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By M. D. Gibbs, T. N. Smith, B. Verbaan

When heated in the absence of oxygen, pyrite from refractory gold concentrates decomposes endothermically to pyrrhotite, releasing sulphur. The decomposition starts at the particle surface and progresses inwards, leaving an adhering layer of porous pyrrhotite. Use of the conventional shrinking-core model implicitly assumes a negligible partial pressure of sulphur in the bed, but this pressure is in fact at least equal to the equilibrium vapour pressure of sulphur over pyrite, constituting the principal control of the rate of decomposition. Further experiments showed a decrease in reaction rate as the conversion increased. Both phenomena are attributed to the persistence of non-isothermal conditions in the fluidised bed during pyrolysis, caused by the endothermic nature of the reaction and the relatively slow rates of heat transfer to particles and vapour removal from the bed. Equipment must be developed to maximise these two parameters

Jun 19, 1905

By W. R. Donaghue, R. L. Robinson, C. Scott

Whilst spontaneous combustion has never been considered a major problem in south Durham, certain collieries in the area have a history of heatings and precautions are essential. Three collieries are affected - Shotton, Vane Tempest and Seaham - and in the case of the last two, there are huge areas of high quality coal to work under conditions where spontaneous combustion is a real hazard. The seam being extracted has an immediate roof in goaf left by the incomplete extraction of a contiguous seam worked before the turn of the century. The presence of residual coal stocks and old roadways and cavities adds to the difficulty of preventing unwanted air movement. The main preventive measures adopted are the construction of airtight gateside packs and the use of sprayed surface coatings in the gate. Sampling systems and sampling points are described and, in particular the field of continuous monitoring from the surface is examined. The resulting possibility of a quantitative as well as qualitative assessment of the preventative measures required is discussed.

May 23, 1905

By E. L. Evans

The historical development of South Yorkshire mining is traced and note made of the liability to generate spontaneous combustion of some of the seams which have been worked. The liability factor is analysed firstly as an inherent property in the material of a coal seam, and secondly as a circumstance of a situation in which access is provided for the air necessary to sustain oxidation. The geological settings in which incidents of heatings have been known to occur is discussed and conditions favouring a natural pre-disposition to spontaneous oxidation exposed, particularly the effect of argillaceous material overlying the seam. An extensive strata-dynamic study follows to demonstrate the situations in which stray air currents tend to impinge on readily oxidizable material. Prevention techniques are indicated as the identification of strata-dynamic situations in which air access to broken coal is induced and thereafter th operational action to seal off the voids which have been opened up so as to exclude air from the broken coal. Measures to reduce the tendency for ventilating air to short circuit across waste voids, and to obviate deflection of air into packs are outlined. The importance of face and roadway design features is demonstrated and the consequences of practices inimical to good control of spontaneous combustion are related. Discussions on means of detection and also on the sealant materials available are included.

May 23, 1905

By R. F. Bell, Schultz

The paper briefly discusses the nature of spontaneous heating in mines in the Doncaster area, in the period immediately before 1967 and steps taken to prevent and treat such outbreaks. The changes that led to the increased rates of advice of Barnsley Seam faces since 1967 are listed and the effects of these increased rates on the frequency and location of spontaneous combustion are discussed. The change in methods of control required by the increased rate of advance of the faces and the changes in location of outbreaks are described. Some typical heating situations are evaluated. The methods described include the use of air sealants, water gels for filling of voids in wastes, the balancing of pressures across heating areas by pressure chambers, booster fans, and the resiting of air separation doors, and the sealing of air-ways by flooding. The authors discuss the influence of mine layouts on the risks of spontaneous combustion and advocate that future plans should be designed to limit the number of districts at risk when heatings occur.

May 23, 1905

By T R. Marrero, J W. Wilson

This paper presents costs for a coal log pipeline that can transport coal over distances from 50 km to 1500 km. The coal log pipeline (CLP) concept is a new technology in w hich coal is compacted into water impermeable circular cylinders that can be suspended in water flowing through an underground pipe. CLP includes processes to prepare the run-of-mine coal for compaction, the injection of coal logs into a pressurised water-lilled pipeline, the conveyance of the coal through a pipe including special pumping stations, and the treatment of the coal logs and water at the pipeline outlet. An 8 inch (203 mm) pipeline can transport more than 2 Ml of coal per year. CLP components have been extensively tested in bench-scale facilities where these tests have included start up/shutdown steady state flow behaviour, end of pipeline treatment of water and coal log handling, water hammer effects, abrasion of logs and pipeline, coal log manufacture, and other engineering operations. Several sites are being considered in the United States (US) for the first commercial demonstration that will probably take place in 1998. The cost calculations are based on realistic values for all the components of a CLP. including a return on investment. For pipelines of different diameter, values for coal transportation are presented in terms of $(USVtonne as a function of distance.

Jan 10, 1996

By Mowat D. M., Louis H., Smith W. Mackey W. M., Dron R. W., Ellison C. C., Winmill T. F., Kerr G. L., Haldane J. S., Ashworth J., Garforth W., O'Shea L. T.

Discussion of Winmill's paper, including various anecdotal examples, is presented together with the author's response; topics included: the need to distinguish cubic pyrites from the rapidly decomposing rhombic form known as marcasite; the effects of moisture content in the coal and air; the possible effect of pressure; the heat insulation resulting from heap/stack size; and the means of determining pyrite and moisture contents

Dec 1, 1916

By G. G. Lambert

The paper traces the pattern of spontaneous combustion in the workings of what was originally Hemsworth Colliery, but since July 1967 is now part of South Kirby Colliery. Examination is made of the Barnsley Seam sections and the part played by the top section of the seam as it comes in close proximity to the main seam. In this area of the colliery nine mechanised faces were set away between the years 1953 and 1968, every one "fired" at the pillar edge and six "fired" at the face line when production had ceased. The paper deals with the different preventative measures used, from sandbag walls, cement injections, spraying with polyurethane, until finally using Mandoseal as a sealant. Since the latter method was first used, the last three faces worked in this particular area were all salvaged completely, without any sign of a heating developing.

May 23, 1905

Discussion of the papers with a written contribution and authors' written replies.

Jan 1, 1947

By P. Danson, D. A. White, S. Bashir

Composite ion exchange materials made of SnO2, TiO2 and MnO2 can be used to remove radioactive contaminants from nuclear waste streams. In several cases their selectivity and capacity are enhanced by mixing hydrous silica into the matrix. MnO2-SiO2 materials are especially useful for a number of reasons, such as their selection of heavy elements over caesium. Distribution constants and determinations of exchange capacities show that in many instances the properties of the composites are better than those of the oxides alone, while the presence of a chelating agent has been found to reduce the uptake of nuclides considerably. Methods are being developed for the bulk manufacture of the materials. Further work on sorption mechanisms is required to explain anomalous results, particularly the variation in exchange capacity for different elements and the ability of the oxides to sorb colloidal material in alkaline solution.

Jan 8, 1992

By J A. Hacked

This paper explores the potential to exploit controls over the outputs of the primary blasting operation, arising from the performance consistency benefits gained in using modern bulk emulsion explosives technology. The former, allied with the latest powerful blast predictive software and measuring tools, offers the user the opportunity to apply control over both cost and performance, which has not been possible in the past.

Jan 12, 1997

By A. Hemami

In order to automate the operation of mechanical loaders it is essential to have a knowledge of the forces that act on the bucket and of the trajectory that the bucket should follow. A trajectory for the cutting edge of a bucket is derived from studies of the forces acting during the scooping phase. The proposed trajectory has a minimum energy consumption and is simple to automate. It is determined initially by setting to zero certain components of the resistive forces to the bucket motion which would otherwise result in unnecessary work and consequent energy wastage. The method for finding the appropriate trajectory is discussed on the basis of the properties of the material to be loaded and the loader size.

Jan 4, 1993

By C G. Wall, T S. Daltaban

Three quarters of recent increases in world oil reserve estimates since 1990 have been attributed lo ‘better reservoir management' rather than to new discoveries. For the United Kingdom Continental Shelf (IJKCS), the Department of Trade and Industry (DTI) has on 2.2 bn barrels of extra oil protection through effective reservoir management of existing producing reservoirs. Past practise has been to manage petroleum exploitation on a departmental basis, with exploration assessing and ranking prospects, reservoir engineering assessing development plans and production facilities implementing plans. Any reservations necessary might involve restarting the project evaluation from scratch. Current practice is to manage an operation through asset management teams involving all disciplines. It is hoped that this approach will not only eliminate fruitless directions of effort, but the quality of work in each discipline will benefit from interaction. That is, the result of a team effort is greater than the sum of individual efforts. To date, this is most apparent with the interaction between geology, reservoir geophysics and reservoir engineering through reservoir characterization. This is the current area of greatest effort, with improved geophysical technology and computer power leading to more and more detailed and complex simulation models. The equally important interaction of reservoir engineering and production and facilities engineering applied to fields in decline has not yet achieved the prominence that it deserves. Establishing priorities in reservoir management requires the very critical evaluation of the relative value of objectives. The fact that something can be done (3-D seismic, 4-D seismic, multilateral wells, or three phase multi-layer well test analyses etc) is not a good reason for doing it. Reservoir management should he a study of value added versus cost for any activity possible or proposed. Both in the areas of reservoir data acquisition and of assessing opportunities in the period of production decline, it is likely that expert systems will need to be developed with the associated base of experience, understanding and know ledge. A n other area for the future is the elusive target of ‘enhanced ’ oil recovery, as distinct from ‘improved’ oil recovery. The most likely route forward here is the incessant scrutiny of reservoir regions and units within fields for their suitability for pilot schemes for advanced recovery techniques implemented at a favourable time. Finally, the reduction of costs, the maintenance of low. but viable rates of production and the threat of abandonment costs will increase reserves. An increase which may have appeared insignificant in the past is now more valuable.

Jan 11, 1996

By T. J. White, R. A. Farnfield

Early computerised blast monitoring equipment consisted of a digital version of the existing analogue machines with, perhaps, a few enhancements. Many additional facilities have since been developed to enable the efficient collection of high quality data. These developments are examined with reference to digital sampling, triggering systems, the storage of complete recordings and signal processing. Recent advances have been made in the use of blast monitoring systems that comprise multiple blast monitoring locations with centralised control and data collection. Software has been developed to help record blast parameters and assess environmental effects. Computer databases have many advantages over their paper counterparts. Data can be easily retrieved and processed. The scaled distances used in the prediction and control of peak particle velocities can be calculated rapidly when the data are obtained directly from a database. Since the whole vibration signal can now be recorded, signal processing can be used to provide information such as signal length, dominant frequency and response spectra.

Jan 4, 1993

By M. L. Schmulian

"The Windarra nickel deposits display many of the characteristics that typify Archaean volcanic peridotite-associated nickel sulphide ores of Western Australia. The Fe-Ni-Cu sulphide mineralization, which comprises dominantly disseminated sulphides, occurs at the base of a differentiated ultramafic volcanic pile grading upwards from massive meta-peridotitic flows to thin, locally spinifex-textured meta-picritic units. The entire mafic-ultramafic belt has been subjected to mid-amphibolite- facies metamorphism. The ore-bearing ultramafic is immediately underlain by dominantly sulphide-facies banded iron formation (BIF), which commonly contains nickel sulphides adjacent to its contact with mineralized ultramafic. BIF-hosted ores are formed both by physical remobilization of ultramafic-hosted sulphides and by migration of Ni and Cu into pre-existing iron sulphides.At Mt. Windarra the mineralization comprises eight steeply dipping, steeply plunging elongate oreshoots, which display a marked parallelism with major and minor fold structures in the underlying BIF. Seven of the shoots occur at or close to the base of the ultramafic pile, and are hosted by at least three overlapping flows. The zone of overlap occurs at the northern end of each flow, where picritic ultramafic, representing a dominantly liquid portion of the flow, occupies the basal contact. A gross south- north ultramafic flow direction is inferred. The eighth shoot occurs in a stratigraphically higher position within the ultramafic sequence.At South Windarra at least two overlapping mineralized flows occupy the basal contact, the ore zone having a strike extent three to four times its downdip extent. There is no obvious structural control to the mineralization."

Jan 1, 1984

Discussions of the papers with a written contribution on Paper No. 11 and authors' written replies. Also brief obituary of Dr. T. David Jones on p146.

Jan 1, 1947

By C. E. Dunn

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Evidence is accumulating that reconnaissance-level biogeochemical sampling can provide valuable insight into the chemistry of the substrate. Problems such as seasonal variations in plant chemistry and the lack of a universal biogeochemical sample medium may be circumvented by adopting normalising procedures. The planet can be divided into a few climatic zones, each of which is characterised by one or two common plant genera. If it can be demonstrated that the chemical differences between certain species of a single genus are small - as is suggested by studies of boreal forests - it would seem feasible to apply biogeochemistry as a low-density geochemical mapping tool. The technique could prove particularly useful for assessing the substrate chemistry of areas of dense forest, rugged terrain and difficult access by employing airborne sampling of trees from helicopters

Jul 1, 1991

By L. R. Chimimba

"The Trojan nickel deposit occurs within a pile of ultramafic lavas subjected to a lower amphibolite grade of metamorphism. The lavas form part of the Upper Greenstones (Bulawayan Group) of the Mazoe greenstone belt. The nickel mineralization occurs as disseminated, massive and near-massive sulphides. The massive and near-massive ore occurs along the basal contact of the serpentinite units and is overlain by the more abundant disseminated ore, which occurs within the serpentinite. The main sulphide minerals are pyrrhotite. pentlandite and chalcopvrite. Minor amounts of millerite and pvrite are present. The Ni : Cu ratio in all three types of ore averages 15:1.The intercumulus nature of sulphides in the near-massive ore and similar textures occasionally seen in the disseminated ore indicates a magmatic origin of the mineralization. The basal position of the near-massive and massive ore suggests that the sul­ phides settled out under gravity during the emplacement and crystallization of a peridotitic magma. The deposit has been deformed and some of the primary massive ore has been remobilized into veins and breccias. The disseminated mineralization now occurs mainly as blebs of sulphides intergrown with silicate minerals or as stringers of sulphides between foliation planes in the serpentinite."

Jan 1, 1984

By G. B. Hooper, G. A. Ferguson

The technical capabilities and user-friendliness of the major computer-aided mining design software systems are reviewed. Recent experiences with three systems are outlined to indicate the practical problems that arise. The examples were: Microlynx software from Lynx Geosystems at the Great Dyke platinum mine in Zimbabwe; Lynx software from Lynx Geosystems at a copper mine in central Africa; and PC-MINE software from Gemcom Services at an open-pit gold project in Western Australia. Difficulties in the use of mining design software has led to an alternative approach. Falconbridge, Canada, has developed an integrated mine-planning system on a CAD platform that encompasses ore reserve estimation, stope design, development layout and survey control. Future directions of computer-aided mining design using this basis are discussed. A major advantage of using mainstream software packages, such as spreadsheets, databases and CAD programs, is that most engineers and geologists are experienced in handling such systems in the normal course of their work.

Jan 12, 1992

By H. L. Willett

Wrapping up the symposium, covers incidence of spontaneous combustion in British mines, assessment of liability to spontaneous combustion, precautions, rate of advance, starting a line of a coalface, local heatings at roadsides, burying packs, coal headings, retreating longwall, detection and sealant coatings.

May 23, 1905

By S A. M Crawshaw, J A. B Fortune

Trackless battery powered haulage vehicles have been in operation in British coal mines principally for longwall face transfer and personnel transportation. Changes within the industry have resulted in the introduction of room and pillar coal mining methods and the introduction of increasingly heavier longwall roof supports This has resulted in the introduction of: • Battery powered coal haulage machines, which, without the need for trailing cables, increase productivity within room and pillar mining. • Battery powered longwall shield haulers which are capable of carry ing the heaviest shield supports currently being utilised within the British coal mining industry. The conventional machines have been adapted from an American design to meet the requirem ents of European legalisation. This has seen the- emphasis being placed upon the supplier with the European M achinery Directive being introduced, necessitating the assigning of a 'C E ' m ark to each vehicle. Battery vehicle technology has advanced to meet the demands of the ever changing market and will no doubt he further adapted to meet the requirement of the British coal mining industry.

Jan 10, 1996