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By L. A. Clark

Although vein-, syenite-, and pegmatite-type deposits are known in Saskatchewan, recent intense exploration stems from discovery of several exceptionally high grade uranium and uranium-nickel deposits locallized near the basal unconformity of the 1.3-1.4 b.y. Athabasca Sandstone Formation. Graphitic basement rocks and post-Athabasca faulting or brecciation coincident with the unconformity are important in locallizing uranium deposits which form as tabular, shoe lace-like bodies with grades averaging over two percent and containing up to 50,000 tonnes U308. Some deposits have similar nickel contents. A few published sandstone analyses average 0.8 ppm uranium while basement granitoid and meta-sedimentary rocks vary from 0.5 to 20 ppm. In the proposed genetic model, traces of uranium are leached from these rocks by oxidized formation waters sweeping through the sandstone and along faults. Solutions are reduced and uranium is precipitated as basement graphitic meta-pelites are encountered along brecciated fault zones.

Jan 1, 1979

By Brij M. Moudgil

Florida produced more than eighty percent of domestic phosphate during 1974. This amounted to more than thirty-five million short tons. Ninety percent of this production was used in the production of fertilizers. Other uses of phosphate include food preservatives, fabric dyes, optical glass, photographic films, soaps, plastics, pharmaceuticals and animal feed ingredients. Marketable phosphate rock projections for the nest decade forecast a very healthy growth for the Florida phosphate industry. Associated with the expansion, however, are the corresponding problems of water conservation, air and water pollution and land reclamation. Recognizing mining as an interim land use, the industry is presently engaged in a very active reclamation program. The proximity of the central Florida deposits to rapidly developing urban areas makes it important to undertake successful and well planned reclamation programs. Water use and conservation is of vitil importance to the industry. Water withdrawal from existing aquifers and discharges into drainage systems are closely regulated by state agencies. Water is stored and recycled to maximize usage. In some instances water is even returned to major aquifers through a series of recharge or connector wells. The phosphate industry has spent over 200 million dollars in the past decade for research, development and implementation of pollution abatement and water conservation systems.1 The following discussion outlines various phases of phosphate mining in central Florida today, with emphasis on research in waste disposal techniques and progressive land reclamation programs.

Jan 1, 1975

By M. B. Mooiman

Cyanidation of gold and silver ores by conventional mining and milling techniques has been practiced for over a century. During the past decade, heap leaching has emerged as a viable process for treating certain gold and silver ores. (1) The rapid development of heap leaching for gold and silver ores is largely a result of lower capital and operating costs and faster start-up time than that offered by conventional mining and milling. In general, these features make heap leaching an ideal approach for exploiting either small or large low-grade disseminated deposits of gold and silver considered to be uneconomic by conventional methods. The development of heap leaching technology has evolved from the operations initiated in the western United States. The basic components of a typical heap leaching operation are depicted in Figure 1. Run-of-mine or crushed ore (usually 1 to 5 ppm gold) is delivered to specifically prepared impervious pads. Alkaline cyanide solution is applied to the surface of the heap and allowed to percolate through the heap (typically 10-30 ft high). Pregnant leach solution which drains from the heap is collected and stored in tanks of sufficient size or in collection reservoirs. Gold and silver are recovered from the pregnant solution and the barren solution is recirculated back to the heaps after reagent make-up.

Jan 1, 1983

By R. W. Macqueen

Organic matter commonly associated with Mississippi Valley-type (MVT) lead-zinc deposits may be used to assess the burial/thermal history of host rocks and sulfides. Organic matter may also have been involved in the genesis of H2S required to precipitate sulfide ores. Pine Point, Northwest Territories, Canada, provides an example. Located on the south shore of Great Slave Lake, Pine Point is an operating world class deposit which has produced 58 million tons of ore containing 3.0 percent Pb and 6.1 percent Zn from more than 40 Individual orebodies. Well-documented paleokarst features in a Middle Devonian carbonate complex are the main ore hosts. Sphalerite and galena ores are mainly open space fillings, and, from fluid inclusion studies, were deposited from saline fluids at temperatures of up to at least 100°C. Forms of organic matter occurring in the Pine Point barrier-reef complex Include indigenous organic matter, heavy oil and bitumen. Based on numerous geochemical criteria, it is clear that heavy oils and bitumens were derived locally from indigenous organic matter. The geochemical character of the Indigenous organic matter demonstrates that the barrier-reef complex is immature to marginally mature with respect to petroleum generation, and has not been heated above about 60°C maximum. Thus sphalerite with fluid inclusions that yield temperatures up to about 100°C represents former thermal anomalies. Bitumen is of two main forms at Pine Point: widespread soft, tarry material soluble in organic solvents (unaltered bitumen); and hard, brittle, glassy material that is mostly solvent-insoluble, and associated with white sparry dolomite and lead-zinc ores (altered bitumen). There are also partly altered bitumens. Unaltered bitumens have atomic H/C ratios of about 1.4, sulfur contents averaging 7.8 percent, and sulfur isotope ratios 634S) of approximately +4.6 per mil. Altered bitumens have atomic H/C ratios averaging 1.02, sulfur contents averaging 22 percent, and 634S values of about +12.9 per mil. These data and the organic geochemical character of a large suite of bitumen samples analyzed, strongly support the concept that some bitumen has been involved in the thermochemical reduction of sulfate to produce the H2S required to precipitate the ores. Mass-balance calculations indicate that the amount and degree of alteration of bitumen is more than enough to account for the reduced sulfur species deposited as metallic sulfides at Pine Point. MVT deposits, including Pine Point, seem to require the coincidence of available metallic Ions, pre-existing pore space, and a precipitating agent. A close look at organic matter in more MVT settings may outline trends in distribution or alteration which can be used as indicators of past thermal environments and processes of ore deposition.

Jan 1, 2013

By A. J. Rergis

During the past ten years a number of papers have appeared describing zeolite occurrences in the western United States in Mesozoic sedimentary rocks, altered bedded Tertiary pyroclastics, playa lakes, hot springs, and amygdaloidal basalts. With the emergence of natural zeolites as economic industrial minerals it appears, useful to develop a system of classification to delineate those zeolite deposits of economic interest which were not discovered until the middle 1950's. The first attempt at a classification of naturally occurring zeolites was made in 1914 by Lindgren l when he classified the zeolites into eleven groups based on their mode of occurrence. The zoned zeolites in the Mesozoic rocks of New Zealand and elsewhere were classified according to the mineral assemblages by Fyfe, et al.2 in 1958 as a zeolite facies corresponding to low grade regional metamorphism. In 1966, Hay suggested as an alternative to the preceding classification one which would "classify as diagenetic all mineral assemblages produced in sedimentary rocks under conditions in which zeolites are formed." In this paper a classification is proposed with the objective of providing an overall perspective of the zeolite occurrences in the western United States.

Jan 1, 1967

By Thomas A. Simpson

Hydrogeological techniques were used to solve problems of slope stability in open-pit mines of the Eufaula bauxite district, Alabama. Geologic and hydrologic data were evaluated and used to design a system of dewatering wells to enable the operators to mine bauxite more efficiently and economically. Walls of open-pit mines in the district were subsequently stabilized by the operation of the dewatering system. Three open-pit mines, each at varying stages of the mining process, of the A. P. Green Refractories Company, were used to develop a sequential series of guidelines that indicate how to effectively remove ground water from the formations surrounding the ore bodies in the district. The use of sound engineering principles in well design, in combination with the correct interpretation of the pit hydrology provided the basis for solutions of the slope- stabilization problem aided in the economical removal of bauxite from mines of the district.

Jan 1, 1975

By William L. Rose

Production scheduling is an integral part of intermediate- and long-range open-pit mine planning, affecting equipment selection, manpower requirements and project economics. The development of mining phases, or pushbacks, is discussed in conjunction with generating the best spatial extraction sequence. An approach to scheduling production from these mining phases is then described. Using computers and a production scheduling algorithm, the impact of cutoff grade and advanced stripping policies can be evaluated through sensitivity studies to maximize the return on project investments.

Jan 1, 1985

By G. V. Sullivan, B. E. Davis, T. O. Liewellyn

A technique was devised by the US Bureau of Mines to recover coarse [+1.2-mm (14- mesh)] North Carolina phosphate now discarded as waste. Concentration utilizes the difference in particle sphericity between the relatively flat calcite and the rounded phosphate pebbles. Sizing, treatment in a continuous hydraulic classification system, and grinding upgraded a 17% P,O5 reject to 4.5% P,05 with a phosphate recovery of 63%. The CaO: P2O5 ratio was reduced from 2.49 to 1.66.

Jan 1, 1987

By Hans von Michaelis

The renaissance in extractive metallurgical practices for gold and silver recovery is far from over. This is one conclusion of a three year investigation into innovations in Cold & Silver Recovery by Randol International Ltd. (1981, 1983). The six volume reference report reviews a host of new processes and innovative applications of older metallurgical practices. Some of these were summarized by von Michaelis (1982, 1982a). There are several reasons to expect this renaissance to continue. One reason is the nature of gold and silver deposits. The list of known occurrences of These metals is very extensive. There are literally tens of thousands of prospects but over 99% of these are too low grade, too small or too refractory for a viable operation employing conventional processing.

Jan 1, 1983

By Stanley R. Riggs

The rocks exposed in the phosphate district are of Neogene age and consist of clayey quartz and phosphorite sands overlying phosphatic dolomite. The Bone Valley Formation is redefined as a marine phosphorite containing primary phosphorite and abundant terrigenous sediments. It contains a Middle Miocene vertebrate and invertebrate fauna and conformably overlies the Hawthorn Formation containing similar invertebrate fauna. A new, unnamed formation, with Pliocene and Pleistocene fauna and containing reworked phosphorite, overlies the Bone Valley disconformably. Its phosphorite is derived from the subjacent Bone Valley by post-Middle Miocene erosion and deposition in stream channels and marginal marine environments. The Bone Valley contains two main types of primary marine phosphorite. Orthocbemical phosphorite, a direct precipitate of microcrystalline phosphorite (microsphorite), occurs as a cement or binder in thin beds. Allochemical phosphorite consists of clastic phosphorite particles that were originally formed as microsphorite on another part of the shelf. Microsphorite was deposited in a very shallow open marine environment which had an abnormally high phosphorous content caused by upwelling currents. The mechanism of deposition is still in doubt, but organisms probably were a major factor. Soon after deposition, microsphorite was indurated, periodically torn up, and the resulting fragments transported and deposited elsewhere on the shelf. These processes account for a great portion of the clastic phosphorite in the Miocene deposits of Florida. The primary fossil skeletal material is of minor importance.

Jan 1, 1965

By Harold L. Lovell

The extensive heterogeneity of coal is a fact long recognized by scientists and engineers. However, until recent years the practical implications of such heterogeneity have more often been realized from an undesirable experience than from knowledge or forethought. Variations in the properties of coal, even within the same seam, eventually lead to procedural modifications in mining, handling, preparation and utilization. The concepts considered here propose an enhanced application of information, detailing these properties, realizing the uniqueness of any given coal seam but the practicality of a common approach. Coal preparation practice has been designed primarily for the control of ash and sulfur content to meet market specifications which are similarly specified, Other physical characteristics of size and friability are also commonly employed and, to a lesser extent, properties which are implications of rank. The consideration of petrographic data as indicators of origin, thus total physical and chemical properties, has generally been overlooked as a realistic tool in-the exploitation of coal as a resource. The evolution of descriptive techniques, whether petrographic, physical, or chemical, capable of universal application with any rank of coal, is still beset with problems.

Jan 1, 1968

By D. Marcus

A methodology was developed wherein. the increase in compressive strength, mineralogical changes and pore water composition were all studied simultaneously as a function, of moisturized spent shale curing time. From these results the relationship between the nature of cementation process and the composition of pore water was established. Heavy metals were entrapped in the cementing constituents and the pore water became mainly a solution of alkaline sulfates. While the specific data are applicable only to the material studied, the methodology and general conclusions are useful for evaluating the environmental factors in spent shale disposal and expected leachates composition.

Jan 1, 1984

By Haydn H. Murray

Kaolins and bentonites of economic importance in Australia and New Zealand are described. Clays that are used for structural clay products are not discussed. Residual, hydrothermal, and sedimentary kaolins are utilized including clays associated with coal measures. Bentonites are sedimentary and residual. Very little kaolin and no bentonite is exported presently, but this will change in the near future as transportation costs continue to escalate. Many areas of Australia, in particular, where kaolins are known to occur have not been investigated to determine the quality and quantity of the deposit.

Jan 1, 1982

By Stephen E. Kesler

Carbonaceous sedimentary rocks are abundant in the upper part of the caldera or maar that hosts the Puebio Viejo Au-Ag district, and much of the Moore sulfide zone is in these rocks. These rocks are thinly layered and contain scattered plant remains and variable amounts of volcaniclastic debris and pyrite. The carbonaceous matter in the sediments yields no X-ray diffraction pattern and is not graphite. It has C/N ratios of 4 to 10, and &13C values of about -25 per mil, which indicate that it is dominantly of marine organic origin and partly degraded. Atomic S/C ratios in the unmineralized part of the carbonaceous rocks have a median of about 1.2, much higher than most similar unmineralized rocks, reflecting not only the abundance of pyrite in the sediments, but also the fact that the organic material contains several percent sulfur. Extracts from the organic material indicate that it is thermally mature and that it reacted with the hydrothermal solutions. Atomic S/C ratios in the mineralized carbonaceous rocks are generally higher than those in unmineralized carbonaceous rocks, ranging to values of 5 and more. These differences indicate that significant amounts of carbon were consumed by the reduction of sulfate and metal chloride complexes in the mineralizing fluids as they passed through the carbonaceous sediments. Direct reaction between organic material and ferrous chloride-bearing, acid-sulfate hydrothermal solutions probably caused continuous deposition of pyrite during this period. Intermittent deposition of gold from chloride complexes by the same reaction was probably facilitated by boiling or C02 effervescence.

Jan 1, 2013

By G. H. Kuhnhausen

The Bear Creek Uranium Mill was designed in 1975 to process 909 tonnes per day (1000 STPD) of low-grade uranium ore from the Powder River Basin in Wyoming. The mill was expanded to 1818 tonnes per day (2000 STPD) in 1979. The Bear Creek Uranium Project is owned by the Bear Creek Uranium Company, a partnership of Rocky Mountain Energy Company and Mono Power Company. The original mill design contemplated processing ores from Bear Creek Uranium Company properties exclusively. The expanded capacity has been utilized for tolling ores from Kerr McGee Nuclear Corp. and other mining companies in the region. This paper describes the process of designing the original mill, the lessons learned from operation, and the design of the process modifications required for expansion. The project background, design philosophy, design basis, design criteria, actual flowsheet, special design considerations, and a comparison of assumed operating conditions and actual operating results will be presented. Bear Creek Uranium Company wishes to thank and acknowledge the help granted by the many operating companies who provided invaluable information, insight, and critique of the Bear Creek design through all the various stages and were instrumental in the successful completion and start-up of the mill. Without their contributions, the design philosophy used at Bear Creek would not have been possible and the results obtained would surely have been less satisfactory.

Jan 1, 1979

By Adrian Brown

Floor heave can be a major problem in large open pit mines. Unrestrained floor heave can lead to flooding, equipment destruction, slope instability and subsidence. It is particularly troublesome in coal mines where the floor is frequently relatively flat, and is often underlain by major water Searing units. This paper examines methods of analysis used in computing floor stability, and sets out a simple rational method of evaluating the required level of water pressure control to maintain acceptable floor stability. The approach is illustrated by reference to the stability of the floor of the Morwell open cut lignite project in Southeast Australia, where this approach has been used successfully for over a decade.

Jan 1, 1982

By N. E. Lehman

Cordilleran metamorphic core complexes in the southwestern United States are areas where middle to late Tertiary low-angle normal faulting has uncovered rocks that were at temperatures sufficient for mylonitization during the early part of Tertiary extensional faulting. Large-displacement low-angle normal faults that separate upper-and lower-plate rocks in metamorphic core complexes are termed detachment faults. The significance of Tertiary detachment faulting in the Basin and Range Province has only become apparent in the past 6-8 years, and the association of mineral deposits with detachment faults has only been recognized in the past few years as well. Crystalline rocks below detachment faults have typically undergone chloritic alteration and brecciation over a distance of a few to a few hundred meters below the fault surface (Fig. 1). Chloritic alteration and brecciation overprinted mylonitic fabrics formed during earlier ductile shearing along the down-dip projection of detachment faults. Rocks that underwent pre-Tertiary ductile deformation and prograde metamorphism were subjected, in rapid succession, to middle to late Tertiary mylonitization, brecciation and chloritic alteration, microbrecciation immediately adjacent to the fault, and subaerial exposure. Lower-plate rocks thus experienced rapid decompression and cooling as a result of tectonic denudation and isostatic uplift (Wernicke, 1981; Davis, 1983; Davis et al., 1986).

Jan 1, 1987

By E. G. Williams

Underclays and shales are two natural resources associated with the coal measures. Underclays are widely used as the raw material for refractory, semi-refractory, and face bricks. Shales are useful for sewer pipe and lightweight aggregate. This study concentrates on the geologic controls over the properties of shales for use in the manufacture of lightweight aggregate, and the geologic controls over the properties of underclays for use in the manufacture of bloating ladle refractories. The industrial processes are similar in that both involve the trapping of a gas phase to cause bloating. They differ in that the bloating of lightweight aggregate occurs at lower temperatures (1000-1200°C) than ladle bricks (1350°-1470°C). Lightweight aggregate bloats during an initial rapid firing. Ladle bricks are manufactured by slow firing at 1100°C for up to 80 hours. Bloating occurs when these bricks are reheated to 1350°C . Bloating shales are those which expand twice or more times their original volume during fairly rapid firing. Commercial bloating is usually done by rotary kiln processing or sintering; in both cases the firing rate is much faster than the experimental rate (5/8°C/minute). Bloating results from the entrapment of gasses which are evolved during firing. The material must have adequate viscosity to trap gas bubbles throughout the temperature range of bloating. The finished product contains a high percentage of closed pores with a bulk density between 35-75 pounds per cubic foot. Expanded shale finds its most important use as a substitute for heavy concrete aggregate (crushed stone, sand and gravel) where low bulk density is desired property. The extent of bloating in lightweight aggregate is a function of the mineralogy and chemistry of the shale. Figure 1 shows a corner of the three phase diagram, kaolinite-quartz-(illite and chlorite). Several areas on the diagram are outlined which contain predominantly marine shales, fresh and brackish water shales, and underclays. Each sample was rapid fired and the resulting expansion was plotted on the phase diagram.

Jan 1, 1973

By S. C. Termes

This paper discusses recent Federal Bureau of Mines research on the selective flocculation of various minerals with insoluble crosslinked starch xanthate (ISX). ISX is insoluble, has a shelf life of over a year when kept cold, and has a higher molecular weight due to cross linking than the soluble noncrosslinked starch xanthate used in previous flocculation studies on nonsulfide minerals. ISX readily flocculates a number of sulfide mineral fines but not silicious gangue. Floc formation, floc size, and settling rate are strongly dependent on pH, with the pH dependence differing for each mineral. Bornite has been selectively flocculated from bornite-quartz mixtures, and the bornite-containing flocs were separated from the unflocculated quartz using decantation and washing procedures.

Jan 1, 1982

By William C. McBee

A sulfur concrete technology has been developed by the U.S. Department of the Interior, Bureau of Mines, in which chemically modified sulfur is utilized with suitable mineral aggregates to produce construction materials which are resistant to corrosion by acids and salts. This report presents a summary of the basic technology and results of testing the materials under actual operating conditions in 50 corrosive environments in 40 commercial plants. After 4 years of testing, there was essentially no evidence of material degradation or loss of strength. Regular concrete materials were attacked and in some cases completely destroyed under the same conditions. Testing is continuing to establish ultimate longevity and durability of the sulfur concretes. The materials are finding widespread applications in metallurgical, chemical, and fertilizer processing plants.

Jan 1, 1983