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By A. Hayatdavoudi, E. Apande

Introduction Troublesome shales have plagued the petroleum industry for more than 50 years. Unstable boreholes have been experienced when drilled into shale formations; sane have been studied almost at the beginning of rotary drilling. A little progress has been made since then, but much is still to be learned. No simple solution exists so far, but good drilling practices combined with good mud practices have been helpful. It is well known that shales in general have a strong affinity for water, and when water is adsorbed, the stability of the shale section of a well is reduced; cohesive strength will be re- bed, properties will be altered and shale will generally expand and/or crumble. The amount of water a shale will adsorb depends on the characteristics of its clay mineral and the ionic concentration of surrounding fluid. Fluid loss and the resulting hydration of an unstable formation can lead to serious downhole problems. The rate of fluid loss depends greatly on the permeability of the deposited cake. In impermeable formations, however, there is no loss of fluid into the formation. As such, shale, because of its very low porosity and almost no permeability, could be termed impermeable. Yet there is strong evidence that shale surfaces are wetted by an invasion of fluid into the formation through microfractures and jointed planes. It is this wetting that causes the shales to swell and slough into the hole, resulting in problems such as increased mud volume and treating costs, bridges and fill-up, stuck pipe, overgauge hole, poor cement jobs and increased cement requirements, and logging and completion difficulties. Drilling operations have been defeated by severe shale problems, resulting in & hole being plugged and abandoned after several weeks of drilling. Shales are we1l known as being difficult and costly to drill. Numerous fishing jobs have plagued drilling operations, and the cost of reaming tight holes ad weighting up the drilling mud to control shale sloughing has been high. The concept of controlling water loss to stop sloughing was introduced in the 1920's. It was known-then that calcium in fresh water re- strains clay £ran excessive swelling (theory of osmosis) . This reinforced the belief that calcium-based muds such as lime, gypsum and calcium chloride should minimize hydration of clays. Lime muds were then introduced for this purpose and others in the 1930-1940 decade1. They were used for shale inhibition but were not effective. In an attempt to improve them, a special calcium-type mud beam popular during the 1950's. Hole enlargement continued and they too were considered ineffective. During & early 1960qs, papers were published claiming that shale swelling could be prevented by using high concentrations of chemical thinner called Chrane Lignosulfonate1. This began the era of highly treated lignosulfote muds. Unfortunately, the hole enlargement problem continued. During & mid-1960’s, oil based muds were used for the purpose of inhibition of shales. Not until 1966 did Mondshine2 suggest that the water phase be saturated with calcium chloride. The cost of using oil based mud was considered by most operators not worth the additional hole stability. The potassium chloride-polymer muds were also used in many fields in the United States and western Canada. The use of these muds has been claimed to prevent clay swelling by inhibition and encapsulation in sane areas of western Canada. They are also expensive and their ueneral application is still experimental. To reduce filtrate loss when sloughing shale becomes a problem during drilling is a reasonable practice. This study will investigate the use of cationic organic additives to mud to form a protective barrier between the shale - which are primarily composed of clays - and water that will keep water from entering the microfractures and will also prevent them from hydrating. In so doing, an understanding of modern clay chemistry and & dispersive properties of cationic additives in water based systems will be our most valuable tools. This study will also present and solve a mathematical model for simulating cation transport phenomena in fractured shales using the Framdlich equilibrium adsorption isotherm. The studies will analyze wellbore failure and stability as affected by cationic organic material.

Jan 1, 1986

By Young C. Kim

Because of the high cost of obtaining coal washability samples, it has been difficult to obtain washability variograms in the past. As a result. It could not be determined if geostatistical prediction tool known as kriging can be applied to predict in-situ coal washability characteristics.

Jan 1, 1988

By Yu. A. Polozov, V. A. Lagunov, O. Yu. Lushinkova, Yu. I. Svirskiy, Eh. Ya. Kipko, Roy A. Williams

1.1 GENERALIZED METHODS OF SUPPRESSING THE INFLOW OF GROUND WATER DURING THE CONSTRUCTION OF SHAFTS, DRIFTS AND TUNNELS Various methods are used to prevent or minimize the inflow of ground water into underground workings during their excavation. The two most common methods include freezing the saturated rock and grouting using cement, sodium silicate, polyurethane and/or other chemicals. Each of these technologies for combatting the inflow of ground water is effective only under specific hydrogeological conditions. For example, although the freezing of saturated ground is among the more universally adopted methods, it is designed to provide only temporary protection during construction. Before the saturated rock thaws it is necessary to emplace a waterproof liner which is labor intensive, time consuming, and expensive. Consequently, freezing is used only in exceptionally complex hydrogeological conditions, namely in those cases where the water-bearing strata consist of unstable rock or the ground water has an anomalous hydrochemistry. The classical grouting of saturated rock, carried out from the surface or from the face of the underground workings for the purpose of limiting the inflow of ground water during excavation, utilizes both cement and a variety of chemical grouts. Cement grouting has been regarded as the main method of combatting the inflow of ground water in fractured rock throughout the world. In such countries as the Federal Republic of Germany (FRG), Canada, the Republic of South Africa and Great Britain, cement grouting is the main method of reducing the inflow of ground water during the excavation of mine openings. In Great Britain and the FRG, cement grouting has been used in 80% of all shaft excavations. In the Republic of South Africa cement grouting has been used in almost 100% of all the shafts that have been constructed. The installation of grout curtains into permeable water- bearing strata significantly reduces their permeability and increases the rock strength. Grouting has the greatest effect in fractured sandstones, certain well indurated shales, fractured granites, fractured quartzites, and karstic limestones or dolomites. The following principal factors must be considered when assessing the expediency of grouting rock with cement: the geometry of the network of fracture openings, the saturated hydraulic conductivity of the fractured rock, the hydraulic head acting on the water in the rock, and the chemical composition of the ground water. On the basis of the geometry of the fractures and the thickness of each hydrostratigraphic unit, the characteristics of the cement grout are selected. As a rule, the cementing of large fractured zones with high ground water velocities is carried out using inert fillers (sand, mill slag, loam, loess, crushed limestone), special types of cement, setting accelerators, and high cement concentrations in water. Calcium chloride, soda ash, sodium silicate, sodium nitrate, amino alcohols, tin bichloride, trisulphate nitrate, and lumnite are used extensively as the setting accelerators for cement grouts. In the FRG and Poland, special cement injection compounds that embody a mixture of cement and active cement metal salts, water additives and binding substances are being used for the cementing of saturated zones with rapid ground water velocities. These reagents accelerate the rate of structure-forming reactions. In spite of the wide variety of additives used for cement grouts, the effectiveness of the method in large fractures below the water table is either poor or it leads to a very large consumption of cement due to the erosion of the grout through the cracks before it hardens. At the present time, a large number of cement types and brands are being produced by various countries. These variations permit cementing to be employed in a variety of geological conditions. However, both pure cement grout and grouts with fillers constitute unstable systems with a high water loss rate. Therefore during the grouting of finely fractured rock the cement grout's premature loss of a large amount of free water causes its consistency to increase, whereupon the grout solidifies. Consequently, it inadequately penetrates into the fine fractures of the stratum. In addition the high water loss rate in the cement grout causes unreacted cement particles to remain, which greatly reduces the grout hardness and the resulting rock strength characteristics are weakened. As a result, the binding properties of the cement are utilized perhaps up to 60%. The remaining portion is left in the grout as a filler. All these conditions significantly decrease the efficiency of the isolation effort both with respect to strength and cost. In order to expand the cement grouting method, re- search is being conducted to improve the quality of cement grout, to increase its range of application with respect to permeability control, to reduce its water loss rate and to increase its capacity to withstand the erosive and corrosive effects of poor quality ground water. For example, mixtures of bentonitic clay, carboxymethyl cellulose, aerated sodium sulfide, sulphated alcohol distillery waste, nitrolignin, gip-

Jan 1, 1993

By N. Parra, M. N. Herrera, T. Vargas, B. Escobar, C. Gonzalez

originally published May 1998, Vol. 15, No. 2, pp. 15-1 9 Discussion by G. Rossi, University of Cagliari Reply by T. Vargas, University of Chili

Jan 1, 2000

By A. H. Hassan

Stibiotantalite is a relatively rare mineral not commonly found in the major tin districts of the world, and its separation characteristics have not been documented adequately in the literature.

Aug 1, 1979

By K. Tokutake

Kobe Steel, Ltd. improved the quality of iron ore pellets for blast furnace burdens when it enlarged its blast furnaces. However. there still remained room to increase reducibility at high temperatures for better blast furnace operation. In particular, it was still necessary to lessen the reduction retardation above 1200?C. In the last few years, by employing iron ore and additives of optimum size structure, large pore pellets with a high porosity have been obtained. By using this method. Kobe Steel. Ltd. has accomplished the technology to produce pellets with remarkably high reducibility.

Jan 1, 1989

By Dominigue Francois-Bongarcon

This paper presents a step by step vulgarized review of the applications of geostatistics to the estimation of the mineable, recoverable reserves of the Cinola gold deposit in British Columbia.

Jan 1, 1988

By Mark Springett

Microcomputers have rapidly evolved to the level at which they can perform almost all of the computational tasks required for exploration, evaluation and exploitation of mineral deposits. The present capabilities of microcomputers are reviewed by examining their use on typical projects from the initial capture of exploration data to the subsequent technical and financial evaluation by microcomputer. Emphasis is placed on the need for compatible software and on the importance of a consistent hardware acquisition policy.

Jan 1, 1987

By Dennis K. Mortensen

Improvements in metallurgical performance are continually being made in the attempt to achieve the metallurgist's goal of maximum concentration, minimal loss of recovery and at costs that maximize profit margins. Innovative technological advances provide a means for the metallurgist to more thoroughly understand the mechanisms of separation and foster new ideas from old. Problems associated with the implementation of new technology can be overcome effectively if the metallurgist thoroughly understands the metallurgical systems with which he is working.

Jan 1, 1991

By H. L. Ehrlich

Processes involving biological solubilization of metal values from ores, or removal of mineral constituents that interfere with metal value recovery from ores by abiological means, published mostly in the last 10 years, are reviewed. Many of them, though promising, have yet to be tested on a pilot scale or applied industrially.

Jan 1, 1987

By Håkan Stille, Kjeld Boye-Møller, Lars Lundström

BACKGROUND Forsmark Power Station is a nuclear power plant under construction at the Baltic abt 120 km north of Stockholm. Investigations on the Site were started in 1969. Areas were reserved for a maximum of 6 units of which the buildings for two of them, Unit 1 and 2, were nearly finished in 1976, when the investigation for Unit [3], here presented, was carried out, cf Fig. 1. [ ]

Jan 1, 1979

By M. C. Fuerstenau

Collophane, cryptocrystalline fluorapatite, is examined as a substrate for plant water and wastewater remediation. The attenuation of Fe3+, Cr3+, Fe2+, Cd2+, Hg2+ and Pb2+ is presented as a function of metal ion concentration, amount of collophane, initial pH and conditioning time. TCLP results for Pb2+ contaminated collophane are presented. Mechanisms of adsorption for divalent and trivalent species are suggested. Key words: Collophane, Wastewater remediation, Heavy metal removal

Jan 1, 2003

By Mark L. Matthews

In 1978, Congress enacted Public Law 95-604, the "Uranium Mill Tailings Radiation Control Act of 1978." The Act authorizes the Department of Energy to stabilize and control the tailings from designated inactive uranium mill tailings sites in a safe and environmentally acceptable manner. DOE has established the Uranium Mill Tailings Remedial Actions (UMTRA) Project Office to implement, in cooperation with the affected States, Indian tribes and owners of the sites, remedial actions at the sites. The UMTRA Project Office has initiated efforts to perform remedial actions in accordance with EPA cleanup standards.

Jan 1, 1981

By John N. Murphy, Edward F. Fries

The availability of fast, low-cost computer hardware and advanced software is opening new opportunities for minerals extraction and processing. Programmable Logic Controllers (PLC's) are currently used extensively in the minerals industries; this paper looks beyond PLC's and that vintage of “computer control”--it looks toward what the authors see as new in the next five years. Topics covered include expert systems, neural networks, intelligent signal processing, and hierarchical controllers as applied to mining and mineral processing operations.

Jan 1, 1993

By Howard R. Postovit, Bonnie C. Postovit

Raptors are birds of prey. In recent years, these birds have become highly regarded and have been given protection under various state and federal statutes. Surface coal mining can have both negative and positive impacts on raptors. Mitigation strategies and enhancement techniques can be implemented to alleviate negative impacts. The success of habitat reclamation will determine the long-range impact of mining on raptors.

Jan 1, 1989

By Dennis A. Giardino, Leonard C. Marraccini

This paper surveys noise levels, noise exposure patterns, and frequency spectra found in the mining environment; the effects of mining noise on the working population; and the quantification of hearing loss in the coal mining industry. Federal mining noise regulations and the present state of the industry, with respect to noise control technology, are discussed. Examples of proven noise controls for mining are included along with measured noise reductions.

Jan 1, 1986

By M. Ghoreychi, M. Fauueau, P. Lebitou, P. Berest

A brief study of the history of gas caverns in salt formations enables us to consider creep mechanism in a cavity as a phenomenon of dissymmetrical deformation. Among different parameters affecting such a phenomenon, gravity forces, especially in large caverns, seem to be responsible for important bottom heaves as compared to roof releases. This fact is demonstrated here by means of certain theoretical considerations concerning elasto-viscoplastic constitutive laws relevant to rocksalt rheological behavior.

Jan 1, 1986

By G. Tapia, R. J. Kelley

Empresa Minera de Mantos Blancos S.A. operates two copper mines in Chile: Mantos Blancos and Mantoverde. Oxide ore is processed by acid leaching followed by SX-EW to produce copper cathodes. In order to define the leach process adequately for each ore, an extensive metallurgical testwork program was carried out during the feasibility study for each of these projects. A combination of heap and dump leaching was selected for Mantoverde, while a modification to the existing vat leach operation was selected for Mantos Blancos.

Jan 1, 1998

By J. C. Stankus, S. Guo, S. S. Peng

In this paper, a model is developed for a resin anchor bolt system in which the smooth bar is modeled by using one-dimensional truss elements, and the resin annulus is modeled by using axisymmetric elements. These two submodels are combined and then incorporated into an existing computer code called Roofbolt. After this development, all of the components in the resin anchor bolt system, including smooth bar, bearing plate and resin annulus, can be correctly modeled.

Jan 1, 1997

By Henry Brehaut

The International Network for Acid Prevention (INAP) was formed in 1998 by 17 international mining companies to promote significant improvements in the management of sulphidic mine materials and the reduction of liability associated with acid drainage through knowledge sharing and research and development of technology. Since its inception two panels have been formed to identify and move forward with research projects and eight networks have been constituted to initiate interaction and knowledge sharing within the membership in specific areas of technical interest. An INAP web site has been developed to facilitate the sharing of information and to encourage the exchange and development of new ideas.

Jan 1, 2000