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By T. N. Matveev, V. V. Getman, A. Yu. Karkeshkina, L. B. Lantsova, N. K. Gromova

Sulfide-type tin deposits in Russia are characterised by the complex mineral composition of ores and dump products of their processing. Tin-sulfide ores contain industrial quantities of copper, lead, zinc, tungsten, silver, rare and trace elements (indium, scandium, etc.). In addition, the ores are characterised by uneven dissemination of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin minerals (cassiterite, stannine, etc.). X-ray phase and spectral analysis, scanning electronic microscopy (SEAM), laser SIM and AFM microscopy helped to identify the selective fixing of sodium dibutyl dithiocarbamate (DBDTC) on chalcopyrite and galena, as well as the tall oil fatty acids (TOFA) and IM-50 on cassiterite. For the first time, collectors and flocculants of slurry fractions of silver and tin, thermomorphic polymers TMPF were used to isolate more than 80% silver from the tin tailings of the Solnechny mine into a copper-silver rough concentrate. It has been established that preliminary ultrasonic treatment and desliming according to the 0.02 mm class removes up to 20% of sludge material, which impairs the process of gravity separation. The combined flotation-gravity scheme using new reagent compositions helped to obtain tin concentrate with a tin content of 5.42%, which meets the requirements for further metallurgical processing (at least 5%). This work was supported by the RSF according to the research project No. 17-17-01292. Keywords: Flotation, flotation reagents, tin-sulfide ores, casiterite, adsorption, flocculation

Jan 1, 2020

By I. Kaabachi, F. Meunier, N. Morales

In open pit mining, ore and waste are hauled outside of the excavation area by trucks that move along a system of ramps. The design of these ramps must be carefully addressed because they have to comply with geomechanical constraints to ensure the stability of the pit walls, provide access to the different levels and phases, but also maximise the value of the extracted ore and reduce the extraction of waste. Because an optimisation approach able to deal with the design of the full ramp system seems to be out of reach at the moment, this paper addresses the problem of designing one ramp providing access to a single pushback, which has been determined beforehand. The optimisation objective is therefore to find a ramp that gives access to one given potential volume, while minimising its impact on the economic value of the volume. Two versions of the problem are formalised. One version allows the extraction of ore and waste only if this extraction is necessary for the ramp system. This version somehow minimises the intrinsic value of the ramp system. In the second version, it is possible to extract more than is needed by the ramp system. For instance, this takes into account the possibility of attaining ore on the wall opposite to the ramp as soon as the ramp reaches its level. In the setting mentioned above, the contribution of this work is three-fold. First, the computational complexity of the two different versions of the problem is presented and discussed; in particular, they are shown to be NP-hard. Second, compact integer programs modelling these two versions are proposed. Third, an efficient GRASP algorithm able to cope with the large instances of the problem is proposed. To assess the proposed approaches, the models and algorithms are applied to real instances with an off-the-shelf solver, illustrating and discussing their potential and relevance for the two versions of the problem. They are also compared with other approaches from the literature in terms of value and resulting designs.

Sep 1, 2021

By X. Yang, G. D. Zhai

The prop is the most important part to ensure the proper functioning of hydraulic support. When the hydraulic support is impacted by the roof, the prop is prone to extrusion deformation, expansion, and even bursting. In order to study the stress on a doubly-telescopic hydraulic support prop under impact load, an impact simulation was carried out based on the drop weight method. First, the impact model of the hydraulic system of the prop was established in AMESim software and the dynamic response curves of the bottom and middle cylinder of the prop obtained. Then, according to the conservation of energy, the pressure formulaes in the hydraulic cylinder of the prop under impact load were derived and verified by the AMESim simulation results, and the maximum pressure on the inner surface of the hydraulic cylinder of the prop obtained. Lastly, the transient dynamic simulation of a hydraulic support prop was carried out in ANSYS Workbench software, and cloud diagrams of stress and deformation of the prop obtained using Workbench simulation. The AMESim simulation process describes the change in fluid pressure in the prop, and the pressure formulae can be used to estimate the internal pressure of the prop under impact load. The finite element analysis results show that the stress of the middle hydraulic cylinder is much greater than that on the bottom hydraulic cylinder under impact load, which can provide a reference for prop design.

Jul 2, 2022

By J. Githiria, C. Musingwini, J. Muriuki

"The maximization of net present value (NPV) is a primary objective in open pit mine planning processes. In an attempt to meet this objective, cut-off grades are considered in all the stages of mining. There are three stages involved in resource extraction, namely mining, processing, and refining/marketing, which are all defined in Lane’s approach. Using Lane’s approach, the economics involved in each stage are identified independently and interact to provide an optimum cut-off grade.A hypothetical block model is used to illustrate how a computer application (Cut-off Grade Optimiser) that was developed in this study is used in the optimization of cut-off grades using Lane’s algorithm. This paper analyses the application of Lane’s approach for a single element in cut-off grade optimization as applied in the calculation of the optimum cut-off grade through a computer-aided application.Although Lane’s approach is not complex it is not widely applied to maximize the NPV of mining operations as the iterative calculations can be lengthy. The computer application developed in this study shows how Lane’s algorithm combined with a linear programming function can optimize cut-off grade with regard to the complex situations faced by mining operations. The application saves users from performing otherwise lengthy, iterative calculations.Background and previous researchAn open pit mining complex constitutes multiple pits, ore processing streams, and metal refining options. An open pit mine produces ore (valuable) and waste material. Ore is transported to an appropriate processing stream for producing concentrate. A refinery processes the concentrate to produce marketable metal product (Lane, 1964, 1988).Cut-off grade optimization is based on Lane’s theory, where a mining system consists of three major stages such as mining, milling, and refining. In this approach the cut-off grade selection is done between six cut-off grades that involve all stages of a mining operation. Selection of the optimum cut-off grade influences the net present value (NPV) by maximizing the net cash flows from the operation."

Jan 1, 2016

By S. T. L. Harrison, A. Kotsiopoulos, J. R. Amaral Filho, J. L. Broadhurst

The land disposal of voluminous fine-grained tailings from the processing of mined ore bodies poses a long-term risk to the surrounding environment and local communities, while also representing a loss of valuable natural resources; including water, land and mined minerals. To date, the development and practical implementation of alternative approaches and technologies for removing risk and reducing the burden associated with these wastes, particularly in South Africa, remains limited, and value recovery is largely limited to the extraction of precious metals. To this end, researchers at the University of Cape Town have developed a programmatic multi-phased approach to explore and develop opportunities for the valorisation of large-volume mine wastes, based on the innovation value chain. This paper outlines this conceptual approach and presents key outcomes from its application for the specific case of sulfide-bearing coal processing wastes from South African collieries. Through the application of a combination of qualitative and quantitative tools and methodologies, a number of potentially viable opportunities and processing routes for value recovery and bulk re-purposing of these wastes have been identified and tested on a laboratory scale. Studies have, however, also shown that there are several technical and non-technical factors currently constraining commercial application of these opportunities. Overcoming these constraints will require a commitment to innovative waste management approaches and effective multi-sectoral collaboration. Keywords: Coal processing wastes, physical separation, waste re-purposing and utilisation, technology transfer

Jan 1, 2020

By D. B. deur Mostert

This paper was presented at the Coloquium on Management Techniques in the Mining and Metallurgical Industry, which was organized by The South African Institute of Mining and Metallurgy and held in Pretoria during June 1988. The author asks whether technical audits are of any use to management. Technical auditing he defines as an evaluation undertaken by an outsider of whether a technical activity is being carried out correctly. After examining the types of technical auditing, and its prerequisites and procedures, he describes its application in regard to quality, and to production processes and their adequacy. He then answers his question by saying that, not only are technical audits very useful, but they form an essential element in the provision of quality products. In addition, they give management the opportunity of testing whether the activities of the organization are being conducted correctly. This is their most important function in that they alert management to areas of potential growth, modernization, and innovation. However, the use to which technical auditing is put remains the key to its value; that is, its value depends on the positive action that each manager takes as the result of a technical audit.

Jan 1, 1989

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By V. M. Lovell, N. P. Finkelstein

The concepts involved in flotation research are discussed and aims are presented. Three different method. of investigation can be used, all of which are applied at the National Institute for Metallurgy (N.I.M.), and these are the empirical, trial and error method, the chemical engineering method, and the physicochemical approachs This paper is devoted to the last of these. Because of the complexity of the physicochemical interactions involved, the work has, to a large extent, been concentrated on only one aspect, viz. the interaction between the mineral surface and reagents in solution, which was considered of major importance in the understanding of the process. The aspects on which work has been done are the concentration of uranium, the reaction between salt minerals and fatty acids, mixed xanthate-cationic collector systems, and the reaction between sulphide minerals and thiol reagents. Selected problems from the first two of these are discussed in some detail and deal with the agglomeration flotation of uranium and the chemical control of the flotation process for phoscorite. A detailed discussion is also presented of the progress made in the understanding of the interaction between sulphide minerals and thiol reagents, which is of more general application. Finally, an indication is given of the future direction of physicochemical research at the N.I.M.

By R. R. M. Cousens, W. S. Garrett

SYNOPSIS The paper gives a background to the water hazards of the so-called West Wits Line and refers to some geological aspects of the Wonderfontein Valley in which the West Driefontein mine property lies. It describes the precautions taken against flooding during shaft sinking, development and stoping; these include cover hole drilling with cementation, provision for water storage in worked-out areas, installation of water tight bulkhead doors and pumping capacity well in excess of the mine's normal requirements. The plan of campaign adopted after the inrush took place is explained and the reorganization and expansion of pumping arrangements are discussed. When it became clear that the only means of saving the mine was to construct plugs to isolate the inrush while still maintaining all emergency pumping measures, the work was put in hand with the utmost dispatch. In considering the design of the plugs a number of major factors had to be taken into account. The most vital was the need for speed which was complicated by difficulty of access to the plug sites because of the huge volumes of water flowing in the drives. How this and other factors affecting plug design and construction, leakage problems, sequence of operations and final closure of the valves, were overcome is detailed in the paper. INTRODUCTION The inrush of water into the West Driefontein mine, the biggest gold producer in the world, which began on 26th October, 1968 and continued unabated for 23 days before the flood was stemmed, was unprecedented in the history of mining. Also unprecedented were the tremendous efforts and organization which made it possible to bring the situation under control and so save the mine from being lost for a matter of years. BACKGROUND Before going into details of how the situation was brought under control it is appropriate to consider the background to the event. The water problem on the so-called West Wits Line has been recognized for many years. As far back as 1912 the Pullinger Shaft, situated in the centre of what is now the Venterspost mine property, had to be abandoned because there were no means then available of coping with the large quantity of water encountered. To appreciate what vast quantities of water were involved, it helps to refer to some geological aspects of the Wonderfontein valley in which the West Driefontein property lies. The narrow tabular Witwatersrand gold-bearing beds, which dip at about 25 degrees towards the south, are overlain by a surface layer of dolomite which reaches a maximum thickness of some 4,000 ft at West Driefontein. A number of vertical syenitic dykes intersect the valley more or less at right angles to its course (Fig. 1). These dykes are about 150 ft thick on average and are spaced at about eight-mile intervals in the West Driefontein area. They penetrate both the dolomite and the Witwatersrand beds and as they are impervious to water they divide the valley into a series of large underground water compartments.

Jan 5, 1969

By V. M. Lovell, N. P. Finkelstein

The concepts involved in flotation research are discussed and aims are presented. Three different methods of investigation can be used, all of which are applied at the National Institute for Metallurgy (N.I.M.), and these are the empirical, trial and error method, the chemical engineering method, and the physicochemical approaches. This paper is devoted to the last of these. Because of the complexity of the physicochemical interactions involved, the work has, to a large extent, been concentrated on only one aspect, viz. the interaction between the mineral surface and reagents in solution, which was considered of major importance in the understanding of the process. The aspects on which work has been done are the concentration of uranium, the reaction between salt minerals and fatty acids, mixed xanthate-cationic collector systems, and the reaction between sulphide minerals and thiol reagents. Selected problems from the first two of these are discussed in some detail and deal with the agglomeration flotation of uranium and the chemical control of the flotation process for phoscorite. A detailed discussion is also presented of the progress made in the understanding of the interaction between sulphide minerals and thiol reagents, which is of more general application. Finally, an indication is given of the future direction of physicochemical research at the N.I.M.

By W. P. Channon, J. B. See

The reduction of fluxed and non-fluxed manganese, ores by ferromanganese silicide by W. P. CHANNON, B.Se. (Eng.), M.Sce. (Eng.) Wits. (Visitor) and J. B. SEE, B.Sce. Hons., Ph.D. (New South Wales), M.I.M., M.I.M.M. (Member) In South Africa, medium-carbonferromanganese is produced by the silicothermic reduction of slags containing MnO. Because of its importance in the production of refined ferromanganese, a study was made of the reaction between a premelted South African Mamatwan manganese ore and various ferromanganese silicide reducing alloys, with and without fluxing agents. Because the reaction is highly exothermic, temperature appeared to have little effect on the rates of manganese transfer to the metal and silicon transfer to the slag, and an apparent equilibrium was rapidly approached. Limits were determined for the favourable effects of fluxing additions, and manganese recoveries were found to decline as the ratio of CaO to MgO decreased as a result of the addition of basic flux. The recovery of manganese passed through a maximum, and subsequently decreased for variations in the ratio of alloy to ore. The results obtained, when used in conjunction with other physicochemical data related to this slag-metal system, suggest optimum slag compositions for the efficient manufacture of medium-carbon ferromanganese from Mamatwan ore.

Jan 3, 1977

By E. Córdova, A. Anani, W. Nyaaba

Optimization of panels, haulage fleet, and waiting area involves deterministic and low-fidelity methods and experiential knowledge. The process is challenging because coal recovery and operational capabilities must be considered in the solution. The approach in this manuscript comprises the development of an integrated stochastic simulation model of a coal room-and-pillar system that addresses these challenges. The decision variables evaluated are panel width, number of shuttle cars, and change-out time (COT). The results show that the mine should implement the shortest possible COT, decreasing the cycle time and thereby increasing productivity and continuous miner (CM) utilization. The highest productivity and CM utilization for a fleet size of three shuttle cars is found in the 15-entry panel width. For the evaluated fleet sizes, the 19-entry panel width is optimal for the four and five shuttle cars. Among the three variables studied, panel width and fleet size had the most significant effects (5% increase) on the CM productivity, cycle time, and utilization.

Apr 2, 2022

By J. P. T. Kapusta

"The copper smelting industry faces increasingly stringent environmental regulations and must continue driving innovation to reduce energy usage in its production chain. With the coming of age of ‘bottom-blowing’ copper technologies in China over the last decade, much renewed attention has been brought to tuyere bath smelting for clean copper-making. Since bottom-blowing sonic injection was originally developed and implemented in steelmaking in the 1970s and lead smelting in the 1990s, the time seems appropriate to revisit the sonic injection concepts and dispel some myths. After reviewing the trends in the copper industry and providing a brief historical context of research and development related to sonic injection, the author presents a comparison of the main submerged tuyere bath smelting technologies, namely the Noranda Reactor (NR), the Teniente Converter (TC), and the Chinese Bottom-Blowing Smelting Furnace (SKS/BBS) for copper, and the Queneau-Schuhmann-Lurgi Reactor (QSL) for lead. The core of this article, however, consists of a brief description of the fundamental theories for sonic injection (jetting regime) and ‘sonic flow mapping’ to illustrate the relationship between the minimum tuyere back-pressure required to achieve sonic flow and the tuyere internal diameter. The article also offers a comparison between side- and bottom-blowing in jetting regime before concluding with the author’s vision of the new trend in submerged tuyere bath smelting. IntroductionIn the last decade, developments in the copper smelting industry have been driven by two key concepts: (1) increasing cleaner smelting capacity to meet the world’s growing copper demand, as illustrated in Figure 1, and (2) increasing process off-gas capture to comply with more stringent environmental regulations and abide by a corporate social responsibility ethic of a clean work environment (for smelter employees) and clean air (for families living around smelters). The copper smelting industry has also faced some major challenges in the last few decades, including (1) low treatment and refining charges (TC/RC or processing fees) impacting custom smelters, (2) lower concentrate quality and grades with higher levels of impurities (e.g. As and Hg), (3) higher processing and transportation costs due to the rising cost of energy, (4) restrictions in process intensification (tonnage oxygen usage) due to furnace integrity limits, and (5) scarcity of educated and trained personnel due to fewer metallurgists graduating from pyrometallurgical school programmes combined with a high retirement rate of skilled workers."

Nov 1, 2018

By B. P. Watson

Uniaxial tests performed on core from instrumented sites at Amandelbult 1 shaft, Impala 10 shaft and Union Section Spud shaft showed a nonlinear elastic relationship between applied load and induced deformation. This nonlinear behaviour does not appear to be dependent on borehole orientation but in the case of the Amandelbult and Union sites appears to have been influenced by the stress condition of the rock mass at the time of drilling. Cores drilled at these two sites under destressed conditions, such as over a stope, showed a linear elastic response to the applied load whereas most of the cores drilled under relatively high radial stresses were nonlinear. The Impala 10 shaft tests, however, all showed strong nonlinear behaviour irrespective of the stress condition of the rock mass at the time of drilling, although high stress conditions may have influenced the severity of the nonlinearity. A comparison between underground stress change measurements and an elastic model indicated that the rock mass became nonlinear when the virgin stress condition was relaxed to about 10 MPa. The cores for laboratory testing were retrieved from vertical boreholes drilled up from the centre of a stope and from horizontal boreholes drilled over pillars and stopes at about 600 m, 1 100 m and 1 400 m below surface for the three sites respectively. The k-ratios under virgin conditions were estimated from sockets, modelling and stress measurements to be 1.0, 1.3, and 0.5 for the Amandelbult, Impala and Union sites respectively. Of the three sites, therefore, Impala 10 shaft appears to have had the highest virgin stress state. Tests performed on similar rocks from shallower depths at Impala Platinum essentially showed a linear relationship between stress and strain. From the small Impala Platinum rock test database available to the project, it appears that the nonlinear elastic behaviour initiates at this mine from about 1 000 m below surface and seems to become progressively more nonlinear below this depth. In addition, the nonlinear elastic rocks are weaker, have a lower Young?s modulus and a higher Poisson?s ratio than their linear elastic equivalents. Interestingly the tangential Poisson?s ratios of the nonlinear elastic materials are often greater than 0.5 at 50% of the failure stress, suggesting an early failure initiation. The paper describes the microscope and modelling work done to determine the causes of the nonlinear behaviour and discusses some implications of the behaviour for deep-level mining.

Jan 1, 2009

1. Book review Technology of metal powders- recent developments, edited by L. H. Yaverbaum. New Jersey, Noyes Data Corporation, 1980. 400 pp. (Reviewer: B. K. Loveday) 2. New books The use of microprocessors, by M. Aumiaux. New York, Wiley, 1980. 176 pp. $25,50. Aluminium smelter technology, a pure and applied approach, by K. Grojtheim and B. J. Welch. Diisseldorf, Aluminium-Verlag GmbH (P.O. Box 1207, D-4000, Federal Republic of Germany). 146 pp. DM48. Coal-bridge to the future. New York, Harper & Row, 1980. $35. System modeling and response.. theoretical and experimental approaches, by O. Doebelin. New York, Wiley, 1980. 576 pp. $26. Environmental and climatic impact of coal utilization, edited by J. J. Singh and A. Deepak. New York, Academic Press, 1980. 646 pp. $39,50. Proceedings of the Third European Conference on Mixing, York, England, April 1979, edited by H. S. Stephens and C. A. Stapleton. BHRA Fluid Engineering (Cranfield, Bedford Mk43 OAJ, U.K.), 1980. 2 volumes. 500 pp. $50. Lignite technology, edited by P. Nowacki. New Jersey, Noyes Data Corporation, 1980. 228 pp. $42. The application of rock mechanics to cut-and jill mining. London, Institution of Mining and Metallurgy, 1980. Papers presented at the Fifth International Symposium on Jet Cutting Technology, Hanover, Federal Republic of Germany, June 1980, edited by H. S. Stephens and B. Jawis. BHRA Fluid Engineering (Cranfield, Bedford Mk 43 OAJ, U.K.), 1980. 438 pp. £38. World coal resources.. methods of assessment and results, by G. Fettweis. Amsterdam, Elsevier, 1979. 425 pp. $80,50. Geophysical and geochemical techniques for exploration of hydrocarbons and minerals, edited by M. Sittig. New Jersey, Noyes Data Corporation, 1980. 300 pp. $40. Financial Times mining international year book 1980. Longman Group Ltd (Periodicals and Directories Division, Longman House, Burnt Mill, Harlow, Essex CM20 2JE, England). £24 surface, £34 airmail. National Symposium on the Availability of Strategic Minerals, edited by M. J. Jones. London, Institution of Mining and Metallurgy, 1980. 109 pp. 3. NIM reports Report No. 1941 The recovery of chromite and platinum from the UG-2 Upper Chromitite Layer .of the Bushveld Complex at the Pandora Mine (first published 10th Mar., 1978). Report No. .2012 A mineralogical investigation of borehole cores from the Trompsburg Complex (first published 6th Apr., 1979). Report No. 2038 The leaching of sphalerite in acidic ferric sulphate media in the absence of elemental oxygen. Report No. 2052 An investigation of the impurities in native gold by neutron-activation analysis. Report No. 2056 The mineralogy and geochemistry of the copper, lead, and zinc sulphides of the Otavi Mountainland. Report No. 2058 A n elementary introduction to image analysis - a new field of interest at the National Institute for Metallurgy. Report No. 2059 Distributed computer control of industrial processes. Report No. 2060 The analysis, by atomic-absorption spectrophotometry, of activated charcoal.

Jan 1, 1980

By A. A. Oakes, P. M. C. Wilson

This paper describes some aspects of the planning of a new colliery which commenced production in the Middleburg district in 1966. An account is given of some of the problems encountered in the early years of operation and of what was done to solve them. The conclusion is reached that design of plant and machinery should be flexible to permit multiplication of units.

By A. C. Legg

BCL Limited operates a nickel-copper flash smelting operation at Selebi-Phikwe, situated in north-eastern Botswana. The original furnace was commissioned in 1973 and produces a high grade sulphide matte, from its own concentrates plus additional custom feeds, which is shipped to refineries in Zimbabwe and Norway for further processing. In 2004 the company embarked on a study to modernize the flash smelting complex, with an emphasis on extending campaign life, improving the furnace integrity and enhancing throughput and process efficiency. First phase initiatives from this exercise, including the fundamental switch to a single concentrate burner operation of the flash smelting furnace, were implemented in July 2007. This paper summarizes experiences prior to implementation, details the specific improvements made to the flash smelting furnace and associated operations, highlights the improved plant performance after modernization, and outlines second phase expansion plans that are currently under consideration.

Jan 1, 2009

By L. C. Stilwell

The paper will attempt to identify the threats, however obscure, that could confront the South African platinum industry. South Africa has the largest reserves of platinum group metals in the world, and is the largest producer of those metals. This situation is no different from that which existed in the gold sector fifty years ago. Since then South Africa?s share of world gold production has dwindled, and the gold mining industry has lost its dominance. Unlike gold, platinum has widespread use as an industrial commodity. Its investment value is a minor portion of its total value. It is therefore subject to different market forces. The sheer magnitude of the industry in South Africa obscures the fact that it is a wasting industry, and that South Africa exports almost all its production as a refined metal in the form of autocatalyst. Since Hotelling published his seminal work The economics of non-renewable resource in 1931,the science of mineral economics has developed exponentially. The paper will present a background of mineral economic theory and compare to this the development of the South African platinum industry. Of particular concern to a mineral exporting country is the question of mineral rent?its definition and employment. This will be the mail theme of the paper.

Jan 1, 2006

By El-Sayed M. Sherif, J. D. Comins, Erasmus R. M.

Corrosion of copper in aerated acidic chloride pickling (0.5 M HCl) solutions and its inhibition by 3-amino-1,2,4-triazole-5-thiol (ATT) have been investigated using electrochemical techniques and weight-loss measurements, along with Raman spectroscopy. Electrochemical measurements for copper after varied immersion periods of 0, 24 and 48h showed that the presence of ATT and the increase of its concentration significantly decrease cathodic, anodic, corrosion (jCorr) currents and corrosion rates (KCorr), as well as the dissolution currents at 300 mV vs. Ag/AgCl, while increase polarization resistance (Rp), degree of surface coverage (?) and inhibition efficiency (IE%) to a great extent. Weight-loss measurements after different immersion periods of 6 ~ 48h revealed that the dissolution of copper decreased to a minimum and the corresponding IE% increased with ATT concentration increases. The detection of ATT molecules on the copper surface by Raman spectroscopy indicated that inhibition of copper corrosion is achieved by strong adsorption of ATT molecules onto the copper surface. Aerated acidic pickling solutions; 3-Amino-1,2,4-triazole-5-thiol; Copper corrosion; Corrosion inhibition; Raman spectroscopy

Jan 1, 2006

By C. Snyman, M. Le Roux, Q. P. Campbell, S. Engelbrecht

Due to the ultrafine particle size required for effective processing of chromite ores, dewatering of the concentrates presents a challenge. It is not uncommon for the ore to have elevated moisture contents even after dewatering, which must be reduced to required levels of between 8% and 10% by mass for further processing. Contact sorption drying has shown promise in test work on fine coal. This method was used to study the dewatering of chromite on a laboratory scale using 3 mm spherical activated alumina ceramic beads as a sorbent. Three different sorbent-to-chromite mass ratios, namely 0.5:1, 1:1, and 2:1, were tested with different process conditions, including dewatering in a stationary and a rotatingl bed. The experimental work showed that it was possible to achieve the target moistures in less than 10 minutes, irrespective of the sorbent-to-chromite ratio used. Ratios of 1:1 or higher, however, proved to be the best. The sorbent reusability at mass ratios of 1:1 and 2:1 were therefore tested. With a 1:1 mass ratio, the sorbents could be reused for three cycles, while with 2:1 ratio, the number of cycles increased to six. The sorbent-to-chromite mass ratio used had a significant influence on the required contact time and the reusability of the sorbents.

Oct 3, 2023