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By Y. Guan

The dissolution behavior of copper and gold from their pure state and from Au/Cu alloys in cyanide solutions has been investigated using a rotating disc. Oxygen was used as an oxidant. The effect of the composition of the alloys, stirring speed of the disc, concentration of lixiviants and temperature on the overall dissolution kinetics has been studied. Gold/copper alloys of three compositions were used in this study. The atomic percent of gold in these alloys was 75, 50 and 25, respectively. The dissolution behavior of these three alloys was compared with that of pure gold and of copper under the same chemical conditions. In general, the dissolution of copper and gold from alloys is partially controlled by surface chemical reaction and largely by mass transfer.

Jan 1, 1992

By J. F. Brune

This is a shortened version of the paper ?The Methane-Air Explosion Hazard Within Coal Mine Gobs published in the 2013 volume of SME Transactions (Brune, 2013). This paper analyzes the explosion hazard resulting from the formation of methane-air mixtures in the mined-out gobs of underground longwall coal mines. Evidence from numerous mine explosions suggests that explosive methane zones can form within longwall gobs. Explosions and fires resulting from these methane accumulations have led to severe and fatal injuries to the miners, including the explosion of the Upper Big Branch mine in West Virginia, where 29 miners lost their lives. The paper also reviews current research on numerical modeling of gas flows in longwall gobs and outlines how targeted injection of nitrogen into gobs can effectively reduce the volume of such explosive methane zones. The paper concludes that comprehensive monitoring of gas compositions along the accessible fringes of the gobs along with inertization, improved ventilation schemes and further research are necessary to control this explosion hazard and make mining operations safe.

Feb 23, 2014

By Randy Reed, Barbara J. Arnold

Respirable crystalline silica poses a significant health risk, with the American Lung Association estimating that 2.3 million workers are exposed to silica in the workplace. This includes mine workers as well as those in many other industries. Reducing dust formation is sometimes not possible so other methods to reduce exposure are critical. These methods include the use of surfactants to reduce airborne dust particles. However, it is the proper selection and application of surfactants that leads to reduced dust exposure. A discussion of how surfactants work, especially for silica dust, leads to guidance for surfactant selection followed by a review of technologies for their application.

Feb 1, 2024

By J. E. Hoffman, Corby G. Anderson, T. J. Keefe, O&apos, Suzzann M. Nordwick

Antimony removal has become necessary as it is commonly found in precious metal refractory ore bodies. The Sunshine Mine in Kellogg, Idaho has recovered metallic electrowon antimony from its argentiferous tetrahedrite (Cu2S'Sb2S3) deposits for over fifty years. Recently, Sunshine conducted an intense research effort to improve and modernize its antimony facility. This paper presents information which was learned about the antimony electrowinning processes and the development of a single¬-electrolyte antimony electrowinning technology. The relevant effects of process variables were investigated. The research results and the relevant chemistries involved in metallic antimony electrowinning will be discussed.

Jan 1, 1993

By B. J. Arnold

With the passing of the 1990 Clean Air Act Amendments, many utilities are opting to switch to lower sulfur coal to meet new SO2 emissions requirements. This lower sulfur coal may be from new suppliers or it may be from current suppliers that modify existing cleaning plants or build new plants to produce this higher quality coal. New, sophisticated coal cleaning simulators are useful tools for optimizing cod cleaning circuit operating parameters to maximize the production of clean coal that meets more stringent specifications for SO2 emissions potential. The examples in this paper were developed using the Coal Cleaning Simulator (CCS), running under ASPEN PLUS™, that was developed under a Department of Energy project cosponsored by the Electric Power Research Institute. With advanced sensitivity analysis and optimization features, CCS allows a quick, efficient, cost-effective review of coal cleaning plant performance to meet current production goals and to plan future changes in plant operating parameters or circuitry configurations.

Jan 1, 1995

By Allan E. Hall, Kuda R. Mutama

Jet fan (ductless fan) ventilation in underground mines and tunnels is a subject requiring further attention. At present there are no accepted procedures or guidelines for this type of ventilation. The main reason has been the absence of sufficient general data, which has hampered the development of rules. There is great potential for using jet fans in terms of both effectiveness and economics because they eliminate the need for ventilation tubing. In the present studies a procedure is described and results are presented from a jet fan modeled in a square section wind tunnel. The major purpose of the studies was to provide fundamental data on jet fan performance after it was realized that previous work had been limited and too site specific. The jet fan position in relation to the tunnel walls was varied in order to study the influence of confining walls on entrainment rates and the resulting aerodynamics. A clearer understanding of the fundamental principles of jet fan applications was obtained.

Jan 1, 1995

By Mark R. Stanton, Douglas B. Yager

Integration and synthesis of mine-site topography, geophysical, and geochemical data yields both two- dimensional and three-Amensional perspective models for the May Day mine located in the Cement Creek drainage near Silverton, Colorado. Induced polarization, geophysical data are spatially registered with geochemical data acquired from drill hole cuttings that are contoured m three-dimensional space, thereby permitting determination of the most metalliferous and sulfur rich zones of a waste pile. This spatial modeling application was developed to be a visually intuitive tool to aid in mine waste reclamation.

Jan 1, 2000

By M. K. Mohanty

Due to inefficiencies of the flotation process, significant effort has been recently provided to develop gravity separators for treating ultrafine particles. As a result, several enhanced gravity concentrators have been developed and commercialized. The Altair Centrifugal Jig is an enhanced gravity separator that provides relatively efficient separations on +25 µm size fractions. An experimental program conducted on -600 µm coal found that the Altair Jig reduced the ash content of the 600 x 44 µm from about 30% to 10% with an 86% combustible recovery value. The pulse water pressure, feed volumetric rate and ragging volume were found to be the key operating parameters affecting the separation performances obtained from the process. An extremely low density cut point of 1.54 and an Ep value of 0.08 were indicative of the high process efficiency values achievable by the Altair jig.

Jan 1, 1998

By William H. Breeding

The remarks that follow are based substan¬tially on experience covering 45 years, 80% of which have been in placer work, rather than on a review of available literature. Most commercial placers have been deposited by the action of water. The richer and more-difficult-to-mine placers are those in the headwater areas where gradients are steepest. The most lucrative placers are generally in intermediate areas where volumes are greater, fewer boulders are present, and gradients are from 3% to 1 ½ . The higher volume, lower grade placers are in the lower reaches of river systems where gradients are lower. Where gold-bearing rivers have discharged into the sea, wave action can concentrate values on beaches, past and present.

Jan 1, 1984

By H. R. Manouchehri

"Pyrrhotite (Po) is one of the most abundant sulfide minerals in processing industry and must be rejected in most cases. Particularly, Po rejection and its selectivity against pentlandite (Pn) have long been a challenge due to similarities in the mineral composition of the two minerals and the collectorless flotation characteristics of Po. Xanthates have been widely used to promote sulfide mineral flotation; however, in the presence of xanthates, the redox potential established at the mineral/solution interface is most important, determining the flotation performance. In this paper, the importance of electrochemistry in Po and Pn flotation has been demonstrated and a comprehensive study was conducted on two different feed streams (i.e., magnetic concentrate and scavenger cleaner streams, containing magnetic and nonmagnetic forms of Po, respectively), from Vale’s Clarabelle Mill in Sudbury, Ontario, with an objective to determine if improvements in Po rejection and Pn recovery could be achieved by controlling pulp electrochemistry. By conducting a series of flotation tests under different Eh conditions and reagent usage schemes, it was revealed that higher Po content in the magnetic stream may protect Pn from being oxidized, improving Pn recovery. The results indicated that at low oxidizing pulp chemistry, the rest potential for the Pn is still high enough to allow the formation of dixanthogen to promote its flotation. Using a Pt electrode, it was found that by controlling pulp potential at -50<Eh< +50 mV, the Pn recovery and Po depression would be satisfactory. The results, using mineral electrodes (Outotec Chena analyzer), indicated that selective separation can be achieved if low-to-moderate oxidation potentials (0 to 100 mV) or reduction (0 to -100 mV) potentials are monitored using Pn and Po electrodes. Mixing two streams at 50:50 wt % would be possibly beneficial in selective separation.IntroductionPyrrhotite (Po), Fe1-xS, is one of the most abundant sulfide minerals in the processing industry. It is an iron-deficient sulfide that occurs either in monoclinic or hexagonal form. The monoclinic one is richer in sulfur and is ferromagnetic, whereas the hexagonal Po is poorer in sulfur and has no magnetic properties. In general, the ferromagnetic properties of natural Po increase with increasing sulfur content. Although Po holds significant iron content, it is not used as a feedstock for the iron and steel industry due to the difficulty in achieving complete removal of sulfur. The common availability of iron oxide ores makes the iron sulfides irrelevant for the steel industry."

Jan 1, 2015

By V. Rastogi

Acid rock drainage is the result of exposure of sulfidic materials, such as pyrites and sulfidic ores, to air and water. The oxidation of these sulfides is catalyzed by more than a million times by the bacteria Thiobacillus jerrooxidans and close families. Inhibition of these bacteria can mitigate 98% or more of the acid loading generated. This can be achieved by the use of certain surfactants that are selectively bactericidal to the lithotropic acidophilic bacteria. Bactericides are used in two ways. As periodic or continuous treatments for prevention of acidification of material actively handled and moved, and in controlled release form for reclamation where treatment sets up a change in site microbiology to replace Thiobacillus jerrooxidans with heterotrophic bacteria and creates a stable site without need for further treatments. Use of bactericides begins with laboratory testing of the site material to qualify the site for bactericide treatment and dosage determination. Site specific treatments are designed for active sites and reclamation. Once acid production is controlled, solubilization of metals is correspondingly reduced. Results and economics of use from active and reclamation sites are presented.

Jan 1, 1995

By Charles P. Lazzara, Alex C. Smith, Mark W. Ryan

The U.S. Bureau of Mines developed an experimental method to evaluate the relative effectiveness of water additives on the extinguishment of coal fires. The experiments were conducted in the fire zone of the multiple entry section of the Bruceton Experimental Mine. Chambers filled with one hundred and eighty kilograms of Pittsburgh seam coal were ignited and allowed to burn until well developed fires were achieved. Extinguishing agent-water solutions were then applied to the fires and the quantity required to extinguish the fires compared to the amount of water alone required to extinguish similar fires. A 20% diammonium phosphate-water solution required an average of 22 L to extinguish the coal fires, while two commercially available additive-water solutions required an average of 30.6 and 30.3 L, respectively. The average amount of water required to extinguish the fires was 28 L. An analysis of covariance, using the thermal energy of the coalbed, Q, to quantify the fire at the time of extinguishment, showed that the diammonium phosphate-water solution was slightly more effective at extinguishing these coal fires than water alone, while the two commercially available additive-water solutions were statistically equivalent to water alone.

Jan 1, 1992

By HASAN SERKAN GOKCEN, SERKAN CAYIRLI

The purpose of this study was to investigate the dry grindability of calcite powders in a vertically and horizontally orientable laboratory batch type stirred mill. The experimental results were evaluated using stress intensity analysis. The performance was also compared in terms of mill orientation. The results showed that the d50 values decreased with increasing stress energy down to a certain point and then increased for both milling orientations. Even though the optimum stress energies for both vertical and horizontal orientations were in the range of 1*10−3 to 5*10−3 Nm at 750 and 1500 kJ/kg energy consumption, the product size was finer for the horizontal orientation at the same stress energy value. Additionally, to the best of the authors’ knowledge, this is the first study to compare mill orientation (vertical vs. horizontal) for the same mill and under the same test conditions.

Apr 21, 2021

By Todd Kilduff, Paul Wilkinson

Microtunneling is rarely a straight forward “business as usual” endeavor. More often than not, these projects take twists and turns that require on the fly, out of the box solutions to get the project completed. This paper is a case history of a 63-inch diameter, Permalok, microtunneling project, extending nearly 700 linear feet under a hill forming the left-hand abutment to an earth embankment tailings dam. The job had three major and unexpected challenges that required unorthodox solutions. Challenge #1— Face Configuration: The Santiago Formation, a cemented sand formation with widely varying strengths, presented a challenge to configuring the face with regards to the number and length of pics and cutters. Subtle differences in type and size of the tooling had a big impact on the performance of the machine. Challenge #2—Eccentric Loading: Issues at the launch shaft with the Permalok pipe adaptors caused eccentric loading on the casing pipe. This issue resulted in overstressing and breaking of several pipe joints that ultimately led to seizure of the tunnel. Challenge #3—Back-tunnel Excavation and MTBM Recovery: There were many detailed considerations into excavating a recovery tunnel to retrieve the MTBM, especially being under a high hazard earth embankment dam.

Jun 13, 2021

By Suresh K. Bhatt

A mathematically simulated modeling technique is used in this U.S. Bureau of Mines paper to represent a hypothetical mining operation with existing mining technology and prevalent mining costs. Mining scenarios are prepared and evaluated for potential benefits and costs available through computer-assisted mining. Base criteria, parameters, and methodology are described.

Jan 1, 1991

By Ron L. Schmiermund

The Ferris-Haggarty underground mine was abandoned circa 1910, and portal discharge has since resulted in degradation of a trout fishery in the receiving waters of Haggarty Creek. Although tunnel discharge varies dramatically in volume throughout the year due to infiltration of snowmelt, compositionally it is a nearly constant low-TDS, pH-neutral, low-sulfate, copper-silicate dominated water. Between infiltration events, components of ARD accumulate in unsaturated, oxygenated environments within upper workings and are delivered to the main haulage level by the subsequent annual snowmelt flush. Mixing with non-ARD mine waters results in neutralization, dilution, and precipitation of amorphous copper carbonate and silicate phases. These mechanisms, combined with variations in the water balance, control the composition of the portal discharge. Understanding the chemical and hydrologic control mechanisms was critical to the design of a passive treatment system to decrease effluent copper concentrations.

Jan 1, 2000

By Carol A. Hill

Native sulfur occurs with barite, celestite, and bioepigenetic calcite in the Culberson, Pokorny , and Leonard Minerals deposits, Delaware basin. The sulfur in these deposits, in "castile" masses, and in deposits of the Fort S tockton district have 6 34s values between +9 and -15. Native sulfur in the caves of the Guadalupe Mountains is somewhat lighter [(634s = -15 to -25)]. Barite in the Culberson, Leonard Minerals, and Comanche Creek sulfur deposits have 63% values of +35 to +73; celestite in the Culberson and Leonard Minerals occurrences have values of +38 and +36, respectively, and 87Sr/86Sr values of 0.707808 and 0.708138, respectively. Barite associated with sulfide, deposits, Guadalupe Mountains, have [634s] values of +41 to +62. Barite at Seven aeart Gap, Apache Mountains, is somewhat less enriched in heavy sulfur [(634s = +14 to +37)].

Jan 1, 1992

By R. M. Carland, F. F. Aplan

Six natural zeolites were evaluated for their ability to selectively remove heavy metal cations from solution. Ion selectivity was found to be Pb+2>Zn+2>Ni+2 and Cu+2>Co+2 from their respective solutions. The presence of K+, Ca+2 and Mg+2 in the actual waters to be used may seriously interfere with the ion exchange and elution of cations from zeolites. Zeolites were found not to be effective in removing precious metals from their cyanide solutions.

Jan 1, 1995

By T. K. Kim

Iron, cobalt, and nickel in waste ferric chloride solutions were separated from each other by solvent extraction. The iron was extracted from the cobalt and nickel by the use of methyl isobutyl ketone, and then the cobalt was separated from the nickel by the use of a high-molecular-weight quaternary amine dissolved in a solvent of high aromatic content.

Jan 1, 1980

By E. H. Cho, Q. Luo

Pittsburgh No. 8 coal, cleaned by conventional froth flotation, was oxidized in a 2-L Parr stirred bench-top autoclave. Autoclave tests were carried out for up to 5 hrs under the following conditions: 150 to 225ºC, 60 to 500 psi 02 and 15 to 60 g of coal per 600 mL of distilled water. The oxidation of coal was evaluated by measuring the total acidic group formed on the surface of the coal and by measuring the adsorption (under standard conditions) of calcium ion from a solution. The degree of oxidation of the coal increased continuously, without much leveling off, with increasing oxygen pressure. With increasing temperature, the oxidation of the coal increased sharply between 150 to 175ºC and then leveled off above 175 °C. The adsorption of calcium was >3% on coal oxidized under the most favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The loss in Btu was found to be sensitive to oxidation temperature. This study concluded that the optimum oxidation of coal is achieved over 3 hrs at high oxygen pressures (e.g., 500 psi) at ~170ºC. This study also concluded that, when measured in terms of calcium adsorption, Btu loss and reaction time, the oxidation achieved in an autoclave is far superior to that achieved in a fluidized bed.

Jan 1, 1996