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By Jonnie M. Estes

A two-constant equation is presented for helium from 30° = T = 1,473° K. This equation is developed by modifying a generalized equation of state originally presented by Redlich and Kwong (20).3 The modification consists of setting B = 0.06372 Tc/PeT. This modified equation represents the compressibility factors of each of 80 isotherms tested in this temperature range to less than 1 percent average deviation.

Jan 1, 1967

By Charles B. Kenahan

Application of ultrasonics in the electrolytic deposition of metallic manganese and manganese dioxide from sulfate electrolytes had several effects. Ultrasonics produced finer-grained deposits of electrolytic manganese at all current densities than obtained in normal cell operation, but at high current densities it resulted in less adherent deposits. Ultrasonic radiation did not affect cell voltage or cathode current efficiency. In the electrodeposition of manganese dioxide at 70° C., ultrasonic-; increased the current efficiency and decreased the cell voltage at a current density of 9 amperes per square foot, but it had little effect at current densities above this. The decrease in cell voltage was caused by the depolarizing action of ultrasonics at both anode and cathode. Ultrasonic radiation produced a smooth, glossy, adherent, and pit-free deposit at all current densities and at each temperature. Radiation had no effect on current efficiency or cell voltage at 90° C. Ultrasonics was more effective than conventional agitation in producing all of these effects.

Jan 1, 1962

By N. L. Kozlinsky, B. W. Gandrud

"The Marvel mines 1 and 3 of the Roden Coal Co. are located in the Cahaba field in Bibb County, Ala., nearly southwest from Birmingham, an airline distance of roughly 30 miles. The coal of the Clark seam at this point has some coking properties, but at present it is sold exclusively as a domestic and steaming coal.This paper, which is the second of a series on the washability of Alabama coals, like its predecessor dealing with the Mary Lee seam,5 contains screen-sizing and float-and-sink tests of a representative sample of the raw slack, and slotted-screen tests showing the proportions of flaky particles in certain selected sizes; inasmuch as this coal is not used for coke manufacture, no crushing tests have been made. These data have been obtained in connection with an exhaustive study of coal preparation in Alabama, now being conducted by the United States Bureau of Mines and the University of Alabama with the cooperation of the different coal operators. As the work progresses, other papers will follow containing further data on Alabama coals and giving results obtained in preparing these coals by various methods.The only published investigative work on the Clark seam is that of Forbes,6 who gives a number of sections of this seam in Marvel No. 3 mine with proximate and ultimate analyses of face samples taken in the mine and also some analyses of delivered coal.The available information on this coal indicated that the preparation problem was one of ash reduction. In order to substantiate this information a complete analysis of the 3/4 by 3/16 inch size, and sulphur determinations and ash-fusibility tests of the float-and-sink fractions have been made; these results are given in Tables 1 and 2. As these results also indicate that the preparation problem is one of ash reduction, the tests and discussion have been devoted to that subject."

Jun 1, 1930

By L. L. Brown

As part of the Federal effort to help maintain an adequate supply of fertilizer materials, the Bureau of Mines conducted research to characterize complex low-grade Michigan phosphate materials and to devise methods for recovering fertilizer-grade phosphate concentrates. The rock is from middle Precambrian sedimentary formations in the Marquette Range located in the central part of the Upper Peninsula of Michigan. Occurrence of phosphate-bearing sediments in Precambrian rocks is rare. This deposit, containing 12 to 15 pct P205, is believed to be the richest Precambrian phosphate deposit in the United States. Petrographic examination showed that the conglomeritic rock contains crystalline apatite both in "black pebbles" and in quartz matrix. Attrition scrubbing and sizing tests showed that there is no tendency for phosphate to concentrate in any of the sized fractions. In beneficiation tests, which included grinding to minus 325 mesh followed by phosphate mineral flotation using a fatty acid-fuel oil collector, a phosphate concentrate was obtained that had a grade of 30 pct P205 and a P205 recovery of 72 pct. This concentrate should be suitable for fertilizer manufacture.

Jan 1, 1981

By R. R. Sayers

The terms "sanitation and }\Vgienen are often used interchangeably, but it is more "' usual to apply ttsani tat ion'' to th environment or surroundings, and nr.ygieneto the iiiividual, The subject,. h9wever, is so broad that only a few of the phases of sanitation will be di.acusae in ·this paper, vmile the various Fsea of hyg:tene will be deferred for later consideration. One of the bes.t .iaf ini tions of sanitation that I have hearci was given by ur. L. L • Lumsden, of the U, S. Public Heal th Service, who state.d that "'sanitation is t-he c.oir .. 'Don-sens$ application of the principles of cleanliness,

Aug 1, 1922

By J. F. McIlwain

Cobalt-base hardfacing alloys used for wear resistance consist almost entirely of metals largely imported into the United States. As part of an overall research program to help alleviate this foreign dependency, the Bureau of Mines has been investigating an iron-base alloy system as a potential replacement for cobalt-base alloys for some uses. To ascertain the melting ranges, thermal analyses were made of cast heats of alloys containing, in weight percent, 59-61 Fe, 16-19 Cr, 8-9 Ni, 1 Mn, 1 W, 1 Mo, 0.5 Cb, 0.6 Si, 0.3 C, and 0-12 stoichiometric TiB2. Powder alloys within this range of composition, prepared by mechanical alloying, were sized and applied to mild steel test coupons by nontrans-ferred-arc plasma spraying. The resulting thin coatings were >95 pet dense, with bond strengths of 35 MPa and hardness of 400 to 840 DPH. Abrasive and adhesive wear test data were compared to those of a plasma-sprayed cobalt-base alloy. A range of boride contents resulting in most promising properties was determined for further research.

Jan 1, 1985

By L. C. IlsLey

A list of permissible mine equipment approved by the Bureau of Mines before January 1, 1940, was published in Bureau of Mines Information Circu- lar 71103. Information Circular 71584, published as a supplement thereto, listed equipment approved during the calendar year 1940. The present list contains the information given in those two circulars, as well as approvals issued during the calendar year 1941. It embraces electrically operated air compressors, coal drills, conveyors and loading machines, electrical equipment for mine fans, mining machines and trucks, mine pumps, rock- dust distributors, room hoists, storage-battery gathering and haulage locomotives, storage-battery power trucks and shuttle cars, mine telephones, junction and distribution boxes, electric cap lamps, flame safety lamps, electric hand and trip lamps, electric flood lamps, flashlights, methane detectors, and single- and multiple-shot blasting units. The equipment listed is not approved by the Bureau of Mines until found by inspection and test to comply with minimum standards of safety as outlined in "schedules" prepared upon the basis of many years of ex- perience in dealing with safety problems confronting the coal-mining in- dustry. The use of such equipment in mines that are known to be gassy,. as well as in those that may become so, is earnestly recommended in the interests of safety. This circular is published so that the industry may be kept informed as to the many types of machines, devices, and lamps that are available for reducing explosion and other hazards incidental to coal mining.

Apr 1, 1942

By Robert C. Ellman

The Bureau of Mines investigated the factors that cause agglomeration of lignite by freezing during winter shipment and sought methods to avoid it. Tests showed that lignite may be freezeproofed by removal of the relatively small quantity of moisture involved in forming the frost crystals which cement particles together, or by controlling the crystal characteristics. Adding dried lignite fines proved to be an effective and superior freezeproofing method. Commercial adoption of this method has been successful.

Jan 1, 1965

A study was conducted by the Bureau of Mines to evaluate natural gas as an automotive fuel and to provide guidelines for optimum engine adjustments for low exhaust emissions. The study was conducted using a single-cylinder engine, a multicylinder engine, and a total of eight vehicles. Results from single-cylinder engine tests showed that the light-load, lean-limit misfire region for natural gas begins at an air-fuel ratio between 150 and 160 pct of stoichiometric. Changes in ignition timing significantly influenced emissions of nitrogen oxides and hydrocarbons, but had little effect on carbon monoxide emission. Low emissions can be achieved with current-design engines by adjustment of engine parameters, but only with heavy penalty to engine performance. Emissions from vehicles fueled with natural gas are virtually unaffected by ambient temperature change within the range 20° to 100° F. The organic emissions from engines fueled with natural gas were estimated to be 22 to 25 pct as reactive as the emissions produced using gasoline. Levels of exhaust emissions from vehicles fueled with natural gas were unchanged over 10,000 miles of normal driving.

Jan 1, 1973

By G. St. J. Perrott

Through the development of manufacturing processes whereby ethylene glycol can be made on a large scale; ethylene glycol dinitrate is now being used in high explosives (dynamites and permissible explosives) by some manufacturers as a low-freezing ingredient of the "explosive oil" instead of such compounds as nitropolyglycerin and nitrosubstitution compounds. The amount of ethylene glycol dinitrate being used constitutes 25 to 50 per cent of the oil. The purpose of this report is to give the results of toots, to determine the effect on the safety and physical properties of permissible explosives of subsituating 25 peg cent of ethylene glycol dinitrate for an equal amount of nitroglycerin or a mixture of nitroglycerin and nitropolglycerin.

Jan 1, 1929

By W. G. Bradley

THIS PAPER describing the quarrying, mining, and crushing of gypsum at the Blue Diamond mine, 11 miles from Arden, Nev., on the Union Pacific Railway, is one of a series on gypsum mining being prepared for and published by the Bureau of Mines. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total production costs might in some instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By Don M. Coulter

"INTRODUCTION The district comprising Union, Lafayette, Pontotoc and Calhoun Counties, Miss. (fig. 1), was examined in October 1941 by R. W. Smith of the Bureau of Mines, accompanied by J. W. Adams of the Mississippi Bauxite Co. 3/ Subsequently, geologists of the Federal Geological Survey made a more detailed study of the area. 4/Bauxite had been reported as present in several localities in Pontot. County, and large deposits of kaolin are known in Pontotoc, Union, Calhoun, and Lafayette Counties. Many of the bauxite deposits, such as those on Big Hill, Second Hill, and Third Hill, in Pontotoc County, form the caps on hills and are outliers of Wilcox deposits on the Midway formation. Such deposits could have no extensions because of erosion and were not examined, as they were investigated by the Mississippi Geological Survey. 5/ Most of the bauxite was known to be low-grade, with a high iron content. However, Pontotoc County in particular presented possibilities of finding high-grade bauxite with a low iron content by drilling down the dip from the Wilcox-Midway contact. Consequently, with few exceptions the investigation was confined to drilling in this direction.Headquarters were established in Tupelo, Miss., on July 13, 1943, and mineral agreements were obtained covering 8,367 acres of land, with 62 land-owners in Pontotoc and Union Counties. Holes were drilled on properties of three of the landowners in Union County and 36 in Pontotoc County."

Apr 1, 1948

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By Arthur L. Murray

"Oil-shale camps are peculiarly favored, in that before they are establishes it can be ascertained with a degree of certainty, that the life of the project is not limited. Unlike camps at metal mines, where the metal content of a given area is frequently an unknown quantity until after years of development, oil-shale camps should, from the outset, be planned and. built as permanent types of camps. Where this procedure is followed camps will be established which better serve the needs of the industry and the cost of their general care and upkeep will be less.Selection of camp or townsite.The site of the camp or town' whether on company property or not, should be selected with care. It should be separate if possible from the location of the plants of the company so as to be free from noise and fumes and so as to provide a change of environment for employees in going from their work to their homes.The principal features governing the site to be selected are as follows:Drainage. The general contour of the surrounding country should be such that drainage is away from the site. The camp or town should, if practical, be situated on higher ground than that in its immediate vicinity.Soil. The nature of the soil on which the camp or town is located may bear a decided relation to health. A porous, well underdrained top soil of at least four feet in depth insures dryness and facilities the placing of foundations and the laying of water mains and sewer pipes. Such a soil also is an advantage in growing trees, shrubs and grass plots, which are a decided adjunct to making the community attractive.Enviroment. The contiguous territory should afford no unwholesome sur¬roundings such as swamps Or accumulations of stagnant water.General Considerations. The water supply to be provided and the method of disposal of wastes influence to a certain extent the location of the camp or town-site. The means of supplying water, whether by gravity or by pupping, and the disposal of sewage, whether by outfall, system, sewage disposal system through septic tanks, broad irrigation or filter beds, or cesspools will govern the location of the site topographically in relation to source of water and point of disposal of sewage.* This article was prepared as part of the paper ""Use and Supply of Water for the Oil-Shale Industry"" by J. J. Jakowsky, to be published by the Department of Metallurgical Research, University of Utah, in cooperation with the United States Bureau of Mines."

Jul 1, 1921

By Tobias W. Goodman, George N. Aul, Joseph Cervik

The Bureau of Mines conducted research to degasify a virgin block of coal in the Beckley Coalbed using long horizontal holes drilled in an array from the bottom of a ventilation air shaft. Eight horizontal holes and an in situ pressure hole were drilled in a radial pattern to depths ranging from 418 to 910 ft (127 to 277 m) and 205 ft (62 m), respectively. The investigation showed the shaft was in a basin saturated with water, which resulted in low gas flows from holes. The in situ pressure at 200 ft (61 m) into the coalbed was 79 psig (544.6 KN/m2). The aver- age gas and water flows for the eight holes were 94,100 ft3/day (2,665 m3/day) and 13 gal/min (49.3 l/min) . After 514 days of degasification, 18.7 million ft3 (0.53 million m3) of gas had been drained. Methane face emissions, which were measured as a section advanced toward the shaft, were reduced about 77 pct, emphasizing the value of drainage by this technique. All holes were grouted before the area around the shaft was mined.

Jan 1, 1982

By James C. Cawley

This National Institute for Occupational Safety and Health study was conducted to focus future research on the most significant electrical problems in the mining industry. Data from 1,926 mine electrical accidents (including 75 fatalities) that occurred between 1990 and 1999 were studied. Coal and metalnonmetal operator- and contractor-reported data are presented. All data used in this analysis were MSHA closeout data, except 1999, which were preliminary data.

By Jr. Gabler

Methods for the direct spectrochemical determination of impurities at the parts-per-million level in tungsten metal and oxide are presented. Several published procedures were investigated and numerous modifications were made in establishing procedures with improved precision and extended lower levels of determinability. Details of standards preparation are presented, experimental work is described, and three preferred methods are described in detail. A germanium carrier-distillation procedure is applicable to the determination of 13 elements in tungsten powder; a silver chloride carrier-distillation procedure provides for the determination of 24 elements in tungstic oxide, and a sustaining ac arc method is applicable to 26 elements in tungstic oxide. The choice of methods to be used depends upon sample form, elements and concentrations to be determined, and the precision and accuracy required. The investigations reported here were undertaken to develop direct spec-trochemical methods with increased accuracy and precision to determine impurities in high-purity tungsten and tungstic oxide, to define the lower concentration levels of detectability and measurement for the common impurities in tungsten by direct spectrographic means, and to present the details of the developed or modified methods that have proved applicable.

Jan 1, 1965

By J. D. Marchant

In the spring of 1953 a series of heats were made using a 3-phase, size ST, Pittsburgh Lectromelt arc furnace to develop a method suitable for melting, refining, and granulating cobalt powder produced by the Calera Mining Co., at Garfield, Utah. According to specifications stipulated by General Service Administration, the granules had to pass a 2-inch screen and be retained on a 6-mesh screen, be low in phosphorus and sulfur, and contain a minimum of 98.7 percent cobalt plus nickel. Various combinations of water temperature, water jets, and rate of pouring were tried early in the campaign to produce desirable granules. It soon became evident that a properly refined and deoxidized molten bath was the major requirement for a satisfactory product. The physical characteristics of the granules were improved also if, just before pouring, the surface of the molten metal bath was pre-pared by a method involving the use of silica flux. The Bureau processed 107,750 pounds of cobalt powder. A total of 104,810 pounds of cobalt granules meeting General Service Administration specifications was returned to the producer. The refining slag, which was also returned to the company, contained 1,781 pounds of metal.

Jan 1, 1955

By H. A. Doerner

"The following report is submitted, in compliance with the request made by the Honorable W. H. Sproule, Chairman of the Committee on Mines and Mining, to the Director of the United States Bureau of Mines, that the bureau investigate the most modern processes for the production of radium from its ores. A thorough search of technical publications and patent office files was made. Outstanding authorities on the subject as well as persons claiming novel or secret methods were interviewed.Unlike most other elements, it is not possible for radium to occur naturally in a pure or concentrated form. This is because radium is one of a series of unstable elements which, by a constant, spontaneous, atomic disintegration, change from one element to the next in the series. Uranium is the ""grandparent"" of radium. The rates at which radium atoms are ""born"" and ""die"" are so related that only one part of radium can exist in equilibrium with three million parts of uranium. Consequently radium is only found associated with uranium minerals, and the ratio of radium to uranium is never more than one to three million. Since uranium is a rather rare element, the scarcity of radium is almost beyond comprehension. Nevertheless minute traces of radium can be detected in nearly all rocks.The carnotite ores of Colorado and Utah were the chief source of radium for many years.In the fall of 1922 news of the very rich deposits of radium ore discovered in the Belgian Congo caused most complete cessation of domestic production. The Congo ore contains pitchblende and a number of alteration products, including the new minerals bequerelite, curite, krasolite, stasite, and dewindite. Reports indicate that a considerable amount of ore containing over 50 per cent uranium oxide has been produced. It seemed certain that radium could be extracted from the Conga ore at a much lower cost than from the relatively low-grade carnotite; and in order to preserve their elaborate marketing organizations, the larger American producers made agreements with the Belgian syndicate to market the foreign product in this country. The retail price of radium has been held at $70 per milligram, but large orders are filled as low as $50. Extraction of radium from carnotite by the usual methods does not appear to be profitable at that price with one exception, all American firms ceased production after their accumulated stocks of ore had been treated. The United States Radium Co., which continued to treat carnotite for several years, finally shut down its plant."

Dec 1, 1930

By Raja V. Rarnani, Robert L. Frantz

"The more than 75 research projects funded throughout the first 10 years of the Dust Center's operation have resulted in numerous cumulative findings fulfilling the goals of the Center. These project descriptions present the methodologies and project-to-project relationships leading to their various accomplishments and demonstrate the mesh between project objectives and Center goals.To develop equipment for collecting respirable dust samples.To develop experimental methods for particle-by-particle characterization of morphology, size, and chemistry.To develop experimental methods for overall respirable dust sample characterization of size distribution, chemistry, and crystallography.The project directly addresses the Center's goals to enhance the understanding of the scientific and engineering characteristics of fine and respirable mineral particles found in mining and milling atmospheres and to establish the relationship between natural and cultural factors (mine geology, mineralogy, mining and milling methods, equipment, and control measures) in the generation of fine particles. The project also aims to contribute to the development of control mechanisms for reducing ambient respirable dust concentrations and worker exposures.The work on this project is related to similar work on Coal Mine Dust Characterization (Project No. 2701/MN1) and Characterization of Dust Particles (Project No. 4203/PS3).Airborne dust sampling was performed at the following locations: 1) a sand and gravel quarry in Southern New Hampshire, 2) a welding facility, 3) a ceramic powder facility, 4) a metal powder facility, and 5) the air in Cambridge, Massachusetts. A portable sampling box incorporating two Sierra personal cascade impactors was designed and produced. At a 2-LPM flow rate, the effective cut-off diameters of the Sierra impactors were 10.0, 6.0, 3.5, 2.0, 0.9, and 0.5 mm, respectively, for each stage, and the air passed through a PVC filter after the last stage. In addition, the sampling box contained a total respirable dust filter. The substrates were weighed carefully before and after collection, and the weight increases were recorded. All films, foils, and filters were put in the balance chamber for more than 8 hours to stabilize the temperature and humidity before weighing. A Cash 21 microbalance (±0.001 mg) was used to weigh the Mylar films, SS films, and filters."

Jan 1, 1995