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By N. A. Caspero, W. E. Eckard, W. T. Wertman

A thermal oil-recovery experiment was conducted in the Venango First sand, Goodwill Hill oilfield, Warren County, Pa., about 10 miles northeast of Titusville. The Quaker State Oil Refining Corp., Bradford, Pa., performed the experiment with assistance from Sinclair Research, Inc., Tulsa, Okla., and the Federal Bureau of Mines. The Goodwill Hill field was discovered in 1885. Primary-production oper- ations continued until 1930 when an air-gas injection project, which is still in operation, was started. At the location of the combustion experiment, the reservoir is 400 feet deep and 30 feet thick, with wide permeability and porosity variations. The crude oil is typical Pennsylvania Grade paraffin- base oil with a gravity of 43.9° API and a viscosity of 4.55 cp at 60° F. The well pattern for the experiment consisted of 5 producing wells, enclosing an area of 1.28 acres, and a central ignition-injection well. An air-natural gas mixture was ignited in the ignition well on July 29, 1961. Ignition was followed by injection of air and natural gas at various rates. The experiment was suspended January 5, 1962, when it became evident that economic oil production could not be achieved. There was no conclusive evidence that self-sustained combustion was achieved or that combustion increased oil and water production. A slight increase in liquid production was attributed to stripping action caused by the air-injection rates, which were higher than those normally used during air-gas injection.

Dec 1, 1963

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

By K. K. Kelley, L. B. Pankratz, W. W. Weller

Mullite is a substance of prime importance in ceramic technology . Despite this fact , its thermodynamic properties have received little attention . A Bureau of Mines literature survey disclosed the absence of lowtemperature heat capacity data , the absence of an experimental entropy value for 298.15 ° K , and the lack of heat content data beyond the temperature range from 298° to 576 ° K. Data supplied in this Bureau report fill these gaps in the thermodynamic knowledge of mullite . According to equilibrium phase studies of Aramaki and Roy ,3 the mullite phase melts congruently at 2,123 ± 15 ° K , and the equilibrium crystallinephase composition extends from Al Si2013 to Al6.8 Si₂ Q4.2 . The results in this report are for the stoichiometric composition , Al Si¿Qз . • Heat capacity measurements were made over the temperature range from 50 ° to 298 ° K , and the entropy at 298.15 ° K was evaluated . Heat content measurements covered the temperature range from 298 ° to 1,800 ° K. Heat content

Jan 1, 1963

By J. S. Tosh

An equilibrium study of the system potassium carbonate, potassium bicarbonate, carbon dioxide, and water has been conducted with solutions of 20-, 30-, and 40-percent equivalent potassium carboaate concentrations. These equilibrium data cover the operating range of the hot carbonate scrubbing system for removing carbon dioxide from gas mixtures. Such data are necessary to establish the limits of purification and are used to design absorption and regeneration towers. Values of K in the relationship K = (KHCO3)2/(K2CO3)PCO2 were determined for higher temperatures of 70" to 140° C. and greater concentrations, I 20 to 40 percent, than employed by previous investigators. For the 20- and 30-percent concentrations, K is constant at a given temperature; thus, once K has been determined the equilibrium pressure of carbon dioxide can be calculated for any conversion. Variation of & values with changing conversion was observed with the 40-percent solutions, so that equilibrium calculated pressures are less reliable from average K values.

Jan 1, 1959

By Donald P. Blasko

The Bureau of Mines investigated two areas of the Alaska Peninsula (Iniskin Peninsula and Becharof Lake) where oil and gas seeps were known to occur in an attempt to determine (1) whether the seeps are still active and (2) the amount of bitumen contained in the drainage leaving the seeps. The oil, water, oil-water, and gas were sampled and analyzed. Five oil samples were taken at four separate oil seeps. The API gravity of the oil ranged from 8.90 to 21.4° and the sulfur content was from 0.12 percent to 0.59 percent. Four of the seven gas samples obtained revealed fair high caloric values, ranging from 746 to 924 Btu/cu ft, and averaging 844 Btu/cu ft. A total of 44 water samples were obtained. Bitumen content of the water was as high as 9,773 mg/l at one seep, but averaged less than I mg/l where the seep-drainage water entered the Gulf of Alaska.

Jan 1, 1976

By E. W. Dean

The Bureau of Mines is engaged in the work of obtaining data regarding the physical and chemical properties of typical crude oils from the various producing fields of the, United" States. Preliminary reports have been published that cover the eastern fields* and the' Rocky Mountain districts.** Since the appearance of these, reports: it has been suggested that certain additional data. I regarding the samples would be of practical value. It was believed that a knowledge of the viscosity of crude oil was desirable, particularly in connection with the design and operation of pipe lines. In accordance with this suggestion, the authors have made viscosity tests upon as many of the samples of the two series as wore still available for examination. Determinations were made at temperatures of 70° and 100°F., and in addition the oils were Subjected to the A. S. T M, pour-test*** to as certain the lowest temperatures at which they remain in a fluid condition.

Jan 1, 1921

By John C. Machisak

THIS CHAPTER of the Minerals Yearbook (Volume III) contains overall employment and injury experience for coal mines-bituminous, lignite, and anthracite; coke, petroleum and natural gas; and peat and slag plants; metal and nonmetal mines; sand and gravel operations; stone quarries; metallurgical plants, including metal mills and smelters; and nonmetal mills for 1959. Volume I of the yearbook contains injury experience and employment data in the metal, non-metal, sand and gravel, slag, and quarrying industries, and the milling operations and related plants. Volume II contains the injury experience and employment data in the fuel industries--coal, coke, petroleum and natural gas, and peat. Surveys conducted by the Bureau of Mines were the source of injury and employment data used to compile the tables and furnish information for the accompanying text. Response to the surveys was voluntary except that for coal mines. The Coal Mine Safety Act requires operators of coal mines to furnish the information requested.

Jan 1, 1960

By James R. Wait

It is the purpose of this paper to review theoretical model concepts in through- the -earth transmission of electromagnetic waves. While the subject is very broad in its defined scope, we will be conscious of the specific applications to mine rescue and emergency telecommunications in coal mine environments. The plan of the paper is to outline previous theoretical efforts without attempting to attach names or organizations to the specific developments. However, we include a guide to the literature as an appendix. Without pretending to be entirely impartial we include a critique of the limitations of the available analytical models. As I see it the central problem is to calculate the steady state mutual impedance of a four-terminal network that is the black box characterizing the through-the-earth path. Problems of secondary importance include the determination of the input impedances of the two pairs of terminals and the associated transient responses. [ ]

Jan 1, 1973

By L. Mark Irwin, R. A. Marsyla

The objective of this laboratory investigation was to develop a mattesmelting process for the recovery of copper from industrial smelter dusts . Experimentation was conducted on three samples of Cottrell precipitator dust from a northern Michigan smelter with variations in the following conditions : Temperature , charge composition , pelletization , and moisture content . Based on chemical analyses of the furnace slags , poorest recovery of copper was effected in smelting dry charges regardless of composition . Some improvement was noted with uniformly moistened charges and still more with pelletized (but dry) mixes , but best results were obtained from smelting moist , self - fluxing pellets . Under favorable conditions , experiments yielded furnace slags with an average copper content of only 0.15 percent , which is well below that of industrial copper reverberatory slags .

Jan 1, 1963

By R. V. Lundquist, H. Leitch

Two hydrated calcium aluminates , formed by side reactions in the leaching step and desilication step of the lime- soda sinter process , were investigated to better define their influence on alumina recovery . The two calcium aluminates , Caз [ Al ( OH) 6 ]₂ and зCa0.Al½ 03 · ( 8-12 ) H₂ ) , were prepared and identified by chemical and X- ray analysis . The relative proportions of each of these compounds formed in typical leach solutions at several temperatures were determined . The influence of free lime as a promoter of calcium aluminate formation was also investigated . The formation and precipitation from leach liquors of calcium aluminates contributes to the low alumina recoveries in the process . The presence of carbonate ion in the leach solution suppresses calcium aluminate formation and precipitation and results in higher alumina recovery . Hydrated calcium aluminates are formed in the aging of lime - soda sinters in the normal atmosphere .

Jan 1, 1963

By Alfred E. Schwaneke

An improved maximum-bubble-pressure system using the Sugden twin-capillary method for measuring the surface tension and density of molten metals is described. Improvements include (1) internally ground capillary tips, (2) electronic pressure transducers, (3) micrometer adjustment of immersion depth for density measurements, (4) valuing arrangements to allow operation at other than atmospheric pressure, (5) temperature range to 1,100° C, and (6) recorder readout of pressures. Data for surface tension of mercury from 20° to 300° C are given.

Jan 1, 1970

By Graham W. Marks, RALPH MILLS, FRANK COSSEY

To determine the focal length of lenses or the performance of lens systems before mounting them permanently , it is desirable to have a device in which one or more lenses can be mounted easily and their positions relative to a light source and screen changed readily . We have designed and constructed such an optical bench and lens holder . The bench is similar to that of Houstoun5/ but has been modified , whereas the lens holder is , we believe , a new design .

Jan 1, 1948

1. Data from the Mine Safety and Health Administration (MSHA) indicate that a total of 44,015 employees worked in underground mining locations in 2003, corresponding to 44,778 full-time equivalent (FTE) workers. • Ninety percent of underground employees (n = 39,735) were mine operator employees. • Contractors comprised 10% of all underground mining employees (n = 4,280) and comprised only 5.8% of all underground FTEs. • The majority of underground employees worked for coal operators (73.0%; n = 32,130).

Feb 1, 2005

By Laurence G. Britton

Accurate flammability and ignitability data for chemicals form the cornerstone of procedures used to assess the hazards associated with commercial chemical production and use. Since 1967 the ASTM E27 Committee on the Hazard Potential of Chemicals has issued numerous, widely used consensus standards dealing with diverse testing and predictive procedures used to obtain relevant chemical hazard properties. The decision to issue a standard rests solely with the membership, which consists of representatives from industry, testing laboratories, consulting firms, government, academia, and instrument suppliers. Consequently, the procedures are automatically relevant, timely, and widely applicable. The purpose of this paper is to highlight some of the widely used standards, complemented with hypothetical but relevant examples describing the testing strategy, interpretation, and application of the results. A further goal of this paper is to encourage participation in the consensus standards development process. The paper is published in two parts. The first part (in the preceding issue of Process Safety Progress) dealt with the E27 standards pertaining to thermodynamics, thermal stability, and chemical compatibility. The second part, published here, focuses on the flammability, ignitability, and explosibility of fuel and air mixtures. © 2005 American Institute of Chemical Engineers Process Saf Prog 24: 12?28, 2005

Jan 1, 2005

By A. U. Miller

Since coal -mining records have been kept , reports of all mining States show that each year the lives of many workers have been sacrificed in the production of coal , and Illinois has contributed its share , Illinois reports for the 50 years 1882 to 1932 , inclusive , show that 6,673 men were killed -- 6,121 underground , 340 in the shaft , and 212 on the surface . Of the fatalities underground , 3,116 were caused by falls of roof or sides , 1,111 by haulage , 630 by explosives , 577 by gas explosions , 139 by electricity, and 548 by other causes ; 166 of the shaft fatalities were caused by falling down the shaft , 143 by the cage , and 31 by other causes ; 108 of the surface fatalities were caused by railroad cars , 46 by machinery , and 58 by other causes . Most of those engaged in mining are still of the opinion that it is an extremely hazardous occupation and that it is practically impossible to operate without accidents ; however , students of safety in mining now believe that with the proper attention to accident prevention mining may be conducted with little , if any , greater accident rate than that of other supposedly hazardous industries . There is no mystery connected with accidents in mining ; reports show that the majority are due to two main causes , falls of roof and sides and haulage . Mining companies in Illinois , as well as in other States , have proved in the past few years that the hazards of mining , like those of other industries , can be controlled to a large extent and the mines operated with few if any accidents , provided a great enough effort is made by employer and worker . Although the past accident rate of Illinois may compare favorably with that of other mining States it is higher than it should be ; the fact that 6,673 men (an average of 133.46 per year) were killed in and around the mines of the State between 1882- and 1932 indicates that accident prevention should receive more consideration in the future than in the past .

Nov 1, 1934

By P. Kovalchik, S. Peng, G. Cole, R. Matetic

Previous studies conducted by the National Institute for Occupational Safety and Health (NIOSH) have shown that approximately 90 percent of coal miners and 49 percent of metal/nonmetal miners had a hearing impairment by age 50 (Franks, 1997). Mine workers are exposed to additional noise levels underground due to the reflection of machine-generated noise that would otherwise dissipate in an aboveground setting. Determining the sound-absorption coefficients is essential in modeling the sound field in an underground mining environment. Sound absorption is a measure of the amount of acoustic energy that strikes a surface and is absorbed rather than being reflected. The acoustic environment that mining machines operate in is a critical factor affecting the sound pressure level exposure for mining machine operators. Impedance tube testing is an inappropriate method for determining underground absorption coefficients due to the brittle composition of materials such as coal and slate. Classic absorption coefficient estimation using T60 measurements will not work well in an underground environment because the theory assumes a finite room, a diffuse field and a relatively uniform absorption. None of these assumptions are true in an open-ended mine entry. This paper presents a method using a ray-tracing technique to determine absorption coefficients for underground mines. Absorption coefficients are determined and presented for octave bands from 63 Hz to 8 kHz. The absorption coefficients are essential for determining and predicting potential overexposure to machine operators in different mine environments.1

By W. C. Phalan

"Prewar Conditions:Metallic magnesium may be considered a war metal, but a war metal with a future, so far as the industry in the United States is concerned. Its production in the United States prior to 1915, on a commercial scale, was negligible, but imports prior to that year may be taken as a gaze of the demand for the metal. Unfortunately, magnesium was not listed separately by the Department of Commerce prior to the war, among the importations, but was included with other metals, as follows: ""Barium, calcium, magnesium, sodium, and potassium, and alloys of which said metals are the component materials of chief value."" However, the imports of metals enumerated other than magnesium were probably small, so that the importations under the above caption may be considered chiefly metallic magnesium in one form or another and, therefore, is an approximate gage of the demand for the metal in the United States. These imports were as follows:These figures are so close that they give a good idea of the figures for the respective calendar years.Of this prewar use, it has been estimated that about 85 per cent was used annually and in approximately equal quantities in the production of (1) flash-light powder, (2) fire works, (3) aluminum casting work, and (4) nickel and nickel-copper alleys, such as monel metal, etc. The re¬maining 15 per cent was employed for general uses, such as deoxiding brass and other copper alloys in foundry work, and to a small extent in laboratory and research work."

May 1, 1920

By R. V. Ramani, A. S. C. Owili-eger

The rapid depletion of shallower coal reserves dictate that mining in the future will be deeper and more complex with more difficult natural conditions. Consequently, an increase in methane emission is expected. It is becoming evident that more accurate predictions and better planning are necessary to design efficient methane drainage systems. This objective can be achieved by the utilization of the knowledge of the physics of gas flow through coal seams and rock strata and by the application of digital computers in the solution of methane flow problems. Although the methane emission models described here have not been adequately applied to existing field operations, good agreement between actual field measurements reported in literature and the simulation results indicates the potential of these models for initial flow quantity approximations and ventilation planning. This report has, therefore, introduced to the mine operator yet another application of computers as a planning tool. AREAS FOR FURTHER RESEARCH The study reported here is by no means complete. Extensive research efforts should be directed to the following areas: (a) Better understanding of the physics of gas flow through porous media which exhibit fracture permeability. (b) Determination of field parameters which control gas migration. (c) Investigation of the effects of the rate of penetration on the emission rate and fracture propagation.

Jan 1, 1974

By J. L. Ellenberger, P. W. Jeran

A deep longwall coal mine was instrumented with a three-dimensional microseismic system in order to help determine the exact strata mechanics associated with the rock failure, redistribution of stress and the associated gob formation from the longwall. Overall, 5,000 well calibrated seismic events were recorded during the mining of the panel. Analysis of these events showed a close correlation between the seismic activity and advance rate, and that the majority of the recorded seismic activity occurs in the immediate area of the advancing longwall face.

By James H. Aase

Selected glacial lake clay deposits in Minnesota were sampled, tested, and evaluated to determine their suitability for use as a bonding agent in iron ore pellet manufacturing. Preliminary tests conducted on clay samples obtained from five ancient glacial lake basins identified the clays in the Lake Agassiz glacial lake basin near Cook, Minn., as having the greatest bonding potential. An auger drilling program was conducted to obtain substantial quantities of representative material for detailed testing. The drilling indicated the presence of large clay reserves in excess of 500 million tons within the 12-square-mile area investigated. Bench scale tests indicated that the bonding properties of Cook area clays, when activated with relatively small quantities of sodium carbonate monohydrate (Na2C03?H2O), imparted excellent strength characteristics to iron ore pellets. Larger scale continuous pelletizing tests were made to confirm the bench scale results. These tests indicated that use of 1 percent activated clay alone as binder gave the iron ore pellets an overall strength slightly lower than with 0.75 percent bentonite, considered the industry standard. Use of 0.5 percent activated clay plus 0.5 percent bentonite produced better pellet strength qualities than use of 0.75 percent bentonite alone, without increasing the silica plus alumina content. The data from both bench scale and larger scale continuous tests suggest that the Cook, Minn., clays can be utilized after activation either alone or in combination with bentonite at an economic advantage over present pelletizing practice with bentonite.

Jan 1, 1968