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By Paul Clifford

The Florida Institute of Phosphate Research (FIPR) is an independent, state of Florida research agency. It was created in 1978 to conduct research to enhance the competitiveness of the Florida phosphate industry. The institute also conducts research to prevent, minimize or rectify environmental impacts caused by the industry. And it helps educate the public concerning phosphate-related technology and issues. FIPR is funded by a severance tax on the industry and is governed by a five-member board of directors appointed by the governor. FIPR's research is playing a role in enhancing the competitiveness of the Florida phosphate industry. Its technology research program seeks to improve surface mining and pipeline transportation while reducing the energy cost for pumping phosphate matrix. It is developing new and improved methods of beneficiation and fertilizer production. This includes new process flowsheets and on-line analyzers and process control methods. FIPR is also developing uses for the phosphogypsum byproduct of phosphoric acid production and evaluating the risks associated with its uses.

Jan 1, 1998

By Byron Belew, Juris R. Harlamovs, D. B. Dreisinger, John L. Watson, G. A. Kordosky, Thomas O. O’Keefe

Unwanted impurities, present in raw materials, are often coextracted along with desired constituents during leaching. Due to its abundance and ease of extraction, the presence of ferric iron in leach solutions, solvent extraction circuits, and subsequently in electrowinning circuits, has always been a problem. In the case of zinc hydrometallurgical processing, iron is frequently an impurity in leach solutions. Purification of such solutions by solvent extraction, using di (2-ethylhexyl) phosphoric acid (D2EHPA) in a kerosene diluent, results in ferric ions being readily extracted along with zinc into the organic phase. Ferric iron has proven difficult to strip from the organic phase, but it is known that ferrous iron may be easily stripped from D2EHPA, and hence a process to effect reduction of iron present in the organic would have great potential. This research investigated a process to directly reduce ferric to ferrous iron in the organic phase, and to strip the ferrous iron using a dilute acid solution. The process utilized metallic zinc as the reductant and a low concentration sulfuric acid stripping solution. The results of the laboratory tests illustrated that iron could be readily removed from the organic phase by simultaneous direct reduction and acid stripping. The reductive stripping process was subsequently utilized in industry at the laboratory and pilot plant levels. The results of the industrial tests were encouraging and demonstrated the potential of this novel concept.

Jan 1, 1993

By Howard M. Cotton

Early in 1977, Amoco Production Company and Houston Chemicals, a subsidiary of Pittsburg Plate Glass (PPG) Industries, started producing iodine commercially in northwestern Oklahoma. This is significant because it is the first plant in over 40 years to be built in the United States with iodine as its sole commercial product. With the exception of a limited amount of iodine produced by Dow Chemical in Michigan, the United States is dependent upon imports from Chile and Japan for its iodine needs. The two million pounds of iodine produced annually from the Woodward plant will supply over one-third of the United States' requirements. Routine analysis of subsurface brines by the Formation Water Lab at the Amoco Production Company Research Center in Tulsa, Oklahoma, revealed unusually high concentrations of certain potentially economic minerals. Investigations determined that, of the minerals in question, iodine appeared to offer the best potential. The brines in question are located in the Morrow sands (basal Pennsylvanian) at a depth of 7,175 to 7.400 feet, in an area where Amoco has been active in a gas play for the past 20 years. The regional iodine concentration ranges from 10 to 700 ppm and averages around 300 ppm with the project area. The project is located 8 miles north and slightly east of the town of Woodward, where the well-developed, porous, and permeable sands of the Woodward trench contain large volumes of brine.

Jan 1, 1978

By E. Rigopoulos

Mining disturbs the environment, even when the ores or the minerals extracted are non-toxic. Silver & Baryte Ores Mining Co S.A (S&B) is committed to minimizing the environmental impacts of its mining activities, by implementing an integrated rehabilitation program wherever it operates. The paper discusses the principles for mining-disturbed land restoration activities on Milos Island for a successful outcome.

Jan 1, 2003

By Fathi Habashi

WHILE HYDROGEN SULFIDE precipitates metal sulfides from aqueous solutions, other gases such as sulfur dioxide, carbon monoxide, and hydrogen, under certain conditions, precipitate the metals directly. This can be achieved at high temperature and pressure. Such processes are of great technical importance, since metals of high purity are precipitated economically in a powder form. As a result of the availability of such powders on a large scale. processes for compacting metal sheet and other mill forms directly from the

Jan 1, 1970

By G. Vik, P. Chryssanthakis, S. C. Bandis, L. Haruik, N. Barton, M. Christianson, A. Makurat

The large jointed chalk reservoir situated at 3 km depth in the North sea's Ekofisk field is undergoing major compaction after nearly 15 year of oil and gas production. Approximately 150 km 3 of the overlying sediments, mostly shales, are involved in the subsidence. A maximum central subsidence of nearly 3 meters, and a maximum present rate of 45 cm per year has set in motion numerous studies of the phenomenon. Non-linear finite element (FEM) and non- linear distict element (DEM) analyses of the compaction and large scale subsidence were performed. Consistent differences between the continuum and discontinuum analyses were noted. In the latter, slip on hypothetical bedding planes and sub- vertical or vertical faults was allowed, which possibly gives a more realistic simulation of the real processes of subsidence in such a large body of rock. Laboratory studies of the reservoir joints included roughness measurement, JRC and JCS characterization, direct shear tests while saturated in heated Ekofisk oil, and coupled closure-shear-flow tests with heated oil followed by heated sea water. Discontinuum modelling using Cundall's UDEC was performed on representative jointed assemblies (two sets of steeply dipping conjugate joints) to investigate the effect of a major reduction of pore pressure within the deformable matrix and along each joint. It was found that the large shrinkage deformation of the matrix allowed joint shearing to occur despite the constraint of uniaxial strain. Relative mass bulking due to small but widely distributed joint shear possibly explains the observed maintenance of excellent productivity despite large vertical strains in the reservoir.

Jan 1, 1986

By Liguang Wang, Roe-Hoan Yoon

The thin film balance (TFB) technique was used to measure the equilibrium film thicknesses (H3 between two air bubbles in sodium dodecyl sulfate (SDS) and electrolyte (NaCl) solutions. The results were used to determine the magnitudes of the hydrophobic forces (K232) using the extended DLVO theory. The Km values determined from He measurement allowed us to predict disjoining pressure isotherms, which were found to be in excellent agreement with those obtained experimentally using a bike-wheel film holder. The rate of film thinning was measured at low SDS concentrations with varying amounts of electrolyte (NaCl) added. In general film thinning was controlled by the capillary pressure during the initial stages, while it was controlled by the surfaces forces during the later stages. At low NaCl concentrations, it was possible to predict the rate of film thinning using the Reynolds equation, provided that the driving force was corrected for the contributions from the hydrophobic force, which in turn were determined from the KZ32 values obtained from the He values measured experimentally. At high NaCl concentrations, where it was difficult to measure the equilibrium film thicknesses, the contributions from the hydrophobic forces were determined by fitting the film thinning data to the Reynolds equation. The K232 values obtained using both the equilibrium film thickness and the film thinning measurements showed that hydrophobic force deceased with increasing surfactant and salt concentrations. It was found that the hydrophobic force in foam films was very sensitive to the added electrolyte concentration.

Jan 1, 2005

By L. Barry Phelps

The complexity of surface mining operations is increasing as attention is directed towards mining larger tracts of lower grade, higher cost deposits. Large tonnage requirements from these mines necessitate utilization of many large pieces of equipment. This equipment must be utilized efficiently, with production maintained at or near designed capacities. Basically, the problem is to select, size, and schedule equipment to maximize profits and minimize adverse environmental impacts (Anon., 1977). The time, manpower, and cost limitations required to analyze a wide variety of situations and alternatives in planning surface mines have been sidestepped with the application of simulation methods using a digital computer. Since a simulator can be programmed to represent the situations which are to be analyzed, many alternatives can be evaluated in a relatively short time. Input variables are easily changed and the resulting changes which take place in the system can be analyzed. When standard methods of analyses are applied, weeks and many man-hours are involved in analyzing large-scale mining operations. At the same time many simplifying assumptions must be made since these operations are dynamic and transient. Hence, it becomes difficult to make sound engineering decisions and take proper and timely corrective action in the absence of simulation methods. This chapter is concerned with the application of one such method, namely, the open-pit materials handling simulator (OPMHS) developed by the Mining Engineering Section, The Pennsylvania State University (Manula, Albert, and Ramani, 1977).

Jan 1, 1979

By Phillip J. Maddex

After the presentation of a co-authored paper, "The Cost of Transporting Ores and Raw Materials in World Markets", at the February SME meeting, one questioner commented, "You have been talking about the large shipper and ship loads. What does the small shipper do?" This paper will attempt to answer that question, at least in part. Probably the questioner hoped to hear about specific new tools and new techniques that he could apply. But one paper could only scratch the surface of the vast fund of information available; so rather than talk specifics we should take basics, that is, people, management and technology.

Jan 1, 1967

By J. L. Fuller, N. A. Abdel-Khalek

This paper contains a brief summary of design descriptions and generally accepted designations for longwall ventilation systems. Various ventilation systems for longwalls developed using single-entry and multiple- entry systems are discussed. Design considerations specific to longwall mining are included.

Jan 1, 1991

By David Field, David Powell, Richard Hulsen

The Mission Valley Light Rail will loop through San Diego State University (SDSU)and to minimize the impact of construction most of the works will be underground. The project will require construction of a 330-m long (1080-ft), 11.24-m wide (36.9-ft),single twin track tunnel through Stadium Conglomerate, a poorly cemented dense sandy gravel with cobbles. Key technical issues are discussed including the ground conditions and predicted ground response, the use of sequential excavation methods to control deformations and specific construction concerns such as instrumentation and monitoring. Management of the construction process to minimize risk is particularly important in this environment and the strategy selected to control the works is also considered.

Jan 1, 2001

By Richard R. Klimpel

This paper reviews the use of sulfide mineral collectors in industrial flotation practice. The approach of the paper is to characterize sulfide mineral collectors in a number of ways, including by chemical structure, by influences with different classes of mineralogy, by interactions with particle size, and by interactions with frother type.

Jan 1, 1999

By E. J. Miller

The Ventilation Branch is engaged in a project to determine if low level carbon monoxide monitors used for early detection and warning of fire in a coal mine conveyor belt entry can provide protection equivalent to that of thermally actuated point type heat sensors commonly used for fire detection. A series of tests were conducted to determine the required operating parameters, such as sensor spacing and alarm levels of detected carbon monoxide to provide equivalency between' these methods of fire detection. This report summarizes the results of these tests.

Jan 1, 1980

By Ronald E. Yarbrough, Theodore L. Triplett, Larry R. Powell

The Bureau of Mines, in cooperation with the Illinois Mine Subsidence Insurance Fund, is monitoring the response of two foundations to ground movements induced by subsidence from a high-extraction retreat room-and-pillar operation in southern Illinois. The objective of this monitoring program is to study the inter- action between the ground surface and a structure during a subsidence event. Data from such a study should enhance the understanding of the mechanisms that produce structural damage and aid in the design of structures that resist such damage. This paper describes the monitoring instrumentation and techniques as they relate to the mining and site conditions. The capability of a tiltmeter to detect and follow the tilt of the foundations caused by the mining subsidence sequence is demonstrated. Using data from this tiltmeter, the development of curvature in the foundations as they conformed to the displaced ground surface is shown. This curvature is rep- resented by differences in tilt at various points on the foundations, indicating a change in tilt over a horizontal distance. Also, even though subsidence damage has not been fully analyzed, preliminary observations of the cracks that formed in the foundations are reported. These cracks resulted in the separation of one footing into distinct pieces; therefore, their effect on the tilt readings is cited.

Jan 1, 1986

By James A. Brierley

The author has known Professor Wadsworth since the 1960s, when interest in the application of microbial technology for metallurgical processes was beginning its rapid rise. The development of bioleaching and mineral biooxidation was advanced, in part, by Wadsworth's belief in the potential for its application, as well as by his numerous contributions to the understanding of the fundamentals of hydro-metallurgy. Wadsworth is recognized for fostering research and development of the field and adding credibility to microbiological-based metallurgical processes, now often referred to as biohydrometallurgy. This Wadsworth Award is recognition of the field of biohy-drometallurgy. It is an honor to serve as a representative for all those individuals involved in research and commercial development of this technology. Modern commercial application of biohydromctallurgy began with the bioleaching of copper from submarginal-grade. run-of-mine material. Kennecott Copper successfully developed this process in the 1950s at the Bingham Canyon Mine in Utah. Other mining operations around the world followed Kennecott's lead. Today, dump bioleaching remains a very low-cost process for scavenging copper from rock that cannot be economically processed by any other method. Despite the commercial success of dump bioleaching, little effort has been made to enhance the micro Biological component of this leach process. Expansion of biohydro metallurgy into recovery of other metals did not occur until the mid-1980s, when the first commercial plant for the pretreatment of refractory gold-bearing concentrate was commissioned at the Fairview operation in south Africa. Now, processes for copper bioleaching and refractory gold pretreatment are engineered specifically to promote the activity of the microorganisms. This paper reviews the current state of commercial applications of biohydrometallurgy. It examines potential future developments and portrays the role of the microbiologist in facilitating continued growth and commercial acceptance of the technology. The commercia1 examples in this paper illustrate the expansion of microbial processing in the mining industry during the last 20 years. Copper bioleaching Early commercial applications of bioleach technology involved processing submarginal-grade, copper- bearing, run-of- mine rock in dumps. Recent applications of the technology use engineered bioleach heaps. Currently. all of these operations are in the Southern Hemi-

Jan 1, 2000

By David Morrison

On the Corramandel Peninsula of New Zealand, the Waihi Gold Mine has undergone a major redevelopment. The upgrade included the construction of two very large overland belt conveyors, both rated for a capacity of 6000tph. The first of these conveyors (CVR2) traverses a total of 1600m over undulating terrain, including a significant section running through tunnels. A large hill is climbed, just after the mid-section of the conveyor run, before dropping back down prior the discharge point. The second of these conveyors (CVR8) traverses 1100m along an alignment with a horizontal curve, a number of vertical curves and a significant lift before the discharge point. The CVR8 conveyor also included a shuttling head pulley arrangement. The mine they service is inside the town of Waihi. The conveyor alignment runs through the town and out to the metallurgical process site on the outskirts of the municipal area. This paper documents the engineering process that took place in the design of these conveyors. The Martha Hill mine in Waihi, New Zealand is unique. The mine is placed in the township. Consequently there are quite stringent environmental limitations on the mine's operation. In [Figure 1] the proximity of the mine to the town is shown. In the top-centre of the photograph the alignment of the existing smaller overland conveyor can be seen leading from the mine to a tunnel through the hill in the background.

Jan 1, 2000

The purpose of this paper is to describe two systems designed to provide estimations in stratigraphic orebodies for the purposes of detailed mine planning. The first is a completely geostatistical approach and the second is a combined geostatistical/deterministic approach. The essential features of both systems are the estimation of stratigraphic ore boundaries and the subsequent use of those boundaries to provide stratigraphic (or zonal) control for block and point grade estimation (kriging). Both systems are illustrated by application to a section of, the Hilton orebodies, Queensland, Australia.

Jan 1, 1989

By C. J. Bise

Continuous mining accounts for about 69% of the nation's underground coal production. This level is not expected to change much in the near future. This is because continuous mining represents the primary means of under- ground coal production. It is also the primary means of driving development entries for underground coal mines, including longwall mines. The continuous miner worksite contains many characteristics that can lead to personnel accidents. It continues to be an area of concern for mine managers, safety engineers, and training coordinators. In an effort to assist mine management in attempts to reduce the number of accidents and injuries sustained in this area, this paper presents a loss-control-based, non-intrusive strategy for conducting safety evaluations at continuous miner worksites.

Jan 1, 1991

By A. S. Malicsi, M. D. Baker, I. Iwasaki

Fine grinding may he required for- some coals to remove sulfur and ash or to prepare coal-water slurry. Fine grinding leads to increased hall wear and its effect on the surface properties of the ground coal becomes of concern. Marked hall wear - tests were performed to study the effects of oxygen, pH, the soluble species of coal, and the addition of pyrrhotite on hall wear. The synergistic action of coal and oxygen greatly enhanced the corrosion of mild steel halls during grinding. Elec.trochemica1 measurements on a mild steel electrode in coal slurries and SEM observations of grinding hall surfaces were carried out to explore the corrosive wear mechanism.

Jan 1, 1991

By Roderick G. Eggert, John E. Tilton

During much of the 1970s and 1980s, world metal consumption grew more slowly than during the 19505 and 1960s. The slowdown contributed to surplus capacity and low real prices because actual consumption was consistently less than expected as new mining and mineral processing capacity came on stream. Over the last year or so, however, world metal consumption has picked up noticeably, raising the question, Has metal demand returned to the long-run growth rates more typical of the 1950s and 1960s than of the 1970s and 1980s? This paper examines this possibility and, more generally, assesses the factors that will shape demand for the major metals over the longer term. TRENDS IN METAL CONSUMPTION The extent to which metal consumption has recaptured the brisk growth rates typical of the 1950s, 1960s, and early 1970s is shown in Figure 1. This figure traces the consumption of crude steel, primary aluminum, refined copper, refined lead, and refined zinc between 1960 and 1987 for the western world, consisting of the OECD countries (including the United States), and the developing countries. Consumption increased in 1987 for all five metals, and preliminary data for the first six months of 1988 suggest even more substantial increases, at least for the United States (U.S. Bureau of Mines, 1988). However, Figure 1 also shows that the recent increases in consumption are not untypical of similar surges during earlier periods of economic expansion and thus may reflect only cyclical or temporary factors. In short, the available data are unable to provide a clear indication of whether recent increases in metal consumption reflect the beginning of a new era of faster growth or simply a cyclical and temporary upturn associated with the expansionary phase of the business cycle. Consequently, to pursue this issue, we are forced to examine the underlying forces that will shape metal demand trends over the next decade. The approach we have taken involves two steps. The first examines the prospects for overall economic growth. The expectation is, the faster the economy expands, the faster the production of metal-containing goods grows.2

Jan 1, 1989