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By David J. Kruse

Accurate field measurements are essential when validating a conveyor design. They are fundamental in determining a conveyor's behavior, its long-term maintenance requirements, and the life expectancy/ condition of the installed equipment. Field measurements are also invaluable in forensic engineering, particularly when vital equipment has failed This paper will discuss a wide variety of data acquisition equipment, field measurement techniques and accuracies achieved State-of-the-art, custom designed monitoring equipment, as well as, ''08-the-shely instruments and sensors, will be discussed.

Jan 1, 2004

By Kyle L. Brennan, Scott Maybrier, Gang Chen, Scott Huang

Data from about 3200 drill holes in the offshore area at Nome, Alaska was digitized and processed. Most drill hole files have associated lithology, gold value, and blow count descriptions for each drill hole. The gold intensity was used to present the potential gold resource in the study area on the world wide web. A web page was created that gives background information on the project, descriptions about the Nome area, maps of the claim blocks that include all the normalized slices of gold deposits, and links to other relevant sites on the web. The site is located at http://mineral.uafsme.alaska.edu/nomeproject/nomehome.htm.

Jan 1, 2002

By Richard H. Kennedy, G. A. Swanquist, John W. King, Frank F. McGinley, Dale C. Mathews, Hans H. Adler, E. C. Peterson, Ralph M. Wilde

INTRODUCTION From the first historical records of the discovery of uranium as an element and the attempted classification of its minerals in the early 18th century-through its first uses in pigmentation and the coloring of glasses and ceramic glazes-until 1939 when it was discovered that the isotope U235, was fissionable, uranium oxide in the form of pitchblende ores and concentrates (produced mainly in Bohemia, Canada, and the former Belgian Congo) in recent times was the source of uranium compounds incidental as byproducts to the recovery of radium from this invariable associated source. In 1938 this byproduct production from pitchblende concentrates was about 471 st of U3O8, with over 90% from Canada and the Belgian Congo and only 25.85 st from carnotite ores in the United States.1 Under the impetus of the Atomic Energy Commission's (AEC now part of the Energy Research Development Administration) domestic and foreign production incentives and buying programs, and as an initial assurance of atomic armament capability of the United States and the Free World, the growth of the uranium mining and milling industry burgeoned from 1952 to 1962. After a short period of decline, in the second decade and in large commitments beyond, it has again extended its capacity to meet ever-increasing fuel demands of atomic power generation by the electric utilities industry. In 1961 the peak production in the United States alone was 17,758 st of U3O8. Peak aggregate domestic and foreign deliveries of 34,581 st of U3O8 to the AEC occurred in 1960.z Canada's maximum delivery of 13,506 st of U308 was made in 1959. These peak and continued productions in the Free World are largely from: the Mesozoic (Jurassic) and Tertiary (Eocene) sandstones in the United States; the quartz pebble conglomerates of Canada and the Witwatersrand; pegmatites, Jurassic limestones, and Precambrian complexes, with less but significant production; the phosphoria, where byproduct production is minor. This uranium production in the form of precipitated concentrates has come from the milling of ores from these sources, both directly and by retreatment of gold cyanidation tailings on the Witwatersrand. Milling of crude ore has followed these processes: conventional crushing and size preparation, ore drying when required, salt roasting for high vanadium ores and byproduct vanadium recovery, carbonate or acid-leaching processes, classification sand-dine separations or countercurrent decantation (CCD) circuits and complete liquid-solids separations, resin-in-pulp (RIP) or liquid-liquid (solvent) ion-ex- change extractions, clarification of pregnant liquors, precipitation, filtration and washing, sodium and vanadium removals, and drying or roasting and packaging of the high-grade, high-purity uranium concentrate commonly referred to as "yellowcake." Coupled with the hazards and control of dust generation incident to conventional crushing and milling operations, more stringent control of airborne respirable and ingestible radioactive particulates and the protection of personnel against definitive external radiation are inherent to uranium milling. Impoundment and control of tailings and other effluents of uranium milling are more restrictive than in conventional practice, be- cause long-term disposal and containment of the uranium series of radionuclides, whether in solution or in solid form, are requisite to uranium milling and are made manadatory under regulatory agencies of government. 2. GEOLOGY AND MINERALOGY OF URANIUM Early Uses and Byproduct Production of Uranium Uranium was discovered by Klaproth in 1789 but had little commercial importance until the discovery of uranium fission by Hahn and Strassman at the close of 1938. The well-known uranium ores of Joachimsthal, Czechoslovakia, the Congo, and the Colorado Plateau were early sources of radium. Minor quantities of uranium were used for small-scale technical and industrial applications, particularly in coloring glass and ceramics, but most of the uranium was discarded. The Colorado ores were also mined later, chiefly for vanadium. Impetus of Armament Capability and Fuel Demands for Atomic Power Following the discovery of atomic fission, uranium became critically important for military applications and, more recently, as a nuclear fuel. Prior to 1966 uranium was acquired in the United States almost solely for use in the weapons program of the AEC. By 1970 the AEC had procured approximately 325,000 st of U3O8 from domestic and foreign sources. Current and future marketability is primarily dependent upon commercial demand for reactor fuel. Estimates of

Jan 1, 1985

By Jamal Rostami, Jürgen Schmitt, Rohola Hasanpour

"Double Shield TBMs can be used in fast track projects for accelerated completion where there is limited information available on ground conditions and there are possibilities of encountering weak ground and shear zones. As such, the shielded TBMs are the primary choice of the machines in long tunnels, but face the possibility of entrapment in squeezing ground, which entails long delays and major risks. This paper examines the possibility of using ground improvement methods to increase ground strength, and thus, increase the capability of the machines to cope with squeezing ground conditions. In this study, 3D finite difference simulation of a shielded TBM in squeezing ground was performed to estimate the operational parameters including required thrust to get a machine out of an entrapment. This analysis was also used to evaluate the possibility of preventing machine jamming by the implementation of pre-excavation ground improvement to increase the strength of the ground. INTRODUCTION In order to face adverse tunneling conditions especially using a shielded TBM in squeezing ground, new shield designs, with extra thrust and torque, step shield geometry with reduced shield diameter from front to the back, and conical shape shields have been used. In addition, many of the new machines have the capability to implement ground improvement at distances up to 50 m ahead of the face in order to reinforce the ground and further increase in their chances to cope with squeezing ground conditions. While these features have been added to the machine, there has not been a thorough evaluation of their impact on improving the chances to avoid machine jamming in weak rocks at high depth, which is conducive to rapid convergence of the ground."

Jan 1, 2016

By Zhibiao Guo, Jinglin You, Dongshan Yang, Yuanxin Zhao, Yuhui Li, Jingwei Gao

By utilizing collapsed gangue to create gob ribs, roof cutting and roadway maintenance (RCRM) technology enables coal pillar-free mining, presenting a novel approach. Due to their inherent structure, faults, which are common geological formations, can lead to various hazards, including fault sliding and significant deformation of roadways. In this study, a selfdesigned underground engineering simulation test device is utilized to imitate the cross-fault mining of the 11,101 working face in the Qipanjing Coal Mine (East). The objective is to examine the behavior of the surrounding rock and stress evolution. Generally, the experimental findings demonstrate that compared to the return air roadway, the RCRM roadway experiences a 3.3% decrease in maximum coal rib stress. This suggests that the implementation of this technique can effectively alleviate the stress on the surrounding rock of the roadway. The maximum coal rib stress, lateral pressure of the gob rib, and maximum deformation of the roof near the fault of the RCRM roadway are 11.3%, 25.6%, and 86.1% greater than those of the conventional geological conditions, respectively. The roadway deformation is negatively impacted by the fault structure. Based on experimental data and field measurements, a discrepancy in the maximum roof deformation between the test and field monitoring results under typical geological conditions is 8%. This indicates a favorable alignment between the test results and the real-life scenario. In conclusion, the proposed targeted control technique is implemented in the field by integrating the mining invariant equation and gangue volume expansion equation. This not only validates the effectiveness of the technology but also offers valuable insights for the future utilization of RCRM technology under comparable circumstances.

Feb 20, 2024

By Jian Wang, Kun Li, Hao Wu, Juan Nan

In this paper, in order to solve the problems of low accuracy and slow speed of fire flame recognition, an extreme learning machine (ELM) method based on improved Harris hawks optimization (IHHO) is proposed for fire flame recognition. A novel Harris hawks optimization (HHO) is used to solve the problem of parameter selection of ELM. In order to solve the problem that the original HHO is prone to fall into local optimum, firstly circle mapping is used to initialize the population to solve the problem of uneven distribution and small range of the initial population. Then the formula of escaping energy of HHO is modified to make the population have a large range in the middle and late iterations while gradually decreasing in the whole iteration process. Thus, the exploitation stage in HHO is improved to make the search range smaller near the optimal solution to accelerate the convergence process. Finally, at the end of each iteration, a certain number of individuals are selected to perform Gaussian and Cauchy hybrid mutation to prevent the IHHO from falling into local optimization. Through three groups of experiments, the effectiveness of the proposed IHHO and IHHO-ELM is verified. In experiment 1, the convergence performance of IHHO is significantly better than that of the other remaining algorithms in the test results of six benchmark functions. In experiments 2 and 3 of real fire flame recognition case, IHHO-ELM outperforms other remaining algorithms on the whole and has significant advantages in some indexes.

Jan 17, 2023

By L. Darkwah

The use of explosives in coal mining inevitably results in oversize, midsize and undersize (fines) products due to fragmentation. The oversize can be broken into smaller sizes by further processing. However, the undersize have a negative affect on the efficiency of a mining operation. Therefore, limiting the amount of fines can be economically crucial. This paper concerns investigations aimed at reducing fines generation in coal mining. Inherent fractures were identified as one of sources of fines generation. This paper is centered on establishing a relationship between the fracture occurrence, the explosive properties and the blast outputs, which are evaluated in terms of the fines generated.

Jan 1, 1998

By Joern Katzer

It is vitally important to any tunnel project to have an accurate and reliable survey control network inside the tunnel for layouts, as-built surveys, and to provide guidance to the tunnel boring machine (TBM). However, the concepts and methodology to provide such a survey network are sometimes not well understood. For example, the first anticipated survey task that takes place during the bidding process is often ignored, which is to provide a comprehensive survey network preanalysis for the surface network and tunnel traverse based on survey statistics that will be used to make informed decisions on the survey requirements and methodology. Instead, these steps are often only vaguely based on previous results and prior tunneling experience. But each tunnel is different, and a solution that worked for one tunnel project might be unsuitable for another. The purpose of this paper is to provide tunnel project engineers, managers and surveyors with the general concepts for tunnel survey methodologies and examines several statistical tools for a basic horizontal and vertical tunnel survey preanalysis. These survey statistics tools provide useful estimates of the expected lateral and vertical tunnel traverse accuracies, but are not a replacement for a comprehensive tunnel network preanalysis. The proposed formulas do not take centering errors into account, are using average distances for each traverse leg, and assume that the survey data is free of outliers in the measurements. It is very important that the estimated instrument accuracy is based on true values that are reflective of measurement precisions that are actually achievable inside the tunnel to provide accurate results.

Dec 1, 2022

By Richard Newcomb, Michael Rieber, William A. Vogely

INTRODUCTION The solid fossil and nuclear fuels, but especially uranium, are given prominent, indeed leading, roles by energy experts in most long range estimates of world energy futures. Optimistic forecasts are inspired partly by the disproportionately large solid fuels resource base compared to present rates of consumption or to oil and gas resources, and partly by the vision of inexpensive high technology applications. Such a view overlooks the fact that while resource- use disparities and new technologies give allure to the promise of the solid fuels, they do not guarantee cheap solutions to the basic problems of solid fuel uses: viz., their relatively difficult conditions for efficient ignition and control, including the management of environmentally acceptable residuals disposal. Contrary to the varied versions of this optimistic hypothesis, this paper shows that a great many persistent economic and technical problems interfere with such a simple inference. These act as constraints which qualify or dispute much of the national energy policy based on existing modeling of solid fuel requirements and optimistic engineering evaluations. The assumptions and techniques of such exercises are sometimes at fault. As often as not, however, the distortions created in open market fuel com- petition due to misdirected national energy policies themselves are to blame for misdirected efforts. A number of interesting implications result. Among them are the distinct possibility that the low technology applications will dominate, so that more direct coal and less synfuel or nuclear use will occur; that, accordingly, exhaustion rates for uranium will be low, that the most extensive growth of solid fuel through 2000 will be in conventional pulverized coal cumbustors, and that the traded share of the world coal bum will be much larger than predicted. These trends will place much more pressure on oil and gas prices than forecast by most experts. On the way to these findings the paper demonstrates that solid fuel resource adequacy in situ, balanced against the projections of demands as capacity requirements, mean little as conventionally measured by years to exhaustion or potential supply schedules. Indeed, all stock concepts of demand requirements or of fuel re- sources must be tied to the paths of the unit costs and the deliverable prices of all substitute fuels and systems over time. This requires a dynamic analysis of supply and demand, integrated with geological and engineering constraints, to provide insights into the multiple modes of market and product substitution. Market forces rather than technical promise will determine the allocation of the solid fuels. Moreover, the equilibrium paths of individual fuel prices and market shares are not easily simulated by general or network models, and decision makers will continue to rely on the partial, local comparison of alternatives in their choices of fuel systems at any time. 'The economics of the solid fuels differs from that of other energy sources in important ways relating to their form in use, conversion efficiency, (dis)economies and externalities. Petroleum and gas are in a more convenient form for

Jan 1, 1985

By M. Gaft, G. Panczer, R. Reisfeld, L. Nagli

Laser-induced luminescence and breakdown spectroscopy methods appear to be a good tool for real-time evaluation of dolomite content on moving belt. The distinctive feature for time- resolved luminescence is Dy3+ emission in apatite, which is excited by 251 nm laser light and detected with delay time of 5 ms and gate width of 1 ms. The distinctive features for breakdown spectroscopy are 604 nm line of F and P in apatite and 518 nm line of Mg in dolomite. The representative sampling of more than 200 pebbles has been studied by both methods. By luminescence method 100% of dolomite will be identified, while approximately 15-20% of apatite with extremely week Dy3+ luminescence may be mistakenly counted as dolomite. By breakdown spectroscopy the identification is 100% correct both for dolomite and for apatite.

Jan 1, 2002

By L. Whitby-Costescu

The Shebandowan mine and concentrator, with a capacity of 9072 t/week (10,000 st per week), was opened in 1972 after several years of environmental study and planning. The mine is located in a popular vacation cottage .area about 96 km (60 miles) west of Thunder Bay, Ontario. Undertaken before environmental assessment procedures had become an established requirement, Shebandowan is one of the first Canadian examples of effectively integrating environmental work into overall planning. Although it is an underground mine, many of the environmental considerations are common to open-pit operations, and hence, it provides a case history for the use of all mine planners. Computers can play a part in such studies by simulating the annual production of mine wastes, by on-line polling of environmental sensors and by processing sensor data. Early attention was focused on establishing base-line conditions in a two-year water quality monitoring program. Since production began, water quality monitoring has shown that mining has not caused any significant changes. However, mine drainage disposal arrangements had to be modified in the light of operating experience. There is no townsite associated with the mine, and workers commute from established municipalities. Harmonious relations have been achieved with local cottage residents after their initial fears were dispelled. Plans are ready to begin revegetating the tailings when a sufficient area of dry elevated tailings has been accumulated. Rehabilitation of the land disturbed during development was begun before start-up and was completed during initial operations.

Jan 1, 1979

By William A. Vogely, Robert T. Deacon, Walter J. Mead

Oil and gas together are the most important energy sources consumed in the United States. In 1983, 67% of total energy consumption was represented by these two resources (43% was oil and 25% natural gas), while coal accounted for only 23% of U.S. energy use. All other sources (hydroelectric, nuclear, geothermal, wood and other waste products) accounted for only 10% (U.S. Department of Energy, 1983, p. 1). In this chapter we address the issue of regulation in the oil and natural gas sectors of the U.S. energy industry. In addition, we analyze the cartel characteristics of the Organization of Petroleum Exporting Countries (OPEC). If OPEC is an effective cartel, then U.S. oil as well as substitute energy prices, production, and consumption will be affected by cartel action. Further, as the nation learned in the 1970s, major changes in oil prices produced major disturbances in other sectors of the U.S. and world economies. Consequently, it is important to determine whether the roughly ten-fold increase in nominal prices that occurred in the 1970s was the result of cartel action, the result of normal economic forces adjusting to the fact that the world was running out of cheap oil, or some combination of the two. Furthermore, the presence of OPEC- associated oil price increases is related to regulations that were imposed on the energy sector during the decade of the 70s. THE RATIONALE FOR GOVERNMENT INTERVENTION Economists have traditionally judged the state of an economy to be efficient if it is impossible to improve the welfare of any one member of society without harming someone else. Any economy that satisfies this condition is said to be Pareto efficient, after the Italian economist Vilfredo Pareto who first gave rigorous attention to such questions (see Chapter 4.10). It is easy to see why an economy that fails to satisfy this condition could not be efficient; by definition, it would be possible to alter the allocation of resources in a way that improves everyone's welfare.' Much of the appeal of this weak efficiency criterion is that it avoids comparisons of levels of well being among different individuals. The cost of such generality, however, is that in any given economic system a wide array of different Pareto efficient states will typically be attainable. In the simple Robinson Cursoe economy of the undergraduate textbook, for example, efficiency could just as easily be attained in the case where most of the island's resources are owned by Friday as in the case where they are under Crusoe's control. However, the distribution of welfare among the two inhabitants would obviously be quite different in the two situations. Such equity issues cannot be settled on objective or scientific grounds. To decide which distribution of welfare is socially "best" an explicit value judgment is needed. It is useful to keep in mind the preceding distinction between efficiency and equity issues when analyzing the role of government in a market economy. Decentralized market processes will not necessarily result in a distribution of welfare that society considers just. For this reason a potential role for government lies in the redistribution of income among individuals. In some circumstances, however, market pro-

Jan 1, 1985

By P. Bissert, M. Klein, L. Yan, D. Yantek, R. Matetic

"U.S. Mine Safety and Health Administration (MSHA) regulations require underground coal mines to use refuge alternatives (RAs) to provide a breathable air environment for 96 hours. One of the main concerns with the use of mobile RAs is heat and humidity buildup inside the RA. The accumulation of heat and humidity can result in miners suffering heat stress or even death. MSHA regulations require that the apparent temperature in an occupied RA not exceed 95 °F. To investigate this, the U.S. National Institute for Occupational Safety and Health (NIOSH) conducted testing on a 23-person tent-type RA in its Experimental Mine in a test area that was isolated from the mine ventilation system. The test results showed that the average measured air temperature within the RA increased by 9.4 °C (17 °F) and the relative humidity approached 94 percent at the end of a 96-hour test. The test results were used to benchmark a thermal simulation model of the tested RA. The validated thermal simulation model predicted the volume-weighted average air temperature inside the RA tent at the end of 96 hours to within 0.06 °C (0.1 °F) of the average measured air temperature. IntroductionIf an accident occurs in an underground coal mine, miners who fail to escape from the mine can enter a refuge alternative (RA) for protection from adverse conditions, such as high carbon monoxide levels. One of the main concerns with the use of mobile RAs is the potentially adverse thermal environment inside an RA from the metabolic heat of the occupants and the heat released by the carbon dioxide (CO2) scrubbing system. Moreover, the humidity within the RA will increase through occupants’ respiration and perspiration, and from the chemical reaction within the CO2 scrubbing system. The accumulation of heat and humidity can result in miners suffering heat stress, heat stroke or even death."

Sep 1, 2016

By Ethan Steward, Kyle Perry

The study investigates the effects of high-velocity impacts of common mine materials on a reinforced mine seal rated to 120 psi. It found that materials propelled during an underground explosion could generate enough stress to crack or damage seals, even with little visible damage. This highlights the need for careful evaluation of mine seals after any impact or high-pressure event.

Aug 1, 2023

By Omid Asghari, Seyed Reza Ghavami-Riabi, Sajjad Talesh Hosseini

Separation of geochemical anomalies from the background using various methods for identifying areas of higher mineral potential is a critical first step in Greenfield and Brownfield programs. There are several methods for differentiating anomalous regions from the background. The U-spatial statistics is an effective technique that provides the opportunity of reaching this goal by considering the geochemical sample locations in the separation of geochemical anomalies. In this study, a developed form of the U-spatial statistics method is introduced, which not only considers the existence of anisotropic spatial variations in input data but also reduces the computational (CPU) time. While the previous method is based on the isotropic assumption in the study area and a set of search windows at different times, here, the geochemical anomaly is determined by pasting only one ellipsoid window, effectively combining the flexibility of the U-spatial statistics method with the advantages of geostatistical approaches. This paper compares various approaches (the previous and developed version of the U-spatial statistics method, concentrationarea (C–A) fractal model, and probability diagram modeling) for the separation of anomalous areas in the presence of heterogeneous spatial variations. This is done with an application to a Baghqloom porphyry copper deposit located in southeastern Iran. The high potential areas identified via different approaches show an anomalous region in central parts of the Baghqloom area, which partially coincides with an intense potassic alteration area. Compared to other methods, our algorithm separated the high potential areas at a greater spatial resolution.

May 3, 2021

By R. Woods, O. A. Kiehn, C. A. Born, F. N. Bender

Development of the flotation reagent scheme at Climax Molybdenum Company's mine at Climax Colorado is reviewed. Features of the mineralogy, milling practice and background of reagent changes are outlined. Special attention is given to the hitherto unpublished details of the application of depressants for copper and lead impurities. The present rougher flotation reagent scheme utilizes a neutral hydrocarbon oil, low in unsaturates and wax, as collector with a sulfated coconut oil emulsifier and pine oil frother. Lime and sodium silicate are used as rougher conditioning and slime dispersant agents. Chalcopyrite and galena impurities are de- pressed in both rougher and cleaner plants by stage addition of Nokes reagent and sodium cyanide to yield a metallurgical grade molybdenite concentrate containing greater than 90% molybdenite and less than 0.5%, 0.1% and 0.05% iron, copper and lead impurities, respectively.

Jan 1, 1976

By A. Nieto

This article is a review of previous discussions about underground mining method selection and classification with the purpose to clearly define and classify the two groups of variables (indicators) involved in the mining selection process: key deposit indicators (KDIs) and key mining method indicators (KMIs). This paper provides a simple and clear approach for the classification and selection of a feasible underground mining method based on a predetermined set of favorable deposit characteristics, which are defined as key deposit indictors (KDIs). This article also gives a summary of the key advantages and disadvantages associated with every underground mining method based on their key mining indicators (KMIs). The selection method given in this paper is based on defining field KDIs and comparing them to the KDIs that are favorable to every considered mining method. By cross validating a matrix of favorable KDIs, the paper presents a simple approach to rank several underground mining methods using a scale from favorable to less favorable accordingly to the ore deposit characteristics (KDIs). KMIs are used to further complement KDI rankings by analyzing every method’s KMI performance based on the expected productivity of the mining operation being considered. To further assist the reader through the selection process, this paper gives basic sketches representing each of the primary underground mining methods discussed in this paper. Each method is given using the same 3D isometric view as spatial reference to assist the reader with visual interpretation and comparison between methods.

Jan 1, 2010

By C. W. Matthews

Introduction Screening is an art, one of the oldest in the process field today, and one of the most widely used in our present age. Screening is being applied to an ever-increasing number of assignments, in an ever-expanding circle of industries. Screening is defined precisely as a mechanical process which accomplishes a separation of particles on the basis of size and their acceptance or rejection by a screening surface. Particles are presented to apertures in a screening surface and rejected if larger than the opening, or accepted and passed through if smaller. Screens are machines with screening surfaces used to classify materials by size. The screening surface is the medium containing the apertures for the passage of the undersize material. Screens are put to many uses - size separation, dewatering, desliming, media recovery, scalping, trash removal, washing, dedusting, conveying, concentration, and many combinations of these functions. It is interesting to note that screens are used for handling commodities

Jan 1, 1985

By Marco D. Boscardin

During subsidence, the ground surface may settle, change slope, change curvature, go into tension, and/or go into compression. In response to these ground movements, buildings and buried utilities in the subsidence area may settle, tilt, bend, distort, and sustain extension, compression and/or torsion. In order to develop measures to protect existing structures and utilities, or to design new structures and utilities to withstand potential movements in areas of subsidence, it is necessary to understand the interaction between the ground and the building or buried the utility. This paper reviews subsidence-induced ground movements, how these ground movements are transmitted to and accommodated by buildings and buried pipelines, and how these structures may alter ground movements relative to free field subsidence-induced ground movements.

Jan 1, 1986

By Edgel P. Stambaugh

Oxides are important for use in the production of metals, ceramic hardware, paints, permanent magnets, magnetic recording tapes and many other uses. In some of these applications, particle morphology, degree of crystallinity, purity, and homogeneity are relatively insignificant, while for other uses, these same properties are of critical importance. Many conventional processes are based upon recovery of the oxides from aqueous solutions by processes which include neutralization, evaporation of solvent, and precipitation of a complex salt. Consequently, many of these techniques lead to oxides of low quality. There is a growing demand for oxides of high quality, i.e., materials with narrow particle size distribution, controlled particle morphology, high purity, few structural defects, and high degree of crystallinity and homogeneity. This demand has prompted industry to search for new approaches for the manufacture of these special materials. One new approach for preparing high quality oxides is hydrothermal precipitation. This process has been used for preparing simple oxides such as ZrO2; mixed oxides such as ZrO2-SiO2; and complex oxides such as BaTiO3. These oxides were prepared in a high state of purity with a high degree of crystallinity and., in many cases, without the addition of precipitants. Many impurities- that are normally precipitated by conventional methods such as neutralization present no problem since they remain in solution. Nature of the process and its applications are discussed in this article.

Jan 1, 1977