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By T. A. Sullivan

Research undertaken by the Bureau of Mines in 1938 has resulted in the development of titanium from a laboratory curiosity to a commercial metal. Along with processes for producing the metal, it was necessary for the Bureau to develop methods for analyzing the metal, raw materials, and intermediate products. Some of the methods developed have been published.3 4 5/ General Services Administration (GSA) was responsible for purchasing titanium metal under Defense Production Act contracts with commercial producers. GSA designated the Federal Bureau of Mines to analyze this metal and establish its compliance with Government specifications. A substantial quantity of tin was found in some of the samples analyzed, and in July 1957 tin was added to the list of impurity elements to be determined. The specifications limited the amount of tin in titanium sponge to a maximum of 0.10 percent. A program was immediately initiated to investigate methods and techniques for determining tin in the range of 0 to 1.0 percent. A method accurate at the 0.10 percent level was necessary, as this level was the critical range for acceptance or rejection of the metal.

Jan 1, 1960

By K. O. Bennington

The thermodynamic properties of pollucite [(Cs0.650Na0.185Rb0.028)(AlSi2) (05.8630H0.137)?0.19H201 were determined by the Bureau of Mines in collaboration with the Argonne National Laboratory. The standard enthalpy of formation determined by hydrofluoric acid calorimetry is ?Hf°298 = -3,098.52 ±3.63 kJ mol-1. The standard enthalpy of formation from the oxides is ?H298 (from oxides) = -209.50 ±2.38 kJ mol-1. Low-temperature heat capacities were determined by adiabatic calorimetry from 5.0 to 306.1 K. The derived standard entropy is S°298 = 207.24 ±0.43 J mol-1k-1. Enthalpy increments above 300 K were measured by copper-block drop calorimetry from 349 to 674 K. Various experimental data were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of measurements. Standard enthalpies of formation and Gibbs energies of formation are given as functions of temperature. The Gibbs energy of formation is ?Gf°298 = -2,919.9 W mol-1

Jan 1, 1983

By W. H. Eddy

The Bureau of Mines conducted laboratory batch-and small-scale continuous flotation processing tests on waste granite fines from Georgia, to determine the feasibility of recovering usable feldspar and quartz products by flotation. Two flotation methods were utilized for the removal of biotite and other iron-bearing minerals: One was in an acid-cationic circuit, and the other in an alkaline-anionic-cationic circuit. Feldspar was recovered using an acid-cationic method. To produce commercial-grade feldspar and quartz products it was necessary to employ either two sequential froth flotation circuits or one froth flotation circuit supplemented by wet-magnetic separation techniques to remove iron contaminants. Continuous flotation processing yielded a commercial-grade feldspar concentrate containing, in percent, 3.8 Na20, 5.4 K20, and 1.10 CaO, with recoveries of 77.8, 70.3, and 64.4, respectively. The feldspar tailing was high-quality glass sand containing 98.2 percent SiO2 and 0.024 percent Fe2O3. About 42 percent of the quartz was recovered at glass sand specifications. An effective separation of, potash feldspar from the bulk feldspar concentrate was achieved by batch flotation in a mineral separation cell.

Jan 1, 1974

The U.S. Environmental Protection Agency (EPA) and the U.S. Congress are presently considering several approaches aimed at reducing the amount of lead in the environment and society's exposure to lead. One approach is to tax domestic primary lead production or consumption. Objective To assist the Congress and the EPA in their decisionmaking, a study was initiated by the U.S. Bureau of Mines, which assesses the minerals related implications of a tax on U.S. primary lead production and primary lead imports. This investigation analyzes the impacts of a primary lead lax on: (1) domestic primary lead production, (2) domestic lead coproduct and byproduct production (including bismuth, cadmium, germanium, indium, silver, and zinc production), (3) domestic secondary lead production, (4) lead imports, (5) domestic lead recycling activity, and (6) the U.S. lead price. Study Findings Domestic Primary Lead and Primary Lead Coproduct and Byproduct Production. A quantitative analysis based on the application of the Bureau's Supply Availability System (SAM) has been conducted to determine the impacts on domestic primary lead and primary lead coproduct and byproduct production from domestic lead source material for a range of taxes.

Jan 1, 1992

By Rollien R. Wells

A REPORT of technological advancements restricted to a specific 12-month period is impractical. Inherent in the nature and development of technology is the element of time; rarely can a new process or product be attributed to a particular year. An overall picture of general trends and pattern changes, however, is indicative of technological growth. This paper presents selected observations and discussions of current metallurgical research and practices in an attempt to develop' such a picture. Of the estimated $16.5 billion spent for research and development in the United States in 1962, at least 80 percent was earmarked for the aircraft, electronics, chemical, and machinery industries. Much of the effort was of the end-use variety and was oriented closely to the national defense and aerospace programs. Only a small fraction of the total research money was directed to studies of the utilization and improvement of metals. Even if the investigations in allied fields such as solid state physics are included, the total research expenditure for metal and mineral materials barely reached $500 million. An additional $200 million was spent by industry and government for development of minerals recovery and processing methods.

Jan 1, 1963

By Edward A. Mihok

Laboratory batch-flow tests conducted on a highly ferruginous acid mine water with an activated carbon showed that ferrous iron is rapidly oxidized. This indicates that air oxidation of ferruginous acid in mine waters is catalyzed by activated carbon. The ferrous iron content of an acid mine water flowing through an aspirated activated carbon column was reduced from about 700 to about 10 parts per million in less than 1 minute. Highly efficient ferrous iron oxidation was achieved by conditioning the activated carbon by repeated treatment with acid mine water and air. The reaction proceeds rapidly in the acid environment (pH about 2.5) engendered by ferrous iron oxidation. The activated carbon was used repeatedly with little loss in efficiency, no discoloration, or solids deposition. In these batch tests, about one-third of the iron was adsorbed by the carbon, but with continuous flow, little iron adsorption is expected. Incorporating a catalytic oxidation step in the treatment of acid mine waters containing ferrous iron would greatly facilitate neutralization--precise control of pH, lower reagent costs, elimination of aeration equipment, and smaller holding ponds.

Jan 1, 1969

By G. B. Atkinson

To develop technology to help assure an ample domestic supply of zinc, the Bureau of Mines is investigating an aqueous chlorine-oxygen leaching process for treating complex sulfide concentrates. This report discusses the purification of aqueous C12-02 leaching solutions by utilizing zinc cementation to remove Cd, Co, Cu, Ni, and Pb. Additional processing of the purified solution is necessary to produce ZnC12 crystals suitable for molten-salt zinc electrowinning cells. The effects of solution temperature, reaction time, zinc dust concentration, ZnCl2 concentration, and degree of agitation on the removal of impurities were investigated for both simulated and actual leaching solutions. Zinc dust addition to a leaching solution at 30° C decreased the Cd, Cu, Ni, and Pb concentrations to acceptable levels of less than 3 mg/1 each. By increasing the solution temperature to 75° C, the cobalt content was decreased to less than 5 mg/l, an acceptable level for producing electrolytic cell-grade ZnC12. Impurity removal rates from ZnCl2 solutions are Pb>Cu=Cd>Ni>>Co. An increase in the solution temperature increases the rate of removal for these metal impurities.

Jan 1, 1982

By Connie S. Musulin

The Bureau of Mines conducted an experiment at Exxon Mineral Co.'s Buffalo Shaft Operation to determine the time required for radon concentrations to return to a base average after fan shutdowns. Shutdown times ranging from 5 min to 16 hr were evaluated. An equation was derived to calculate a ratio that determines the time required for the radon concentration to return to the average level that existed in the mine prior to shutdown. For fan shutdowns of 15 min or more, underground personnel should be evacuated to areas with natural downcast ventilation. For shutdowns of less than 1 hr, personnel should not return to the working area until the elapsed time is four times the shutdown, or until the working area is resampled and found safe. If the mine is not in production during weekends, the downcast fans can be turned off .from midnight Friday until 4 p.m. Sunday, and the radon daughter concentration should be below 1 WL throughout the mine by the start of the shift Monday. This fan shutdown would conserve energy and save the mining company an estimated $21,000 each year.

Jan 1, 1982

By W. A. Selvig

"INTRODUCTION In 1942, Lowry and Junge 3/ reported the results of a statistical study of errors for the proximate and ultimate analysis of coal and coke when made according to the standard Methods of Laboratory Sampling and Analysis of Coal and Coke (D271-42) 4/ of the American Society for Testing Materials. Some of the laboratories that cooperated in the investigation reported difficulty with determination of the volatile matter of anthracite and low-temperature coke. The small number of analyses reported for these particular fuels was considered inadequate to justify definite conclusions regarding the precision of this determination.The investigation described in this report was made at the request of Committee D-5 on Coal and Coke, A.S.T.M. (A. C. Fieldner, chairman), to secure additional information regarding the errors of the volatile matter determination for anthracite, low-temperature coke, and subbituminous coal; the last fuel also gives trouble in this determination, The committee has recognized that the allowable differences between duplicate determinations of volatile matter for these fuels as given in the standard methods are perhaps too stringent and may require revision."

Dec 1, 1943

By R. E. Peterson

The Bureau of Mines has undertaken beneficiation investigations on samples representing large tonnages of oxidized taconites in order to develop and evaluate applicable technologies for producing iron oxide concentrates from these materials. Information derived from the investigations can be used to expand the domestic iron raw-materials base and to establish the impact these taconite deposits may have on future national iron ore requirements. This report describes a process that includes reduction roasting, magnetic separation, and flotation, applied to a western Mesabi Range sample taken near Coleraine, Minn. The sample contained 36.8 pct iron and 46.0 pct silica, and represented 0.5 to 1 billion tons of crude material. An average of 962 lb/hr of oxidized taconite was roasted with 33 lb/hr of lignite in a 35-foot-long rotary kiln. Pulverized lignite and natural gas maintained the kiln operating temperature at 850° C. The roasted taconite was beneficiated by magnetic separation and cationic flotation in a 900-lb/hr pilot plant and yielded a product analyzing 68.1 pct iron and 4.6 pct silica, and containing 82.4 pct of the iron in the kiln feed.

Jan 1, 1981

By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By Charles E. Munroe

"It has been recently learned that certain foreign manufacturers are offering far importation into this country detonators at greatly reduced prices, some of these detonators being of such low grade (No.4), that their use would greatly increase the dangers in blasting.Detonators and electric detonators are used in initiating the explosion of the various high explosives that are now so extensively employed in a great variety of mining operations. Originally a large number of different grades (or ""strengths"") of detonators and electric detonators were marketed, the grade number indicating the weight of the charge of fulminating material contained in the copper case of the detonator. As late as 1914, a report of the Bureau of Mines (Bulletin 80, A primer an explosives for metal miners) shows that grades Nos. 3, 4, 5, 6, 7, and 8, containing from 0.54 to 2.00 grams each, were being offered for use. However, the writer bad observed as early as 1896, when the more insensitive types of explosives like nitro-substitution explosives began to be introduced for use in mining and other blasting operations, that use of a high-grade detonator was essential to insure certainty of discharge."

Mar 1, 1921

By Gerrit V. R. Goodman, Jeffrey M. Listak, John A. Organiscak

Data on dust control practices, geology, and occupational exposures were gathered for approximately eighty underground continuous mining units. Despite silica contents in excess of 5%, nearly forty units successfully maintained silica concentrations at or below 100 µg/rn3 on a majority of occupational dust samples while the remainder had difficulty maintaining this level. These two sample sets were termed group A operations and group B operations, respectively. Analyses of productivities, geologies, and dust control parameters revealed only minor differences between these two groups. Subsequent analyses of face ventilation design showed considerable differences in silica exposure and silica content between group A and group B at the continuous mining machine and roof bolter operator occupations. These differences were minimal when using exhaust curtain ventilation with a dust scrubber', This face ventilation system may benefit operations having difficulty controlling silica dust exposure and silica dust content. Finally, the collected data showed that occupational samples from group B operations possessed generally higher silica exposures and silica content than similar samples from group A. The single head roof bolter (helper) possessed among the highest silica exposures and silica contents in both groups.

By John C. Edwards, Gerald S. Morrow

The U.S. Bureau of Mines has constructed a smoke chamber and developed sensitivity tests for smoke detectors. Response of ionization- and optical-type commercially available smoke detectors have been investigated. Six smoke detectors were measured with respect to visually obscuring smoke characterized by a corresponding optical density for smoldering and flaming coal combustion in the smoke chamber. It was determined that for one type of ionization smoke detector the alarm time was nearly equivalent to that of an odor monitor's alarm for smoldering coal combustion experiments and earlier for flaming coal combustion experiments. The experiments showed that an average CO concentration of 5 ppm corresponded to an optical density of 0.022 m for smoldering and flaming-1coal combustion. Two of the commercially available ionization-type smoke detectors were more responsive to flaming than smoldering coal combustion at an optical density of 0.022 m, whereas the optical smoke detectors-1showed the opposite trend. The responsive characteristics of the detectors evaluated with respect to known smoke conditions in the smoke chamber shows their potential for use as mine fire sensors or part of a mine atmospheric monitoring system to improve mine safety.

Jan 1, 1995

By Richard C. Repsher

Intermittent mining in the slope section at Dutch Creek No. 1 mine, Carbondale, Colo., of the Mid-Continent Coal and Coke Co. has resulted in erratic and minimal rock noise data, which, in turn, has necessitated a change in the method used to plot daily mine noise in order to be useful to the researchers at the mine. Daily and weekly cumulative plots of rock noise under these conditions have not shown significant stress changes as clearly as bimonthly or longer noise rate plots. Hence, longer term cumulative rock noise plots, as described in this Bureau of Mines report, have been added to the data analysis at Dutch Creek No. 1 mine, and have been shown to delineate unique areas of rock noise activity more clearly than shorter term plots. The longer term plots should aid in the detection and delineation of potential failure areas, when used in conjunction with other proven forms of data analysis.

Jan 1, 1979

By Miller, ALEX U, Edward Thomas

In March 1937 the entire country was shocked by news of an explosion of gas in a New London (Tex.) schoolhouse, which resulted in the death of 280 pupils and 14 t eachers. The Government investigators of this disaster believed that the cause was the ignition and explosion of a large volume of explosive natural gas-air mixture that had accumulated in a poorly ventilated space beneath the first floor of the main school building and that this accumulation was due to leakage from gas lin suspended underneath the floor to carry the gas supply to the school.!i/ For some years there has been a potential explosion hazard in school houses and other buildings that are supplied with water from deep wells in certain parts of Illinois. Notwi thstand.ing the disaster at New London, Tex., and the fact that there had been gas ignitions at four water wells in different parts of the State, the explosion hazard in schools and other buildings was not fully recognized until a few months after the disaster in Texas, when an explosion occurred in the settling basin of the municipal water works of Clinton, Ill., and another in a pump house of the municipal water works in Normal, Ill, The explosion in the settling tank of the municipal water works in Clinton, Ill., occurred on August 12, 1937, and a.id considerable damage to the settling tank, but fortunately no one was injured. At the time of this explosion rapairs'and aJ.terations to the water plant were in progress, and 10 men were employed in the immediate vicinity of the settling tank. Two of these men were enlarging a hole in the concrete side with an air hammer for the installation of a larger discharge line.

Aug 1, 1938

By Oliver Bowles

The United States Bureau of Mines has within its ranks a group of engi- neers who are engaged in working out quarry problems, the solution of which will be of general benefit to the industries involved. The problems undertaken are approached in a systematic and thorough manner, all the evidence for and against any proposed change or new development being collected as carefully as an attor- ney would prepare his data on an important case. Unlike the attorney, however, the Bureau engineer does not take sides; his judgment is based entirely and in- partially on the array of facts presented. In order to gain the desired infor- mation he visits many plants, consults with the leaders in the industry, works out experiments in his laboratory, and supplements this information with a stu- dy of all available literature already published on the subject in any part of the world. As an engineer who has for eight years conducted such inquiries in the stone industry, I propose to discuss the Bureau of Mines viewpoint; and it may be of interest to consider with me in a brief and general way the engineer's method of looking at quarry problems, and some of the results attained through past and present labors. While the Bureau has conducted no investigation directly for the crushed- st one industries, two years of investigative work at cement-plant quarries, and work now being conducted at lire-plant quarries, has a very direct bearing on the problems of the crushed-stone industry, since stripping, drilling, blasting, loading, and transportation are similar in many respects in all stone quarries. The results of cement-plant quarry investigations are to be found in Bureau of Mines Bulletin #160. (b) Two short papers on lime-plant quarry problems have been issued in mimeographed form as Serial #01 (c) and Serial 3 (d).

Jan 1, 1923

By S. A. Gustavson, H. E. Olund

This report has been prepared to review the history of the Premium Price Plan for copper, lead, and zinc, which was in operation from February 1, 1942, to June 30, 1947. It includes various charts and tables comparing costs and production data, and data on exploration premiums that were included in the Plan during the last year of its operation.

Jan 1, 1950

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

1. Introduction This document represents Part II of our final report on the development of a "Remote Sealing System for Extinguishing Coal Mine Fires. " It is a technical report which summarizes the results of system development and field demonstration. Part I of this two - part final report is an Operator's Manual for the application of the Remote Sealing System to a coal mine fire. 1.1 Background When coal mine fires go out of control and can no longer be fought directly, the standard fire fighting technique is to construct air-tight seals in the mine passages leading to the fire area so'--,that the oxygen supply to the fire is". cut off. Ultimately, it is desirable to isolate the fire zone in such a way that normal operations can resume in the remainder of the mine. The construction of seals in the- mine causes the atmosphere to pass through a toxic and explosive phase. Explosions, if they occur, are not only hazardous to the men working at the sealing operation, but can also undo much of the sealing work which has already been accomplished. Sealing of passageways surrounding the fire zone from within the mine is extremely difficult and dangerous. Methods for direct sealing are detailed in "Control of Mine Fires'. 1 An alternative to this approach is the technique of remote sealing. This involves drilling boreholes which intersect the mine passages at the locations where the desired seals are to be constructed. The seals are then constructed by pouring material down the borehole and filling a segment of the passage from bottom to top. During this operation, there are no personnel in the mine, all operations taking place on the ground surface.

Jan 1, 1973

By Bruce K. Cantrell, Winthrop F. Watts

The U.S. Bureau of Mines and others have conducted a number of occupational exposure surveys since the publication of the International Agency for Research on Cancer report of 1989(1), which labeled diesel exhaust as a probable human carcinogen. These surveys have assessed diesel exhaust exposure using measurement of diesel aerosol and/or specific polycyclic aromatic hydrocarbons as indicators of exposure. This report reviews, available diesel exhaust aerosol and gas measurement techniques. Measurement of human exposure to toxic agents is the first step in determining the exposure-dose-response relationship. It is a fundamental step in risk assessment. Measuring exposure to diesel exhaust pollutants is particularly challenging due to the complexity and variability of exhaust components. This paper reviews current occupational health standards for diesel emissions and available diesel exhaust gas and aerosol measurement techniques. Although surveys in mines have primarily assessed diesel exhaust exposure using diesel particulate matter (DPM) some exhaust gas measurements have been used as indicators of exposure. DPM is emphasized because it is a major component of diesel exhaust, is suspected to make a major contribution to the health hazard, and is measurable. OCCUPATIONAL HEALTH STANDARDS Occupational exposure surveys of diesel exhaust frequently measure regulated pollutants, or pollutants that are suspected carcinogens, even if no permissible exposure limits (PELs) have been established. In the United States, various organizations recommend a range of allowable values for diesel exhaust gaseous constituents, including carbon monoxide (CO), carbon dioxide (CO2), sulfur dioxide (SO.), nitrogen dioxide (NO2), nitric oxide (NO), and formaldehyde (HCHO). Table I summarizes these recommended levels, showing 8-hour or 10-hour time-weighted-average values where available; where these are not available, 15-minute short-term [ ]