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By Oliver Bowles

Calcareous rocks, of which the principal varieties are marble and lime¬stone, are used extensively for building and ornamental purposes. Onyx and travertine, subdivisions of these groups, are sufficiently distinctive in origin and use to merit separate classification. The purpose of this paper is to define the terms "onyx" and "travertine" and to describe the occurrences and uses of the materials bearing these names. ORIGIN AND CHARACTER Confusion exists in the use of the word "onyx." True onyx is a banded chalcedony, a form of silicon dioxide related to jasper, agate, and flint. Calcium carbonate is commonly deposited from solution in successive layers of varying color closely resembling onyx, and for this reason such calcareous rock is also called "onyx." To distinguish the calcareous from the siliceous

Jan 1, 1940

By L. H. Adami

This paper reports the results of solution calorimetry conducted to obtain the heats of formation of crystalline FeS04?6.952H20 and FeS04?1.008H20, from. which values were derived for the stoichiometric compounds FeS04?H20 and FeS04?H20. Also included are derived values of the free energies of formation and dehydration. This work was undertaken primarily to fill a need for data for pure, easily obtainable ferrous compounds that are suitable for use as calorimetric intermediates, The ferrous sulfate hydrates meet the essential requirements for this use.

Jan 1, 1963

By P. T. Brooks

Electrochemical machining sludge, a troublesome fluid waste product, was dewatered on a bench-scale basis by three alternative methods tested by the Federal Bureau of Mines. These methods would enable recycling 89 percent or more of the liquid content of the sludge and allow the dewatered solids to be dumped as landfill or processed further to recover contained nickel. Dewatering by vacuum precoat filtration was estimated to be the least expensive. Based on treating 20,000 gallons per day of sludge, precoat filtration costs were estimated as totaling 1.96 cents per gallon of sludge. Two options of an alternative method, comprised of acidification, reprecipitation, thickening, and filtration, were estimated to cost either 3.41 or 3.60 cents per gallon of sludge.

Jan 1, 1976

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX D DEVELOPMENT AND EXPERIMENTAL VERIFICATION OF ACOUSTIC SEAL CHECKER THEORY 1. Introduction In Section 7 of the report the acoustic seal checker concept was described in a general manner and the parameters which affect the signal level at the microphone were discussed briefly. In this appendix the theoretical basis will be presented and the experimental program described which permitted the extension of the theory into practice. The basic goal of the acoustic seal checker is to relate the reduction in sound pressure level to the size of the residual hole in the fly ash barrier. The smallest hole size that may be measured is determined by the signal to noise ratio, where the noise in this case includes the ambient noise in the mine, the internal microphone noise and the sound transmitted from the acoustic source via the flanking paths through corridors adjacent to the one being sealed. The latter source of noise can be discriminated against, at the expense of increased complexity of the acoustic system, by employing a pulsed source and pulse gating of the microphone signal set to accept sound via the barrier path and to reject the delayed flanking path signals. In order that the acoustic system be insensitive to precise source and microphone location and to permit assessment of system performance on an acoustic power flow basis, a broad frequency band of pseudo-random noise is emitted by the loudspeaker source. The preferred frequency range must be determined, the advantage of a directive source must be assessed, and the necessity

Jan 1, 1973

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESRJ spectrum of the hydroxyl (· OH) radical spin adduct with .the spin trap 5,5-dimethyl-1-pyrrolintt-N-oxide has been obtained in suspensions of freshly ground quartz particles. The concentration of the spin adduct (and hence of the • OH radicals) increases with the amount of grinding. The dust's potential for the generation of the· OH radicals is maximum when fresh (i.e., immediately after grinding) and decreases to 50% in about a day on storage in air. Studies involving metal chelates .indicate that the • OH radical formation involves mainly the silica surface and H20 rather than the Fenton reaction. The results suggest that hydroxyl radical reaction(s) could be important in the lipid peroxidation and fibrogenicity by quartz dust, particularly .in acute silicosis. INTRODUCTIONIn this paper we report on our electron spin resonance (ESR) detection of the formation of hydroxyl (·OH) radicals in aqueous suspensions of freshly crushed quartz particles. This work was undertaken with a view to find possible clues to the role of free radicals in the pathogenesis of quartz-induced fibrogenicity, commonly known as silicosis. We noted that while silicosis is one of the major health hazards in coal and mineral industries, the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still poorly ·understood (Reiser and Last, 1979; Singh and .Rahman, 1987). It is generally thought, nevertheless, that the action of quartz particles on the biological membranes is the starting point of the silicotic process (Parazzi et - al., 1968). A possible clue to the mechanism of the membrane damage by quartz particles, in terms of the role of oxygenated free radicals, is suggested by the following observations. A suspension of quartz particles in contact with alveolar macrophages has been reported (Gabor et al., 1975; Koike et al., 1982) to initiate an enhancement of lipid peroxidation, defined broadly as the oxidative deterioration of polyunsaturated components of lipids. Hydroxyl (· OH) radicals are known to be capable of peroxidation by abstracting hydrogen atoms from cell-membrane lipids (Halliwell and Gutteridge, 1985) and of initiating lipid peroxidation in lysosomal membranes. (Fong et al., 1973). Arong other lines, it is known that exposure of cell membranes, fatty acids, and unsaturated food oils to ionizing radiation, which generates· OH radicals, causes rapid peroxidation (Halliwell and Gutteridge, 1985). Thus • OH radicals (and also other oxygenated species such as Oi, 10 2, and H20 2) might be expected to play a role in the toxicity of quartz. Earlier studies of the aqueous chemistry of quartz suspensions have reported detection of H2O 2 (Kalbanev et al., 1980), implicating the formation of ·OH radicals as transient species. However, we are not aware of any report of the detection of • OH radicals in quartz reactions, and thus the present study was undertaken. Since it-is known that, because of their high reactivity (hence short lifetime) in aqueous media, the • OH radicals cannot be detected via ESR directly (Finkelstein et al., 1980; Buettner, 1982) we have used .ESR combined with the spin-trap methodology (Finkelstein et al., 1980) for studying the· OH formation. The results show that· OH radicals are indeed formed in aqueous suspensions of freshly ground quartz; thus pointing to ·a possible new clue to the cytotoxicity of freshly formed quartz particles and thereby to silica fibrogenicity."

Jan 1, 1988

By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By A. L. Engel

The sample of ore on which the work described in this paper was done came from Mina Oriente, Carrizal Bajo, Provincia de Atacama, Chile, South America, and was sent at the request of the Chil.ean Government through the Foreign Minerals Division of the Bureau of Mines. This ore had been tested locally for treatment by flotation and cyanidation without satisfactory results. An additional difficulty was the absence of water near the ore deposits, so that in any treatment method considered the water requirements would have to be very low. It was desired to develop a practical method of recovering the gold and, if possible, the copper in the area. No data of previous investigations were made available. The sample received was mostly quartz, highly brecciated, with limonite and hematite in the fractures. Copper occurred as malachite and azurite, also in the fracture s and to a slight extent as a stain in the quartz. Some fine-grained pyrite with a little arsenopyrite occurred within the quartz. An occasional grain of chalcopyrite was observed. No free gold was seen during examinations of the ore, but amalgamation indicated that some was present.

Jan 1, 1949

By C. V. Davis

In the lnvestlg::ìt1on of mAthods for aSS8.7ing platin",. conducted by the Bureau ot MinAs, reoent experiments have d~velopad tha~ with ce..tain orei, especially when thr, quantity Of platinum 1s eonlidarablfl, nit'!le acid w111 not etfßct a iepard-Han of platinum and pa11adium. 'lhe following m;lthod has been found to be accurate and to reiu1 t in a complete S''lun''ation of' th~3:l metals. It is therefo 1" '!eeommei:ed that 1 t ba followed rath::r- than the method of separation with nitrio acid, givèn in Technical Pape'! 270.* At line 22, pagi 14, of that paper, bAglnnlng with ~tarm th,~ metals '.'ith dilute¡ nitrio acid," strikE out the rest of the paragraph, and substttutt~ the pro_t cedure g1 ven below. ?lunder and Thuringer.. have developed mnt¡iods for th"i sflparation of palladium from all the platinum metals exoept platinum bj m ,ans of dlmethy- 19lyoxlme. They state that the~ is no action for several hours if an excess of dimeth¡lglyoxime is added to an aqueous solution of ohloroplatinic acid in the cold, alio that only on boiling is the platinum pTecipi ated ¡~d than only PST't of the platinum i srenoved from the sUut1on. They found that palladium 1s p~ecipi tated quati tat! vely in the oold as (CaH 4N40 Pd) which is insoluble tn water, dilute hydroohlorio acid, dilute acetIc aofd or in 50~ ethyl alcbhol. All of their pT'90ipi tations we~p Carl". ied out ~hile the solutions were being heated. This caused a pal"tia~recipltation of the platinum along wi th the

May 1, 1922

Heavy liquids have come into use in ore-dressing investigations, as they make possible the separation of an ore into its specific-gravity components. A paper containing a general dissertation on heavy liquids has been written by John D. Sullivan,4 and the practical application of heavy liquids is explained by Box and Crabtree5. Some heavy liquids become discolored after continued use, and the lack of transparency impairs their value. Since they are fairly expensive, reclaiming is desirable. This paper briefly discusses the preparation and care of some of the more common heavy liquids.

Jan 1, 1928

By David C. Oyler

Methane-drainage holes must be completely filled by grout before mining to prevent the emission of large quantities of gas during mine-through, which would constitute an explosion hazard. In November 1980, seven horizontal holes at the multipurpose borehole, a small-diameter shaft drilled as a Bureau of Mines coalbed methane-drainage installation on the property of the Federal No. 2 Mine, Monongalia County, WV, were plugged using a sodium silicate gel grout. This report de- scribes the grout mix and the use of the grout at the multipurpose borehole, and discusses the results observed upon mine-through of the holes in early 1981. Cost data for the sodium silicate grout are also presented.

Jan 1, 1984

By Lars Osen

This investigation was undertaken to contribute to the understanding of underground pull tests by conducting laboratory tests under closely controlled conditions. Steel bolts, instrumented with electrical resistance strain gages, were anchored in an aluminum block, a granite block, and a steel sleeve, and were subjected to pull tests. The bearing plates used were either flat7 dished, or embossed. In pull testing a bolt that is prestressed, there is a range of loading during which bolt load is greater than the jack-applied load, This study showed that preload, the size, shape, and type of bearing plate; and the geometry of the system determine the point at which bolt load and applied load become equal. The effects on bolt load of both a theoretical solution and actual pull tests were analogous and led to similar results.

Jan 1, 1965

By T. G. Mayhew, A. A. Bergeron, R. J. Mahany

This report describes an operational communications system which provides remote intra-terrestrial wireless transmission of environmental information. Design and modification specifications of requisite equipment are included along with a detailed description of system operation

Jan 9, 1976

By W. T. Benson

In May l942, the Bureau of Mines started exploring for manganese on the Black Poch manganese property, Esmeralda County, Nev., to determine possible reserves of manganese in the deposits. The work was done by the Bureau in cooperation with the Federal Geological Survey and comprised a study of the geology, mapping the area, and exploring by trenching, test pitting, and sampling. All ore bodies were examined and sampled, and the three most important areas were explored by trenching and test pitting. This report notes the location, ownership, and history of the deposits; explains the physical features of the district; mentions briefly mine workings and metallurgy; and describes the geology and ore bodies. The Bureau erected a temporary camp, repaired 5 miles of temporary road, constructed 1,000 feet of new road, dug 3,173 foot of trenches with a vertical crone section of 4 x 10 feet and 91 test pits with a cross section 3 x 6 feet, averaging about 6 feet deep, and cut 134 samples.

Jan 1, 1950

By Richard G. Burdick

The Bureau of Mines conducted this research to determine the feasibility of using soil redox measurements, a relatively new method in mining geophysics, to locate or define a variety of conditions that are hazardous or otherwise of interest to the mining industry. The method was used in three widely separated areas in an attempt to de- fine subsurface concentrations of methane, the edges of coal-burn areas, and a hydrothermal vein set. Both a description of the method used and test cases are given in this report.

Jan 1, 1982

By H. B. Cooke

In connection with its researches on the crude petroleums of the United States, the Bureau of Mines has made a particular study of apparatus for the distillation of hydrocarbon mixtures. While this study is still incomplete it has already resulted in the development of considerable laboratory and semi-plant equipment, motet of which has been described in various publications of the Bureau. The laboratory apparatus (Hempel distillation) and method gives satisfactory comparative results in the laboratory examination of crudes and have been found applicable to crudes of all types, but the agreement of laboratory and plant distillations is not as close as might be desired. This is due, in part, to limitations in size and construction of the laboratory apparatus. Some refiners claim that the Bureau of Mines' laboratory method (Hempel distillation3) for distilling crude petroleum, does not show the full gasoline content of the oil, while others have stated that it indicates more gasoline than can be obtained from the crude commercially. This difference of opinion among refiners results largely from the great variation in stills used and methods of operating them. The Bureau's experience has shown that crude oils from different fields vary widely in character; in fact, that it is not yet possible to classify crude's adequately on the basis of their Down chemical and physical characteristics. As a result of the differences that exist among crudes, and of the difficulty of designing refinery equipment, no standard practice has yet been adopted for the commercial distillation of petroleum, and ma" types of stills are used in the refineries of this country. Although many factors enter into the design of equipment and the development of commercial practice in refining of crude oil, there

Jan 1, 1924

By E. D. Gardner

"Introduction Ore from stopes in metal mines is generally dumped or drawn into chutes or raises through which it passes by gravity to the haulage levels. Occasionally, and under some conditions quite frequently, the ore in a chute will wedge or hang and refuse to run. This hanging of the ore may be due to the packing of damp or clayey material, to boulders forming an arch, or to loose lagging or other timber becoming lodged in the chute.In drawing material from a loading chute it is drawn out a car at a time, and the intermittent flow of the material .increases its tendency to hang. When the obstruction in the chute is near or at the loading gate, the chute pullers start the ore by punching it with iron bars inserted through openings in the chute gate. When the obstruction is beyond reach of the bars, other means of starting the ore must be used.In some systems of mining, chutes or ore raises are built with timber as the stope extends upward. Generally, a manway is left alongside of the chutes, and when the ore hangs in a chute usually it can be started by a miner from the manway ladder by pounding on the timbers of the chute or by punching the ore with a bar inserted through small holes in the chute lining. Special methods of starting clogged ore, such as shaking a chain left hanging in the chute, are used at some places.In other systems of mining, ore passes or chutes are run through solid rock and when the ore hangs in one of these passes, either it must be blasted or else started from the top. Sometimes the ore can be started by running water into the top of the chute, but if the water does not start the ore moving, it must be blasted from underneath. This is done by detonating a bundle of cartridges under the obstruction in the chute or raise."

Jan 1, 1927

By Alton B. Cook

Equipment has been designed and fabricated for study of the vaporization of oil during gas-cycling operations, A sand-packed steel tube, which can be rotated to minimize gravity drainage, is used as a model oil reservoir. A minute windowed cell at the discharge end of the tube through which the liquid-gas interface may be observed, makes possible the separate removal of produced free gas and gas-saturated oil. The operation of the model oil reservoir, and auxiliary equipment, are described by use of a schmatic flow diagram. Details of the specially designed equipment are illustrated by isometric and pictorial drawings, and a description of the experimental procedure is given.

Jan 1, 1959

By Frank E. Cash

The iron-ore ranges in the Lake Superior district are the liarquette in Michigan, Menominee and Gogebic in Michigan end Wisconsin, and the Vermilion, Mesabi, and Cuvuna in Minnesota. These ranges produce about 85 percent of the iron ore mined in the United States. Accident experience in connection with this production is better than that of the regions producing the remaining 15 percent. Production and shipments vary slightly from year to year but closely approximate each other over a period of years. During the 4-year period 1940 to 1943, inclusive, 323,667,599 long tons of iron ore was shipped from the Lake Superior district.4/ Michigan and Wisconsin shipped 65,386,608 tons, or 20.2 percent of the total, and employed approximately 15,000 men; Minnesota shipped 258,280,991 tons, or 79.8 percent of the total, and employed approximately 10,000 men. The tons produced per man employed is much, greater in Minnesota than in Michigan and Wisconsin owing to the large open-cut production in Minnesota.

Jan 1, 1945

By John W. Brown

Electrical resistivity surveys were conducted at three sites in Wyoming in an attempt to detect underground rubble zones in oil shale and to determine their size and resistivity contrast. The zones were detected at Rock Springs sites 4 and 5, but none were detected at Green River site 1. The resistivity of the rubble zones at sites 4 and 5 is greater than that of the surrounding rock. The zones at sites 4 and 5 are concluded to be roughly ovaloid in shape, with a horizontal diameter of 33 m and a vertical thickness of 24 m. Both rubble zones and the blasting that created them are considered to be centered at a depth of 24 m.

Jan 1, 1972

By R. M. Santmayers

[This paper presents one of a series of digests of foreign mining legislation that is being prepared in advance of a general report relative to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the mining legislation of Bulgaria was prepared from a copy (in French) of the Mining Laws of Bulgaria, promulgated by Royal Decree No. 33 of I. arch. 31, 1910, and published in the "Journal Official," No. 83, April 14, 1910, and checked against a digest prepared by Maynard B. Barnes, First Secretary, American Legation, Sofia, Bulgaria, dated June 10, 1932, which was transmitted through the courtesy of the Department of State. CLASSIFICATION OF MINERAL SUBSTANCES Mineral deposits are classed either as mines or quarries. (Art. l.) Tunes are deposits, the products from which must be processed. Under this class specific mention is made of the metals (gold, silver, copper, lead, zinc, iron, chrome, titanium manganese, tungsten, tin, mercury, platinum, cobalt, nickel, cadmium, aluminum, molybdenum, bismith, uranium, antimony, arsenic), sulphur and other "analogous" mineral substances, phosphate rock, iron pyrites, sulphates, saltpeter, alum, boracic acid and its compounds, talc, asbestos, amber, graphite, merschaum and precious stories of all kinds, reek salt and other salt, peat, coal, petroleum, ozocerite, asphalt and all other bituminous substances. (Art. 2.)]

Jan 1, 1933