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By M. S. Celik

Adsorption of sodium dodecylsulfonate (SDS) and dodecylaminium hydrochloride (DAH) on Buller seam coal, New Zealand, have been studied. Both surfactants adsorb effectively on the coal below pH 8, and the adsorption isotherms established at pH 4 are essentially the same at lower concentrations. These findings suggest that the adsorption of these two ionic surfactants on coal is controlled by a hydrophobic bonding mechanism. However, the results of calorimetric studies suggest that coulombic attraction also plays a part in the adsorption mechanisms. It has also been found that both the SDS and DAH adsorbed in the first monolayer are not removed by lowering the surfactant concentrations in the bulk solution.

Jan 1, 1993

By W. R. Hibbard

Emerging from discussions of U.S. energy policy: from the Project Independence Blueprint; from President Ford's statements to Congress; and from several independent appraisals of the situation; there is a clear objective to achieve an appropriate balance of supply and demand in the near term future (1) by developing more efficient ways of using energy and (2) by extending domestic sources of energy. More specifically, the strategy for achieving this goal has three parts (1) Conservation of energy through greater efficiencies in automobiles, appliances, lighting, heating, and industrial processes. (2) Increased domestic production of oil and gas through new sources such as the outer continental shelf and new efficiencies such as tertiary recovery. (3) Substitution of coal and uranium for oil and gas in utility power plants and industrial heating. The goal of energy research and development is to help achieve these goals and to help minimize the economic, environmental and social impact of our shift from imported energy to domestic sources. The focus of this paper is the implications of the expanded use of coal, and the research and development which may help achieve the above goals in so far as coal is concerned.

Jan 1, 1975

By David R. Cole

Before discussing some of the specific public relations issues in Colorado mining, I would like to define public relations, identify the "publics," review Colorado's population profile, and outline Colorado's mining history. Public Relations In describing public relations, a definition which is frequently quoted appeared in the PUBLIC RELATIONS NEWS, and is as follows: "The Management function which evaluates public attitudes, identifies the policies and procedures of an individual or organization with the public interest, and executes a program of action to earn public understanding and acceptance..' As you can see, this covers a "multitude of sins."

Jan 1, 1975

By John K. Adams

Phosphorus may be incorporated into sedimentary rocks in at least four different ways: (1) by the accumulation of detrital mineral fragments, (2) by the accumulation of phosphatic organic debris, (3) by diagenesis and (4) perhaps by the primary precipitation of calcium phosphate. Based-on the petrographic examination of Cretaceous and Tertiary sediments from the northern and central parts of the Atlantic Coastal Plain, Diagenesis is the most important of these mechanisms. Both syndiagenesis and epidiagenesis are required to explain the origin of all the diagenetic phosphate mineral species which occur in the northern and central parts of the coastal plain. Syndiagenesis produced much of the coastal plain's apatite. It was operative below the sediment-water interface while the substrate was being compacted. Compaction forced pore waters, which were enriched in phosphate by the decomposition of organic matter, upward through calcareous sediments. The PO43- radicle replaced the CO23- and calcareous nodules, pellets and shell fragments were converted to apatite. Epidiagenetic reactions occurred in the subaerial environment where downward percolating meteoric waters carried phosphate in solution to cites where cation activity was sufficiently high to form new minerals. Vivianite may form where ferrous iron is available and wavellite and variscite may form in the presence of aluminum rich minerals. Textural evidence suggests that many of the reactions were repeated. The present day appearance of apatite, vivianite, wavellite and variscite in the coastal plain may represent several generations of diagenesis.

Jan 1, 1972

By G. Reed Marchant

During the past two decades, we have witnessed the computer revolution. Like other revolutions, it has been successful in many ways; however, it has not been without difficulties. One of the areas where these difficulties have been more prevalent has been in the application of computers for the purpose of controlling industrial processes. During the early 1960's, many people naively assumed that bridging the gap between data processing and process control was a simple matter of connecting a few wires, doing a little programming, laying off most of the people and watching the plant make great increases in production as the lights on the computer blinked on and off. Unfortunately, it has not been that simple. Instead, a whole new-set of disciplines has been required to overcome the major obstacles that exist. Nevertheless, current successes are proving that the digital process control computer is here to stay, and that through the application of digital computers an attractive return on investment can be obtained in many applications.. The purpose of this paper is to illustrate some of the requirements for successful implementation of computer control systems, with particular attention to the following four objectives: First: Acquaint the reader with the general control problems so that he may more fully recognize the major requirements for successful implementation. Second: To acquaint the reader with the types of control hardware that can be considered for use in the development of control systems. Third: To discuss some of the major obstacles that must be overcome for successful implementation of computer control systems. Fourth: To discuss the systems approach in the development of control systems and to illustrate it in the implementation of an actual control system.

Jan 1, 1971

By G. B. Glass

In 1996, 92.5% or 233 Mt (257.4 million st) of coal produced in Wyoming came from the Wyodak coal zone in the eastern Powder River Coal Field. While the mined portions of the zone consist of one to three beds of coal with an aggregate thickness between 15 and 33.5 m (50 and 110 ft), the thickest expression is 61 m (200 ft). The delivered coal from this zone averages 0.33% sulfur, 5.12% ash, and 19.98 MJ/kg (8,590 Btu/lb). This coal zone occurs at or near the top of the Paleocene Fort Union Formation, which is overlain by the Eocene Wasatch Formation. There is also production from two coal beds in the lower portion of the Wasatch at the southern end of the basin. Production of coalbed methane derived from the Wyodak coal zone is currently an estimated 10.2 billion cu ft a year. This production is occurring just west and downdip from the coal mines and is increasing each year.

Jan 1, 1998

By Olav Moklebust

The R-N Process is an outgrowth of the development by the National Lead Company's Norwegian subsidiary Titania A/S, of a process for producing metallic iron and a high titanium content co-product from ilmenite. Development of the process for the treatment of iron ores was continued as a joint project of the Republic Steel Corporation and the National Lead Company in 1953. More recently in July, 1957, the R-N Corporation was created by these two companies to undertake the commercial promotion of the results of this joint project. This paper has been prepared with the permission and encouragement of these three companies. The R-N process has as its objective the making of metallic iron from iron ores or iron ore concentrates. The general principles of the process have already been disclosed in technical papers and patents. In general the process comprises the following steps: 1. Iron oxide in crushed natural iron ores or iron ore concentrates is reduced to about 95% metallic iron, without fusion in a rotary kiln in the presence of solid carbonaceous fuel,*such as, coke or char, limestone and combustible gases. 2. The kiln discharge, consisting of metallized ore, coke, lime and coke ashes, is cooled. The excess coke is regenerated and recycled to the kiln feed.

Jan 1, 1959

By W. J. Adamson

Strategic Data Planning (SDP) is an emerging technique for the analysis and design of information systems. This paper describes the use of strategic data planning in the formulation of a complete integrated set of mining technical systems for the Koolan Island iron ore mine. Applications covered include hydrogeology, geology, mine planning, surveying, quality control, laboratory and mine production recording. Koolan Island is 13 kilometres long and 5.5 kilometres wide at its widest point. Its sole industry is an open pit iron ore mine of 3 million tonnes annual capacity, owned and operated by BHP Minerals. Some of the production is used by BHP Steel International, but most is exported. The orebody is steeply dipping and is mined bench by bench. Outturn grades for run-of-mine product are iron 66.5%, silica 3.0%, alumina 1.0%. Computer systems are run on Data General equipment, currently an MV10000. Computer applications, which are shared across mine sites, are developed and maintained by BHP Information Systems in BHP's Melbourne Office.

Jan 1, 1986

By S. Mathur

Oxide particles are commonly used as fillers in plastics, paper, rubber etc. (particulate composites). The successful fabrication of such composites is dependent upon the adhesive strength of the filler particles to the matrix. The compatibility of the matrix and the filler particles is generally enhanced by adsorption of surface modifiers such as surfactants and polymers at the particle-matrix interface. In order to develop a scientific basis for selection of appropriate modifiers it is necessary to understand their adsorption mechanism(s). Specifically, adsorption of polymeric additives is attributed to a combination of chemical and electrostatic interactions, hydrogen bonding and van der Waals forces. Hydrogen bonding has been suggested to be the primary adsorption mechanism for non-ionic polymers. However, a literature survey of Poly(ethylene oxide)(PEO)-oxide system suggested PEO, a non-ionic polymer, to be substrate specific. A systematic study was undertaken to investigate the adsorption mechanism(s) of a PEO on oxide particles. It was determined that strong Bronsted acid sites on the surface interact with the ether oxygen, a Lewis base, of PEO to induce adsorption. In this work characterization of PEO binding sites on oxides is reported and the mechanism(s) of PEO adsorption discussed.

Jan 1, 1997

By J. B. Zachwieja, P. E. Richardson, G. W. Walker

The electrochemical nature of mineral-collector interactions and their relationship to flotation have been investigated to develop a better understanding of the factors controlling sulfide mineral beneficiation. Spectrophotometric and electrochemical techniques have been used to examine the reactions occurring on electrodes composed of a bed of bornite particles in the presence and absence of potassium ethylxanthate (KEtX) at a pH of 9.2. The combined techniques showed that KEtX sequentially reacts with bornite by (1) a chemisorption reaction forming ca hydrophobic species between --0.4 and -0.2 V (SCE), (2) an electrochemical oxidation reaction forming cuprous xanthate between -- 0.2 V and the xanthate/ dixanthogen redox potential, and (3) oxidation to dixanthogen when the potential exceeds the reversible value for the xanthate/dixanthogen couple. The flotation response of bornite closely parallels spectrophotometric and electrochemical evidence for adsorption of KEtX by the reactions listed above. The degree of surface oxidation resulting from the formation of iron oxides on the surface dictates the flotation response as evidenced by the fact that oxidized bornite floats at more anodic potentials than unoxidized bornite. The strong correlations between the flotation response, degree of oxidation, and potential indicate that chemisorbed xanthate produces a hydrophobic layer sufficient to float unoxidized bornite, but cuprous xanthate and dixanthogen arc required to float oxidized bornite.

Jan 1, 1988

By J. Groff

The Getchell and Twin Creeks mines are located along a north-northeast trending structural zone in Humboldt county, Nevada approximately 40 miles northeast of the town of Winnemucca. Gold mineralization at the Getchell mine is represented principally by sulfide-rich ores, which contain significant amounts of realgar and\ orpiment, with the gold being recovered through processes which involve pressure oxidation. In contrast, oxide ores are currently being mined and processed at the Twin Creeks mine although large reserves of sulfide ores, some of which contain orpiment-realgar-stibnite, have been defined (Bloomstein et al., 1990). The Getchell and Twin Creeks mines represent major gold orebodies but very little has been published pertaining to mineral paragenesis and the characteristics of ore-forming fluids for these deposits.

Jan 1, 1994

By Judith A. Marks, Deane K. Smith, Jan M. Mutmansky, Maria Klimkiewicz

The mechanical mining of coal seams where roof, partings, and floor rock are extracted along with the coal often introduces large numbers of quartz particles into the mine atmosphere. This study concentrates on the quartz properties in situ and in the airborne dust to determine how they are released from the source rock and whether they are fractured by the mining machinery. Three mines using drum-type continuous miners from different geographic areas were sampled to provide a data base. The roof and floor rocks were primarily siltstones containing 5% to 25% quartz measured by the X-ray powder diffraction (XRPD) method. Much of the work presented here is based on the morphologies of the mineral grains determined by the scanning electron microscope (SEM). The study concentrated on particles of 0.2 to 10.0 µm and on particles containing > 75% Si. Mechanically-crushed quartz particles were also examined for comparison purposes. Particle shapes from the airborne samples suggested that fractured quartz particles were rare. Particle statistics also show that the average size of quartz particles in the airborne samples were similar to the average size of all particles. The conclusion is that very few quartz particles from the source rocks are fractured during mining due to their small initial size and the protection of the associated clays.

Jan 1, 1991

By Y. Zeng

Experiments were performed under batchwise wet grinding conditions with dolomite mineral. The vibration signal was received by an accelerometer and transmitted to a mini-processor. The signal was first stored on a digital tape recorder (OAT) in voltage format during the grinding tests. The original signal was then re-sampled and converted into data format for IBM or compatible personal computer by a digital oscilloscope. The root-mean-square (RMS) and power spectrum was estimated on the time-domain vibration signal. A partial correlation analysis was applied to the frequency-domain signal to detect the non-zero correlation between the frequency bands and the operating parameters. A multiple stepwise regression was used to locate the key frequency bands for describing a particular operating parameter. After vibration analysis, the operating parameters in grinding, for example, the mill speed, the powder filling, the pulp density, the pulp temperature and the particle size were found to be strongly correlated with a few frequency bands. The grinding process could therefore be monitored using the vibration signal.

Jan 1, 1992

By Phillip J. Maddex

During the last 10 years there have been many new developments in transport and handling equipment. Important technical and economic developments that can be used to reduce costs are; new terminal and materials handling concepts large river tows - 40,000 tons and 9000 hp towboats slurry loading and unloading of ocean vessels long distance pipelining of solids development of the shuttle train (unit train) large ocean barges ? 25,000+ tons ? pushed & towed 150,000 ton self-unloading super tankers - 300,000+ tons container shipping Some of these developments have been discussed at SME meetings in papers describing the transportation of minerals from new mines. But, only a few papers described improved transportation from older operations. Since transportation is a major part of the delivered cost for minerals, the economic benefits to be gained by putting new transportation developments to work are very substantial. Frequently good transportation planning and management makes the difference between a marginal ore body and a very profitable one.

Jan 1, 1972

By C. Maltesh

Anionic conditioning of phosphate ores prior to fatty acid flotation is a very critical step that determines the eventual selectivity, recovery and hence the economics of the process. However the chemical mechanisms operating during this conditioning step are not established. Several studies have been conducted in the past to determine the mode of interaction of collectors with the phosphate fractions however these have been done on a laboratory scale using pure phosphate minerals. In order to test the relevance of the observed effects to plant practice in this work a comprehensive survey of plant practice was first conducted and then adsorption on flotation feed and francolite were studied under simulated plant conditions. Effects of conditioning energy and water chemistry as well as solids loading and fuel oil were determined. Most importantly, different adsorption mechanisms were found to be dominant under laboratory and plant conditions. In plant water, there was some physisorption of oleic acid on phosphate flotation feed and francolite in addition to chemisorption. However, in distilled water under laboratory conditions only chemisorption was detected. Fuel oil reduced the residual oleic acid in solution after adsorption, which explains the beneficial role of extender in phosphate flotation. The dissolved species in solution arising from the flotation feed or plant processing water are shown to clearly play a major role in determining the adsorption of oleic acid on the substrates. The study also specifically demonstrates the importance of conducting research tests under plant mixing conditions and plant water chemistry for the results to be useful commercially.

Jan 1, 1996

By Richard Stoltz, Gary Smith

This paper presents the findings of a face ventilation investigation, conducted by the Ventilation Division, Pittsburgh Health Technology Center, at a underground coal mine operating in the Illinois No. 5 coal seam. The purpose of the investigation was to evaluate the effectiveness of a blowing face ventilation system in controlling methane liberation in the face area while mining with brattice distances up to a maximum of 40 feet from the face (extended cut). The continuous miner on this section was remotely controlled and equipped with a machine mounted dust collector. Data collected during this investigation included methane concentrations, intake and return air quantities in the face area, and scrubber air quantities. In addition, a time study was conducted to correlate the methane peaks to activities in the face area. In conjunction with the face study on Section A, separate methane liberation studies were conducted on three additional sections: B, C, and D. This was done in order to compare intake methane concentrations and methane liberations from other sections in the mine to the test section. Calculations indicated that the minimum intake air quantity necessary at the inby end of the line brattice for the section investigated was 7,000 cfm. Due to the higher intake methane concentrations and average methane face liberations measured on three other sections, the minimum air quantities necessary at the inby end of the line brattice were determined to be 13,900 cfm, 11,100 cfm, and 15,000 cfm, respectively.

Jan 1, 1991

By Eugie Kabwe

The effective employment of a pretensioned bolt within support structures requires an appropriate installation tension as a result of sufficient bolt head/nut preload. In this paper, a load indicator washer (LIW) able to withstand an assigned static loading as well as provide an appropriate pretension is presented. The different LIW breadths are numerically analyzed with ABAQUS finite-element code to estimate deformation when a designated 60 kN preload is applied. The numerical simulation employs the bilinear isotropic hardening constitutive law governed by the von Mises yield criterion. The simulation also considers the nominal temperature of the nut-LIW-rock bolt connection. Therefore, long-term relaxation effect on bolt pretension as a result of stress relaxation is neglected. The compressive force required to achieve the LIW predetermined deformation is the bolt pretension. It is drawn from the simulation results that LIWs with thicknesses of 1.5, 2.0, 3.0, 3.5 and 4.0 mm are completely flattened when subjected to 28, 42.5, 65, 76 and 88 kN preloads, respectively.

By D. M. Bodily, V. J. Hucka

INTRODUCTION Interest in the recovery of methane from coalbeds has increased rapidly over recent years, because of its potential as an energy resource and to alleviate pollution and safety problems. The resource base of coalbed methane in the United States has been estimated at 11.2 Gm3, roughly equivalent to 20 years consumption (Mroz et al., 1983; Kuuskraa and Brandenburg, 1989). Methane contributes to the adverse environmental impacts of global warming, tropospheric ozone formation (smog), and potentially stratospheric ozone destruction. Association of methane with coal has always presented a safety problem in mines due to the potential for explosions. The rate of release of methane depends on the amount adsorbed by the coal, the adsorption isotherm for the coal, and the size of the coal particles. Mining operations can affect the particle size distribution and the production of fines and therefore the rate of release. The time the mined coal remains in the mine may also be important in determining total emissions. The methane content of some Utah coals was determined in this study. The methane content of the coals is compared with the chemical and physical properties of the coals and the properties of the seam and neighboring strata. Correlations are developed to better understand the formation and retention of methane by these coal seams. METHANE FORMATION IN COALBEDS Three mechanisms for methane formation may be considered: (1) nonbiogenic formation, (2) formation by anaerobic bacteria during plant material deposition and the early stages of diagenesis, and (3) formation from pyrolysis of coal material during coal maturation. Nonbiogenic formation by thermal processes involving carbon- and hydrogen-containing compounds has been proposed as a mechanism for methane formation in the earth. It is not likely to be of importance where other fossil fuel materials are present. Coal would not survive the temperatures required and hence the methane would need to migrate and be trapped by the coal seam. This mechanism is unlikely for coalbed methane. Formation of methane by anaerobic bacteria undoubtedly occurs during coalification, but the methane may not be trapped until the pore system of the coal is developed, and would likely be displaced by methane formed during further coalification. Methane formed by maturation of the coal material as it progresses from peat to coals of various rank is the most probable mechanism for the formation of coalbed methane. Most of the methane is adsorbed onto the walls of microvoids in coal. It has been estimated that the surface area of one kilogram of coal is between 20,000 m2 to 200,000 m2. Surface area measurements depend on the coal and also on the method of measurement. At 20 atmospheres, in some coals, the adsorbed methane is 10 times greater than methane as a free gas. At 100 atmospheres the adsorbed gas can be as densely packed as a liquid. The volume of methane gas held in coal depends on the volume of gas that exists as a free gas and the adsorbed gas capacity. The volume of free gas in the coal can be calculated from the kinetic theory of gases (methane can be assumed to be an ideal gas because errors would not be greater than 1 % for normal mining pressures). Langmuir (1916) derived an equation for the adsorption of gases on uniform surfaces and this is applied to the adsorption of methane on coal:

Jan 1, 1993

By Harry M. Parker

Exploration for sandstone-type uranium ore bodies which will be exploited using underground mining techniques is usually executed in sequential fashion. Geostatistical methods can be used at the earliest exploration stages to design drilling programs which have a high probability of success in the location and delineation of mineable ore-grade mineralization, should such mineralization exist. In succeeding development stages, geostatistics may be used to outline and define the potential grade of reserves and to apply confidence limits on the grade estimation. Delineation of mineable reserves for mine planning requires extensive development drilling; using such drilling data geostatistical methods may be used to minimize the drilling needed to achieve a desired level of confidence in the calculation of mineable uranium ore grade and tonnage. Because sandstone-type uranium deposits tend to be pod-shaped and are generally aligned along a mineralized trend, this paper proposes a geostatistical method of calculating uranium ore reserves which accounts for this fact and predicts the area within a trend which is underlain by ore. This method uses an indicator value; that is, drill holes which contain mineable ore-grade intercepts are coded as 1, those that do not are coded 0. The indicator may be kriged over the mineralized trend to obtain an estimate of the area underlain by ore. The thickness and grade-thickness may be kriged, and the average ore grade may then be obtained by dividing grade-thickness by thickness, as is conventional for stratabound deposits. The mean grade is then multiplied by the kriged mean thickness to obtain an estimate of the volume, and thence tonnage, of mineable ore within the trend.

Jan 1, 1979

By Brij M. Moudgil

Separation of oil shale from waste material or into high grade and low grade fractions can have a major influence on the economics of the surface (ex-situ) retorting process. Different components of shale rock vary significantly in physical and surface chemical properties such as specific gravity, color, water wettability etc. Various techniques which utilize the difference in one or more of the above propartis have been proposed to preconcentrate the oil shale before retorting. A discussion of the techniques proposed such as gravity separation, sorting and froth flotation is presented.

Jan 1, 1982