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By J. E. Tress

The Bureau of Mines prepared submicron tungsten powder by reducing tungsten hexachloride with hydrogen. The particle diameters of the resulting tungsten powders ranged from 0.015 to 0.046 micron. Within the limits of the variables investigated, no clear-cut correlation was found between process conditions and final size of the powder. Oxygen was the major contaminant in the product; being present both as an adsorbed gas and as suboxides of tungsten. Studies showed that the powder yielded compacts of approximately 45 per-cent of theoretical density when compacted mechanically. Low-temperature sintering produced more rapid densification in these compacts than in compacts prepared from conventional powders. Adding up to 20 percent ultrafine powder to conventional tungsten powder caused an increase in density upon compaction with maximum densification occurring at approximately 12 percent ultrafine powder.

Jan 1, 1966

By J. H. East

The occurrence of hydrogen sulfide in the gas in solution in the oil produced from the Tensleep sandstone in the Elk Basin oil field in Wyoming constitutes a serious hazard to persons working in, that field. Aware of the general conditions because of petroleum reservoir studies being conducted in that field by its engineers, the Bureau of Mine's willingly agreed to a request of the Petroleum Administration for War to publicize the hazard and the measures for overcoming it. In October 1943 and November 1944, the Bureau of Mines investigated the method's used in handling the oil and in disposing of the hydro¬gen sulfide that occurs with it. This circular reports the results of these observations. HYDROGEN SULFIDE OCCURRENCE IN THE. ELK BASIN OIL FIELD The Elk Basin oil field is in Park County, Wyo., and Carbon County, Mont. It is about 18 miles north of Powell and 12 miles west of Frannie, Wyo. The original Elk Basin oil and gas field was situated in an eroded depression surrounded by an inner rimrock about 200 feet high with a bordering higher plateau about 500 feet above the basin floor.

Jan 1, 1945

By C. L. Chaney

Investigations were conducted to develop spectrochemical methods capable of determining 0.01 to 100 micrograms of metals in 50 milliliters of solution. The use of gallium hydroxide (Ga(OH)3) as a carrier-precipitant to concentrate metallic ions is described. A porous-cup graphite electrode is used to collect the precipitate. A specially designed plunger permits the electrode assembly to serve as the sample-containing electrode in the subsequent spec-trographic analysis. Analytical curves are presented for antimony, arsenic, beryllium, and zinc. Sensitivities of detection are given for 13 elements. The techniques were applied to identify impurities separated from tungsten, to determine trace impurities in solutions containing high concentrations of magnesium, cobalt, or nickel, and to identify trace impurities in hydrofluoric acid. Laboratory glassware was a serious source of contamination when low levels of zinc were determined.

Jan 1, 1963

By Richard D. Miller, Geraldine P. Norrell

This publication contains routine analyses and related source data for 295 natural gas samples from 18 States collected during calendar year 1963 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4 Five previous publications have been made to present the results of 5,998 gas analyses made by the Bureau of Mines Helium Activity , prior to 1963. The first three , Bulletin 486,5 Bulletin 576,6 and Bulletin 617,7/ contain analyses and source data on 5,214 gas samples collected from 1917 to January 1 , 1961. The fourth and fifth publications , which are published as Information Circulars , supplement the three Bulletins and contain 784 analyses of samples collected during 1961 and 1962. The present Information Circular is the third annual publication supplementing the three Bulletins .

Jan 1, 1965

By Paul W. Jeran

This Bureau of Mines report has been prepared to provide a means whereby mineworkers without specific geologic training can recognize and record the existence of potentially hazardous geologic features encountered in coal mines. Each geologic feature described in this report has been implicated in roof failure. Through the recording of the observations of mineworkers, based on this report, a geologic map of mine workings and the associated ground control problems can be compiled. From such maps, the trends of changes and features can be determined and projected ahead of mining. The face crew can be alerted to a potential problem and what to look for as the face is advanced.

Jan 1, 1983

By M. B. Shirts

Bench-scale studies were made on a reductive hydrometallurgical procedure to convert chalcopyrite flotation concentrate to copper metal or a readily leachable sulfide. Reductive conversion of chalcopyrite and dissolution of iron and sulfur were accomplished in hydrochloric or sulfuric acid solution by the addition of metallic copper, iron, or lead. Use of metallic copper as the reductant enabled extraction of 95 and 46 percent of the iron and sulfur, respectively. The products were ferrous iron, hydrogen sulfide, and a copper sulfide. Use of metallic iron or lead as the reductant enabled extraction of 95 percent of both the iron and sulfur. The products obtained with metallic iron or lead were ferrous iron, hydrogen sulfide, and metallic copper.

Jan 1, 1974

By J. B. Zink

The Bureau of Mines developed a spectrochemical method to determine six constituents in coal ash in the following concentration ranges: silica 9 to 63 percent, alumina 7.5 to 35 percent, ferric oxide 2 to 30 percent, calcium oxide 1 to 29 percent, magnesium oxide 0.5 to 6 percent, and titanium oxide 0.5 to 4 percent. Samples of coal ash are fused with a mixture of lithium tetraborate and vanadium pentoxide. The resulting beads are crushed, mixed with powdered graphite, and briquetted. The pellets are analyzed spectrographically, using controlled high-voltage spark excitation. Vanadium serves as the internal standard. Effects due to matrix variations are minimized by fusion with lithium tetraborate. Intensity ratios of selected analytical lines are determined photometrically, Concentrations are read from analytical curves, prepared from synthetic standards, relating log intensity ratios to log concentration. A combustion procedure is used to determine sulfur tri-oxide. The method is most useful when large numbers of coal ashes must be analyzed but a high degree of accuracy is not essential.

Jan 1, 1967

1. In 2003, a total of 1,972 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 13.7% of all mining operations. • Bituminous mines comprised 92.5% (n = 1,825) and anthracite mines 7.5% (n = 147) of coal mining operations. • More than 70% of all coal mines were located in three states: Kentucky (29.0%), West Virginia (20.9%), and Pennsylvania (20.2%). • Bituminous coal mines reported the production of over 1 billion coal tons.

Feb 1, 2005

By W. K. Tolley

This report presents data collected during research by the Bureau of Mines on corrosion of grinding media. Corrosion rates of eight alloys commonly used in grinding media were tested in synthetic mill water using an ultrasonic grinding device especially designed for this work. Electro-chemical measurements showed variations in corrosion rates for these alloys between 9.8 mpy for medium-carbon steels and 0.14 mpy for high chromium white irons. Bureau data are discussed along with data from the literature to indicate that corrosion causes less than 10 pct of the wear of grinding media in commercial grinding mills. A comparison of corrosion rates for various types of grinding media shows that alloying elements and electrochemically active inclusions in steel affect the corrosion behavior of the media.

Jan 1, 1984

By E. J. Gleim

Many people consider the mining of coal to be an extremely hazardous occupation; but it should be remembered that most large industries have to meet special conditions which, if not dealt with properly, might become hazards to life and property. Mining men may not always be fully aware that some practices and certain equipment that is incorrectly designed or maintained can lead to dangerous conditions. In endeavoring to help the coal-mining industry to prevent accidents and disasters, the Bureau of Mines has engaged in a program of education on conditions and practices that must be avoided. An effective way to teach safety is by visual demonstration. For example, it is generally known that certain kinds of electrical flashes have ignited explosive atmospheres in mines, but actually to see and hear explosions caused by electrical sparks of different size and character under laboratory control is likely to teach a much more emphatic and lasting lesson than would be learned by merely reading about them. The interest manifested by those who witness the demonstrations seems to prove that this is true. The purpose of the demonstrations is not to discourage the use of electricity in mines, but rather to indicate what types of equipment (including some generally regarded as harmless) can ignite gas and what safeguards have been developed to prevent such ignitions. It is hoped that this information will improve the ability of mining men to cope with underground hazards.

Jan 1, 1937

By H. H. Fukubayashi

This Bureau of Mines report describes the development of a pyrometallurgical process for the recovery of the zinc and lead contained in brass smelter flue dusts, which constitute a recycling or disposal problem. Tests on brass flue dust from several sources were made in a quartz tube, heated by an electric furnace to temperatures as high as 1,050° C. The dusts were mixed with carbon and heated in an oxygen-free atmosphere. It was demonstrated that 98 pct of the zinc and 12 to 25 pct of the lead, both in the metallic state, could readily be removed from the dusts. It was also found that 75 pct of the zinc could be recovered, with less than 0.1 pct of the lead, in the absence of chlorides. Pelletization techniques were investigated and 0.6 inch pellets were found to be optimal. Pelletizing results in a tenfold reduction in volume.

Jan 1, 1974

By C. A. Rhoades

A major contributor to the problem of short life expectancy for blade-type conveyor belt cleaners is uneven wear along the blade edge. Uneven wear results in the formation of channels in the blade edge, which allow material to be carried back between the blade and the belt. In an effort to reduce the uneven wear problem, the U.S. Bureau of Mines has studied the mechanisms responsible for effective belt cleaning. From this study emerged a design for a cleaner blade that would greatly reduce uneven edge wear. The design consists of a standard cleaner blade incorporating air passages that allow for the expulsion of air along that part of the blade edge in contact with the conveyor belt surface. The results of 18-h tests indicated that the expulsion of air on the blade edge prevents scratches from developing into deep grooves. These tests showed that effective blade cleaning life can be extended 25 times using the pneumatic cleaning blade, compared with solid metal cleaning blades.

Jan 1, 1989

By Philip G. Burkhalter

Total yield and backscattered electron coefficients were measured in this Bureau of Mines study in an microanalyzer as a function of atomic number and of primary crier: ;y in the 15- to 35-kilovolt range. The electron coefficients were obtained indirectly from measurements of the specimen electron current and the primary beam current collected in a Faraday cage and were measured with a precision better than 0.5 percent. Secondary electron emission was suppressed with opposing potential applied to a screen grid surrounding the specimen. The values of the backscattered electron coefficients agreed with published values within 5 percent.

Jan 1, 1965

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

The Federal Coal Mine Health and Safety Act of 1969 has dictated major changes in mine ventilation with regard to both air quantity and quality. Requirements have also been placed on the ventilation of beltlines, gob and face areas, and air velocities on trolley haulage roads are limited. Escapeways, separate from trolley haulage roads and on an intake split of air, must be maintained continuous to the surface. These and other similar requirements have not only precipitated several modifications to existing ventilation systems but also have greatly increased the complexities of new mine ventilation planning. It is apparent that the use of computers in ventilation system analysis and design is a necessity. SUMMARY Although computer oriented analysis of mine ventilation systems was introduced over two decades ago, it has yet to receive widespread acceptance in the United States. Central to this problem is the fact that, while many computer programs for network analysis have been developed, no attention has been paid to the development of computer input data. Consequently, without this foundation, program applications have been infrequent. This thesis has directly attacked this problem and has presented all pertinent information basic to the development of good computer input data. The areas that were covered include quantity measurement, pressure measurement, fan testing, survey data balancing, and the development of a network schematic from the ventilation survey results. These discussions on data collection and the corresponding reduction to computer coding have been illustrated by an application of a ventilation simulation program to an existing mine in Southwestern Pennsylvania. The use of a ventilation

Jan 1, 1977

By R. L. Grayson, S. S. Peng

"Research has been conducted during the past year on a study to correlate respirable coal mine dust characteristics with worker positions and coal seams. The first characteristic of respirable coal mine dust which has been addressed in the correlation study is respirable dust mass concentration. In fulfillment of this objective, two mines operating in different coal seams have been selected for respirable dust mass sampling on both longwall panels and continuous mining sections. At present, sampling has been completed on the longwall panel operating in the first mine, and one half of the planned sampling has been accomplished on the continuous mining section.The first mine sampled is operating in the Pittsburgh coal seam. The average mining height is approximately 78"" with an average of 8"" of bottom shale being mined. The mine is primarily a longwall mine, and continuous mining machines are used to support the longwall.Figure 1 shows the layout of the longwall panel which was sampled. Intake air is coursed via the track heading up to the headgate area. The air splits at the headgate. Approximately 20,000-30,000 cubic feet of air per minute (CFM) is used to ventilate the longwall face and about 5,000-10,000 CFM is routed down the belt entry. Substantial leakage across the gob was noted during the sampling period. An average of 1800 CFM per 100 feet of face leaked through the shields into the gob from #1 shield to #112 shield. A substantial amount of leakage also occurred between the #1 shield and the solid rib of the headgate development panel. The path of the air used to ventilate the panel is shown with arrows in Figure 1. Direction of air flow was opposite to the coal moving direction on the armored face conveyor.A double-drum ranging shearer is used on the face to cut a 30-inch web of coal. Normal practice is to cut from the tailgate to headgate with the leading drum raised and the tail drum lowered for cutting bottom. After reaching the headgate, the shearer is reversed and both drums are lowered for a clean-up pass. The last 40 feet of face on the tailgate is cut on the clean-up pass.The shearer is equipped with 2 banks of 4 water sprays each and 2 large sprays on the headgate end and 1 bank of 4 sprays on the tailgate end. Additionally, sprays are located above bits on the cutting drums. Actual cutting speed was approximately 14-18 feet per minute, depending on conditions.The cross sectional area for air flow on the face was approximately 60 square feet before a pass was mined and 80 square feet after a pass was mined but before the shields were advanced. The cross sectional area at the shearer was about 35 square feet.The condition of both the tailgate and headgate of the panel was good with no signs of significant roof problems. The roof conditions along the face during the sampling period were variable. At times, as much as 3 feet of drawslate fell from the roof for a span of as much as 40 shields. Generally, however, relatively local areas of falling roof were encoun-tered, usually limited to a 10-20 shield span when appearing.Ten days were spent gathering respirable dust samples on the longwall panel. Mine Safety Appliance (MSA) sampling units equipped with 10-mm nylon cyclones, pre-weighed MSA PVC filters, and constant-flow DuPont pumps were used to obtain thesamples. The pumps were calibrated at a 2 liters-per-minute flow rate. The 10-mm cyclone was selected for classifying total dust into the desired respirable fraction in order to obtain ""legally defined"" respirable dust samples for detailed physical characterization."

Jan 1, 1988

By Ralph L. Brown

The chemical properties of the unsaturated members of the aliphatic series of hydrocarbons are such as to render them " made to order" starting points or basic . materials for the synthesis of hundreds of important organic chemicals . The tremendous quantities of these unsaturated compounds that are being produced daily in the various coal carbonization and oil refining processes , and which at present have little value other than that of fuel , render a survey of the identity and ex- tent of occurrence of these compounds important from the viewpoint of economic utilization and resource conservation The increased need of liquid fuel and the relatively early exhaustion of petroleum resources will eventually require every utilization of liquid fuel products obtainable directly or indirectly from coal . Accordingly , the Bureau of Mines took advantage of an opportunity for examining the gaseous unsaturated hydrocarbons found in the gas obtained when a mixture of water- Collection of the material gas tar and coal is distilled in a gas-making retort . for examination was made possible through the courtesy of the Trent Process Corporation , Washington , D.C. , which was at that time carrying on at the Georgetown Gas Works , distillation of " amal gams " prepared from various coals and oils by the Trent process for cleaning coals . Kanawha gas coal ( 70%) and water gas tar ( 30 % ) from the Washington Gas Light plant were used in the " amal gam" being distilled at that time . The results obtained in this examination are presented here .

Feb 2, 1922

By Wilder D. Foster

In estimating the hazardous qualities of a dusty atmosphere it is frequently desirable to determine the composition of the air-borne dust. Samples collected from ledges or from the rock itself are likely to be unsatisfactory for this purpose owing to the possibilities of differential disintegration of the rock and of variations in settling rates of the different components of the minerals. It may be necessary, therefore, to collect samples of dust from the air. Samples collected from the air may be analyzed chemically, by X-ray diffraction, and by the petrogrephic microscope. Chemical methods are unsatisfactory owing to the small samples usually available and to the limitations and complexities of present methods. X-ray technique requires expensive apparatus not ordinarily available except in research laboratories. Owing to the simplicity and rapidity of petrographic examination of atmospheric mineral dusts, it was considered worthy of further study.

Jan 1, 1938

By E. J. Gleim

During the past 10 years the Bureau of Mines has had a broad experience in the tasting and inspection of electric motors for gaol-cutting machines, cowl drills, storage-battery locomotives and other equipment Which is used in mines where explosive mixtures of methane and air may be encountered. From this experience the Bureau's engineers have reached the conclusion that the most satisfactory method of protecting a motor so as to prevent any sparks resulting from rough commutator, loose contacts or short-circuits in it, from igniting he surrounding atmosphere, is to totally inclose the motor with a substantial casing; having flanged joints. These joints should be metal-to-metal contact so that the shortest path from the interior to the exterior Of the casing is not less than one inch in length. On account of this experience with mining machinery, the Bureau has been asked whether an equal or loss degree of protection would be sufficient for motors for service in or about places such as refineries, gasoline filling stations, cleaning establishments and pumping stations, or in any place where there is liklihood of explosive mixtures of gasoline or naphtha vapors and air accumulating.

Jan 1, 1922

By K. D. Luxbacher

Understanding methane emissions in underground coal mines is critical for a safe and productive mine. In addition to reasonable estimation of initial coalbed reservoir parameters, it is also crucial that changes in effective stress due to mining and pore pressure reduction are taken into account due to their effects on porosity and permeability. Primary parameters for estimation of emissions or modeling of the mining environment for this purpose are porosity and permeability which can change dramatically as a result of stress redistribution associated with mining and gas desorption from a large coal volume. These parameters affect the emission rates and ventilation requirements, as well as water inflow into the working environment. Stopping leakage, on the other hand, is a secondary stress dependent factor in estimation of emissions, as convergence of the roof and floor strata, compromising the integrity of the stopping, may result in leakage, making prediction of ventilation requirements difficult. This paper aims to examine the effects of porosity and permeability changes of the coal seam on methane emissions in an underground continuous miner section. The models were developed and executed in a dynamic fashion to simulate an advancing section. Through this process, the changes of effective stress in coal, particularly their change paths, on porosity and permeability were incorporated into the models and methane emissions, concentrations, air requirements, water inflow and possible leakage from the stoppings were investigated using a conventional coalbed methane reservoir model.

Jan 1, 2009

By S. J. Pearce

"INTRODUCTION AND SUMMARYComplaints have been made regarding dust respirators that may be used in coal-mining operations. Some of these complaints may be due to improper use of the respirator, inadequate knowledge of its purpose and mode of functioning, poor choice, poor fitting, or inadequate maintenance. It is hoped that this circular will answer these complaints by discussing the various factors relating to the proper use of dust respirators in general and in coal mines in particular.It is pointed out that dust respirators are not to be used as a substitute for dust-control measures. The construction, functioning, choice, fitting, and maintenance of dust respirators are discussed.FIELD OF USEThe function of the dust respirator is to prevent the wearer from inhaling harmful quantities of dust by removing dust from the air he inhales.A dust respirator is not to be used as a permanent substitute for dust-control measures. It is to be used as a temporary substitute until dust-control measures can be instituted or as a protective means where dust-control measures are impracticable, as in applying rock dust in bituminous-coal mines.The following sections of the ""Federal Mine Safety Code for Bituminous-Coal and Lignite Mines in the United States"" 2/ emphasize the fact that every effort should be made to keep the amount of dust in the air of the working places as small as possible:"

Mar 1, 1950