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By W. K. Tolley, D. G. Kotlyar

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.

Jan 1, 1995

By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By Michel L. Van Sint Jan, Gabriel Fernandez-Delgado, Edward J. Cording, James W. Mahar

INTRODUCTION Shotcrete behavior observed in subway tunnel construction in the U. S. has been primarily in blocky or blocky and seamy rock in which rock loads develop from the self weight of individual rock blocks that tend to loosen from the wall and roof of the opening. Such conditions can be classed as loosening ground, in contrast to squeezing ground in which high pressures are generated on the tunnel lining with time as the ground creeps under the natural ground stresses. In the philosophy often associated with the New Austrian Tunneling method, emphasis is placed on the use of shotcrete and other support elements in squeezing, highly stressed ground, in which the support system is designed to allow controlled movements so that high lining stresses do not develop. In contrast to these conditions, the concern in loosening ground is to provide support soon enough to minimize loosen-

Jan 1, 1979

By Joao Felipe Costa, Jair Carlos Koppe, Alexandre Grigorieff

Discrepancies in raw materials properties informed by both producer or consumer is a common problem in most areas of the industry. Commercial contracts in the mineral industry normally penalises the producer, if contaminants in the ore exceed established limits. In some situations, the supplier is penalised if the quality of the ore is below a contracted amount. Differences in lab analysis are due many sources of error, such as distinct practices used in two laboratories for sampling, preparation or analysis. Rigid contracts impose to the miner the use of rigorous quality control program and in these situations sampling plays a major role. Sampling theory provides the tools to analyse errors involved in sampling, preparation and analysis. This paper proposes a methodology to check the precision and accuracy of a given sampling protocol emphasising the application of Gy's sampling theory to broken ore. A procedure to measure the error on each step of the protocol is introduced and the results compared to the fundamental error measured by Gy's theory. The results show the applicability of the method and its relevance to audit sampling procedures aiming at error minimisation. The methodology is illustrated in a case study at a major coal producer in Brazil.

Jan 1, 2002

By A. T. Sapulek, C. S. Özveren, D. W. Dixon

The prediction of underground methane emission from longwall coal faces has been extensively researched for a number of years and numerous prediction methods have been devised. Many coal mines employ sophisticated environmental monitoring equipment which generates large amounts of data including, methane concentration, air velocity and barometric pressure. Presently this information is mainly used only to indicate alarm and danger levels of the monitored data for management purposes, however, the potential uses of this data are enormous[1]. This information could be used to good effect within a production/methane emission strategy as detailed in a previous paper[2]. The paper presents a practical application of artificial neural networks to underground methane prediction. Data on methane concentration and coal production has been obtained from an underground coal mine. The data is used in a neural network architecture and forecasts of methane concentration have been obtained. The forecasts are examined and there is a discussion of the potential use of the predictions from neural networks in the field of mining production control.

Jan 1, 1995

By R. Kanniganti, M. Karmis, C. Haycocks

An extensive review of multi-seam under-mining literature was conducted and a data base of case studies was assembled . A critical review of the design principles outlined in this literature resulted in the compilation of specific design criteria for the design of lower seam mines. Analysis of this criteria demonstrated the necessity for a protocol for the design of unsymmetrically loaded pillars. Such a design criteria was developed using finite element methods for a wide range of possible loading conditions. This design criteria can be utilized for underlying pillar design when the loading conditions can be determined. To facilitate using all the under-mining research results by field/planning engineers a Windows TM based software package was developed. This software package contains a multi-seam tutorial, analytical tools and a case history database. The package is user friendly and fully interactive and supported with extensive on-line help. The package contains numerous case studies of multi-seam mines that can be reviewed to facilitate analyses.

Jan 1, 1996

By André Vervoort, Jef Caers

Compound lognormal distributions serve as new generalized distribution laws for analyzing and estimating ore value distributions or related properties such as the average ore grade. These models are an alternative to the well known lognormal distribution. They are the translation of general geological constraints on the genesis of the deposit cumulated in suitable statistical properties. In this paper a maximum likelihood framework is established for estimating the parameters of such laws or parameter functions thereof. It is shown that under certain conditions maximum likelihood estimation is accurate and efficient in estimating the mean value even when relatively few samples are available. The method is based on a numerical maximization of the likelihood function of these models given the data. Confidence limits on these estimates are set up using resampling techniques such as the bootstrap. By this a complete methodology is presented for inference on ore grade distributions such as is shown in an example of gold data from the Merriespruit mine (South Africa) and the diamond size distribution of the Bougban deposit (Guinea).

Jan 1, 1996

By R. Y. Wan, J. D. Miller, P. L. Sibrell

Three different refractory carbonaceous gold ores from the Carlin operation in northeastern Nevada were investigated to characterize the effect of passivation treatments on the nature of the carbonaceous material. The carbonaceous material was chemically isolated from the ores and passivated residues, and examined by FTIR spectroscopy, elemental analysis, and gold adsorption capacity. The main component of the carbonaceous material in these ores was found to be a naturally occurring activated carbon-type compound. Hydro-carbons were detected on rare occasions, but no evidence was seen for humic acids. Ore samples were passivated by autoclaving, or by treatment with sodium hypochlorite or gaseous chlorine. In some of the passivation tests, a new peak was observed in the IR spectra of the isolated carbonaceous material, that was due to carbonyl functionalities. However, all of the passivation treatments tested decreased preg robbing significantly. This suggested that the appearance of the carbonyl peak was due to the severity of the conditions during passivation, rather than the method used.

Jan 1, 1990

By Alice Blount, F. Patrick Carr

The quantitative evaluation,of quartz and other minerals in acid-insoluble residues from carbonate rocks and other industrial mineral products derived from sedimentary and low-grade metamorphic rocks is difficult. Commonly there are a dozen or more minerals present, and the suites vary from sample to sample. Because of these factors, either the absorption coefficient must be determined on a sample to sample basis or an internal standard must be used. Internal standards in general use are unsatisfactory. For example, [A1203] is often present in product samples because of ceramic grinding elements used in their production; CaF and LiF have peaks which overlap or nearly overlap mineral peaks in the samples. A careful evaluation has shown that magnesium aluminate (synthetic spinel) works particularly well as an internal standard for these types of samples. Not only does it have few, strong diffraction peaks which do not overlap, the peaks are in the same 28 region as the minerals, usually quartz and silicates, for which quantification is desired. Spinel also consists of equidimensional particles without prominent cleavages; this promotes a random orientation of the minerals in X-ray diffraction mounts. In addition, spinel can be used to correct for loss of diffracted-beam intensity due to thin sample preparations which are often unavoidable.

Jan 1, 1991

By T. Eisele, T. Weldum, G. Rajala, H. Walqu, S. Kawatra

The throughput and energy efficiency of comminution circuits is reduced when ore characteristics change, causing bottlenecks in some portions of the circuit while leaving excess capacity in others. The results of analysis of three years of daily grinding circuit operating data for a full-scale plant has shown that the location of bottle-necks in the circuit will change depending on the nature of the feed ore. The circuit tends to be limited by the primary mill capacity when the ore hardness increases, and limited by the secondary mill capacity with softer ores. Two methods are considered for shifting load in the circuit to relieve bottlenecks by taking advantage of excess capacity in other parts of the circuit: 1) Addition of supplemental comminution operations, such as high-pressure grinding rolls, to process specific size fractions that are not handled efficiently by the primary mill; and 2) Use of screens to shift grinding load upstream from the secondary mills back to the primary mills. In the case of the plant examined in this study, it was found that 58% of the time there was sufficient excess capacity in the primary mills that the throughput of the circuit could have been increased by using screens to shift the grinding load from the secondary mills to the primary mills.

Jan 1, 2004

By Changwoo Lee

Under drastically deteriorated situations, diesel equipment was introduced to some of local coal mines, aiming at higher productivity and better safety. To accommodate various diesel equipment in conventionally developed mines, mining system itself had to be modified; much larger trackless haulage ways were excavated. Possible health hazards of diesel not taken into account at the beginning become a serious concern and effective control measures are being searched for. The purpose of this paper is to study the diffusion characteristics of diesel exhaust in local coal mines. One of the parameters affecting dispersion of diesel contaminants is the coefficient of turbulent diffusion. Since CO2 is known to be closely correlated with other contaminants such as CO, NO, NQ, SO2 and RCD, it was chosen as a tracer gas in a series of dispersion experiments. A large diesel passage as well as a conventional track haulage way were the sites for the experiments. Rectangular dispersion pulses were generated for 30 ~60 seconds and CO2 concentrations were recorded at several locations 50~190 m downwind. The diffusion coefficients calculated graphically vary between 0.10~0.48 m2/s at both haulage ways. The results are analyzed to find any correlation with the air velocity and the distance from the disperser. Skobunov's empirical formula is applied to the experimental data for comparison and the relationship between Reynolds number and Ex/Dp/sci0.4 Sc1…

Jan 1, 1995

By Richard Crawshay, Duncan Hutchison

Continuous Mining Systems Limited have developed an efficient, high-capacity, in-line loading unit capable of handling shot rock in tunnel driveages at extraction rates up to 970 tonnes (1,000 tons) per hour. A smaller 408 tonnes (450 tons) per hour loader is also available These in-line loading units called "Osciloaders"® provide a continuous flow of material from the muck pile to an anciliary conveyance eliminating the cyclic or interrupted movement noramlly associated with gathering arm or bucket type loaders. The osillating lip fluidizes the material, reduces the penetration force required and facilitates and regulates the material flow onto the adjacent conveyor. The conveyor is wide and accommodates very large material with ease, transporting and elevating it to a height suitable for a waiting conveyance at the rear of the machine. The "Osciloader"® is currently being utilized for production mining by a major company in Sudbury, Ontario. Both truck and conveyor anciliary haulage are being utilized. The paper describes the development of the loader and how it may be applied in tunnelling applications.

Jan 1, 1987

By R. Mohan Srivastava

In any operating mine, especially in precious metals operations, immediate improvements in profitability m readily achievable through more effective grade control. Just as the oil industry has come to recognize that enhanced oil recovery (EOR) in existing oil fields yields a higher return on investment than exploring for new oil, so too must the mining industry recognize the benefits of enhanced metal recovery (EMR). Current grade control practices are generally dismal. The very word "control" suggests a willingness to make the best of a bad situation -- as in "damage control" or "disease control" -- and a failure to perceive the opportunities for improved profit. While damage and disease can merely be controlled, success and improved profit can be engineered. This paper presents one approach to enhanced metal recovery. It shows how existing methods can be used to address the issue of ore/waste discrimination. The following sections outline the problem, describe the current state of the practice of grade control, propose an alternative approach and. illustrate the application of the proposed alternative to actual blasthole data from an operating gold mine.

Jan 1, 1992

By T. L. Brekke, T. R. Howard

Stability of an underground opening can be defined in several ways. To geologists and engineers that are used to working in geological environments where the major parts of the works after careful scaling can be left unsupported during the construction period as well as during operation, any rock mass behavior that requires reinforcement, support or lining may be regarded as a stability problem. To colleagues excavating underground openings in geological environments that require continuous use of reinforcement or support and lining "stability problems" are often associated only with those parts of the work where "standard" construction procedure and method of reinforcement or support and lining is inadequate, and special measures therefore needed. In either case, a major objective is to assess the stability problems correctly -as far as possible at the planning stage -- and choose methods for excavation and reinforcement or support that will bring the opening safely and as economical as possible through the problem areas. INTRODUCTION It is not uncommon that stability problems associated with faults or seams have been described as "unexpected." This term has unfortunately been used to indicate that no one knew that the fault or seam existed prior to excavation. A careful review of documented cases where serious stability problems have occurred revealed that the existence of these zones most often was known, but that their behavior was incorrectly assessed prior to or during construction. Miscalculations have been made in terms of the type and magnitude of loads that developed, and in particular in terms of the time-dependant behavior.

Jan 1, 1997

A series of laboratory based push and pull tests were carried out to investigate how surface profile influence the load transfer mechanism of bolt/resin interface. Tests were carried out in both 75 mm and 150 mm long steel sleeves. Three types of bolts were examined, they were bolts most commonly used for strata reinforcements in underground coal mines in Australia. The bolts had near equal core diameter but of different profile configurations. The change in the length of the encapsulation sleeve was examined in light of the small number of profiles encapsulated effectively in short 75 mm long sleeves. The results showed that peak loads and displacements were directly related to the height and the spacing of the bolt surface profiles. Profile spacing appears to have greater influence on load transfer capacity than the profile height.

Jan 1, 2006

By Samuel Sigman, Martin M. Cooper

A basic ingredient for rapid tunnel excavation is material handling. In construction of tunnel projects in urban areas material handling requires additional input to maximize performance. Urban projects share the same problems experienced in all tunnel construction and they must be dealt with. Howeve.., Urban constraints add a larger dimension. APPLICATION ENGINEERING A MUST A word of caution. To achieve increasing speed of excavation in tunnels whether in Urban areas or elsewhere will require much creative thought and energy. It would be a false premise to assume that major breakthroughs will result from this conference, or shortly thereafter, or to hope that a success here or there can translate into a universal solution. The reality, as we see it is that rapid progress and great economies will accrue on any given project only if effective application engineering is carried through. By all means take advantage of past experiences but, do not at the peril of costly undertaking, blindly accept the program of a successful job elsewhere as automatically suited to your project. Tunnel construction in urban areas is at best a difficult undertaking made more difficult in this period of greater awareness of environment, of conservation and of the quality of living by sophisticated urban communities,. A construction job represents a necessary nuisance to urban communities. To minimize this nuisance many regulatory laws are adopted. These regulations can and do slow down tunnel jobs and pyramid costs.

Jan 1, 1974

By Robert G. Page

"Stabilization" of copper differs from sin in at least one respect - no one seems to be against it. Every time a tycoon in the producing industry pontificates on the economic history of copper, or prophesies its future, he is likely to praise the virtues of "stabilization". Consumers of copper constantly bemoan fluctuations in the supply and price of the metal. Governments in some producing countries, to a greater or lesser degree dependent upon exports of copper for foreign exchange and upon taxation of copper profits for substantial parts of their budgets, are perhaps more eager than any other group for "stabilization".

Jan 1, 1962

By Carl R. Peterson, John Herrick

INTRODUCTION The need for substantial advances in underground excavation technology has produced considerable research activity on a wide variety of concepts under a variety of Government funded programs. One goal of this "Rapid Excavation" effort has been the development of a means to apply the well-known virtues, both technical and economic, of the drill and blast method in a continuous process. The spiral blast concept, aimed at this specific goal, has been funded for initial studies (1) by the ARPA Rapid Excavation Program and, for the experimental work reported herein, by the Department of Transportation (2). The economy enjoyed by the drill and blast method stems from two factors: explosive energy is relatively cheap; and this energy is released so as to cause rock fragmentation largely through tensile failures. The relative ease and efficiency of tensile rock failures have long been recognized. The drill and blast process of course cannot be truly continuous since drilling and blasting (and other necessary functions) simply are separate, distinct operations. Although some surface explosive work has been done to avoid the need for drilled blast holes (3) it does appear that the high performance associated with explosive excavation requires placement of the explosive beneath the rock surface. This paper describes studies of blasting pattern which, in simplest terms, replaces the occasional heavy blast of conventional practice with frequent, much smaller blasts. The objective, of course, is to reduce the size of individual blasts

Jan 1, 1974

By C. T. Twort

As technology and economic conditions allow mines to operate at ever greater depths, increasing demands are placed on the environmental engineer to adjust the capacity of the installed mine . - refrigeration systems. At the same time the engineer must satisfy the changing legislation, which demands that developments are carried out in as an energy efficient and environmentally accept- able manner. Following the trends outlined above, this paper is written to give an overview of the current and potential future refrigeration technology available to the mining industry. The effects that may be produced by the adoption in mining applications of the new generation of 'green' refrigerants are examined both at the design stage and when considering the viability of retrofitting existing systems so that they comply with the Montreal Protocol. An introduction to the concept of Total Energy Warming Impact (TEWI) is provided, with an explanation of its use in optimising system design and performance, and its incorporation as part of an environmental audit strategy. The paper concludes with a discussion of innovative refrigeration techniques and the possible future developments in legislation.

Jan 1, 1997

By Stephen J. Klein, Fernando Orduz, Randall J. Essex

INTRODUCTION The Keystone Tunnel project consists of widening an existing 7.3 m-wide (24 ft) highway tunnel to a width of 13.7 m (45 ft) to provide a three-lane, two-directional highway tunnel. The 13.7 m-wide tunnel was excavated in a staged drill-and-blast sequence through foliated schist, and was supported using pattern rock reinforcement and shotcrete. Notable project features are: the low vertical cover over the tunnel is less than the span of the opening; the project is the second instance where the Federal Highway Administration (FHWA) has accepted rock reinforcement as a permanent support element; and the project is the first instance where the FHWA is accepting shotcrete as the final interior surface of the tunnel. This paper covers the design and construction phases of the project. PROJECT DESCRIPTION The South Dakota Department of Transportation (SDDOT) retained Woodward-Clyde Consultants (WCC) to evaluate the feasibility, prepare construction plans and specifications, and provide construction management services for the widening of the Keystone Tunnel. The tunnel is located in the Black Hills National Forest area of South Dakota near the southwest corner of the state. The Keystone Tunnel is on U.S. Highway 16A, about 0.8 km (1/2 mile) north of Keystone which is approximately 32 km (20 miles) south of Rapid City (Figure 1). Highway 16A serves as an important transportation link between Rapid City and the Mount Rushmore National Monument which is located about 2 miles west of Keystone. The road through the tunnel consisted of two lanes about 7.3 m (24 ft) wide, and is being widened [ ]

Jan 1, 1989