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By H. M. Krieg, M. J. Ungerer, C. G. C. E. van Sittert, D. J. van der Westhuizen

"The transition metals tantalum (Ta) and niobium (Nb) are of significant importance, for example in the nuclear energy sector where they are used as cladding materials, as well as in capacitors and specialized materials. For these applications a high-purity metal is needed. The separation of Ta and Nb is always a challenge since they are found together in nature and have similar chemical and physical properties, resulting in costly and laborious separation processes. A technology that has been used successfully for the separation of these metals entails solvent extraction (SX)1. While separation was achieved in a previous SX study using a sulphuric acid (H2SO4) medium with the extractants diiso-octyl phosphinic acid (PA) and di-(2-ethylhexyl) phosphoric acid (D2EHPA), due to the absence of speciation data for Ta and Nb it is not clear how the separation occurred.One method that might be suitable for determining the speciation of a reaction is molecular modelling. Calculations based on the densityfunctional theory (DFT) are now used not only for light elements and small molecules, but also metal complexes, heavy metals, and especially metal separation in SX2. In this study the aqueous phase used during SX was investigated by studying periodic systems of Ta, as a metal and in salt form, when it is in contact with H2O and H2SO4. The results were used to predict the reaction mechanism occurring during SX. Results showed that (i) in a 1:1 acid-water ratio, the deprotonation of H2SO4 was endothermic, (ii) in a 1:5 ratio deprotonation was exothermic forming HSO4 -, and (iii) in a 1:10 ratio double deprotonation occurred to form SO42- exothermically."

Jan 1, 2017

By Anuttam Patra, Romain Bordes, Andreas Fredriksson, Tommy Karlkvist, Krister Holmberg, Kota Hanumantha Rao

The present investigation aims to develop and distinguish mineral specific reagents with two functional groups for use in flotation of calcium containing minerals. For this purpose, a series of dicarboxylate-based surfactants with varying length between the carboxylate groups (one, two or three methylene groups) were synthesized. As reference, a surfactant with the same alkyl chain length but with only one carboxylate group in the polar part was synthesized. The adsorption behavior of these new reagents on pure apatite and calcite mineral surfaces was studied using Hallimond tube flotation, FTIR and ? potential measurements. The relation between the adsorption behavior of a given surfactant on a specific mineral surface and its molecular structure over a range of concentration and pH values, as well as the region of maximum recovery were established. It was found that one of the reagents, with a specific distance between the carboxylate groups, was much more selective for a particular mineral surface than the other homologues synthesized. This selective adsorption of a given surfactant to a particular mineral surface relative to other mineral surfaces as evidenced in flotation studies is substantiated by ? potential and infra-red spectroscopy data.

Jan 1, 2014

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By S. Chander, S. W. Musselman

The molecular structure of hydrophobic and hydrophilic groups in nonionic surfactants has been related to the wetting and dispersion of selected pigments. The nonionic surfactants included in this study are acetylenic diol based surfactants and ethoxylated alkyl phenols. The Langmuir model could be used to fit adsorption data. Further analysis of the data showed that the free energy of adsorption was a function of adsorption density of the surfactants at the interface. The change in free energy with adsorption density could be interpreted by considering a change in the orientation of the adsorbed molecules. Acetylenic diol based surfatants were found to have an area per molecule of 2-3 times that of similarly ethoxylated alkyl phenols. The wetting and dispersion properties of lamp black, a model hydrophobic surface, by these surfactants were investigated by contact angle measurements and particle size analysis. Acetylenic diol based surfactants with ethylene oxide contents between3.5 and 10 moles per molecule and alkyl phenol based surfactants with approximately 9 moles of ethylene oxide per molecule were found to provide superior wetting abilities. Longer ethylene oxide chains were required for superior dispersion capabilities within each family of surfactants. Complete wetting and dispersion was found to occur above the critical micelle concentration of the surfactants.

Jan 1, 2000

By Chia-Fu Chang

We revise the applicability of the theory of self-organized criticality (SOC) to the process of magnetic relaxation in type-II superconductors. It is demonstrated that the driving parameter of self-organization of vortices is the energy barrier for flux creep and not the current density. Power spectrum of the magnetic noise due to vortex avalanches is calculated and is predicted to vary with time during relaxation.

Jan 1, 2006

By Jesus Frisancho Cabrera

El aumento de precios por la demanda de acero en China, consolida a dicho país en un importador neto de molibdeno desde 2010. En ese contexto, el presente texto señala la influencia del molibdeno en la exploración del pórfido de cobre -en tanto los bajos niveles de las exportaciones de crudo de China continúan obligando a los productores de acero de Corea y Japón de molibdeno utlizarlo como fuente de Occidente.

Sep 12, 2011

By Arthur R. MacPherson

Este capítulo revisa las etapas que deben seguirse desde el momento de considerar la molienda autógena en el desarrollo de un nuevo depósito de mineral o en la expansión de una planta existente, hasta la compra de un molino autógeno. En este caso el término autógeno incluye: semi-autógeno, molinos de pebbles secundarios y molino de bolos (trozos), así como los sistemas de molienda autógena total. También se han incluido las alternativas por vía húmeda y seca. Antes de programar el ensayo debe decidirse cuantas muestras brutas son requeridas para calcular propiamente las posibilidades de molienda autógena del depósito. También ha de tomarse la decisión, de como y donde deben tomarse las muestras, por ejemplo: planta piloto situada en el sitio de localización de la planta o en otro lugar establecido; molienda en húmedo y/o en seco....etc. En el mismo programa del ensayo se obtendrán ciertos datos fundamentales. Los ensayos deberán incluir un trabajo suficiente. para determinar cuál de las moliendas, totalmente autógena o semi-autógena, debe utilizarse; y qué tipo produce la máxima eficacia en la potencia consumida. También, los otros datos pertinentes deben ser recolectados, como por ejemplo: potencias, tonelajes, alimentación, carga, tamaño del producto, carga circulante, etc. Si es necesaria una molienda secundaria para obtener el tamano final, la decisión de qué molienda debe emplearse (molino de pebbles o molino de bolas) puede requerirse un ensayo de trabajo adicional. Finalmente, la concentración del mineral puede jugar un papel importante en la selección del circuito y debería ser una parte del ensayo final una vez que se ha establecido la molienda. Para determinar qué tipo de molinos pueden satisfacer los requerimientos establecidos por la planta piloto, debe tomarse una escala para ciertos datos como: potencia del molino, consumo de acero, simple o doble etapa de molienda, tipo de molino secundario. Para asegurar un posterior entendimiento del depósito de mineral y sus características de molienda, deberán efectuarse algunos trabajos adicionales a pequena escala utilizando pequeñas muestras y molinos para producir unos datos comparables de molienda. También, algunos ensayos tales como medio de molienda óptimo, e índice de trabajo, deberán ser completados.

Jan 1, 1982

By Jorge Ganoza

El proceso del diseño de circuitos de molienda (SAG) en la planta de flotación de pórfidos de cobre, flotación de minerales polimetálicos o plantas de cianuración y minerales de oro y plata, implica energía que puede variar al procesar minerales blandos o duros. En este sentido, se buscan las operaciones que acepten el tratamiento de minerales duros en los circuitos de molienda y la clasificación del mineral de acuerdo a la dureza.

Sep 1, 2016

By Dave Otto, Ron Elliot, Ed Hatch

This paper is a summary of the work carried out by an international team of specialists in the successful explosive compaction of the sand fill core of the Molikpaq offshore oil production structure. The sand fill core is an essential element for the stability of the structure. The sand core must resist liquefaction forces caused by heavy wave action, ice loading, and earthquakes. Explosive compaction methods were used to improve the stability of 220,000 cubic meters of coarse dredged sand placed in the core area. This project was challenging for a number of reasons. It was performed offshore in Russia, seven kilometers off the East Coast of Sakhalin Island. Logistics were a challenge, not just in getting the men and materials to the site, but also working with restricted headroom inside an operating oil drilling platform. This project called for the use of specialty explosives, strict blast vibration controls requiring a complex sequential blast design, and use of custom designed drill rigs. As Russian equivalent explosives were not available, the project involved getting approval for use of North American explosives in Russia, and use of a combined Russian - Canadian blasting crew. The blasting program was carried out successfully, meeting the required densification target _in a safe, effective manner, with no damage to the structure.

Jan 1, 2000

By Chester A. Rowland

La conminución de Ios minerales es, generalmente, una etapa de preparación de la alimentación para las subsiguientes etapas del proceso. La molienda, fase de conminución de productos finos, requiere una gran inversión de capital y frecuentemente es el área de máxima utilización de potencia y de materiales resistentes al desgaste. La molienda se produce normalmente en tambores rotativos que utilizan un medio de molienda que se pierde en la misma, al elevarse con la rotación del tambor, se rompe el mineral por combinación de los efectos de impacto, atrición y abrasión, hasta producir el producto especificado. El medio de molienda pueda ser: - El propio mineral (molienda autógena - primaria y secundaria). - Medio no metálico, natural o fabricado (pebbles) - Medio metálico (barras o bolas de acero) Este capítulo tratará de molinos de barras y bolas que utilicen medio metálico de molienda.

Jan 1, 1982

By M. Cassir

"The unique properties of molten carbonates offer a large scope of applications in the field of energy. In effect, these molten salts are in the center of chemical and electrochemical reactions involving carbon and carbonaceous species, carbon dioxide and carbon monoxide, significant for energy generation or even for the production of fuels. Moreover, such media have also an oxidative character; they dissolve molecular oxygen and oxygen reduced species, O 2-, O22- and hypothetically o-, which may have an important role in waste treatments, homogeneous catalysis and synthesis of oxides. In this presentation, an overview will be given on the principal physicochemical properties of molten carbonates, before focusing on their main known application, the molten carbonate fuel cell (MCFC). Progress in other new fuel cells applications will also be analyzed, such as direct carbon fuel cell (DCFC), hybrid carbon fuel cell (HDCFC) and composite high-temperature fuel cells combining the features of MCFC and solid oxide fuel cell (SOFC). Afterwards, membranes for the separation and capture of C02 will be reviewed. Finally, other topics, as the oxidative coupling of methane in molten carbonates, will be briefly mentioned.IntroductionIn the thirty past years, the molten carbonate science and advances have been mainly dedicated to the understanding and optimization of the molten carbonate fuel cell (MCFC), which is still a major issue in the heart of a new vision of energy development. More recently, new topics related to other kinds of fuel cells (DCFC, composite SOFC/MCFC systems) and C02 capture have emerged and are concentrating important research and technological efforts. Moreover, new fields of implementation, related to molten carbonates, are also present: geology, glasses, production of nanocarbon particles etc. Considering other areas where this molten phase plays a major role, such as catalysis, waste destruction, surface treatment, it can be confirmed that the field of molten carbonates is very rich and offers many opportunities for fundamental science and competitive applications. Whatever their specific application, molten carbonates activity is associated to more efficient energy systems with low production of C02 and, in a prospective sense, to non-polluting energy using the value of C02. A recent event, the International Workshop on Molten Carbonates & Related Topics, IWMC201 I, held in Paris in 2011 , have put in evidence the importance to improve and exploit this investigation and technological domain."

Jan 1, 2012

By Uday Pal, Shizhao Su, Thomas Villalon

Compared with the current Hall–Héroult process for smelting aluminum, the Solid Oxide Membrane (SOM)-Based electrolysis process brings various advantages such as simplified design, lower cost, lower energy use, and many other environmental bene fits. However, the state-of-the-art SOM electrolysis process is limited by the solid oxide membrane’s stability and its compatibility with the molten salt and the electrode materials. This work will identify cost-effective molten salt compositions and membrane materials/architecture along with electrodes and current collectors that are all chemically compatible and provide optimum electrochemical properties for efficient aluminum oxide electrolysis.

Mar 1, 2017

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

Magnetic separation of precipitated magnetite as iron resources in copper slag is one of the potential effective ways to recycle the slag. It is preferable to convert molten fayalite slag after copper smelting process to magnetite slag via oxidation. With a TTT (Time-Temperature-Transformation) diagram, the crystal composition of the slag obtained after air isothermal oxidation could be estimated through a designed cooling path. The crystallization behaviors concerned with molten oxidation was studied for better understanding of the trade-off relationship between magnetite and hematite during molten heat treatment. Moreover, a brief consideration was implemented of the reaction mechanism.

Jan 1, 2014

By Antoine Allanore, Luis A. Ortiz, Donald R. Sadoway

"The steelmaking industry has drastically reduced its energy consumption in the last fifty years, and today’s technologies are considered to operate at their optimal efficiency with respect to energy needs. To cope with new constraints related to greenhouse gas (GHG) emissions, a change of paradigm is necessary. One of the promising technologies that could be deployed to help reach CO2 mitigation targets relies on the intensive use of electricity: molten oxide electrolysis (MOE). This paper presents the key process parameters that need to be tuned to address the practical needs for both high productivity in a steelmaking reactor and for an energy efficient process. Herein we show that contrary to common perception, the electrolysis process for ironmaking requires less energy than today’s chemical reduction route. Furthermore, we prove that most of the energy that must be provided to operate the electrolytic iron production cell is thermal energy which is readily generated by joule heating during electrolysis due to large currents being passed through the electrolyte. The energy consumption of the electrolysis cell is therefore shown to be highly dependent on the cell configuration and the chemistry of the electrolyte. As a consequence, the CO2-impact of the technology strongly depends on both the power production mode and the technological choices for design of the process, including cell configuration. Surprisingly enough, even when the electricity generation is not carbon-free, MOE still appears to be viable from the perspective of reducing GHG emissions providing sound reactor design considerations are made.IntroductionIn the context of greenhouse gas (GHG) emissions mitigation, the steelmaking industry is considering several techniques that could sustain the efforts and progress achieved by this sector in the last decades [1]. A recent report [2] on potential routes for low-CO2 steelmaking highlighted for all techniques both the strong dependency of CO2 emissions on electric power production mode and the need for a decrease in energy consumption per tonne of steel. Incited to innovate with respect to this last criterion, the steel industry considers electrolysis to be a promising technological solution, and in particular the molten oxide electrolysis (MOE) process. This process conducts electrolysis in a mixture of oxides that dissolve the iron oxide feed, which by the action of electric current is decomposed into liquid iron and oxygen gas. The opportunity for reduction in energy consumption during steelmaking by MOE is commonly attributed to the “direct” pathway from iron oxide to liquid metal offered by the use of a molten oxide melt and operation at a temperature above the melting point of iron, ideally 1600°C, to provide enough superheat for tapping the molten iron product:"

Jan 1, 2011

By J. J. Moore, B. Mishra, D. L. Olson

The production of radioactive and reactive metals, such as plutonium, uses various pyrometallurgical techniques that generate significant quantities of waste salts contaminated with hazardous, reactive or radioactive materials. Health concerns, environmental regulations and economic considerations require proper mitigation processes to recover the valuable components and for recycling or unrestricted release of these salts. The Oxygen Sparging Process converts soluble metal halides, such as chromium-, plutonium-, cerium chlorides, into insoluble oxides and/or oxychlorides which can be consolidated and separated for long-term storage or further processing. The matrix salt phase, viz. calcium and/or alkali chlorides, are clean after oxygen sparging and fit for recycling. This method has been described and its optimized parameters discussed to show that RCRA regulated elements, such as, chromium, lead, cadmium, etc. report to the consolidated phase making the salt recyclable. Salt Scrub Reduction Process for the recovery of radioactive and RCRA metals from the waste salts has been developed. The process uses a Ca-Ga intermetallic alloy which recovers over 98 percent of the reactive metals. The matrix salt phase in this process, viz. calcium or alkali metal chlorides, are clean after salt scrub reduction.

Jan 1, 1995

By D Sert, A Jayasekara, P Gardin, B J Monaghan, S J. Chew, P Zulli, D Pinson, X F. Dong, R Ferreira

In an ironmaking blast furnace (BF), molten slag and hot metal form in the softening-melting (cohesive) zone and then trickle through the coke packed bed before being discharged from the taphole. During their downward flow, there are significant interactions occurring between liquids and other phases, such as gas and packing particles. Overall, the formation, dripping and discharging of these liquid phases, particularly molten slag, have a significant impact on BF operations in terms of furnace permeability, fuel consumption, process stability, product quality and ultimately, productivity. Hence, understanding the liquid flow behaviour in the BF lower zone is critical for designing optimal operations. In the current investigation, the flow behaviour of slag droplets was investigated at a mesoscopic level using a combined numerical and physical modelling approach. The interaction between slag and carbonaceous materials was studied using sessile drop wetting experiments, slag flow through a funnel and a high temperature packed bed and the Volume of Fluid (VOF) modelling technique. Molten slag flow and counter-current gas-slag flow in the packed bed was investigated in terms of superficial gas velocity, slag properties and packing structure. The gas-slag flow behaviour at a mesoscopic level was numerically visualised, with gas velocity gradually increased up to the flooding point. The strong interaction between gas and slag was uniquely identified, which can cause localised slag flooding as well as gas channelling. Detailed information concerning the effect on slag holdup distribution, residence time and flow patterns of wettability, slag properties and bed structure were obtained. The current investigation highlights the significant role of research at a mesoscopic level in understanding macroscopic slag flow behaviour. Gas channelling, which is a critical phenomenon in a packed bed with counter-current gas-slag flow, is predicted. It can be speculated that significant gas channelling in the BF can inevitably occur prior to operational limits being reached. In the BF process, the formation of permanent gas channelling and large slag rivulets should be avoided to maintain appropriate contact between phases and hence, furnace permeability.

Jun 19, 2024

By M. F. Chambers

Neodymium metal was electrowon from a molten-chloride electrolyte at 650° C using a molten-metal cathode. A 50 mol pct NdC13-50 mol pct KC1 mixture served as the electrolyte. Binary metal alloys of &apos;Mg with Zn and Mg with Cd were used as molten cathodes. Under the best conditions, current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode. Vacuum distillation was performed at 1,100° C for 30 min under a vacuum of 10-3 to separate the cathode metals from the neodymium. Neodymium metal of 99.9+ pct purity was recovered from the Mg-Cd alloy cathode. Almost 2 pct zinc remained in the neodymium recovered from the Mg-Zn alloy.

Jan 1, 1989

By P. Amelunxen

This paper presents the authors? personal experiences in the design and operation of moly separation circuits in copper-moly concentrators. Topics discussed include column cells versus mechanical cells; use of nitrogen; use of CO2 and sulfuric acid for pH modification; and general equipment selection and sizing. A benchmarking of main operating parameters for industrial plants is presented. Upgrading curves for commercial column and mechanical cleaning circuits are also presented, showing that with average flotation kinetics and rougher concentrate grades, technical grade concentrates can be easily achieved with five column cells operating in counter-current configuration.

Jan 1, 2009

By R. Amelunxen

"The molybdenite associated with copper porphyry ores is generally treated in a flotation circuit consisting of a separation and a cleaning section. In the last few years column flotation cells have replaced the numerous counter-current stages that were previously used in the cleaning section. Despite this, little has been published regarding the number of column cleaning stages required. Therefore a Moly flotation database is assembled with the objective of verifying the existence of a common upgrading profile. This can then be used as a guide in the prediction of the number of stages required to achieve a given concentrate grade.INTRODUCTIONAlthough the first use of Column Flotation was on copper flotation products, the popularity and understanding of their operation was not really achieved until they were widely implemented in Moly circuits in early 1983. The use of columns in Moly plants has since left a legacy of information, both published and unpublished. The data collected since that time has been used primarily used to establish column operating parameters and to determine upgrading potential within the circuit.Byproduct Moly generally occurs with porphyritic copper ores in concentrations less than 0.1% MoS2. As such, piloting a new moly ore to produce, say 5 Kg/Hr MoS2, in a slurry approximately 1 Lt/min (at 10% solids), requires a moly plant feed of about 570 Kg/Hr, which translates to a mill feed rate of 200 to 800 Tonnes per day (depending whether you deal with Chilean or Canadian ores). Piloting Moly for any lower tonnage would reduce the accuracy of the testwork.Thus a need exists to collect operating data in order to establish the existence of process relationships that could be used for feasibility and design purposes.The object of this paper is to expose a preliminary relationship that could be used for the purposes described above and to apply the findings to a preliminary design of a moly cleaning circuit flowsheet."

Jan 1, 1990

By J. E. Sepulveda, R. Morrow

"The Linear Wear Theory provides a reliable framework for the assessment of grinding media performance at full scale. This theory can be applied for analyzing grinding media consumption rates in any given grinding operation as well as the evaluation of alternative grinding media products, based on actual operational data, correcting for conditions like ore hardness, feed and product sizes, mill power and circuit throughput; all of them unrelated to the grinding media intrinsic quality attributes. A series of Moly-Cop Tools 3.0 applications have been developed to facilitate the calculations involved. Moly-Cop Tools 3.0 is available, free of charge, to all interested parties through the corresponding author.INTRODUCTION Mineral grinding circuit operators recognize the significance of grinding media (balls) consumption on the cost structure of any full scale grinding facility. The effective cost associated with this essential consumable depends on two factors: delivered price and durability (quality) of the grinding media. When evaluating alternative grinding media varieties, there is a well accepted evaluation criterion by which a given media type is considered to be “cost-effective” when its unit application cost – normally expressed in $/ton of ore ground – is shown to be lower than that of a nominal reference condition: Grinding Media Cost = Ball Price x Ball Consumption (1) ($ /ton ground) ($/ton balls) (ton balls/ton ground) Under this criterion, an alternative, higher-price grinding media product could be “cost-effective” if its associated consumption rate is sufficiently lower than the reference media, enough to yield a lower grinding cost, as dictated by Equation 1. For the proper application of the above criterion, evaluators must rely on representative indicators of grinding media quality, ideally independent of most mill operating conditions. In each particular case, ball price is always a known component; however, it is not so evident how media performance (quality) differences amongst alternative product types could be assessed with a reasonable degree of accuracy and precision."

Jan 1, 2014