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By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By Terence G. McCusker, Bruno Dietl

The only previous attempt to use a tunnel boring machine in the rock formations encountered in New York City was unsuccessful. However, technology has been developed since then which made a new attempt a practical proposition. Nine thousand feet each of 8'6" and 11'0" diameter tunnels were driven in Manhattan schist using Jarva TBM's together with 1100 ft. of the smaller diameter driven conventionally in Inwood marble and earth. (1) The selection of tunneling method was largely based on the need to avoid community reaction and hazardous tunneling conditions where the larger diameter tunnel passed beneath residential structures in poor condition in seamy and blocky rock. Experimentation with cutters and cutter mountings indicate that good cutter life and ease of change are available. It was found practical to use unusually large muck cars for an efficient muck disposal system. Conventional tunneling was successfully executed beneath a subway station whose invert was less than seven feet above the crown of the tunnel. Attempts at chemical consolidation and dewatering were unsuccessful in the earth section which was completed under compressed air.

Jan 1, 1974

By James Lonergan

This paper describes the application of the Graphics Assisted Under Ground Engineering (GAUGE) software to a 2-layered room and pillar hard rock mine. The graphics- assisted mine modeling and mine planning capabilities of GAUGE are demonstrated. The system uses polygons to model the room and pillar mine design and displays the model in plan view on the graphics screen,. The planning engineer interactively specifies areas to be mined in the medium or long term. The system calculates and accumulates tonnages and grades for the user-specified areas based on the layer being mined and the particular unit operation (drifting, widening or benching).

Jan 1, 1989

By Robert N. Evans, Delon Hampton

During construction of the Washington Metropolitan Area Transit System, the hand-mining of a mixed-face condition was anticipated on a portion of tunnel located in the downtown area of Washington, D.C. The Section, consisting of two circular tubes, extends from Station 12+80, heading in a westerly direction, traverses along a curve under Lafayette Square, and ends in a northwesterly direction at Station 37+62 (see Fig. 1a). It was near the northernmost portion of the section that the mixed-face condition was encountered. Decomposed rock was first encountered in the invert at Station 31+00. From this point the rock gradually increased in height until it intersected the springline at Station 37+62, the project limit. Summarized within this paper are measurements of the soil load on a horseshoe-shaped portion of tunnel located in the mixed face condition. These measured loads are compared to the soil load on tunnels as determined by current design methods. The paper also discusses rib and surface movements associated with the post loading process. Comments will be made on how the presence of a mixed face condition might help or hender the tunnel design and construction procedures.

Jan 1, 1974

By Timothy C. Smith, S. Andrew Jacobs, Douglas E. Gonzales, Sandy J. Schexnailder, Carl Urban

At the Schwartzwalder Mine (Cotter Corporation, Golden, Colorado) ion exchange resins have been used in mine water treatment experiments. The experiments, initiated in October 1979 and currently in progress, demonstrate that mine water uranium values can be reduced to levels as low as 10 ppb. Duolite® A-101D, a strongly basic anion exchange resin, was tested in laboratory-scale columns (1 inch diameter) initially and then in pilot-scale columns (4 inch diameter), using both co-current and counter-current operational modes. Observations and conclusions resulting from these studies can be summarized as follows: (1) Duolite® A-101D appears to have successfully extracted uranium at influent levels of approximately 2.0 ppm over multiple loading and elution cycles, consistently producing effluent concentrations as low as 10 ppb uranium. (2) Based upon present test data, counter-current regeneration appears to be the key to successful operation. Upflow loading and downflow elution are the preferred modes for service and regeneration, respectively. (3) Filtration is a necessary pretreatment to remove fine clay and inorganic precipitates that will foul the resin, causing excessive pressure drop and poor loading and elution kinetics. (4) This waste treatment application is unique in that it offers the opportunity to recover some or all of the capital investment in the treatment facility

Jan 1, 1980

By J. C. Norman

The boron review arrived too late to appear in the June issue. The United States was the world's second largest producer and the largest consumer of boron compounds during 1991. According to the US Bureau of Mines, boron mineral concentrate and chemical production in the US totaled about 1.1 Mt (1.2 million st), yielding about 608 kt (670,000 st) of BO, in 1991. Total estimated value was $440 million. That level of production was equal to 1990 revised production figures. Value was greater by $37 million, however, reflecting a strengthening of boron product prices. The US continued to supply essentially all its own boron while maintaining a strong position as a source to foreign markets of sodium borate products and boric acid. Domestic employment in the mining and beneficiation of boron products in 1991 remained at 1100 people, about the same level as in 1989. The Bureau of Mines estimated total world production of boron in 1991 - mineral concentrate and chemical - at about 2.9 Mt (3.2 million st). That corresponds to about 1.2 Mt (1.3 million st) of BO ,. World production in 1991 was about equal to revised 1990 levels. US production Mines and processing operations in southern California were the only domestic sources of boron mineral concentrates and chemicals in 1991. US producers, in order of quantity of production, were US Borax and Chemical Corp., North American Chemical Co., and American Borate Co.

Jan 1, 1992

By G. S. Dobby, N. J. Contini, S. W. Wilson

Scale-up and simulation of flotation columns requires construction of mathematical models which employ, as a minimum, rate constants for quantifying particle recovery in the collection zone as well as split factors for quantifying froth zone performance. To date, measurement of these rate parameters has proven to be difficult, due to the interdependent nature of the collection and froth zones. This paper describes a technique for making these measurements. The method requires recovery data from two modes of operation: countercurrent and cocurrent. In cocurrent flow slurry is fed at the bottom of the column and tailings are withdrawn a short distance below the froth interface. Countercurrent mode is conventional operation. The critical difference is that particles which are dropped out of the froth in cocurrent mode are immediately lost to tailings, while in countercurrent mode the particles are subjected to recollection. Fitting of the measured recoveries to the equations that describe flotation in the two modes yields rate constant or recovery values for both the collection and the froth zones.

Jan 1, 1988

By Eugene F. Casey

The next ten to fifteen years will be exciting ones for the construction industry because three city agencies alone have started or will start, on tremendous expansion programs, the cost of which will exceed a total of four billion dollars. The major portion of this work will be done by the use of tunnelling methods. *Tunnelling is construction by any method of a covered cavity of predesigned geometry whose final location and use under the surface, whose cross-sectional area is greater than two sq. meters. The New York City Transit Authority's expansion program will provide for approximately 52 miles of new subways. The Board of Water Supply has already started on City Tunnel No. 3 which, when completed will provide the City with enough water until the year 2000, and the Board of Water Resources has embarked on a tremendous program to clean up the surrounding waters. Yes, these will be exciting years, particularly when one reads about the new novel exotic methods of rock breaking and disintegration, coupled with the new methods of soft ground tunnelling.

Jan 1, 1997

By Hiromu Kusakawa, Tetsuo Kanematsu

INTRODUCTION In urbanized area with heavy street traffic and with environmental requirements to lessen construction noise and vibration, the cut-and-cover is not always a feasible method to build a small diameter tunnel for sewage, water or other utilities. That is where the use of the shield machine to bore such a small diameter tunnel should be considered as a more acceptable alternative. Although the shield machine of this type should be small enough to meet specific requirements for a given tunnel, it should be big enough to provide some working space inside of the tunnel. Recently, we have successfully developed the fully mechanized small diameter tunneling method which enables us to bore a tunnel as small as 600mm in finished diameter. This paper discusses the concept of this newly developed method, including a case history where sewage tunnels of 800mm finished diameter were constructed by using this method. OUTLINE OF METHOD Developed from the original slurry shield pipe-jacking tunneling method, this method is highly automated so that all operations inside of the tunnel can be remotely controlled. Various data including the advance rate, position and inclination of the shield are transmitted to the central control room outside of the tunnel and monitored by the CCTV and the instrument panel at all times to

Jan 1, 1981

By Walter G. Steblez

The countries of Eastern Europe are former members of the Council for Mutual Economic Assistance (CMEA). Geographically, they are located in Central Europe (Poland, Hungary, Czechoslovakia) and Southeastern Europe, largely in the Balkans (Yugoslavia*, Bulgaria, Romania and Albania*). It is important to remember that all of the countries of Eastern Europe had central planning imposed on them by the Soviet Union during the years following World War II. "Stalinist" policy for industrial development had three important tenets: • central economic planning, or a nonmarket-based command economy with administratively set prices; • economic priorities that stressed the development of heavy industries such as mining, metallurgy (steel) and heavy machine building; and • self-sufficiency at all costs, which was aimed at abolishing reliance on the world capitalist market, or reducing it to a minimum. Essentially, the system of industrialization that was used in the Soviet Union in the 1930s and 1940s was imposed on Eastern Europe. Organic market economic development in Eastern Europe ceased during this period. The flaws of this experiment became apparent when mineral processing facilities were set up in many areas of Eastern Europe that did not have reliable resources. Poland, Hungary and Romania are good examples of this situation. The Soviet Union became the principal supplier of iron ore and other minerals and mineral fuels, not only to these countries but to the Bloc as a whole.

Jan 1, 1992

By James J. Brady, James S. Lewis, Robert B. Gordon, Jimmy W. Honeycutt

INTRODUCTION Tunnel construction has always been an extremely high risk form of contracting primarily due to the inaccessability of information concerning the ground conditions to be encountered during excavation. We certainly make every effort to overcome this problem through borings, geological research, site visits, etc.; but at best owners, engineers and contractors alike are only able to interpolate a relatively small amount of factual data from isolated sections of the project into a forecast of ground conditions for the entire project. In essence this becomes an "educated guessing game" with risk to reward ratios (and subsequently the bid price) in direct relationship to the contractor's confidence in the quality of the guess. In many instances it is economically or physically infeasible to obtain information and of course the total picture is never known until the project is complete. This problem effects the contract format as well as price. The contractor's ability to handle unforseen problems on the project become extremely important as to the project's overall success. The following pages contain an actual case history of a project which affords an excellent example of the entire spectrum of situations resulting from tunnel construction in difficult ground conditions.

Jan 1, 1983

By Leo Wagner

In relation with the construction of the Sölk power station in Steiermark, Austria, tenders were called in October, 1976, for the construction of the 12-km "Donnersbach collector tunnel" by "Steirische Wasserkraftund Elektrizitäts AG". The specified showed both conventional blast tunneling as well as mechanical excavation with a tunneling machine, diameter 3.55 m. Total construction time from the date of the invitation to tender was given as 4 years. Part of the project was the construction of a concrete circular tunnel lining 20 cm thick. In 1977 the contract was awarded to "Arbeitsgemeinschaft Donnersbach", a joint venture formed by two companies, G. Hinteregger & Söhne, Salzburg, and G. Hinteregger, Bregenz. It provided for the project to be carried out with a tunnel boring machine. GEOLOGICAL DATA The entire tunnel was to be bored through a complex of the garnet mica schist group of the Wölz schists formations. These range from highly quartz-bearing to quartzitic mica schists, with thick, discordantly interstratified beds of marble and dolomite. In the western sector the axis of the collector tunnel intersects the bedding at an angle of 30° to 40°, in the eastern sector the bedding is about

Jan 1, 1979

By S. K. Mishra, S. B. Kanungo, D. Biswal

An attempt was made to beneficiate low-grade, high-phosphorus manganese ores of the Garividi-Garbham region of Andhra Pradesh, India, by using wet high-intensity magnetic separation (WHIMS). The distribution behavior of both mass and chemical constituents in different size fractions of a typical highly weathered ore sample was studied to obtain information about the liberation characteristics of various chemical constituents. Magnetic separation indicated that in the +208-µm size fractions, P and acid insolubles were concentrated in the magnetic fractions. However, in the -208-µm size fractions, P and acid insolubles were concentrated in the nonmagnetic fraction because of a lower recovery of the magnetic fraction. Variations in field intensity between 1.3 and 1.75 T had little effect on the recovery and the grade of concentrate. The results also demonstrated that phosphorus was associated with all three major constituent phases, namely, oxides of Mn and Fe and aluminosilicate gangue minerals.

Jan 1, 2000

By I. Iwasaki, T. Fujuita

The removal of phosphorus from steelmaking slags is essential for recycling such slags to blast furnaces for recovery of their manganese, iron, and lime contents. Phosphorus is mainly concentrated in the dicalcium silicate phase of the slags (Fujita and Iwasaki, 1988, 1989; Suito, et al., 1977). Slow-cooling of steelmaking slags in an air atmosphere increased the grain sizes of constituent minerals; however satisfactory magnetic separation results could not be attained because of the close association of a strongly magnetic ferrite phase with dicalcium silicate (Fujita and Iwasaki, 1988). Curie point of the strongly magnetic ferrite phase in the slow- cooled steelmaking slags was investigated and an attempt was made to separate the phosphorus-bearing dicalcium silicate phase in ground slag pulps heated to a temperature exceeding the Curie point. Materials and methods Slag samples, heated to its fusion temperature of 1370°C and slow-cooled in an air atmosphere, were ground dry to -90 µm (about 170mesh) in a ring grinder. The ground sample was pulped to 1% solids in distilled water using 1 kg/t sodium hexametaphosphate as a dispersant and separated in a Sala high gradient magnetic separator, Laboratory Model 10-15- 20B, using a 100-mesh expanded metal matrix and 300 m/h flow rate.

Jan 1, 1990

By Odd E. Hanssen

In April 1982, the contracting Companies, ABV of Sweden and Hoyer-Ellefsen of Norway forming the Consorcio Escandinavo Agoyan, signed the contract for the construction of the civil works of the Agoyan Hydroelectric Project, located in Ecuador, South America. The project is located in the Andes mountain region of Ecuador - one of the smaller countries in this part of the world, located on the Pacific Coast. The contract was signed with the Instituto Ecuatoriano de Electrificación (INECEL), a public institution in charge of the development of all major energy producing projects in Ecuador, for a value of approximately US$ 120,000,000. The contract's main elements are - Concrete gravity dam with a total volume of approximately 210,000 cu m. (60 m wide x 45 m maximum height, 320 m crest). - 2,400 m of headrace tunnel, interior diameter of finished lining 6 m of which 450 m is in-situ tunnel formed in a trench. - Pressure shafts, 132 m long, the lowest meters with sheet lining, the rest with concrete lining. - Powerhouse cavern with an excavated volume of approximately 25,000 c m in which two turbines of 78 MW each will be installed. - Two 140 m tailrace tunnels with a finished diameter (concrete

Jan 1, 1985

By F. Chavan

1. Introduction The new Cleuson-Dixence development project in the Valais region of the Swiss Alps, involves the construction of a new link between the Grande-Dixence dam (still world recordholder with a height of 300 m) and a power house on the banks of the Rhone consisting of approximately 20 km tunnels and shafts, and involving a fall of about 1900 m. This 1200 MW project will replace an existing 900 MW structure built in the 1960s, no longer considered efficient. The new project comprises a head race drift about 15.8 km long, a surge tank, an inclined cascade shaft 4,2 km long, and an underground power station. The work for lots C and D (head race drift from Tortin to Tracouet, surge tank, six adits ans the complete inclined shaft) was awarded to our group (Prader, Locher, SELL, Losinger, Evéquoz, Dénériaz, Imboden and Bouygues). The geological conditions are: Lower part of the shaft (300 m) : sedimentary - sandstone and soft tertiary sandstone. Middle and upper part (2600 m) : metamorphic - upper and lower carboniferous, interrupted by triasic chipping. The horizontal section (7 km) consists of mica

Jan 1, 1995

By Welland L. Ott, Hans J. Rumland

The Falconbridge Dominicana laboratory receives samples from all parts of the operation. Ore, metal and oil samples are taken by operating departments, gas and water samples by the laboratory staff. Physical sample preparation is essentially standard and produces comminuted samples for wet-chemical analysis and X-ray fluorescence analysis (XRF). T he main operating sections of the laboratory are described indicating in each case the type of instrumentation and method used, sample types analysed and comments on problems experienced. Emphasis is given to the sample preparation and X-ray sections especially with regard to the difficulties caused by our heterogenous ore material, calibration of the instrument and operational malfunctions. General problems related to our remote location and the tropical climate are discussed. Limited statistics on instrument availability, and stability, accuracy, precision, etc., are given.

Jan 1, 1979

By Karl J. Ellefsen

A geophysical investigation can provide valuable geologic information needed to characterize sand-and- gravel deposits and can be an attractive complement to more common characterization methods such as drilling. Although such investigations have been conducted already, a comparison of the different geophysical methods used in these investigations apparently has never been done. For this reason, a study was initiated by the Mineral Resources Program of the U.S. Geological Survey to determine the advantages and the limitations of different geophysical methods when used to evaluate alluvial sand-and-gravel deposits. The study is focused on those geophysical methods that are commonly available, because these are most likely to be used by industry. Furthermore, the study is focused on surface geophysical methods. Heretofore, four different methods have been evaluated. Three of the four methods-time-domain electro-magnetic (TEM) soundings, frequency-domain electro-magnetic profiling, DC-resistivity soundings-are similar in that they all measure the electrical resistivity of the ground with depth. Ground-penetrating radar, however, maps changes in the dielectric permittivity and for the electrical resistivity with depth. For all, four methods, the objective is to relate the measured physical quantity to the stratigraphy of the alluvial sediments.

Jan 1, 1999

By J. F. T. Agapito

Significant economic benefits can result when rock mechanics is applied within a practical framework and integrated within the other engineering functions of the mine organization. Such application and integration requires management support and understanding of rock mechanics as a practical tool to help attain high standards of safety, productivity and resource recovery. For such an approach, a long-term geotechnical program is needed in most operations to build an adequate data base and to ensure that design and ground control issues are handled in a cost-effective manner. Best usage of rock mechanics in mining occurs when management recognizes the application as a long-term investment, where time is needed to realize good returns. The need for this approach is due to the difficulty in accurately predicting ground conditions ahead of mining. The practical application of rock mechanics must follow an iterative process of design and verification based on site-specific experience to account for geologic and mining impacts. Ground conditions experienced during mining must be used to check the initial mine design and, if necessary, to provide a basis for design modification. Such a practical rock mechanics program includes comparative experience, in situ instrumentation and numerical modeling. The program begins with the geologic site investigation and continues throughout the life of the mine. It is an integral part of mine planning and operation.

Jan 1, 1991

By A. Exikis

Simulating a ventilation network of an underground mine can help in solving complex ventilation systems with many features, selecting proper fan specifications, location and settings. Early computer systems running simple network simulations were able to provide solutions to the most common and immediate problems regarding underground mine airflow. The more advanced systems available today can perform more sophisticated modeling and simulation of a mine?s ventilation network and present their results in a more understandable and easy to communicate form. This paper presents a ventilation network case study from an underground mine. All aspects of mine ventilation network modeling and simulation are discussed as well as the results from the simulation process. The algorithms and techniques used are thoroughly explained. Some useful guidelines for the application of ventilation network software are also provided in the text.

Jan 1, 2006