis used by the author was to use this shotcrete layer, not only as a substrate, but also as a thermal insulation against the frozen rock and the membrane during both application and curing time. The authors knew from experience that shotcrete could be applied successfully over frozen rock. But the shotcrete temperature curve over time was unknown and no information were found in the available literature. Testing was required to determine whether a suitable mix of shotcrete could be applied to the frozen shaft wall to provide enough heat of hydration for a suitable period of time to create conditions suitable for membrane application and curing.

Jan 1, 2012