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By K. E. Tame

An alkaline leaching procedure for recovering uranium from a submarginal 0.1 percent Ug Og calcareous carnotite ore from the Shiprock , N. Mex . , area was investigated . A recovery of 72 percent of the uranium was attained in a preliminary test embodying the commonly accepted practice of ( 1 ) alkaline leaching at 90° C , ( 2 ) multiple stage filtration and washing for recovery of a clear pregnant solution , and ( 3 ) caustic precipitation of uranium as sodium diuranate , with recycle of the barren solution to the leaching and washing circuits . Ion exchange resins were used in a second , less orthodox test that comprised ( 1 ) sodium carbonate leaching of minus 10- mesh ore at 90 ° C to dissolve the uranium , ( 2 ) filtration to recover the leaching reagent for reuse , (3 ) recovery of the uranium- bearing solution in the filter cake as a pregnant slime slurry by repulping of the filter cake followed by a sand- slime separation and countercurrent decantation (CCD ) washing for rejection of the sand fraction , (4 ) recovery of the dissolved uranium from the pregnant slime slurry by resin- in- pulp (RIP ) , ( 5 ) elution of the uranium from the resin with a solution of ammonium chloride acidified with hydrochloric acid , and (6 ) precipitation of the uranium with ammonia gas . About 83 percent of the uranium was extracted from the ore and 95.5 percent of the dissolved uranium recovered by ion exchange . Improved laboratory results were obtained using the RIP process , but larger scale tests would be necessary for economic evaluation of the two processes .

Jan 1, 1964

By A. G. Starliper, H. Kenworthy

A procedure was developed for the separation of lead and sulfur in industrial concentrates of galena by a combination of chlorination and fused - salt electrolysis . Galena could not be satisfactorily electrolyzed in the various media tried ; however , when it was treated with chlorine the resulting lead chloride could be effectively separated electrically into lead and chlorine . An apparatus was designed and constructed to chlorinate galena and to volatilize simultaneously most of the chloridized impurities . By electrolyzing the chlorinated concentrate , a high percentage of lead was recovered . Anodic chlorine was drawn from the cell and was used to chlorinate new feed . In many runs , the recovered metal analyzed from 99.8 to 99.9 percent lead . Lead was also distributed as a chloride in the bath , and a small portion was in the volatile fraction produced during the chlorination step . During a tinuous operation , only 0.1 percent of the total lead was discarded ; 99.9 percent was accounted for in the metal , electrolytic bath , and washed or leached chlorination condensate which was essentially lead chloride . About 95 percent of the sulfur from the galena was recovered as a byproduct of over 90 - percent grade .

Jan 1, 1964

By Jerry W. Ramsey

The Bureau of Mines examined a low-, a medium-, and a high-volatile Pennsylvania anthracite by densimetric methods using four mesh si.s of each anthracite. Using high-pressure mercury the macropore volumes and distributions of these pore volumes determined, densities in mercury were calculated, and specific pore vo1.r. ware obtained from these mercury densities in conjunction with helium densities. The helium densities were also used with the ultimate analyses of these anthracites in calculating structural parameters by statistical densimetric methods. The effect of 106 or 108 rads of gamma irradiation in the presence of air and in vacuum upon the properties studied with two mesh sizes of each anthracite. Results of the statistical densimetric method seem to show some breakdown of condensed ring structural units at the lower irradiation level, with subsequent polymerization at the longer period of gamma irradiation. The structural parameters obtained also indicated that in going from high- to low-volatile anthracite, either the number of condensed rings per structural unit increased, or the degree of polymerization increased.

Jan 1, 1965

By D. A. Larson

The Bureau of Mines conducted research to develop preliminary engineering data necessary if the cobalt-rich manganese crusts that occur in the Exclusive Economic Zone (EEZ) of the Hawaiian Archipelago are to be mined. The research was divided into the following sections: (1) physical, mineralogical, and chemical descriptions; (2) mechanical property testing, such as compressive strength, tensile strength, and a rippability index; and (3) mechanical cutting characteristics, including average and peak cutter forces, the specific energy, and cuttings size distribution. Section 1 utilized microscope, X-ray powder diffractometer, and electron microprobe analyses. Section 2 utilized standard mechanical property testing techniques. Section 3 utilized a converted planer mill with full-size coal cutters to fragment the crust and substrate samples. The manganese crust samples were mainly manganese and iron oxides and hydroxides with an average cobalt content of 1 pct and had a nucleus or substrate of rock or sediment. The significant results shown by the mechanical property and cutting tests are that the crust and all but two types of substrates (basalt and trachyte) are weak materials and easily cut with standard drag cutters. The crusts are generally comparable to medium hard coal in strength and in their resistance to cutting.

Jan 1, 1987

By Bernard Porter

The densities of LiF, NaF, and KF, of binary mixtures of these alkali fluorides, and of binary mixtures of UF4, ThF4, YF3, LaF3, and CeF with each of tie alkali fluorides were measured as functions of the melt composition and temperature. Molar volumes at 1,000° C were calculated for all the mixtures. Binary systems containing LiF exhibited molar volume ideality. Binary fluoride systems containing either NaF or KF as the alkali fluoride exhibit positive deviations from molar volume additivity. However, molar volumes in the NaF-KF system are ideal.

Jan 1, 1966

By D. A. Rice

As part of a cooperative effort between the Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input from the phosphate industry, the conversion of phosphogypsum to sulfur is being investigated. The proposed process incorporates the thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to sulfur (S°). The research described herein is focused on the latter half of the process. It was demonstrated that calcium sulfide could be converted to ammonium bisulfide (NH4SH), and that ammonium bisulfide could be oxidized by air in the presence of a catalyst, to elemental sulfur, which was adsorbed on the catalyst. Two methods for recovering sulfur from the catalyst were developed: (1) thermal treatment to volatilize sulfur, and (2) leaching the sulfur from the catalyst with liquid anhydrous ammonia. Over 90 pct of the sulfur adsorbed on activated carbon (the catalyst) was recovered by both methods. Based upon the encouraging laboratory investigations, a hydrometallurgical scheme was proposed for the overall conversion of calcium sulfide to elemental sulfur.

Jan 1, 1990

By S. H. Katz

Tar and suspended matters are removed from manufactured gas used for domestic and industrial purpose.

Jul 1, 1922

By L. G. Trudell, J. W. Smith, K. E. Stanfield

Representation of actual oil yields from sections of the Green River formation oil shales by two types of drill - cutting samples was evaluated . Average oil yields of single sets of mud cuttings from hydraulic rotary drilling in Colorado and gas cuttings from pneumatic rotary drilling in Utah were compared statistically with yields of core samples taken from adjacent holes . Oil yields from gas cuttings were identical to oil yields of core samples . Mud cuttings appeared to represent a section of the formation conservatively , the deficiencies increasing with increasing richness of sample . Because a large amount of the oil - yield data currently available for the Green River formation is based on mud- cutting samples , development of a valid correction method by additional testing is needed .

Jan 1, 1963

By Robert H. Ridgway

This circular outlines salient facts regarding the pyrites industry of the United States and the world. It is founded chiefly upon published information available in the literature of the subject. The United States Bureau of Mines has in its files additional and more detailed data upon many of the subjects presented very briefly here, and will endeavor to assist the mineral industries and the public by giving further information in response to individual inquiries. The bureau will welcome comments, criticisms, and contribu- tions of data that may assist in making later editions of this circular of information more accurate, or may aid in developing more fully the files pertaining to pyrites.

Sep 1, 1931

By A. T. Coumbe, I. F. Avery

The Bureau of Mines has completed a survey of petroleum pipe - lines by direct correspondence with the oil companies and the use of the records of the Interstate Commerce Commission in order to cover both interstate and intrastate systems . The review shows that crude petroleum and product pipe -lines in the United States had a total length of 152,814 miles on January 1 , 1950 , an increase of 25,463 miles since May 1 , 1941 , the time of the last previous survey . The expansion in pipe -line systems was due largely to new trunk-line construction , as the mileage built to carry refined products increased by 11,880 miles , and those intended for crude -oil transportation gained 6,193 miles . Trunk lines represented 60 percent of all pipe -line mileage on January 1 , 1950 , compared with 58 percent in 1941 . The average diameter of trunk -lines for crude oil , as calculated on the various sizes and weighted according to their respective lengths , increased to 9.8 inches on January 1 , 1950 , compared with 8.4 inches on May 1 , 1941. The mileage for lines up to 8 inches used in crude trunklines has decreased since the 1941 survey , while those of larger sizes have increased . The extensive use of large- diameter oil pipe -lines has developed since the construction of two major lines from Texas to the East Coast at government expense as a World War II emergency measure . The successful operation of these lines proved their economic advantages over smallerdiameter lines as well as their effectiveness in moving unprecedented volumes of oil during the period when tanker movements were restricted by submarine action in the Atlantic Ocean . The 24-inch diameter " Big Inch " line carries over 300,000 barrels daily of crude oil , and the 20 -inch " Little Big Inch " carried over 230,000 barrels daily of gasoline and light fuel oils to destinations where they were urgently needed . Hence , Although these lines were sold and converted to natural -gas service in December 1946 , after fulfilling their wartime mission , their record proved to the industry that significantly lower operating and investment costs per barrel -mile of oil moved could be achieved than were possible with the comparatively small lines in general use up to that time . the several major oil pipe -line projects that have been constructed since the late war are of large diameter pipe . To assure supplies and market outlets of sufficient magnitude to support such lines and provide adequate flexibility , ownership is often shared by several large companies whose transport needs are served in common . The principal recent expansion in facilities has been from supply points in Southwestern States toward markets in the North and East and to Gulf tidewater .

Dec 1, 1950

By S. L. McGill

The U.S. Bureau of Mines has determined the microwave heating rates for a suite of minerals and reagent-grade compounds. Maximum temperature achieved for the samples and the time required to reach temperature are reported. Heating rates of powdered samples are presented as a function of incident powers up to 3,000 W at 2,450 MHz. Descriptions of the microwave cavities, test cells, and a thermocouple assembly used to measure temperature in the microwave field are given. Many minerals of value heated in the microwave field, whereas host rock or gangue materials did not. In general, heating rates increased as incident power was increased. Exceptions to this were some very good (CuO, Fe304, and PbS) and very poor (CaC03 and SiO2) microwave-absorbing materials that showed negligible changes with increased power. Applications demonstrating the use of microwave energy in mineral processing that are described herewith include oxidation-reduction reactions, mineral liberation, and mercury retorting-vaporization. Microwave data on mineral heating rates will provide insight to possible chemical and mineral processing applications as well as assist in predictions of processing parameters.

Jan 1, 2010

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 6 Listing The following is a listing of the Mine Evacuation Simulation Program

Jan 1, 1976

By Jay F. Colinet

Longwall mining in lower seam heights may necessitate the use of single-drum shearers to overcome size constraints associated with standard double-drum shearers. To avoid the operational problem of clearance in the tailgate entry with one single-drum shearer, two single-drum machines can be operated on the same face, with each shearer responsible for mining a predefined portion of the face. However, utilization of two shearers on the same face necessitates the positioning of one shearer operator and a jacksetter in the return air of the upwind shearer, thus complicating respirable dust control on the longwall. In an effort to evaluate the unique dust control problems associated with this type of mining, the U.S. Bureau of Mines conducted dust surveys on two multiple-machine longwall operations. Sampling was done to quantify major sources of respirable dust and to identify potential solutions to problem areas. Sampling results indicate that the cutting sequences utilized on multiple-machine faces may have to be designed to minimize dust exposure, as opposed to optimizing productivity or facilitating operational requirements. Also, state-of-the-art dust control techniques typically found on double-drum shearer longwalls must be employed to help minimize the exposure of all face personnel to traditional dust sources.

Jan 1, 2010

By Steven A. Fechner

In 1984 the Bureau of Mines cunducted mineral investigations of specific sites within the Yentna Mining District. One hundred eight placer and rock samples were taken. Reconnaissance placer samples were collected from drainages in the Talkeetna, Susitna, and Yentna River basins. The highest placer gold values were found in the historic placer gold producing creeks of the Cache-Peters Creek area. Samples taken from an outcrop in the Middle Fork of Iron Creek in the Talkeetna Mountains contained previously unreported high lead, zinc, and silver values.

Jan 1, 2011

By John E. Pahlman

The U.S. Bureau of Mines has continued its investigation of chemical additive drilling fluids that produce a zero surface charge (ZSC) on a rock to better define the boundary conditions of the phenomenon. Laboratory drilling tests were performed on Minnesota taconite, Tennessee marble, and Sioux Quartzite using diamond-impregnated coring bits or tungsten carbide spade bits. Drilling fluids were made from chemical additives such as inorganic salts, cationic surfactants, cationic polymers, acids, or nonionic polymers in either distilled, deionized water (DDIW), mine pond water, mine well water, or tap water. These additives were tested below, at, and above their respective ZSC concentrations. Penetration and bit life improvements obtained with ZSC concentration solutions ranged from 88 and 56 pct, respectively, to over 650 pct and over 400 pct, respectively, for the additives tested. Polyethylene oxide (PEO) was found to be the best additive for ZSC-controlled drilling because a continuous range of PEO solution concentrations produced the enhanced ZSC-controlled drilling performance.

Jan 1, 1989

By Noel N. Moebs

This report summarizes a U.S. Bureau of Mines study on the application of geotechnology to identify and minimize ground control hazards in talc mining operations in northwest Georgia. The major ground control hazard is pillar sloughing attributed to the steeply dipping orientation of a pronounced foliation in the talc ore body. The sloughing problem, which gradually reduces the effective support area of a pillar through attrition, can be minimized by appropriate artificial support, as determined by a rock classification system, and by a more uniform pillar design. A boundary element model confirmed the advantages of using a uniform pillar design to avoid excessive loads on portions of irregular pillars. Instrumentation to measure roof convergence and pillar loading was installed at selected locations in an active talc mine but failed to detect any significant changes, suggesting that the gneiss hanging wall constitutes a strong roof that probably can support large spans between pillars and permit high extraction ratios. This interpretation also is supported by a rock classification of the hanging wall gneiss.

Jan 1, 2010

By L. C. George

The Bureau of Mines measured vapor pressures of selected mixtures in the binary system SnCla-ZnC12 by the static pressure method. Equations expressing the vapor pressure) and the heat and free energy of vaporization) as functions of temperature were developed by numerical analysis based on the sigma-plot method. It was found that the vapor pressure of any SnCl2-ZnCl2 mixture) at any temperature within the range of this investigation) could be accurately calculated from the derived values for the heat and free energy of vaporization for the mixture, with a probable error of 0.01 cm Hg or less.

Jan 1, 1967

By R. H. Sprute

The Bureau of Mines conducted a feasibility study and designed an operational system for consolidating waste coal sludge in a 110-acre pond by applying direct current between buried and floating electrodes. Consolidation would reduce the sludge to half its present volume, there-by extending the working life of the pond as well as creating a safe, stable impoundment. The project was conducted by the Bureau under an agreement with the Washington Irrigation and Development Co. (WIDCO), located near Centralia, WA. Part 1 of this report, published as Report of Investigation 8666 in 1982, covers the results of laboratory tests at the Bureau's Spokane Research Center and of a small-scale field test at WIDeO's coal preparation plant. Test results show the process is efficient and cost-effective when power is applied at low current density. Part 2 (this paper) describes a detailed design for an electrokinetic system to dewater WIDCO's 110-acre pond with a 27.4-acre electrode array. Densification of the inactive sludge pond will require 3.6 yr of treatment for a total cost of $1,450,000. The study and design are site specific, but design procedures and analyses are sufficiently detailed to serve as a guide for applying the process to any sludge pond.

Jan 1, 1988

Minerals are vital to any industrialized civilization. Annually, the United States uses more than 4 billion tons of new mineral materials, or about 40,000 pounds per person-about half being mineral fuels and the other half metals and nonmetallics. Stable and economic domestic mining, mineral, metal, and mineral reclamation industries are essential to the economy. The value of United States energy and processed materials of mineral origin exceeds $200 billion annually. Although a number of minerals are imported, especially some designated as "strategic and critical," most U.S. mineral supplies are derived from the domestic mines and processing facilities that you will be seeing, reading about, and visiting as you use this visitor guide. We hope you enjoy your experiences. This pamphlet, a guide to mining and mineral operations that may be observed or visited and some other points of interest relating to minerals, is intended to aid tourists and students who are interested in mining. Some may wish to study our Nation's romantic past; others may plan to enter the minerals industry as a career; still others may have a primary interest in conservation practices. The pamphlet is also intended to aid State and local officials, Chambers of Commerce, and mining firms in answering some of the many questions of tourists and students.

Jan 1, 1977

By R. V. Lundquist, H. Leitch

Sodium aluminate is the principal aluminum compound formed in the sinters prepared by the lime - soda sinter process for recovering aluminum from silicate source materials . The properties and characteristics of this compound were studied to improve the efficiency of the process . Crystalline sodium aluminate was prepared by sintering stoichiometric quantities of soda ash and calcined alumina for 1 hour at 1,250 ° C. The extent of aluminum extraction from sodium aluminate was determined in water and in solutions of NaOH and Na₂ CO3 . Nearly complete extraction of aluminum from sodium aluminate was achieved only in solutions containing free NaOH in excess of that supplied by the salt through hydrolysis . About 42.2 to 68.8 percent of the aluminum was extracted in water or in solutions of Na₂ CO . The precipitation of alumina trihydrate from sodium aluminate solutions was shown to be part of a continuous , reversible reaction according to the equation Al (OH ) A1 (OH )3 + OHThe reverse reaction dissolves alumina trihydrate in NaOH solutions to produce sodium aluminate . Approximate equilibrium concentrations were determined for the reaction at 30° , 50 ° , and 70 ° C. False apparent equilibrium conditions for the dissolution reaction appear when only a small excess of alumina trihydrate is present in the NaOH solutions . A large excess of alumina trihydrate must be present before the true equilibrium point is assured . The engineering significance of the data is summarized , showing controls that should be exercised for a successful and efficient process .

Jan 1, 1964