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By H Sofatzis, J Kinal, J Siliezar, B Kirkwood

Ernest Henry Mining (EHM) is a copper, gold and magnetite mining and processing operation located 38 kilometres north east of Cloncurry in the Mount Isa - Cloncurry mineral district of north west Queensland, Australia. The EHM ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite.At the end of 2009, after a series of promising laboratory test work, EHM converted the ball mill media charge from forged steel to high chrome media. Laboratory test work also indicated that with the use of high chrome media, the pH was able to be reduced with no negative impact on plant performance. At high pH values (above 10.5), the forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response.This paper provides an overview of the effects of reducing the pH in the EHM copper rougher flotation circuit. The pH in the roughers was dropped from 10.6 to 9.6 to determine the impact on the rougher performance and the subsequent performance of the whole copper flotation circuit. It was found that there was a slightly increased improvement in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold.With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.CITATION:Kirkwood, B, Kinal, J, Siliezar, J and Sofatzis, H, 2013. Low pH trial in the Ernest Henry Mining copper rougher flotation circuit, in Proceedings MetPlant 2013 , pp 371-377 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

"The Ernest Henry Mining (EHM) ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite. At the end of 2009, EHM converted the ball mill media charge from forged steel to high chrome media. At high pH values (above 10.5), forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response. Given this, the pH in the roughers was dropped from 10.6 to 9.6 and it was found that there was a slight increase in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold. With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.INTRODUCTION The Xstrata Copper Ernest Henry Mine (EHM) is situated 38 km north east of Cloncurry, Australia. The mine began as an open-cut operation in 1998 and transitioned to a multi-sourced operation in December of 2011, utilising ore from the newly completed underground mine in addition to ore mined from the Mount Margaret Mining operations. EHM produces a combined copper gold concentrate containing 25 000 t of copper and 35 000 oz of gold annually, utilising a three stage grinding circuit along with a four stage flotation circuit. In addition to this EHM also produces 1 000 000 t of magnetite concentrate annually via a further grinding and three stage magnetic separation circuit. Based on metallurgical test work performed by Magotteaux between 2002 and 2008, the step to change from forged steel media to 18 percent chrome media was taken in 2009 in a bid to alter the pulp chemistry to improve the flotation performance in the plant (Greet, Kinal, Twomey, & Peatey, 2010). This plant trial resulted in: • Increased dissolved oxygen levels within the pulp, • A ball mill discharge Eh shift of 25 mV to more oxidising pulp potentials, and • An EDTA extractable iron percentage reduction. These improvements in the pulp chemistry resulted in an increase of 1.7 ± 0.6 percent in copper recovery and an increase of 2.9 ± 1.7 percent in gold recovery. As the plant trial using high chrome media was successful, the use of the media was adopted as the standard for the ball mill. This implementation opened the door for further process improvements around the flotation circuit."

Jan 1, 2014

By R. F. Favreau, Patrice Favreau

In many quarries and construction sites visited by the authors over the last 50 years, the latter have observed muck piles from blasting with explosives, which included numerous large blocks, in some cases of dimensions larger than the input to the crusher. The names of these sites cannot be given in the article because the owners insist that data obtained on such visits be kept confidential. Often the blasters felt that the natural fissures in the rock would compensate for the use of a low powder factor, and they asked the authors to explain why such blocks were present. A detailed analysis of the situation often indicated that the cause of the blocks is that explained by figures such as 6 and 7 below in the article.

Jan 1, 2018

By A. Niedbalska

A technique was developed for low pressure diamond synthesis using a specially prepared glassy carbon. The glassy carbon is produced in the form of solid plates by slow carbonization process of phenol formaldehyde resin interrupted at temperatures of 1273° K, 1073° K, and 923° K. The diamond synthesis is performed using cobalt plates as a catalyst-solvent. Synthesis was carried out at applied pressures of 6.0 and 3.8 GPa and a temperature of 1970° K and 2170° K. The products were analyzed by the x-ray powder dyffraction method and by microprobe to identify the diamond crystallites. The samples were taken from the place of contact between the glassy carbon and the cobalt catalyst. They were separated from the charge by a chemical method. Diamonds of the best form and the largest size were obtained at pressures that were much lower than those used in the traditional graphite method of diamond synthesis.

Jan 1, 1989

By Moxon N. T

A series of low shock energy water resistant emlulsion based explosives have been developed by combining inert materials, such as Perlite P500, into the formulation. The material handling, water resistance and explosive properties of these mixtures were determined as a function of inert additive type, density, charge diameter and emulsion base. Of the emulsion bases tested Emulite produced the best and most stable low density mixtures ranging in density from 0.8 to 1.35 g/cm3 producing velocity of detonations (unconfined) ranging from 3000 to 5500 nits. The mixtures could be detonated successfully at these densities at diameters as low as 25mm. Low shock mixtures formed by combining Emulite with Perlite P500 were successfully trailed at the Cadjebut zinc mine in Western Australia. The performance of the explosive, at three densities, was monitored using both continuous and point to point VOD techniques. The fragmentation produced by the blasts were compared by photographic analysis. During this trial the low shock emulsion mixtures were shown to be as effective as the currently used explosives (packaged emulsion) at a significantly reduced cost.

Jan 1, 1990

By V. Matthews

"INTRODUCTION Typical grinding electrification requirements are defined by high power, constant torque and slow speed. Dual pinion mills also include a need for tight tolerances in torque between the two motors, to avoid overloading any single motor. Standard induction (asynchronous) motors have often been used but only in combination with mechanical gearboxes (reducers), required to reduce process speed to the correct level for mill pinions. The gearbox introduces added system complexity, capital cost, maintenance and energy cost due to mechanical losses. SYNCHRONOUS AND ASYNCHRONOUS MOTORS Elimination of the gearbox requires a motor designed to operate at a very low speed (rpm). Traditionally, mill motor requirements were best served by synchronous motors. The benefits of synchronous motors include- • Higher Efficiency (no conductor losses in rotor) • Very high power at low speed • Flexible Power factor (leading or lagging) • Constant speed (not load dependent) • More accurate speed control Synchronous motor cost is higher due to construction complexity, need for exciter and excitation panel, brushes, brush lifters. Figure 1 represents the equivalent circuit for a synchronous motor.Asynchronous motors, also known as squirrel cage induction motors, are singly excited, per Figure 2, the resulting equivalency circuit is less complex and only in need of a single voltage source.Commonly, a DC voltage supply is connected to the rotor (both physically and electrically) via brushes. The DC voltage enables the production of flux in a single direction. The brushes are connected to rings. The slip rings encircle the rotor but are insulated from the rotor. The slip rings are connected to a rotor winding known as a field winding. On large motors, brushless exciters are often used. A brushless exciter is a small AC generator whose field circuits are mounted on the stator and armature circuits are mounted on the rotor shaft. The exciter generator’s 3-phase output is rectified to DC by a 3-phase rectifier (mounted on the shaft) and fed into the main DC field circuit. It is possible to adjust the field current on the main machine by controlling the small DC field current of the exciter generator (located on the stator). [1] Brushless synchronous motors are often preferred over the traditional brush design but introduce additional complexity to motor construction in the form of additional windings and rectifiers comprising the excitation circuit. It stands to reason that because of the additional complexity, a synchronous motor will be higher in cost than an equally rated asynchronous induction machine."

Jan 1, 2015

By Jay A. Berger

Nondestructive testing of deep foundations for integrity problems made great strides in the late 1980's. Inexpensive portable computers have allowed the immediate and rapid processing of field measured acceleration records which can provide insight into the relative structural integrity of a previously installed foundation member. Although the gathering, processing and displaying of the data is now straightforward, interpretation remains at times rather challenging. This paper provides a brief introduction into the theoretical basis for data interpretation and the hardware necessary for data acquisition. Five case studies are discussed which demonstrate the varied applications of low strain integrity testing of deep foundations and the efficiency at which they are completed. BACKGROUND One dimensional wave mechanics, when applied to a linear elastic pile with a length that is an order of magnitude greater than its width, provides a straightforward basis for the interpretation of motion measurements made at a pile top. When impacted, a stress wave travels through the pile at a wave speed, c, which is a function of the elastic modulus, E, and mass density p (i.e., E=pc2). The applied load F, and particle velocity v, at a point are related by the equation F=Zv. For a cross-sectional area A, the proportionality constant Z is equal to EA/c. Because Z is a measure of the pile's resistance to change in velocity it is called the pile impedance.

Jan 1, 1990

By Michael M. Jackson

"The mining industry has for some time compared explosive energy requirements to theresults obtained using ANFO. Drill patterns, powder factors, and explosive bulk strengthshave all been developed based on the detonation characteristics and blasting resultsexhibited by ANFO. However, there are some mining applications where the use of ANFOcan cause over_blasting if loaded to acceptable collar heights or surface breakage problemsif collar heights are reduced. A specialized, low strength, low density water gel explosivehas been developed that has loading densities in the range of 0.4 to 0.7 g/cc. The uniquecharacteristics of the low density water gel explosive is that the explosive can beformulated with a range of available bulk strengths while maintaining excellent detonationsensitivity for use in applications involving ore/waste control, restricted blast patterns,small bench heights, etc. The"

Jan 1, 1993

By J. F. McDermott

The problem of converting our raw coal, and especially those coals that are not suited for long storage, in other words soft, into a fuel which would be at once clean; of a high B. t, u. content and low ash, is one that has occupied the minds of many able chemical engineers and hydrocarbon technologists during the past few years. Low temperature carbonization is the present outcome of this line of research, and many methods have been evolved of recent years to turn out a serviceable, useful fuel, and at the same time, save the by-products. As most of the research and data within my experience and knowledge pertains to lignite or sub-bituminous coals, I will confine my remarks to coals of that character and grade: I might say that Colorado coals, commonly called lignite, are not in reality true lignite, but are sub-bituminous, although I have in my possession an analysis of a Colorado coal which shows a moisture of 17 per cent, volatile 31.5 per cent, fixed carbon 28.8 per cent, and an ash of 22.7 per cent, and B. t. u. less than 8,000. Even this, though useless for domestic or indeed industrial purposes, could not be classified as true lignite. However, for the purposes of this paper I will refer to these coals as lignite. Two thousand pounds, or one ton, of raw lignite carries about 20 per cent moisture. This, of course, varies in some coals, but is, I believe, a fair average. For carbonization purposes this is usually dried to a 5 per cent moisture, therefore leaving but 1,700 pounds of coal to be placed in the retort. From present knowledge, and with the average process of carbonization, 70 per cent of this coal will come out carbonized, or 1,190 pounds, to which is added about 10 per cent pitch, which is fried out as the coal passes through the retort, and which is used as a binder, making a total of 1,360 pounds of coke or carbonized coal. This is usually in appearance a dark colored, rather porous coke of about the size of pea coal. It burns without smoke and have a very high B. t. u. content. According to most authorities on this subject, carbon, hydrogen, oxygen, nitrogen, sulphur and ash constitute the only elements on which carbonization value of a coal depends, and of these hydrogen is the most important. It is claimed the value of a coal for carbonization purposes may be roughly surmised from the hydrogen content. If this is promising, that is, showing an available hydrogen content of from 3 to 5 per cent, the coal should be given a careful ultimate analysis. Should the seam, as often happens in lignite coals, show varying bands of coal of different structure or appearance, samples should be taken from each band as well as a gross sample taken down the face of the seam in the usual way. This is in order to determine what part of the seam is most promising for by-product processes. A seam showing a high nitrogen content adds to the attractiveness of the coal in carbonizing as; if available nitrogen is 2 per cent or better, it should give a very high ammonia yield.

Jan 1, 1923

By Shenghui Guo, Ying Lei, Wei Li, Jinhui Peng, Libo Zhang, Yu Li

"Abstract: In this work, low temperature carbothermic reduction of Panzhihua low grade ilmenite after ball milling were investigated. The ball milling of ilmenite and graphite were processed in a ball mill. The milling process can attenuate the particle of ilmenite, and the ilmenite characteristic peak were broadened and weakened. The reduction temperature and behaviors are studied on the thermo gravimetric apparatus; lower temperature and higher reaction rate were obtained for the reduction of ilmenite with graphite after milled. The reduction temperature and times of ilmenite decreased to 1000-1025°C and 40-60min via milled for 4 or 8h; Low down the reduction temperature can eliminate the solution of Mg2+ and FeTi03 in a certain degree; the reduced ilmenite has an obvious loose structure, can favored the subsequent procedure such as leaching.1 IntroductionThere is about 9.66 billion tons of Vanadic Titan-magnetite deposited in Panzhihua, China. In this reserve, there is about 8.73x108 t ofTi02, Accounting for 90.54% of the Chinese reserves, and 35.17% of the international reserves and ranking first in the world. [JJ Titanium mineral deposits major classified into Rock type and Placer type. Rock type is the igneous mineral, which have great content of FeO (Relative to Fe20 3) and gangue. The rock textures are compact and almost are complex ore. Rock type Titanium mineral major are ilmenite and titan magnetite ore, difficult to separate the metal ore and gangue. l.21 Thus, the Ti02 grade of Rock type ilmenite much lower than the Placer type (Table land 11). Panzhihua ilmenite are the typical Rock-type, due to the higher contents of MgO, CaO and Si02 and the complex mineralogy in ilmenite in Panzhihua region, making its direct reduction progressively more difficult. Mechanical activation, usually carried out by energetic milling or ball milling, was reported to significantly decreased the reduction temperature and accelerate the reaction rate of reduction of ilmenite with carbon, silicon and Magnesium. f3·(>J It reported that the process temperature were decreased to 600-1000°C and the annealing time were reduced to 30-120min after milled for 50-400 h. Shorter milling time involved was imported for else procedure such as direct leaching. 171 Hardly any research had referred to the carbothermic reduction reactivity of ilmeite milled for a short time as 1-1 Oh. In the present work, the aim is to investigate the reactivity and reaction temperature of carbothermic reduction of Panzhihua ilmenite. The Phase composition and micro morphology of samples are characterized."

Jan 1, 2011

By Ray Y. Lin

Chemical vapor deposition of tungsten carbide on the surface of steel has been investigated at temperatures between 400 and 550C in an atmosphere containing tungsten hexafluoride, hydrogen and benzene. The tungsten fluoride flow rate was maintained at 20 ml/min. The hydrogen flow rate was at 100 ml/min. The benzene concentration varied from 1.15 to 5.56% in the reaction gas. It was observed that the higher the temperature, the faster the deposition rate for tungsten carbide. But the dependence of the deposition rate on the benzene concentration was not systematic. From the x-ray diffraction analysis, it was observed that W, W2C and WC are all presented in the coating. The amount of each phase presented in the coating depends on the temperature and, to a less extent, on the benzene concentration. The microhardness measurement has also been done for all CVD carbide coatings obtained in this study.

Jan 1, 1992

By Nick A. Hasenack

A full survey of the laboratory and blast-furnace tests on 2 types of acid pellets is given. From the laboratory tests, carried out in an atmosphere containing hydrogen, it appears that type B, produced out of 100% magnetitic ores, has a far better low temperature disintegration index and a lower reducibility index than type A, produced from a hematite/magnetite mixture. The swelling index, chemical composition and mechanical properties of both types of pellets do not differ significantly. From the blast-furnace test, carried out with a burden consisting of 45% of pellets and 45% of sinter with basicsty ratio about 2.2, and at constant driving rate, it follows that there is no significant relationship between the disintegration value of the pellets and the blast-furnace permeability. If also is concluded that the lower reducibility of the type B pellets leads to a significantly higher coke consumption.

Jan 1, 1975

By Nick A. Hasenack, Heinz Kister, Rolf B. Vogel, Kees H. van Toor

A full survey of the laboratory and blast furnace tests carried out on two types of acid pellets is given. From the lab tests it appears that type B has a better low temperature disintegration index and a lower reducibility index than type A. The chemical composition and swelling indexes do not differ for both types. From the blast furnace test periods, carried out with a charge of 45% of pellets and 45% of sinter, it follows that both types of pellets lead to the same pig-iron production, blast furnace permeability, and blast furnace dust production. It also can be concluded that type B pellets cause a significantly higher coke consumption.

Jan 1, 1977

By F. C. Miller

The briquetting of fuel is an industry centuries old and has followed the hammer and tongs method of making use of any by-product fuel by the simple process of sticking the mass together with anything that will stick. If fuel briquetting, as an industry, once in the lead over coal mining, had kept pace by introducing science, there would not at this time be the mad scramble to look up the fuel briquette family tree and accept every new method as fruit without the cultivation that makes fruit worth while. Cultivation of industry is a mass of evidence showing a tremendous expenditure of money for mistakes paving the way to success. Cultivation of the mining industry is practiced by nations and low temperature distillation and fuel briquetting will in the near future receive the same consideration. Fuel briquettes were used as a winter fuel in Ireland and Scotland before the discovery of America' or the introduction of coal as a fuel to replace briquettes in Ireland. This industry was practiced by the peasants who collected peat from the bogs and cut it into brick-shaped blocks, which were set up to dry in the sun and stored under cover for use or for sale. Demand for peat briquettes led to competition that resulted in a highly refined fuel. In some localities the peat was ground and purified from the earth by washing before placing in presses to squeeze out the excess moisture and form a block of peat about four inches thick. These blocks, after standing in the sun for a few weeks, were cut into briquettes about four inches square by twelve inches long and moved under cover where they remained until thoroughly dry. In this form peat makes an excellent fuel with considerable heat, small amount of smoke while burning, and tough enough to stand hauling in carts and boats without breakage. Slack from domestic coal, non-coking and anthracite, has until recently commanded a very low price and the attention of briquette men has centered on ways and means of preparing this class of fuel for the market in the form of briquettes. Industrial plants with automatic stokers have taken kindly to cheap slack or slack that was cheap because the price has been boosted to a figure where the cost of slack plus the cost of binder and operation makes fuel briquettes somewhat expensive. However, fuel briquettes are being turned out in commercial quantities to compete with prepared lump coal and the demand is in favor of the briquette man. Science has been called to aid the briquette and it is possible to purchase a complete coal briquetting plant that will turn out between four tons per hour and thirty tons per hour of briquettes at a calculated cost per ton to cover material and every item down to insurance on the plant. A few briquettes are being ' made with a mixture of- Portland cement and pulverized coal, where this class of briquette is cheap in the making, there is the increased amount of ash due to the cement to contend with and the briquette is not one that can compete with lump coal. Most binders have a fuel value, such as coal tar, pitch, asphalt residium, flour, glue and secret binders. Most briquettes are of an egg shape, weighing between one and one-half ounces and five ounces, pressed to form with a pressure varying between 1,000 pounds and 2,500 pounds per square inch. This' pressure, together with the binder, make a lump of fuel harder than most grades of soft coal. Most of the briquettes are free from pitch odor, and any tendency to leave a trace of the binder on the fingers, easy to handle, quick to, ignite, high in heat value and capable of indefinite storage without any change. Evaporative efficiency of briquetted fuel in stationary, marine and locomotive boilers has proved that a great many low-grade coals can be fired successfully in the briquetted form, where the same fuel without briquetting failed to give boiler rating.

Jan 1, 1923

By C. Moreland

Fluidized low-temperature carbonization of coal, a recent development, offers a possibility of reducing fuel costs of coal-burning electric ?generating plants. The Research Council of Alberta have built a pilot plant and are conducting a programme to -develop a carbomzation plant for Alberta sub-bituminous coals which will produce char suitable for use as a .boiler fuel, and tar of a potentially high value as a ?chemical raw material. The economies of the process as a whole, and the value of the tar, have yet to be assessed.

Jan 1, 1958

By M. Rafieazad, P. Fathi, M. Mohammadi, A. M. Nasiri

This study examines the impact of low-temperature heat-treatment cycles on microstructure and corrosion performance of Direct Metal Laser Sintered (DMLS) AlSi10Mg_200C alloy. It is known that the morphology and the size of eutectic silicon are the two most critical factors affecting mechanical properties of the AlSi10Mg alloy. Although high-temperature heat-treatment cycles are common practice for the strengthening of the cast Al-Si-Mg alloys, in the case of DMLS fabricated AlSi10Mg alloy, high-temperature solutionizing and low temperature annealing cycles result in mechanical properties degradation primarily due to a dramatic decrease in the solubility of Si in the super-saturated a-Al matrix of the as-printed alloy. In this study, low-temperature heat-treatment cycles that only promote precipitation of Mg2Si accompanied by the interruption of the silicon network were investigated. SEM and XRD analysis were utilized to observe the evolution of microstructure after different annealing heat-treatments at 200, 250, 300, and 350°C for 3 h. Increasing the heat-treatment temperature contributed to the Si networks interruption and an increased precipitation of Mg2Si phase. Low-temperature annealing from 200 to 350°C was found to promote the homogeneity of the microstructure characterized by a uniform distribution of eutectic Si in ??-Al matrix. Additionally, in order to investigate the impact of different heat-treatment cycles on corrosion resistivity of DMLS-AlSi10Mg_200C, the potentiodynamic polarization testing and electrochemical impedance spectroscopy were performed in a 3.5 wt.% NaCl solution. The results revealed more uniformly distributed pitting attack on the corroded surface by further increase in the annealing temperature, which was attributed to the uniformity of Si dispersion. In comparison, low temperature annealing at 200°C led to a penetrating selective corrosion attack along the melt pool boundaries, resulting in a higher corrosion rate associated with the lower absolute value of impedance of the protective passive film on the surface.

Jan 1, 2018

By Huaiyang Zhou

"Hydrothermal systems are a major component of the processes that shape the composition and structure of the ocean crust, providing a major pathway for the exchange of heat and elements between the Earth’s crust and oceans, and a locus for prolific biological activity on the seafloor and underlying crust. On the other hand, the structure and composition of hydrothermal systems are the result of complex interactions between heat sources, fluids, wall rocks, tectonic controls and even biological processes.Ultraslow spreading ridges, including the Southwest Indian Ridge and the Gakkel Ridge, are most remarkable end member in plate-boundary structures (Dick et al., 2003), featured with extensive tectonic amagmatic spreading and frequent exposure of peridotite and gabbro. With intensive surveys during the last decades, it was suggested that ultraslow ridges are several times more effective than faster-spreading ridges in sustaining hydrothermal activity. This increased longevity can be attributed to deep mining of heat and even exothermic serpentinisation (Baker et al., 2004).Distinct from faster spreading ridges, one characteristics of hydrothermal mineralization on seafloor in ultraslow spreading ridges, including the active Dragon Flag hydrothermal field at 49.6 degree on the Southwest Indian Ridge, is the abundant and pervasive distribution of lower temperature minerals (such as Fe-silica or silica, Mn (Fe) oxides, sepiolite, pyrite, marcasite, etc.) in the hydrothermal fields. Structures formed by lower temperature activity in active and dead hydrothermal fields can also be identified. High temperature minerals such as chalcopyrite are rare or very limited in hydrothermal chimneys at ultraslow spreading ridges. The distribution of diverse low temperature hydrothermal activity is consistence with the deep heating mechanisms and hydrothermal circulations in the complex framework of ultraslow spreading tectonics. On the other hand, deeper and more extensive mineralization at certain locations along the ultraslow spreading ridges can be reasonably presumed."

Sep 1, 2014

By Thomas C. Ruhe

The Bureau of Mines conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) saves energy, reduces oil imports, and reduces mining costs. Low ambient temperatures may cause these recycled oils to become too viscous for proper absorption by ammonium nitrate (AN) prills and result in poor blast performance, safety hazards, and environmental problems. To help quantify and resolve these issues, viscosity, mixing, and performance tests were conducted at various temperatures. Diesel fuels No. 1 and No. 2 were studied separately and in blends with 25,50, and 75% RO. Good quality ANFO mixes (94-6) were produced with dry absorbent prills and blended fuel (No. 1 diesel plus RO) at temperatures as low as -40°F (-40°C) with 75% No. 1/25% RO, and at -20°F (-29°C) with 50/50. Diesel fuel No. 2 also made good mixes as low as -30" F (-34°C) with 75% No. 2/25% RO, and at 0°F (-18°C) with 50/50.

Jan 1, 2008

By J. C. DeSantis

Thin, highly reflective rhodium films with metal compositions greater than 98% (elemental -weight percentage) have been deposited by chemical vapor deposition using Rh(allyl)3 (ally1 = q3-C3H5) in the presence of a hydrogen plasma. Uniform, crystalline films that adhere well to several types of substrates result from depositions at temperatures as low as 150°C. Depositions using H2 (no plasma), or an argon plasma yields material that is amorphous, contains a significant amount (>14%) of residual carbon, and has a dramatically slower growth rate. The composition of these materials does not vary significantly from that of the materials obtained from the in vacuo thermal deposition with Rh(allyl)3.

Jan 1, 1992

By Renaud Cousin

Supported gold catalysts were prepared by Direct Anionic Exchange on an alumina support and tested during the reaction of CO oxidation and of saturated and unsaturated hydrocarbons (C1 to C3). The catalysts showed high activies over a range of concentrations and temperatures compatible with an application to automotive exhaust cleaning. Furthermore, a complete resistance to thermal ageing at 600°C in the absence or presence of water was observed due to the obtention of strongly anchored nanosized gold particles during the preparation step.

Oct 1, 2003