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By Richard D. Graves

Pitch from low-temperature carbonization of bituminous coal was hydrogenated at cracking conditions in a continuous bench-scale unit to produce low-molecular-weight oils and tar acids. The pitch contained 15.6 pct benzene-insoluble material, 4.0 pct hexane-soluble oil, and 80.4 pct asphaltene by weight. At 475° C, 7,500 psig, and 1.5 hours residence time, hydrogenation products, based on the weight of pitch, were about 36 pct oil boiling below 325° C, 24 pct hexane-soluble heavy oil, 17 pct asphaltene, 1 pct benzene insolubles, and 12 pct hydrocarbon gases. The yield of tar acids boiling below 250° C was 4.3 pct, and the yields of C6 to C8 paraffins, naphthenes, and aromatics were each less than 1.0 pct. The yield of tar acids was within the range of yields obtained by hydrogenation or high-temperature carbonization of bituminous coal (2 to 5 wt pct). Yields of oil boiling below 325° C increased with increased residence time or temperature. There was little or no effect of residence time on yields of alkali- soluble material which contained tar acids. Yields of hydro-carbon gases increased markedly with an increase in temperature from 475° to 500° C. Lowering the hydrogen pressure to 4,500 psig resulted in yields similar to those obtained at 7,500 psig.

Jan 1, 1962

By Charles M. Mason

The Bureau of Mines evaluated equipment and procedures for drop-weight testing of explosive liquids as prescribed by Test 4) a widely used method. It was demonstrated that partial ignitions, originally designated as negative results, should be designated positives; it was also shown that wear or erosion of the sample cups and the type of mount used for the apparatus had important effects on the results. Relative sensitivity as measured by Test 4 was found to vary slightly with temperature. The Bureau also designed a fixed 2-kg weight and associated electromagnetic release, which subsequently were incorporated as standard in a revision of Test 4. The original concept that the test involves only adiabatic compression was found to be an oversimplification; an alternate mechanism for the initiation process is proposed in which due consideration is given to the effects of cavitation and microjets.

Jan 1, 1966

By F. H. Gibson

In recent years physico-chemical techniques have been applied for rapid analysis of coal and coke ash as replacements for classical wet-chemical methods. Although the classical methods are accurate, they are time consuming because many chemical separations are necessary to complete an analysis, and they require skilled analysts for accurate work (12).4 For the past several years the Bureau of Mines has applied some of the newer physico-chemical techniques in its continued search for new and improved methods at analysis. The methods of analyzing coal and coke ash evolved from this work include spectrophotometric methods far SiO2, A120, , Fe203 , TiO2, and P2O5; chelatometric titration for CaO and MgO; and flame photometry for Na20 and K2O. The methods are rapid and direct, are suitable for analyzing a group of samples at the same time in production work, and dire results with almost the same accuracy as classical procedures. With the new methods, complete analyses in duplicate can be obtained at a rate of 2 to 3 times that of conventional methods.

Jan 1, 1962

By Eugene Frey

"INTRODUCTION The ti taniferous-iron deposits in the Iron Mountain area of the Laramie Range, and particularly the Shanton deposit, were examined by several engineers. 3/ of the Bureau of Mines during 1942, 1943, and 1944. A dip-needle survey also was made early in 1945. 4/ Interest in this property has increased as a result of the exploratory work completed by the Bureau in 1944 on the Iron Mountain deposit, 6 miles northeast of the Shanton property.ACKNOWLEDGEMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Special acknowledgment is due to Paul T. Allsman, chief, Salt Lake City Division, Mining Branch; James A. Marsh, district engineer; Paul E. Pesonen, Frank L. Wideman, and Frank H. Gunnell, Bureau of Mines engineers; and to S. R. Zimmerley, chief, Salt Lake City Division, Metallurgical Branch, for analyses of samples."

Aug 1, 1946

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

"INTRODUCTION The float-and-sink test 5/6/ is generally the first test used in determining the washing characteristics of coal. The simplest form of the test is that of using one solution of such specific gravity that the test sample is separated into ""float"" and ""sink"" fractions. In practice, however, a series of solutions is used, and the sample is separated into a number of fractions of a definite specific-gravity range. Analyses of a series of fractions of this type are often referred to as the ""specific-gravity analysis,"" and are of great value in the selection, construction, and operation of commercial washing equipment.The test is rather simple to use, provided a number of conditions are recognized and as many as possible held constant, such as:1. In laboratory testing, two types of solution are available -Aqueous solutions of calcium and zinc chlorides.Mixtures of organic liquids such as carbon tetrachloride, benzene, gasoline, bromoform, etc.2. Absorption of the solution by the coal,3. Solvent action of the solution toward the coal.4. Constancy of specific gravity during the test is affected by temperature changes, dilution, and evaporation.5. Personal technique of the test, such as the time the coal is in the liquid, rate of adding the sample to the liquid, stirring, time of draining, etc.6. Moisture content of the coal as tested."

Dec 1, 1947

By Kenneth E. Hjelmstad

In situ leach mining operations often encounter difficulty maintaining adequate leach solution flow into the are formation. Swelling and dis-persion of clay particles in the formation are often responsible for this permeability loss. Permeability and leaching tests were done in the laboratory on clayey ores to evaluate a clay-stabilizing polymer's effectiveness in preventing these problems. Test results indicate that treating the ores with the stabilizer could maintain permeabilities two to five times greater than the long-term permeabilities present in untreated ores. Both alkaline (pH 8.5) and acidic (pH 2.0) leaches were used in the permeability-leaching tests. Since in situ leaching throughput rate is directly related to permeability, these results also indicate a potentially beneficial effect on operating parameters such as capacity and injection pressure. To determine the reasons for the success of the clay stabilizers, an investigation was conducted to cieter-mine the effect of the stabilizer on clay swelling and dispersion. Clay-swelling tests indicated that the clay stabilizer reduced clay swelling. Zeta potential measurements made on fine clay particles treated with the stabilizer were compared to measurements made on untreated particles and indicated that the stabilizer was electropositive and, therefore, could reduce the degree of negative charge on the particles and their tendency to disperse or migrate.

Jan 1, 1984

By D. E. Hirsch

The Bureau of Mines, as a part of American Petroleum Institute Research Project 60, Characterization of the Heavy Ends of Petroleum, has made extensive use of gel permeation chromatography (GPC). Data developed in this study were used to develop several correlations that greatly expanded the usefulness of GPC and the data have been used as an aid in the interpretation of mass spectra (MS). GPC retention volume data on pure compounds were used with molecular structure to develop correlations that can be used to accurately predict retention volumes, molecular volumes, densities, chain lengths, and ring numbers of many components of petroleum without resorting to further laboratory experimentation. Conversely, the correlation can be used to select or reject some compounds from several possible compounds that are indicated on the basis of MS analysis. The utility of these correlations in compound type characterization is demonstrated by showing their application to 330° to 550° C fractions from a low-sulfur and a high-sulfur crude oil.

Jan 1, 1974

By George T. Faust, S. R. B. Cooke

"The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the preparation of pulverized coal for fuel. In this study the relative amount of surface in various products and samples had to be assessed. Because of the familiarity with screens and because of the simplicity of using the inverse ratio of the opening for ascertaining the amount of relative surface in the respective sizes, screens down to and including 270-mesh were used. This choice was made in full cognizance of the irregularity of screens, but it seemed that if the same screens were used throughout all the tests the relative values would be satisfactory.In dealing with the subsieve sizes, pneumatic elutriation was used to make several fractions to extend the sizing analysis into the range of hypothetical screens. This kind of a sizing analysis was thought necessary because it is familiar to all operators, and, furthermore, it is amenable to several ways of plotting curves that bring out the characteristics of various coals and various methods of grinding.The method of obtaining the data from which to set up the hypothetical screen scale is the subject of this paper. It consists in determining the average projected area of the particles in the respective elutriated products. By extending the ""area method"" to sieve sizes, a factor is found that may be applied to the subsieve sizes, and thus the scale is projected in a regular manner. This method avoids contentions about specific surface and steers clear of ""average diameter"" except as material sized on screens may be said to have an average diameter."

Aug 1, 1939

By Lance R. Barron

Over the past decade, the U.S. Bureau of Mines (USBM) has studied longwall gate road stability at four mines in the Book Cliffs and Wasatch Plateau Coalfields of Utah. These operations are characterized by multiple-seam mining, abruptly varying cover depths to 914 m (3;000 ft), and massive rigid, sandstone units in the main roof or floor. Such conditions encourage severe bumping, roof instability, and occasional floor heave problems.' Various gate road configurations have been employed to alleviate' these problems. Although the mines have comparable basic conditions, the lithologies and qualities of the immediate roof, floor; and seam ate different in each mine and often vary in a single mine. Gate road systems that mitigate hazards in one mine may prove inappropriate in another or for different areas of the same mine. This report relates the geology of the coalfields; describes the location, geologic setting, specific mining conditions, operating history, and the USBM field study and results or conclusions for each mine; summarizes the relative performance of the gate road systems; and emphasizes the need for site-specific geotechnical data to evaluate gate road conditions and performance.

Jan 1, 1994

The wealth of a nation may be measured in many ways, but one of the most important is its natural resources, particularly its minerals. Minerals create the wealth upon which economic prosperity and defense preparedness rest. Managing mineral resources for the benefit of all Americans continues to be an important national goal. In its 78-year history the U.S. Bureau of Mines has established itself as the world's premier mineral information and research agency. Its authoritative, comprehensive data and pioneering research have contributed significantly to a strong U. S. mineral position in the world.

Jan 1, 1988

By A. C. Fielder

It is with some diffidence that I venture to address the Montreal Section of the Society of Chemical industry on the subject of motor fuel from coal at a time when crude petroleum is produced in greater quantities than at any time in history, and at a time when the known reserves exceed all expectations, even the optimistic estimates of the Committee of Eleven of the American Petroleum Institute. Not only are new fields being discovered in America a -an embarrassing frequency but sources outside of the North American Continent show, unmistakable signs of adding materially to the world's sources of oil. Were it not for the tremendous scientific and technical importance of the work done in the past few years in transforming coal into liquid motor fuels, I should prefer to let this subject rest until a more propitious time, such as prevailed some years ago, when the gasoline consumption curve was rising rapidly and the production curve was slowing in its upward rise. That was the period which stimulated the researches which resulted in tetra ethyl lead and anti-knock gasolines on this side of the Atlantic and in methanol, synthetic gasoline and hydrogenation of coal on the other side. Some of you will recall a symposium on Motor Fuels and Oil Conservation held at the Chemists' Club n New York in September; 1925. Dr. R. L. Brown and I presented a paper at this meeting on "Complete Utilization of Coal and Motor, Fuel, in which we pointed out that coal was the most likely raw material source of gasoline substitutes if and when needed. We grouped the present and future, processes' for obtaining motor fuel from coal in three classes, namely:

Jan 1, 1928

Spectrochemical methods were developed to determine beryllium in the concentration range 0.0015 to 4.0 percent in siliceous mineral beneficiation products. Two methods are described. They are (1) a fusion-pellet-spark procedure (spark method) and (2) a sustaining alternating-current arc procedure (arc method). In the spark method the sample is fused with lithium tetra-borate and vanadium pentoxide. The resulting bead is crushed, mixed with powdered graphite, and briquetted. This is analyzed spectrographically using controlled high-voltage spark excitation. In the arc method the sample is diluted with germanium metal, graphite, and vanadium pentoxide. Weighed charges are packed into cupped graphite electrodes and subjected to excitation with a sustaining alternating-current arc. Vanadium serves as internal standard for both methods. Effects due to matrix variations in samples and standards are eliminated either by fusion with lithium tetraborate in the spark method or by dilution with germanium and graphite in the arc method. Beryllium determinations show deviations from accepted chemical values of approximately 5 and 8 percent for the spark and arc methods, respectively. Analyses can be made more rapidly by the arc procedure with a sacrifice in precision and accuracy. Either method can be applied to the determination of beryllium in silicate rocks.

Jan 1, 1962

By F. E. Block

The metallic reduction of vanadium chlorides was investigated by the Federal Bureau of Mines as a possible new route for preparing vanadium metal in an effort to develop a production process that would be adaptable to large-scale plant production and would yield metal of uniformly high quality. Vanadium tetrachloride was usually prepared by chlorinating vanadium pentoxide in the presence of carbon. Although oxygen-?free tetrachloride was difficult to prepare this way, it could be prepared by the direct chlorination of vanadium carbide. Lower valent vanadium trichloride was prepared by the thermal decomposition of vanadium tetrachloride. Vanadium dichloride was also prepared by the thermal disproportionation of vanadium trichloride.

Jan 1, 1961

By M. M. Fine

"INTRODUCTION One of the principal activities of the Bureau of Mines during the recent war was to help to increase the supply of strategic and critical minerals. Fluorite was one of the most critical of the nonmetallic minerals because of the increased demand for it as a flux in basic open-hearth and electric steel furnaces and as a raw material for the production of artificial cryolite used in the aluminum industry. Wartime developments in the technology of hydro-fluoric acid, such as the use of the anhydrous acid as a catalyst in high-octane-gasoline production and the use of organic fluorides as carriers for insecticides, also increased the demand for acid-grade fluorspar. 2/ In 1943 the consumption of acid-grade fluorspar was advancing at a more rapid rate than production and was only slightly less than production during the latter half of the year.The outlook for the postwar market for fluorspar is encouraging. Steel production is expected to remain high until the domestic demand for commodities not manufactured during the war is satisfied. The uses for hydrofluoric acid also are expected to increase under the impetus of war-initiated research. In consideration of these and other factors some authorities predict a new peacetime demand for fluorspar equal to 60 to 75 percent of the war production, 5/ 6/ and others believe that the fluorspar industry will be permanently expanded. 7/"

Dec 1, 1947

By Frank E. Cash

Accident prevention is an integral part of the operating procedure of the petroleum industry, and refinery officials and employees throughout the United States are exerting concerted effort to reduce the frequency and severity of accidents and are realizing definite results. In other words, the petroleum industry is safety conscious to a much creator decree than most of the other mineral industries. On January l, 1936, there were 11 operating, refineries in Louisiana with a crude-oil capacity of 199,750 barrels per day.4/ This report deals with safety in four of these refineries representing. 72 percent of the refinery capacity of Louisiana.

Jan 1, 1940

By Robert L. Rough

The 1954 field tests consisted of six experimental shots in relatively deep holes in a sandstone similar to many oil-bearing sandstones. Water-injection measurements were made before and after each shot to establish the change in conductivity of the fluid caused by the shot. The pressure pulse produced by the shot was recorded in nearby holes to monitor the shot and to determine if any relation existed between the change in conductivity and the nature of the pressure pulse. The results of water-injection tests showed the range of conductivity of fluid before and after shooting with two different types of explosives. Because of the large spread in data for similar shots, not enough information was available to evaluate the differences in increased conductivity produced by the two explosives or any relation between the increased conductivity and the nature of the pressure pulse. However, these results, with the results of other tests involving explosive shots in rock, provide guidance for future research on the oil-well-shooting problem.

Jan 1, 1957

By R. Duncan Gardner

This paper describing the mining practice at the Harmony mine, Baker, daho, is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts in the United States. About 150 tons of copper ore containing 4 per cent copper, 0.001 ounce gold, and 0.1 ounce silver, is being produced daily from the Harmony mine by the shrinkage method of mining. The ore is taken by an aerial tramway 1/3 mile long to the mill, where it is concentrated. The concentrate is shipped 8 miles by truck to the railroad and thence by rail to Utah for smelting.

Jan 1, 1930

By O. C. Blade

This report on the properties of motor fuels sold through service stations In the United States was made In accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items Is confidential. 1t presents analytical data for 4, 802 samples, representing the products of 117 companies. The samples were collected during December 1954 and January and February 1955. As in previous surveys, the gasolines covered 6y this survey Include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation, A list of the National Motor-Gasoline Survey reports published during the past 10 years is given on page 5.

Jan 1, 1955

By Frederick K. Allgaier

This report presents the final data from a 5-yr Bureau of Mines study designed to determine the surface subsidence characteristics resulting from longwall coal mining in a geologic environment common to the Western United States, It includes a description of the geologic setting of the study site, the mine plan, measurement techniques, and results of the monitoring program. Measured subsidence values were obtained over four adjacent longwall panels- Major subsidence characteristics such as longitudinal and transverse profiles, angles of draw, time-related subsidence development, and critical width are discussed. The maxima subsidence value of 5.8 ft was 68 pct of the mining thickness. The average angle of draw was 30°, Subsidence at the center of the first panel continued for 46 months following undermining. The lengths of the longwall panels precluded a definitive determination of the critical width and maximum possible subsidence.

Jan 1, 1988

By R. C. Hickman

Manganiferous breccia formations on three properties were prospected by the Bureau of Mines from January to November 1954 in Johnson County, Tenn. The prospecting consisted of diamond drilling, trenching, shaft sinking, and crosscutting. The results of the exploratory work show the manganiferous material to be low-grade, with little vertical extension. The manuscript on this report was completed February 1955. LOCATION The prospects are in Johnson County, Tenn. (fig. 1), within a radius of 12 miles from Mountain City. The nearest railroad terminal is Damascus, Va., 14 miles from Mountain City.

Jan 1, 1956