Search Documents

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By M. A. Marticorena, R. Stratton-Crawley, C. I. Basilio

Diethylenetriamine (DETA) is a selective depressant for nickeliferous pyrrhotite during pentlandite flotation. Laboratory flotation tests conducted on ore and process samples showed that pyrrhotite rejection is greatly improved by small additions of DETA; however, the effectiveness of this depressant is most noticeable when the mineral sample is oxidized. LIMS and XPS analyses conducted on flotation products and pyrrhotite specimens showed that the difficulty in pyrrhotite rejection arises from inadvertent activation of the mineral by heavy metal ions, such as Ni2+, cu2+ and Ag+, that are present in the process water. In the presence of DETA, however, the mineral is deactivated under oxidizing conditions. The deactivation mechanism may involve oxidation of the activation products, which are likely in the form of heavy metal sulfides, followed by solubilization by DETA. FTIR spectra of pyrrhotite electrodes contacted with DETA showed no trace of the reagent on the surface, substantiating the view that its role is one of complexing agent that enhances the dissolution of activation products under oxidizing conditions. FTIR spectra of pyrrhotite contacted with amyl xanthate solutions showed that both dixanthogen and iron xanthate are formed on the surface, the latter becoming more predominant at higher potentials. In the presence of DETA, however, only a small amount of xanthate is adsorbed on the mineral at potentials (Eh) approximately 200 mV higher than the case without DETA.

Jan 1, 1995

By Luís Tavares Ribeiro

Nowadays there is a greater need for detailed reservoir modelling in the oil industry. It is generally recognized that nearly all reservoirs are heterogeneous and idealization of rock characteristics in flow calculations is unrealistic regarding actual physical and textural conditions encountered in geologic formations. The heterogeneity of oil reservoirs considerably influences the distribution of fluids, as well as their displacement. It would be advantageous if a reservoir petroleum engineer was able to construct a precise mathematical model of the detailed reservoir rock variability characterizing the degree of reservoir heterogeneity in an unambiguous way. This paper presents a geomathematical model describing the spatial behaviour and distribution of the principal reservoir properties. The model is based on the Theory of Regionalised Variables and the Kriging technique. The model is performed by a set of computing programs and is tested on an Abu Dhabi oil reservoir in United Arab Emirates.

Jan 1, 1986

By R. D. Schmidt, S. E. Follin

Introduction Mineral recovery from an in situ leaching operation is determined by the often complex interaction of hydrology, mass transport, and chemical kinetics. The operating conditions of many pilot and production scale uranium leaching operations involve heterogeneities in aquifer permeability. Differences in permeability may be naturally occurring, the result of differences in main size or cementation, or they may be induced by leaching activity. Variations in permeability directly affect the fluid flow streamline pattern, fluid flux, and so also leaching geochemistry and uranium recovery. An in situ leaching hydrology model (ISL) and a mass transport-oxidation rate model (ISLGC) have been developed for use in making site specific predictions of the leachability and productive potential of heterogeneous ore deposits, and for the optimal design of leachant injection and recovery operations. The two models are linked by output and input requirements. The ISL hydrology model generates a leachant flow streamline pattern between injection and recovery points in a flow domain incorporating regions of arbitrary permeability. The ISLGC transport model describes the changing solution concentrations of uranium and oxygen and the changing mineral concentrations of uranium and pyrite resulting from convection, longitudinal dispersion, and oxidation reactions. ISL hydrology model Basic equations The differential equation for steady-state two- dimensional flow in an isotropic porous medium is

Jan 1, 1988

By V. Rastogi

Surfactant-based bactericides are able to control acid formation in sulfidic materials such as pyrite and sulfidic ores, thereby helping to abate acid rock drainage. Bactericides are used in the following two ways: as periodic or continuous spray treatments for the prevention of acidification of material actively handled and moved and in controlled-release form for reclamation. Site-specific bactericide treatments are designed for active sites and reclamation. Results from two active coal refuse sites show that acid production can be reduced by 88% or more. Results from reclaimed sites show that bactericide treatment can be more effective than the addition of alkaline materials such as limestone and can reduce acid production from 3,500 to <30 ppm. The controlled-release-pellets treatment outlasts the life of the pellets, as shown by a study of a site now 10 years old A single treatment sets up a change in site microbiology to replace acid-producing Thiobacillus ferrooxidans bacteria with heterotrophic bacteria and creates a stable site without the need for further treatments. A secondary beneficial effect of bactericides is on revegetation, and biomass from treated areas is almost 10 times that from areas not treated with bactericide. Depending on the application, bactericide treatment can be cost effective upfront and certainly long-term, compared to the perpetual water treatment that could be required, even after productive use of the site is completed

Jan 1, 1997

By H. P. Schlanger, L. Paterson, B. H. G. Brady, B. E. Hobbs

A novel principle for a waste repository, based on a backfilled thermosyphon as the functional unit, is proposed. Such a unit reduces temperatures and temperature gradients in the vicinity of a waste package and in the repository near field, reducing leach rates from packages and thermomechanical disturbance of the rock mass. Preliminary analyses confirm the mode of performance of the system, and reveal some interesting features of material transport and sealing in backfill and rock fissures. The thermosyphon combines attractively with the prospect of developing a near-field geochemical trap with chemical specificity for radionuclides. It is proposed that a thermosyphon repository may provide superior performance of engineered and natural barriers compared with conventional designs. The achievement of the ability to predict accurately the performance of the thermosyphon, relative to other isolation schemes, will represent a benchmark in the understanding of the absolute performance of any repository.

Jan 1, 1986

By John A. L. Dr. Campbell, James W. Haskew, F. Hoy Lee, Elliott P. Dr. Doane

Emissions of particulates, unburned hydrocarbons, nitrogen oxides (NO[ ]) and carbon monoxide (CO) from diesel engines are of concern in mines, particularly underground mines. All these undesirable products except NOx are the result of incomplete combustion in the cylinders. Various approaches to achieving more complete combustion in diesel engines have included different fuel compositions, use of catalysts, fuel additives, engine modifications, and oxygen-enriched intake air. The present study shows that injecting minute quantities of primarily platinum group metal catalysts into the intake air of a Deutz/MWM D916-6 mine diesel engine substantially reduces emissions in the exhaust. The catalyst injection system, which was developed by National Fuelsaver Corporation (Robin. 1981), transfers catalyst compounds in solution to a stream of air bubbles by a process called Bubble Fractionation (Lemlich et al.. 1966, 1968. 1970). The amounts are so minute that concentrations in the engine exhaust should be well below OSHA/NIOSH Time Weighted Average (TWA) exposure limits at steady state, a fact that was confirmed by analysis of collected particulates in the exhaust. When the catalyst injection was used along with a pleated paper filter to remove exhaust particulates, the filter operating life was shortened greatly. Therefore, this system is not recommended for use on diesel engines equipped with a water scrubber and a filter. It does offer a practical and relatively economical way of reducing exhaust emissions from other diesel engines, such as those in outby mine service

Jan 1, 1995

By Richard Meriwether Smith

Mining-related earthy bodies in contact with the atmosphere are now counted, generally, as minesoils. Because soils within this broad category are extremely young the influence of parent material is stronger than in older soils, where climate, organisms, and topography have had time to interact with near-surface rocks to form more distinctly differentiated profiles. Understanding of minesoil properties and processes is aided by definitions of rock types in terms of chemical, physical, and mineralogical characteristics that are, with some degree of consistency, translatable into soils. Geological correlations based on age or sedimentary sequences are helpful if they assure details of mineralogy and lithology, but our pedologic objectives demand that any conflicts involving rock types must be resolved in favor of distinctions having strongest implications for soil properties after mining. Chemically this approach emphasizes accounting of potential acid-base status, plant nutrient availability by adapted and calibrated extraction procedures, and absence of biotoxins. Physically it anticipates particle sizes, shapes, and arrangements in readily pervious soil profiles that will favor plant growth with desired levels of moisture and oxygen. Concurrently we are considering soil property suitability for uses other than growth of plants. Above all we need to be able to predict pedogenic processes in the particular environment, including rate as well as direction of chemical and physical change.

Jan 1, 1974

By 1980, the US mining community had reached a broad consensus regarding coal pillar design. The pillar load could be estimated from tributary area theory, and the pillar strength could be estimated from empirical formulas and laboratory coal strength testing. Then the growth of longwall mining required new thinking. Recently, powerful design methods have emerged from analysis of large databases of real-world pillar successes and failures. These include the analysis of retreat mining pillar stability (ARMPS), the analysis of longwall pillar stability (ALPS), the Mark-Bieniawski rectan¬gular pillar strength formula and guidelines for preventing massive pillar collapses. Sophisticated numerical models have also helped transform the pillar design landscape. In the process, the understanding of pillar mechanics has been greatly enriched. A new paradigm identifies three categories of pillars according to the types of failure that are associated with them. These categories are slender pillars (w/h < 3.0), which are subject to sudden collapse; intermediate pillars, in which pillar squeezes seem to be the most common failure mode; and squat pillars (w/h > 10), which are dominated by entry failure (rib, roof or floor) and coal bumps.

Jan 1, 2000

By V. Roze, M. E. A. Robertson, C. J. Sharland

Current Techniques - Fire Assay Fire assay of gold has been used for several thousand years and is a well known technique to the traditional assayer. Very few assayers wish to use the method but to date there has been no viable alternative. Fire assay is expensive in labour, time, capital and running costs. Workers can be exposed to hazards and uncomfortable working conditions such as lead fumes, heat stress, dust and eye strain. The high capital cost of putting up the building and equipping it, together with running costs which increase annually at a prohibitive rate makes the technique less attractive each year. The main requirement in most assay laboratories is to maximise throughput economically. This is difficult with fire assay as it is impossible to automate. Each sample for analysis is handled by at least 12 people and each person represents a potential source of error. Record keeping and report generation has to be done manually which is both slow and prone to errors. Replacement of staff requires a considerable training period and with a large turnover of personnel this presents yet another problem. The presence of silver and dross in the gold sample affects the accuracy at low gold values. X-ray fluorescent analysis Two methods of XRF instrumentation have been used with limited success. The first type is a laboratory instrument employing L X-rays. Small samples of a few grams, which are not representative,

Jan 1, 1988

By Kenneth J. Reid

The application of computers for control purposes in hydrometallurgical processes is not as well-established as in mineral processing plants. This is not only due to the comparatively new development of large-scale application of hydrometallurgy and the relatively small number of operating plants, but also due to some of the basic dynamic characteristics of hydro- metallurgical processes., Basically there is little difference in the development and application of digital control techniques in hydrometallurgical plants from those techniques widely in use throughout the chemical process industry and in nonslurry applications; particularly for those cases involving liquid streams only, the primary sensing elements are essentially the same. On-stream X-ray fluorescence analysis is a well-established method for determination of metal content in the process streams, and standard equipment is used for the measurement and control of pH, flow, density, temperature, pressure, and other variables. Nevertheless, the high proportion of corrosive slurry streams at elevated temperature and pressure poses a challenge to the instrument engineer concerned with developing long-life, reliable instrumentation. One major difference and potential problem area in developing control systems for hydro- metallurgical processes is related to the very long time constants which are common in the larger plant. In these circumstances, it is important to define the overall control objectives very carefully and be prepared to allow for considerable drift in intermediate variables. In larger projects with many control loops the general advantage of lower costs compared to conventional analog instrumentation can be confidently expected. Also in most cases, the process analysis necessary to design and specify a comprehensive computer control system and the increased operator involvement in implementing digital control systems yield additional benefits due to the increased understanding of the dynamic characteristics of the process.

Jan 1, 1979

By Michael G. Nelson

Underground coal mining practice often requires that some coal be left in place at the seam boundaries after mining, for purposes of ground control, quality control, machine guidance, or good operating practice. Many methods for measuring the thickness of boundary coal have been developed, but only the natural % R gamma background method as bee used in routine operations. Use of this method is constrained by the level and consistency of the natural gamma background in the bordering strata, the accuracy of the gamma detection instrument, and the elevation profile of the seam boundary being detected. Computer simulations for three commercially available gamma detection instruments, designed for mine use, showed that measurement of boundary coal thickness by the natural gamma method can provide satisfactory input for horizon control systems when the gamma detector is large, when the sensor is mounted on the mining machine, and when the elevation profile of the seam boundary does not change rapidly in the direction of advance.

Jan 1, 1993

By W. Belobraidich

Kennecott&apos;s Ray mine is located about 145 km (90 miles) north of Tucson in the Mineral Creek mining district of central Arizona. Mining in the district started in the late 1800&apos;s. The Ray mine itself was first mined by under- ground methods in 1911 and was changed to an open-pit operation in 1952. Mineralization is complex and includes sulfide, silicate, and native copper mineralization, as well as minor amounts of molybdenite. Sulfide ore, mined at Ray, is shipped by rail to Kennecott&apos;s concentrator and smelter at Hayden, 32 km (20 miies) away. Silicate ore, mostly chrysocolla, is processed near the mine in a vat leaching-electro- winning plant. The mine consists of two sulfide areas: (1) the West pit and the Central pit (the original Pearl Handle pit) and (2) a silicate area on the northeast perimeter of the Central pit. The pit now is over 304 m (1000 ft) deep and approximately 3048 m (10,000 ft) long. Roads within the ultimate pit are limited to a grade of 10%, while those outside the pit are limited to 8%. The mining equipment consists of 40 Wabco 1094 (120-st) haulage trucks [ranging from 109 to 227 t (120 to 250 st)], 12 electric shovels [ranging from 6 to 23 m (7 to 25 yd)], and 3 11-m (12-yd) Dart production loaders.

Jan 1, 1979

By J. C. Yingling, R. J. Sweigard, P. W. Conrad, J. M. Ringe, D. H. Graves

Much of the land reclaimed since enactment of the 1977 Surface Mining Control and Reclamation Act is overcompacted. Research has shown that excessive compaction in replaced growing media is detrimental to the establishment of trees. If trees are to be grown on reclaimed surface mined sites, something must be done to alleviate this excessive compaction. Dry bulk density and penetration resistance are two soil parameters that can be used to indicate the level of compaction in reclaimed growing media. The University of Kentucky developed test cells on reclaimed areas at a surface mine in eastern Kentucky to determine the impact of tillage (ripping) on soil compaction and tree survival rate. The ripping methods being evaluated include shallow tillage using conventional farm equipment and deep tillage using a dozer with a ripping arm. Each test cell was planted with various species of trees, and for the first two years of tree growth, data were collected at these test cells for soil dry bulk density, penetration depth and resistance, and survival rate of trees. These data were statistically correlated to determine how ripping affects the relationship between soil compaction and tree survival rate.

Jan 1, 2003

By M. Dosemeci, M. McCawley, J. McLaughlin, Z. Wu, F. Hearl, W. Blot, K. Peng

Proposals have been made by two organizations, the International Standards Organization (150) and the American Conference of Governmental Industrial Hygienists (ACGIH) for a revised respirable dust criteria and criteria for thoracic and inspirable dust. These criteria yield different results than criteria based on lung deposition patterns in assessing the hazards due to dust exposure. Since these differences are a function of the size distribution of the dust an analysis of dust size distributions from various mining operations was performed to determine the amount of difference that could occur. The dust size distributions available for this analysis were taken from U.S. coal mines and from Chinese metal mines. The mass of mechanically generated dust that will deposit in the alveoli was found to be in direct proportion to the ISO/ACGIH criteria estimates in the mines studied. Therefore, respirable dust estimates for substances such as coal and silica are not a problem. Estimates of exposure to diesel exhaust in these mines, however, were not always in the same proportion to the estimated alveolar deposition. Also, concern with an excess of bronchitis among miners may not be adequately addressed by the use of samplers conforming to the ISO and ACGIH criteria. The cascade impactors used to acquire the data for this analysis require four to eight substrates per sampler. For daily dust exposure assessment this method is cumbersome and time consuming. Therefore, two new samplers have been designed to meet the need for determination of deposited dust mass. These samplers follow the lung deposition curve rather than the penetration curves proposed by the ACGIH and ISO and require analysis of only two substrates per sample.

Jan 1, 1992

In the UK as existing face capacity is replaced, many of the new faces will have higher installed powers and be located in zones of higher strata temperature. These factors coupled with the need to increase production will result in more faces experiencing environmental difficulies, especially with respect to climatic conditions. In many cases these problems are unlikely to be solved, as in the past, by simply increasing the face air quantity. Therefore other techniques including refrigeration will be necessary, possibly requiring major capital and operational expenditure. It is easy to spend large capital sums and incur high operational expenditure without achieving the desired amount of climatic control. There is therefore a great need for reliable prediction techniques to aid in the making of sound, informed decisions which will have a significant influence in the long term on the level of production costs. A computer program able to predict the heat flows and resultant climatic conditions on a long¬wall coalfaces has been developed. Throughout it&apos;s development underground measurements have been used to validate the computer model and it has been shown that for an advancing coalface under normal production conditions that the program predicts the climate to within 1°C of the measured conditions. This paper outlines a number of methods available to improve climatic conditions on longwall faces. The coalface temperature prediction program is used to quantify the effects of these methods on the climatic conditions for a model coalface and a comparison is given. In conclusion a cool¬ing strategy for longwall faces is outlined.

Jan 1, 1991

By Terry S. Maley

With some exceptions, minerals may be acquired on the unappropriated public lands by one of three methods: (1) mining claim location under the General Mining Law of 1872; (2) mineral lease under the Mineral Leasing Act of 1920; and (3) sale contract under the Mineral Materials Act of 1947. Leasable minerals such as oil, gas, coal and phosphate are specifically designated as leasable in the Mineral Leasing Act so the method of acquisition is clear. As a general rule, metallic minerals are acquired by mining claim location. However the nonmetallic minerals, most of which are industrial minerals or gemstones, present a more difficult problem. These minerals are acquired either by mining claim or a sale contract depending on their chemical composition, physical properties and the use to which they are put. The Act of July 23, 1955 (30 U.S.C. 61 1) provided that uncommon varieties of sand, stone, gravel, pumice, pumicite or cinders are locatable; whereas, common varieties of such minerals may only be acquired by a contract of sale. The widespread location of mining claims to appropriate such deposits has caused many land management problems. Federal court and Interior decisions offer the most useful guidelines in determining the most appropriate method of acquisition.

Jan 1, 1991

By Betty L. Gibbs

Computer software for mining applications has been in development since before 1970. These packages cover tasks from exploration data management through final reclamation planning. These programs were originally written in Fortran and have evolved into colorful, user-friendly packages. Programs that produced printed symbol maps now show color, three-dimensional image of an ore deposit on a computer screen. Pictures can be rotated and looked at it from all directions and layers can be peeled off to show other parts of a model. Computer users have also evolved. In the early Fortran days, users had to learn computer operating systems, have someone punch data cards, set up run files and wait a day or so to find out if there was one little mistake somewhere that caused the program not to run. With today&apos;s technology, users sit at their desks in the office, key in some data, read other data from digital files and build a model within days, rather than weeks or months.

Jan 1, 1999

By Todor P. Stefanov

The thermal draught within ventilation networks of underground mines depends to a great extent on the shafts depths and degree of change of ventilating air density. When the topology and space orientation of a ventilation network are constant, the dynamics of thermal draught is determined mainly by the variations of the heat- and mass-transfer processes in the openings. This conclusion follows from the well known basic theoretical notions about the thermal draught-aerostatics and thermodynamics [1]. Quantitative evaluation about the influence of heat- and mass-transfer processes on dynamics of thermal draught could be made through: direct mine measurements, special experiments and with the aid of mathematical models. The first two methods produce sufficiently accurative results, however it is very difficult to perform such studies, particularly when these processes are evaluated within a large scope and multifactor aspects. Mathematical models of thermal draught allow to overcome easily these difficulties. The degree of accuracy of results, obtained by this method, depends to a great extent on the degree of approximation achieved by the model to the real heat- and mass-transfer processes. In this paper, with the aid of Bulgarian developed method, algorithm and computer program V WT-4 - for complex evaluation of ventilation parameters in active mine ventilation networks [2], the authors investigate some changes in the thermal draught. Basically, the method is an iterating evaluation of an open set of equations, which represents relationships between the following basic parameters of a mine ventilation network: [ ]

Jan 1, 1980

By Chen L. Lin, Luis R. M. Bittencourt, Jan D. Miller

Recently research efforts have been made to obtain a high-purity gibbsite concentrate, suitable for first-class alumina refractories, from a Brazilian bauxite ore containing gibbsite (50%), quartz (35%),and kaolinite (15%). Detailed polished-section microprobe analysis was used to describe the liberation characteristics of the ore. Experimental results suggest that the kaolinite liberation characteristics can be described by King&apos;s liberation model and that only about 11% of the kaolinite is expected to be liberated at a particle size of 75 µ. Bench-scale experiments for the flotation of gibbsite/kaolinite from quartz using alkyl sulfates as collectors were particularly successful at pH 2, and under appropriate conditions a concentrate containing 93.0% A1 0 (calcined basis) was obtained 2 3 at a gibbsite recovery of about 96%. Subsequently, the more difficult separation of kaolinite from gibbsite was accomplished by kaolinite flotation from the alumina concentrate with a quaternary ammonium salt at pH 6 to produce a high-purity gibbsite product, 97.4% A12O3 (calcined basis), at an overall gibbsite recovery from the bauxite flotation feed of about 90%.

Jan 1, 1990