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By J. F. Smith

A series of studies of emissions from large coal-fired steam generators have included measurements of the concentrations of oxides of sulfur and oxides of notrogen. The sampling equipment, method of sampling, and analytical techniques used for processing of these samples are detailed. A method based on the precipitation of benzidine sulfate was developed for determining both SO3 and total oxides of sulfur in the presence of interfering acidic components in the stack gases. In addition, difficulties encountered with sampling and analytical techniques are also described.

Jan 1, 1968

By T. L. Iapalucci

To determine the behavior of chlorine in coal combustion, the Bureau of Mines burned 10 chlorine-containing coals, high-, medium-, and low-volatile, in a laboratory-scale pulverized-coal combustor. At carbon-combustion efficiencies of 94 to 98 percent, 1.6 to 7.1 percent of the chlorine or an average of 4 percent of the chlorine in the coal was retained in the ash; the balance, predominantly hydrogen chloride, was evolved in the combustion gas. Sulfur retention in the ash ranged from 2.3 to 10.7 percent or an average of 6.3 percent, Addition of alkali and alkaline earth carbonates to a medium-volatile coal containing 0.27 percent chlorine by preferentially reacting with the chlorine increased the Cl/S atom ratio in the ash, Lithium carbonate addition at 0.43 percent and K2C03 at 1.59 percent increased the C1/S ratio in the ash from 0.2 to 0.6.

Jan 1, 1969

By E. R. Cole

The Bureau of Mines developed a procedure that enables substitution of zinc cathodes for the aluminum cathodes normally used in commercial zinc electro-winning. Using zinc cathodes eliminates the necessity for stripping and makes it possible to electrowin zinc from solutions derived from material containing excessive amounts of soluble fluorides; for example, zinc concentrates obtained as a byproduct of fluorspar mining in Kentucky and Illinois. To demonstrate the viability of using zinc cathodes, fluoride-containing zinc concentrate was roasted, leached, and purified according to current commercial practice. Electrolysis was carried out in 0.8-, 1-, 5, and 10-liter cells at 35° to 40° C with a cathode-current density of 8 amp/dm2 in a solution containing 65 g/l Zn++ and 200 g/l H2S04 using PbO2 anodes. Zinc deposits were produced on zinc cathodes with good morphology and excellent current efficiency (90 to 94 pct) in solutions containing enough fluoride (~0.5 g/l, F+) to cause sticking of zinc to aluminum cathodes. The approach described has failed previously because of severe solution-level corrosion of the zinc cathodes. The present investigation found that the use of a simple mechanical barrier to prevent oxygen migration from the anode was sufficient to prevent solution-level corrosion of the zinc cathode starting sheet.

Jan 1, 1979

By D. R. Mathews

The solubility of carbon in electrorefined vanadium was determined to be approximately 0.27 wt pct at the eutectic temperature 1,650° C and 0.03 wt pct at 700° C. The tensile strength and hardness of vanadium increased with car-bon content to the solubility limit, but this effect was small, probably because of the narrow solubility range. Between the solubility limit and 0.3 weight-percent carbon, the second phase had essentially no strengthening effect in vanadium. The second phase, observed metallographically at the grain boundaries and within the grains, was shown by autoradiography to contain high-carbon concentrations. This second phase was identified as VgC by X-ray analysis. The VgC in the grain boundaries contributed largely to the poor cold-and-hot workability of vanadium-carbon alloys. Increased concentrations of V2C occurred at the grain boundaries of the high-carbon alloy ingots as a result of homogenization at 1,600° C for 1 hour. Alloy ingots containing more than 0.36 wt pet carbon (a calculated 2.9 wt pct VaC) following homogenization, cracked severely and failed by intergranular fracture upon swaging at 900° C.

Jan 1, 1965

By Bruce D. Hanson

The Bureau of Mines conducted a series of ignition tests with two types of conical bits (plumb bob and pencil) used on continuous mining machines, to determine their ignition potential at various bit speeds, cut depths, and wear conditions. The tests were conducted using single bits mounted on a 34-in-diam drum in a Bureau ignition test facility. The bits impacted blocks of Berea sandstone in a 6.5 pet methane atmosphere at various bit speeds and cut depths. In a new condition, the plumb bob bits were considerably more incendive than the pencil bits, causing ignitions in 32 of 35 tests at 60 rpm, compared with ignitiolls in 2 of 22 tests for the pencil bits. The results from new bit testing also show that reduction of bit tip velocity to 180 fpm does not eliminate ignition potential. When subjected to progressive wear, bits of both types were more incendive when they were locked in place, unable to rotate, than when they were free to rotate.

Jan 1, 1983

By F. E. Brantley

Blister copper was successfully deoxidized with any of a variety of reducing gases; lancing techniques or a vertical-column furnace were used to contact the copper and gases. Of the gases tested, butane, when used to lance molten copper at about 1,200° C, reaction temperature, was slightly more effective than propane, natural gas, carbon monoxide, or reformed gas for deoxidizing copper from about 1.0 to less than 0.1 percent oxygen content, Laboratory-scale tests revealed that the vertical furnace, composed of a heated column packed with silicon carbide chips or hollow carbon cylinders, was significantly faster and more efficient than the lancing technique for deoxidizing molten copper with any of the gases tested. Comparison of the gaseous-reduction method with the conventional poling method suggests that the gaseous method has important technical and economic advantages for deoxidizing blister copper to any readily controlled amount of residual oxygen content.

Jan 1, 1962

By Changwoo Lee, Jan M. Mutmansky

"This paper results from the research at The Pennsylvania State University into establishment of standard procedures for characterization of respirable coal dust performed by the Generic Mineral Technology Center for Respirable Dust and supported by the U.S. Bureau of Mines and the Mining and Mineral Resources Research Institute at The Pennsylvania State University. The research performed within this particular project is oriented primarily toward standard methods of sampling and characterizing respirable coal mine dust underground so that the chemical, physical, and morphological characteristics are known and can be related to the incidence of coal workers' pneumoconiosis (CWP) in Pennsylvania.The research was initiated by con¬ducting a search of the literature to determine what coal and geologic variables may be related to CWP. The effects of coal rank, free silica content, the mass of respirable dust, and the level of trace elements were the major variables studied. It seems to be evident that the free silica content, the rank of coal, and the mass of respirable dust are the major concerns in defining the causes of CWP. However, based on the literature survey, the authors have concluded that verification of the causes of CWP is a multivariate problem and must be analyzed in an appropriate statistical manner.The results of a multivariate analysis of ten trace elements recorded on Pennsylvania coals are presented. Five of these trace elements were found to be of use in differentiating one coalfield from the others. Of these five elements, chromium and zirconium showed a strong positive correlation with the rank of coal while strontium showed a negative correlation.The design of the field sampling work and its application in future research is the final topic discussed. The sampling plan is oriented toward continuous miner sections with eight-stage impactors as the collection equipment. All of the field work will be conducted in the coal measures of the Allegheny Formation and above with both dust and channel samples being collected in the same mines.Coal workers' pneumoconiosis has been an important topic of concern to miners, mining engineers, and epidemiologists for decades. The general cause of the dis¬ease, the inhalation of coal mine dust, is well known, but the specific coal and geologic variables that affect the incidence and severity of the disease are still subject to debate and study. The primary objective of this study is to identify those variables of Pennsylvania coals that contribute to the CWP problem. To accomplish this task, a field sampling program is to be conducted to relate the characteristics of the coal dust, the coal seam properties, and the geologic variables to the occurrence of CWP.The first year of this study has been involved with both a literature review and experimental work oriented toward identification of causal variables related to CWP. The results of this work are presented here along with plans for implementation of the findings in future research.The previous studies of CWP causal variables have been conducted by scientists, engineers, and medical personnel. Many different types of studies have been performed with emphasis on interpreting the effects of dust mass concentration, mineralogy of the coal, the rank of the coal, and trace element concentrations upon the incidence of CWP in various coalfields. Most of the research has been conducted during the last two decades, with the British Isles, West Germany, and the United States being the primary countries involved.The review of the literature was conducted to determine which variables are likely to warrant further study in Pennsylvania. Previous research studies have related CWP to free silica and other mineral content, the rank of coal, the mass of dust in the working place, and the trace elements in the coal and lung dust. In the following sections, each of these topics will be discussed and analyzed."

Jan 1, 1988

By A. Adams

The quality of hafnium metal produced by the Kroll process depends upon the purity of the hafnium tetrachloride. This investigation of methods for purification of hafnium tetrachloride was undertaken to aid in producing a higher purity hafnium metal than is currently produced by the Kroll process, The quantities of metallic impurities in hafnium metal were decreased by contact with molten alkali-metal chloride salt. Contact was achieved by a semicontinuous process of bubbling gaseous hafnium tetrachloride through a molten salt bath or by a batch process, first fusing the tetrachloride with a combination of alkali chlorides and then heating the mixture to sublime the hafnium tetrachloride. Low-melting mixtures of sodium, potassium, and lithium chlorides were used to purify hafnium tetrachloride. About 30 percent of the initial hafnium tetrachloride was trapped during purification with alkali- metal chloride salts. The 95-percent confidence limits (6)4 for the amount of oxygen decrease 60 and 34.3 parts per million when the batch purification is combined with a reduction so that both take place in the same equipment,

Jan 1, 1961

By A. Iannacchione

Major Hazard Risk Assessment (MHRA)1 is used to help prevent major hazards, e.g., fire, explosion, wind-blast, outbursts, spontaneous combustion, roof instability and chemical and hazardous substances, etc., from injuring miners. The structured process associated with MHRA helps to characterize the major hazards and evaluate engineering, management and work process factors that impact how a mine mitigates its highest risk. The National Institute for Occupational Safety and Health (NIOSH) studied the application of this technique to US mining conditions through a field-oriented pilot project. Risk assessment teams used in the pilot project were primarily composed of mining company personnel. Ten case studies were performed over a wide cross-section of mines. These mines were representative of the important mining commodities in the US minerals industry, i.e. coal, metal, non-metal, and aggregate. Also, the sizes of the mines ranged from small to large and were located across the country. The ten case studies demonstrate that most US mines have the capability to successfully implement an MHRA and that the MHRA methodology produced additional prevention controls and recovery measures to lessen the risk associated with a select population of major mining hazards. The basic ingredient for a successful MHRA is the desire to become more proactive in dealing with the risks associated with events that can cause multiple fatalities. A successful outcome is marked by a thorough examination of existing prevention controls and recovery measures. When pressed to consider more controls to further mitigate the risk, a well-staffed risk assessment team was able to identify additional controls. For these mining operations, it was important to add additional controls, even if they were not required by existing mining regulations, to lower the risks associated with the major hazards under consideration. If a mining operation is not willing to commit its best people to an MHRA or will not provide them with sufficient time to see the process through to its conclusion, the MHRA output may prove to be useless. Additionally, if a mining operation is not prepared to discuss its major hazards in an open and honest fashion and to present the findings of the risk assessment in a written report, the MHRA output will be unclear, and attempts to monitor or audit important controls may not be possible. A MHRA is most effective when the mining operation possesses 1) a proper understanding of its hazards, 2) experience with informal and basic-formal risk assessment techniques, 3) proper facilities, machinery and equipment, 4) suitable systems and procedures that represent industry Best Practice, 5) appropriate organizational support with adequate staff, communications and training, 6) a formal and thorough plan for emergency response, and 7) a safety risk management approach that is promoted and supported at all levels of the organization.

Jan 1, 2008

By F. M. Jenkins

Longwall mining systems are used to mine approximately 50 pet of the world's total underground coal production. Single entries are the predominant method of longwall development in Europe and Asia, where mining conditions are more severe than those encountered in the United States. During the 1970's and early 1980's, the U.S. Bureau of Mines and the U.S. mining industry invested nearly $20 million in single-entry and related research. This report reviews the accomplishments of single-entry research in the United States and describes two U.S. single-entry field projects: the Sunnyside single-entry project in central Utah and the tunnel-boring project in northern West Virginia. Also discussed are a single-entry study conducted by North American Mining Consultants (NAMCO) and a single-entry design study conducted by Ketron, Inc. This Bureau report compares the resulting technology with European counterparts to further assess the utility and efficiency of U.S. systems.

Jan 1, 1990

By R. L. Crosby

The Bureau of Mines investigated alloys of copper with 2, 3, and 4 vol pct alumina and with 2 vol pct yttria. Alloys were prepared by a coprecipitation process and were fabricated by pressing and sintering of powders, extrusion, and swaging. Tensile properties at room and elevated temperatures, stress-rupture strength, electrical conductivity, and density were measured. The superiority in elevated temperature strength of dispersion-strengthened copper to OFHC copper was confirmed. Increasing the oxide content from 2 to 4 vol pct produced only a small improvement in strength properties and decreased the electrical conductivity. The 3 vol pet alumina alloy had the best overall combination of properties.

Jan 1, 1969

By D. M. Lewis, J. K. H. Ma, Y. Rojanasakul, J. Y. C. Ma, J. H. Kang, V. Castronova

"Tetrandrine is a bisbenzylisoquinoline alkaloid which has been shown to exhibit antifibrotic activity against silicosis. Tetrandrine is characterized by its strong binding to alveolar macrophages and inhibition of particle-induced respiratory burst activity in these phagocytes. In contrast, tubocurine and tubocurarine are structurally similar to tetrandrine but exhibit little effect on fibrosis or activation of alveolar macrophages. The objective of the present study was to test the effect of tetrandrine on macrophage production of monokines in response to occupational dusts, and to determine tetrandrine's effect on monokine-medicated cell growth using a mouse thymocyte proliferation assay and lipopolysaccharide (LPS) as a positive control. Stimulation of alveolar macrophages by respirable silica dust resulted in a release of monokines which caused a fourfold increase in thymocyte proliferation. Coal dust, on the other hand, had no effect on macrophage production of this cytokine. Tetrandrine was found to exhibit a dose-dependent inhibition of monokine release from both silica and LPS-stimulated alveolar macrophages. In experiments where thymocytes were directly treated with tetrandrine, a dose-dependent inhibition of thymocyte proliferation was noted with both interleukin-1- (IL-1) specific and nonspecific mitogenic (concanavalin A) actions. In contrast to the inhibitory potency of tetrandrine, tubocurarine was found to have no effect on either the production of monokines by LPS-stimulated alveolar macrophages or IL-I-mediated thymocyte proliferation. These results provide a correlation between the ant:fibrotic effect of tetrandrine and inhibition of macrophage activation. INTRODUCTIONThe pathogenesis of chronic pulmonary fibrosis caused by inhalation of occupational dusts has been associated with abnormal activation of alveolar macrophages such as the release of various cytokines capable of inducing fibroblast proliferation and collagen synthesis. These macrophage-derived cytokines include interleukin-1 (IL-1), tumor necrosis factor (TNF), platelet-derived growth factor (PDGF), transforming growth factor-B (TGF-(B), macrophage derived growth factor (MDGF), and interferon [1, 2].Interleukin-1 is a major macrophage-derived cytokine that has been shown to exhibit multiple biological effects on a variety of target cells. It is known to cause leukocyte [3, 4] and endothelial cell activation [5, 6], and to affect the synthesis and maintenance of the extracellular matrix by stimulation of fibroblast proliferation [7-9], synthesis of collagens [10] and gluco-saminoglycans [11], and prostaglandin E2 production [12]. In addition, IL-1 plays an important role in the initiation of an immune response through its direct activation of lymphocytes and stimulation of the production of other cytokines, such as interferons and hemopoietic colony-stimulating factors, needed for the expression of an immune response [13]. As a major cytokine in the immune-inflammatory sequela, IL-1 is also produced by epidermal, epithelial, lymphoid, and vascular tissues after infection, injury, or antigenic challenge [14]. Agents such as lipopolysaccharide (LPS), phorbol myristate acetate (PMA), immune complexes, and particulates are known to activate the synthesis and release of IL-1 by monocytes and macrophages [15]. These substances also trigger intracellular signals leading to altered arachidonic acid metabolism. Although the mechanism is still not clear, prostaglandins have been shown to suppress IL-1 translation via the induction of cyclic adenosine-monophosphate (CAMP), whereas leukotrienes produce a positive signal for IL-1 production [13]."

Mar 1, 1992

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines developed induction slag melting process is of concern to members of the titanium industry. The objective of the research was to determine the effect of CaF2 inclusions on the properties of titanium and its survival rate during melting. The data were obtained from single induction-slag-melted ingots prepared with the normal addition of 4 pct and also with 2- and 1-pct additions of CaF2 slag. The results of this effort showed that the mechanical properties of single-induction-slag-melted Ti-6Al-4V alloy exceed the minimum values specified in Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H, but these materials are much more notch sensitive in fatigue than normal Ti-6A1-4V alloy titanium. First and second vacuum-arc remelts of single-induction-slag-melted ingots fragmented and increased the number of inclusions, while reductions in the amount of flux resulted in an upward trend in the spatial distance between pores in an x-y plane.

Jan 1, 1988

By R. V. Ramani, R. L. Grayson, R. L. Frantz, V. A. Marple, W. R. Myers, K. L. Rubow, Mutmansky. J. M., T. J. Stobbe

"An investigation of protocols for research performed from 1953 to 1988 on pneumoconioses (with emphasis on diseases related to coal and silica) was conducted in the Generic Mineral Technology Center for Respirable Dust. In addition, interviews were conducted with prominent U.S. medical researchers, aerosol scientists and engineers in government, industry, and universities to determine dust sources, dust preparation methods, laboratory protocols, and determinant variables related to in vitro and in vivo research and assess the comparability of results.Since the original report on the protocol project, additional research regarding free radical existence in freshly produced dust particles and the shape and contamination of particles generated for research purposes has further heightened scientists' concerns. As indicated by current research, fresher dust particles and those with more angular shapes may have a different level of reactivity in biological systems than do older or more rounded particles. Therefore, research on dust preparation methods for biomedical studies was undertaken and will be outlined here.Results of protocol review and interviews are summarized. Research on size reduction methods and their particle characteristics plus some recommendations concerning dust preparation methods and reporting in biomedical publications are also presented. Recent evidence indicates that these recommendations may be of importance in comparing and interpreting research results."

Nov 1, 1995

By Norman A. Pace

This paper is one of a series being published by the Federal Bureau of Mines on methods and practices used in mining and preparing crushed stone for market. Performance, in terms of units of work or tons produced per machine and per operator man-hour, is given whenever that information can be obtained. Direct operating costs are useful for comparing different methods and are included, if available. In addition to describing equipment and methods used} the Bureau considered it desirable to discuss the engineering reasons for the choices that have been made. This paper is particularly concerned with operation of the Camak quarry and plant of the Weston-Brooker Co. The quarry and plant are near Cedar Rock, north of State Highway No. 80 and east of Middle Creek in Warren County, Ga., and about 40 miles west of Augusta. Rail access is by a spur line of the Georgia Railroad from Camak, 5 miles southwest. The main office of the company is at Cayce, S. C.

Jan 1, 1959

By J. R. Koehler

Effective barrier pillar design is essential for safe and productive underground coal mining. This U.S. Bureau of Mines report presents an overview of available barrier pillar design methodologies that incorporate sound engineering principles while remaining practical for everyday usage. Nomographs and examples are presented to assist in the determination of proper barrier pillar sizing. Additionally, performance evaluation techniques and criteria are included to assist in determining the effectiveness of selected barrier pillar configurations.

Jan 1, 1995

By Russell J. Foster

Public awareness of, and involvement in, recycling has increased significantly in recent years. Nevertheless, recycling is generally perceived as a new development, and is familiar only in the context of municipal solid waste management. The actual magnitude and scope of metals recycling in the United States have gone virtually unnoticed. Over time, both the quantitative and qualitative aspects of secondary metals recovery and reuse have changed substantially, while the attendant regulations have become increasingly stringent. This U.S. Bureau of Mines report examines trends and developments in major metal demand and recycling, and analyzes the possible impacts of regulations with regard to recycling activities.

Jan 1, 1994

By R. Barany

Thermodynamic calculations pertaining to the minerals gibbsite, kaolinite, halloysite, and dickite have been hampered by the lack of adequate heat and free energy of formation data. Previous data for gibbsite were highly uncertain, and there were no data for the other three substances. By use of hydrofluoric acid solution calorimetry, the Bureau of Mines derived heat of formation values from the elements and from the oxides for the four substances, and the data were combined with known entropy values to obtain the corresponding free energies of formation. The results show that gibbsite and halloysite are thermodynamically unstable with respect to the oxides (a- alumina, a- quartz, and liquid water) at 298.15° K,, while kaolinite and dickite are only moderately stable (to about the same degree), The instability of halloysite, in comparison with kaolinite and dickite, results in a 60°-lower equilibrium decomposition temperature.

Jan 1, 1961

By C. I. Pierce

The Bureau of Mines used an electrolytic tank model to investigate the response of guard electrodes of different dimensions under different simulated reservoir conditions. Sandstone disks from the Berea and Connellsville Formations were used as resistive beds in the model, and agar gel or water was used as conductive beds. In the experiments, bed thickness, hole diameter, mud resistivity, and bed resistivity were varied. The guard electrode is an excellent tool for determining true bed resistivity in the thin-bedded oil reservoirs of the Appalachian area. Vertical resolution and resistivity values are good when there is little or no invasion. Resistivity values are near true bed resistivity in beds thicker than about six hole diameters when the electrode-to-hole-diameter ratio is close to 1. However, low-resistivity muds cause false peaks to appear on the logs near bed boundaries in thick beds, and for resistive beds having a thickness approximately three to five times the hole diameter, apparent resistivities tend to be excessively high when mud resistivity is low.

Jan 1, 1966

By Thomas M. Barczak

This Bureau of Mines report investigates shield mechanics by describing the elastic response and interaction of shield components to applied vertical and horizontal displacements for various canopy and base contact configurations. This research provides information on generalized shield mechanics, which is applicable in describing the behavior of all two-leg shield supports. Utilizing mechanics of materials concepts and known kinematic relationships for two-leg shield supports, free-body diagrams are constructed for each shield component illustrating internal axial, shear, and bending moment responses required to maintain equilibrium for each load case evaluated. Predicted shield (component) responses are verified by controlled displacement of instrumented longwall shields in the Bureau's mine roof simulator (MRS). Conclusions drawn from these analyses include shield structural responses are significantly dependent upon canopy and base contact configurations. Applied displacements also significantly affect shield responses. Horizontal displacement produces different responses than those produced by vertical displacements. The direction of horizontal displacement is also significant in evaluating shield response. Applications of shield mechanics to in situ support monitoring are also discussed. An objective of this research program is to establish unique shield responses to identify in situ load conditions.

Jan 1, 1989