Search Documents

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By W. R. Richmond, T. S. Li, D. Ilievski

The reactive precipitation of ferrihydrite was studied in a laboratory semi-batch precipitator, where a highly concentrated sodium hydroxide solution was fed into an iron nitrate solution. Instantaneous hydrolysis of iron[III] takes place when the two reagents are mixed generating supersaturation, and leading to immediate precipitation of ferrihydrite via a primary nucleation mechanism then followed by limited crystallite growth to 3 to 7nm. A mathematical model of the semi-batch laboratory precipitator was used to simulate the pH responses during the precipitation of ferrihydrite at different reagent feed rates. The model comprised of interconnected compartments of averaged hydrodynamic conditions, incorporating physically meaningful turbulent mixing time constants. The precipitation process is described by the solute concentration conservation equation incorporating a postulated ferrihydrite primary nucleation model. It was found that the semi-batch precipitator model predicted the experimental pH response reasonably well. The experimental results demonstrated that the reagent feed rate has a critical effect on the course of the precipitation of ferrihydrite, i.e. it is a rate determining step given the fast hydrolysis and precipitation kinetics.

Jan 1, 2005

By X. Yang, G. D. Zhai

The prop is the most important part to ensure the proper functioning of hydraulic support. When the hydraulic support is impacted by the roof, the prop is prone to extrusion deformation, expansion, and even bursting. In order to study the stress on a doubly-telescopic hydraulic support prop under impact load, an impact simulation was carried out based on the drop weight method. First, the impact model of the hydraulic system of the prop was established in AMESim software and the dynamic response curves of the bottom and middle cylinder of the prop obtained. Then, according to the conservation of energy, the pressure formulaes in the hydraulic cylinder of the prop under impact load were derived and verified by the AMESim simulation results, and the maximum pressure on the inner surface of the hydraulic cylinder of the prop obtained. Lastly, the transient dynamic simulation of a hydraulic support prop was carried out in ANSYS Workbench software, and cloud diagrams of stress and deformation of the prop obtained using Workbench simulation. The AMESim simulation process describes the change in fluid pressure in the prop, and the pressure formulae can be used to estimate the internal pressure of the prop under impact load. The finite element analysis results show that the stress of the middle hydraulic cylinder is much greater than that on the bottom hydraulic cylinder under impact load, which can provide a reference for prop design.

Jul 2, 2022

By Miller JD, Ye Y

The Air-Sparged Hydrocyclone (ASH) has been developed for the fast and efficient flotation of fine mineral particles in a centrifugal field during the past decade at the University of Utah. Over the years, the air-sparged hydrocyclone unit has shown promising potential for the flotation of copper porphyry ore, low-grade placer gold and auriferous pyrite ores, various industrial minerals, and fine coal cleaning. Many fundamental studies including the X-ray computed tomography (CT) analysis have been carried out in order to understand the multiphase fluid flow phenomena associated with ASH flotation. With data available from these studies, it is now possible to construct more accurate ASH flotation models for different applications in order to analyse the behaviour of the system and to optimise design and operating variables. The ASH flotation model developed in this paper is based on the data given in `Air-Sparged Hydrocyclone/Advanced Froth Flotation Fine Coal Cleaning', Final Report, DOE Contract No DE-AC-88PC88853, submitted by Pennsylvania Electric Company (PENELEC), December 1989. Data from several hundred experiments with the two-inch ASH-2C air-sparged hydrocyclone (capacity 0.1 - 0.3 tph dry coal) are available from the report and have been used for this analysis. In the past, a preliminary model based on limited data had been developed. The current study, however, emphasises the global behaviour of the ASH system by utilising almost all the data from the report for the purpose of scale-up and industrial application. There are two parts in the current modeling and analysis effort for ASH flotation of fine coal. The first part is the modeling/analysis of dimensionless ratio of overflow opening area to underflow opening area, A*, and the dimensionless ratio of air flowrate to slurry flowrate, Q . The second part involves the modelling/analysis of all other variables in the system and an expert system for operation and control is introduced.

Jan 1, 1993

By N. S. Raghavendran

Based on the weld pool length and width calculations due to an empirical model (1) for submerged arc weld metal, an elegant quantitative definition of tandem submerged arc welding is established. On the basis of this theoretical consideration optimum welding parameters for joining 25 mm thick low carbon steel plate in two passes by tandem wire submerged arc welding have been experimentally found out. An assessment of the metallurgical quality of weld metal and the dependence of mechanical propenies on pool overlap has been made. Also the solution of Rosenthal (2) etc. for a moving point source of welding, which was used as a guide line in formulating the empirical model for the calculations of weld pool dimensions, is compared with the solution of empirical model for submerged arc weld pool dimensions.

Jan 1, 1990

The environmental impact of solid waste materials is closely linked to their potential to produce a hazardous leachate once deposited in a landfill. This potential is conventionally assessed with simple laboratory batch leach tests, which find more and more frequent application also in the minerals and metals industry. Such tests are intended to help distinguish between high and low risk wastes, but are completely unsuitable to allow quantitative prediction or modelling of the long-term leachate generation potential. In the present approach the leachate generation process is perceived as a combination of bulk convective transport, stagnant zone and inner particle diffusion, as well as reaction kinetic effects. Model equations are formulated accordingly. A modelling frame work, WASTESIM, has been developed at UCT, which allows flexible combination of the model components and simulation of leach scenarios. Quantitative model parameters are obtained from a systematic laboratory study on the waste material in question. The combined assessment and modelling approach is demonstrated with a study on Cr (VI) leaching from a ferro-chromium slag material. Although not straightforward, the approach is particularly useful in determining long-term liabilities in the context of waste disposal sites with considerably more reliability than has previously been possible. Keywords: waste deposits, waste leaching, heap leaching, environmental, risk assessment, Cr (VI), ferro-chromium, slag.

Jan 1, 2000

By Pengfu Tan

One copper Isasmelt furnace has been operated in Xstrata Copper at Mount Isa in Australia since 1992. A thermodynamic model and computer program, CuModel, has been developed to model the distribution behaviors of Cu, Fe, S, O, Ni, Co, Sn, Pb, Zn, As, Sb, Bi, Au and Ag, copper loss in the slag, and heat balance in copper smelting process, matte converting process and copper continuous smelting process. The thermodynamic model has been used to model the key parameters in the control of the copper Isasmelt furnace. The effects of the process parameters on the control of the copper Isasmelt furnace have been predicted and discussed. These process parameters include SiO2/Fe, matte grade, coal, temperature, spec air of feed, oxygen enrichment, and MgO contents in slag.

Jan 1, 2006

By Robert L. Lagace, Michael A. Grossman, Alfred G. Emslie

This supplement to the final report is a collection of interim and monthly reports and working memoranda prepared during the course of this program to document the progress, methods and results of the work. The supplement is divided into the self-contained sections briefly described below. I. SELECTED MONTHLY TECHNICAL LETTER REPORTS - This section is a collection of selected monthly technical letter reports that briefly summarizes the chronological development of the analyses and results, including the different concepts, theoretical approaches, and methods of data reduction and analysis explored, and the discoveries, insights and findings made along the way. More detailed treatments of the key developments and results are presented in the interim reports and working memoranda reproduced in subsequent sections of this supplementary report, and in the separately published final report. II. BACKGROUND THEORY FOR MEASUREMENT PROGRAM ON MEDIUM AND HIGH FREQUENCY RADIO TRANSMISSION IN COAL SEAMS - Working Memorandum - This working memorandum gives the initial background theory needed to guide the planned measurements and data analyses of this program to describe the propagation of radio waves-in coal seams for the frequency range of 50 to 5000 kHz. III. MODELLING AND DATA ANALYSIS OF IN-MINE ELECTROMAGNETIC WAVE PROPAGATION - Interim Report - This interim report presents detailed treatments of the data analysis and modelling techniques used, and the associated results obtained from conductor-free area propagation data measured by T. Cory in the first set of six coal mines. The mines were located in three highcoal seams; the Pittsburgh seam in northern West Virginia, the Pocahontas No. 3 seam in Virginia, and the Herrin No. 6 seam in Illinois. IV. ANALYSIS OF MF PROPAGATION DATA FROM MARGARET NO. 11, NANTY GLO, EHRENFELD, AND ADRIAN COAL MINES - Interim Report - This interim report presents detailed treatments of several improved data analysis and Modelling methods applied to, and results obtained from, conductor-free area propagation data measured by T. Cory in the second set of four coal mines. These mines were located in three low-coal seams; the Upper Freeport seam in Pennsylvania and West Virginia and the Lower Freeport and Lower Kittaning seams in Pennsylvania. In addition, this report contains a reprint of two papers presented at a Bureau of Mines sponsored EM Guided Waves in Mine Environments Workshop held in Boulder Colorado. One paper describes the three-layer theoretical model and its application to the conductor-free data from the first six mines, while the second paper describes the theory developed for the coupling of loop antennas to a cable in a mine tunnel in a coal seam, and the model's application to data in the vicinity of cables taken at the Margaret No. 11 mine. V. A METHOD FOR NONINTRUSIVE, IN-SITU MEASUREMENT OF COAL AND ROCK CONDUCTIVITIES IN A COAL MINE TUNNEL - Working Memorandum - This working memorandum briefly describes a possible direct method, and its potential advantages and shortcomings, for performing in-situ measurements of coal and rock conductivities. VI. MODELLING AND DATA ANALYSIS OF IN-MINE ELECTROMAGNETIC WAVE PROPAGATION FROM 50 to 5000 kHz - Interim Report - This interim report presents a summary comparison of theoretical and experimental results for conductor- free areas in eleven coal mines located in seven coal seams. It also summarizes the findings and their implications for intrinsically-safe, portable radio communications between roving miners.

Jan 2, 1980

OBJECTIVES ??REDUCE OPERATING COSTS ??INCREASE LIFE COMPONENTS ??EXTEND LIFE of THE DOZER ??REDUCE MAINTENANCE COST ??REDUCE DOWNTIME ??IMPROVE DURABILITY & RELIABILITY ??IMPROVE BOLD JOINTS PREFORMENCE ??IMPROVE SAFETY

May 1, 2004

Open pit mining at Bingham Canyon commenced in 1904 and about two billion tonnes of ore have been extracted since then. There remain just under one billion tonnes of ore in the pit and this will be mined by 2015. Because the porphyry system extends below the ultimate pit limits, Kennecott Utah Copper Corporation initiated a study in 1997 to determine the viability of underground mining. The study was initiated at that time because the results were to be used to compare the economics of a further pit expansion to that of an underground mine. If a pit expansion was viable then overburden removal would have to start in the near future. This paper is a summary of the work that was carried out for the underground study. Block cave mining was determined to be the most appropriate method to mine the deposit. Two block cave areas have been planned with a total production rate of 72 500 tpd. Additional sources of ore will come from skarn orebodies that are associated with the porphyry deposit. The geology of the deposits is described together with the geotechnical techniques that were used to characterise the rock in the absence of more detailed data that are normally available. A general description of the mine plan is given along with the reasons for selecting the particular methodology used. The study was completed at the end of 1998 and demonstrated the viability of underground mining at Bingham Canyon. Funds have been approved for further drilling and technical studies, which will lead up to a feasibility study in 2004/5.

Jan 1, 2000

By M. D. Budeba

Determining the efficiency of a surface coal mine operation is an essential activity, which can help in deciding on the optimal use of input resources, including effective capital allocation, in generating a desired quantity of coal of a specific quality. Mines operate today in challenging conditions, with diminishing reserves of high-quality coal, remote location of new coal deposits, infrastructure problems, environmental legislation, and the effects of climate. All these have an impact on the performance of a mine. Given such challenges, a company has to be technically efficient compared to other existing coal producers in order to generate profits. It can use the measurement of its efficiency to evaluate its productivity, benchmarking this against the best-performing mines and determining optimal variables in order to minimize slack and achieve the desired outputs. This paper discusses the use of Data Envelopment Analysis (DEA) in evaluating the efficiency of a surface coal mine supply chain for the coal export market. The supply chain is considered to be composed of subprocesses that are modelled as a multistage system. Numeric examples will be used to illustrate the application of DEA.

Jan 1, 2014

Modelling and Optimisation of Direct Reduction of Iron Ore by Coal in a Rotary Kiln

Sep 13, 2010

By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By H. P. Kritzinger, T. C. Kingsle

"Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications, including ferrovanadium, nickel carbonate, nickel laterite, iron ore reduction, and spodumene (lithium) production.This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates."

Jan 1, 2015

By S. Özgen

In this study, the possibility of beneficiation of chromite tailings in the Uckopru/Fethiye-Turkey region by a combination of hydrocyclone and multigravity separator (MGS) was investigated. The two significant operational parameters of hydrocyclone, which were diameter of the apex and diameter of the vortex, and the three significant operational parameters of the MGS, which were drum speed, tilt angle, and wash water, were varied and the results were evaluated with the central composite rotatable design. In order to produce a chromite concentrate by hydrocyclone and MGS, mathematical model equations were derived by computer simulation programming, applying the least-squares method using Minitab 15. Second-order response functions were produced for the grade and recovery of chromite concentrates.

Jan 1, 2012

By S. Özgen

In this study, the possibility of beneficiation of chromite tailings in the Uckopru/Fethiye-Turkey region by a combination of hydrocyclone and multigravity separator (MGS) was investigated. The two significant operational parameters of hydrocyclone, which were diameter of the apex and diameter of the vortex, and the three significant operational parameters of the MGS, which were drum speed, tilt angle, and wash water, were varied and the results were evaluated with the central composite rotatable design. In order to produce a chromite concentrate by hydrocyclone and MGS, mathematical model equations were derived by computer simulation programming, applying the least-squares method using Minitab 15. Second-order response functions were produced for the grade and recovery of chromite concentrates.

Jan 1, 2012

By J. Lehmann, H. Gaye

A brief review of Computational Thermodynamics software concerning the modeling and prediction of reactions involving metals, slags and fluxes is presented. Their application for various steelmaking treatments is discussed. Examples concern phosphorus removal in BOF and EAF, ladle steel desulfurization, and specific treatments for inclusions control in semi-killed or Al-killed carbon and stainless steels.

By Ravi S. Bellur-Ramaswamy, Daniel A. Tortorelli, Robert Haber, Nahil A. Sobh

We optimize continuous quench process parameters to produce functionally graded aluminum alloy extrudates. To perform this task, an optimization problem is defined and solved using a standard nonlinear programming algorithm. Ingredients of this algorithm include 1) the process parameters to be optimized, 2) a cost function: the weighted average of the precipitate number density distribution, 3) constraint functions to limit the temperature gradient (and hence distortion and residual stress) and exit temperature, and 4) their sensitivities with respect to the process parameters. The cost and constraint functions are dependent on the temperature and precipitate size which are obtained by balancing energy to determine the temperature distribution and by using a reaction-rate theory to determine the precipitate particle sizes and their distributions. Both the temperature and the precipitate models are solved via the discontinuous Galerkin finite element method. The energy balance incorporates nonlinear boundary conditions and material properties. The temperature field is then used in the reaction rate model which has as many as 105 degrees of- freedom per finite element node. After computing the temperature and precipitate size distributions we must compute their sensitivities. This seemingly intractable computational task is resolved thanks to the discontinuous Galerkin finite element formulation and the direct differentiation sensitivity method. A three-dimension example is provided to demonstrate the algorithm.

Jan 1, 2001

By S. Zhang, Z. Hua, D. Feng, X. Tong, X. Xie

The separation and beneficiation of low grade collophanite has long been a technical challenge in phosphorous production. It requires the joint efforts of process design, reagents optimisation and operational control. In this study, the statistical response surface method was applied for determining the optimum reagent dosing in the flocculate flotation of a low grade (18.59%) collophanite ore. The dosage of three reagents, including a pH regulator (Na2CO3), depressant (Na2SiO3) and flocculant (modified starch), were input parameters of the modelling design. Two quadratic mathematical models were derived for prediction of grade and recovery based on the statistical design. Statistical analysis of the experimental results validates the reliability of the models. Through further calculation, the optimum dosage of the three reagents were found to be 3,020g/t Na2CO3, 1,990g/t Na2SiO3 and 880g/t modified starch, with which a maximum recovery of 75.81% and P2O5 grade of 30.08% was obtained from flocculate flotation test. Keywords: Process optimisation, modelling, froth flotation, collophanite ore, response surface methodology

Jan 1, 2020

By Ioannis K. Kapageridis

The lignite deposits of the Kozani-Ptolemais-Amyntaio basin in western Macedonia (North-West Greece) present a difficult modelling problem. Each deposit consists of several thin lignite layers ranging from a few centimetres to a few tens of centimeters in thickness, and thin intercalated sterile layers of marly limestones, marls, clays, and sands. These layers are practically impossible to model individually due to fast lateral transition of lignite layers to humus clay and vice versa and the lack of reliable and detailed stratigraphic correlation, leading to compositing methods being applied prior to any interpolation and modelling. The complexity of the deposit is further increased by the presence of a number of faults. This paper presents the modelling and estimation procedures applied during the most recent study of the South Western Field ? a new deposit that is considered for development and lignite production over the next years and will support the operation of a new power station in the area. Special focus is given to drillhole database structuring, fault modelling, stratigraphic correlation, mineable lignite intervals compositing, and resource estimation. The use of specialised mine planning software in all stages of modelling and estimation is thoroughly explained.

Oct 1, 2009