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To extract the gold from refractory gold concentrate with high sulfur and arsenic, the gold concentrate was catalytically oxidized to expose the gold for cyanide leaching. The effects of reaction temperature, initial nitric acid concentration, reaction time and initial gold concentrate concentration on the conversion rate were studied. The results show that the appropriate conditions for the catalytical oxidation of this gold concentrate are: reaction temperature of 65 oC; initial nitric acid concentration of 25% (wt.); reaction time of 1.5 hours; initial gold concentrate concentration of 10% (wt.). Under such conditions, the conversion rate of gold concentrate is 92%. The solution can be used to prepare nano-iron oxide red pigment. Gases released in the process can be recycled and reused by oxidation absorption. A chemical background of catalytic oxidation is proposed.

Jan 1, 2014

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By S. H. Morar

Froth flotation is a physico-chemical separation process that takes place in two phases; pulp and froth phase. It is widely recognised as a complex process, due to the range of interactions present within the system. Of critical importance is the role of the froth phase within the system. The pulp kinetics governs the maximum potential recovery within a flotation cell, while the froth phase governs the selectivity via the froth?s stability. Higher froth stability improves recovery at the expense of grade, and lower froth stability improves selectivity. It is well known that the two major factors affecting froth stability are attached particles and solution chemistry. This paper looks at a flotation bank at different froth depth and frother concentrations. The air recovery to the concentrate is determined at each condition and relates the effect of the operating conditions on froth stability and transport to the amount of solids that are recovered to the froth and concentrate by true flotation. The results presented show that, for a given process objective, which in this case was a consistent mass pull profile, depending on the operating conditions, solids recovery in the pulp is affected by the air rate required to maintain the target mass pull. To a smaller extent, the changes in the pulp composition affect down-stream pulp recovery. The variation in solids recovered into the froth drives the froth stability at the start of the flotation bank, while the frother drives the froth stability at the end of the bank. The performance in between these two extreme conditions arises from an interaction of these two effects. The consequences of these interactions can give rise to counter-intuitive responses that can confound efforts to optimise the performance of the bank.

Jan 1, 2014

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By N. Nikolaeva, A. Romashev, T. Aleksandrova

Energetic characteristics identify energy consumption for destruction of prills and kinetic characteristics rate formation of finished size grade in the course of destruction and identify crushing and grinding equipment capacity. And if screen sizing or classification processes are applied in the cycle of ore preparation, then the use of characteristics of separation to size – separating characteristics – is required for theoretical description. Separating characteristics have a lower profile for ore preparation but, nevertheless, they have to be taken into account especially for balance and design calculations of crushing and grinding circuits. In most cases there are impregnations of minerals which vary widely in energy consumption and destruction kinetics and thus polyminerality must be considered as one of priority factor. Raw materials which passed through crushing and grinding processes can be assessed numerically by functions of fractional composition of two types: differential distribution function y ( €) and assay function B( c ) . A set of experiments on grinding of crushed raw materials at different time (up to various sizes) was conducted to analyze effect of grinding size of carbonaceous overburden on function y € and B ( c) as well as to justify the possibility of preconcentration of raw materials at the stage of ore preparation. Analysis of metals distribution per size grades showed that metals are concentrated in size grades of less than 0.315 mm (which is equivalent of cut point for this type of raw material), however, there is no overgrinding and oversludging of material, and enriched product for its further processing can be excluded with the help of classification. The stage of size segregation was tested as a method of preconcentration of raw materials for optimization of ore preparation and further separation.

Jan 1, 2018

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014

By Junwei Han, Kai Xue, Wenqing Qin, Tan Xu, Fen Jiao, Lianbing Cai, Wei Liu

"The research aimed at solving the problem of the stacked spent magnesia-chrome refractories using in non-ferrous metal smelters, which contain various heavy metals and are considered as a hazardous waste. The purpose of the research is to recycle the spent refractories environmentally and economically using gravity separation and flotation to obtain metal concentrates for smelting and using chloridizing volatilization to remove the trace metals from tailings, providing raw material to reprocess magnesia-chrome refractories. In the course of the study, laboratory techniques for the preparation of experimental samples of spent magnesia-chrome refractories were developed including the sequence of operations of material grinding, gravity separation, tails regrinding, flotation, filtration and subsequent unification of concentrates, filtration and chloridizing volatilization of tails, and collection of volatiles. Laboratory tests carried out on several types of samples of spent magnesia-chrome refractories from different smelters showed that gravity separation provided increase in quality of concentrates including about 80% metals (including Ag, Pb, Bi) and flotation separation provided increase in recovery of concentrates under the condition of 200g/t of emulsified kerosene, and 500g/t of combined collector. Based on combined technology of gravity and flotation separation, about 90% metals were recovered from the refractories by a closed-circuit test and the total concentrates contained 40% metals, which can be returned to smelting process as a feeding. Because a small amount of metal in raw materials will seriously affect the performance of refractories, chloridizing volatilization is necessary for removing the remaining 10% metals from tails mixed 8% coke and 13% magnesium chloride at a temperature of 1200°C. Thus, the tailings can be reused as a raw material for new refractories.INTRODUCTION Magnesia-chrome refractory has been used extensively in various industries such as secondary metallurgy, non-ferrous furnaces and cement making due to their high temperature stability, low thermal expansion and outstanding erosion-corrosion performance at high temperatures (Gotod et al., 2005; Vezza et al., 1997; Gregurek et al., 2015). Generally, the magnesia-chrome refractories are produced from a mixture of magnesia and massive variety of chrome ores. However, massive chrome ores are being depleted throughout the world. Even more serious is that the heavy metal chromium (Cr) can transfer into soil and water, which will have an influence on the survival and development of human beings (Zhao et al., 2006; Jiang et al., 2004; Qintie et al., 2013). As a result, regulations treating spent magnesia-chrome refractories as potentially hazardous waste are being enforced, making their disposal difficult and expensive."

Jan 1, 2018

By F. Henríquez

Traditionally, the implementation of an automated control for a ball mill has been a challenging one. First, it must be capable of processing a variable SAG mill feed while at the same time avoiding to become a process bottle neck. Second thing is, it must deliver an adequate quality product (P80) to the process downstream. Then the ball mill itself and its associated classification equipment has problems of its own: it must maintain adequate control of cyclone?s pressure, density and pump-box level with often, less manipulated variables than needed, namely, variable pump speed and the opening/closing of cyclones. Thus, it becomes a non-linear multi-variable type of process with often too multiple and contradictory control objectives to satisfy simultaneously. On top of that, to extend cyclones availability and yet, maintaining their performance, is must both for process and maintenance purposes. Trying to solve the puzzle, Minera Los Pelambres implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control in two of its newest ball mills, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Because of their differences in processing capacity, size and topology, two different stabilizing-control strategies were developed, tested and tuned. Hence, for both control approaches their implementation process, main results, areas of applicability, limitations and their key performance indicators are discussed further. This paper also discusses the need of such advance control technologies in the mining industry, including the impact of these technologies on best practices for their implementation, operation and long term sustainability

Sep 1, 2012

By M. Kanuchová, J. Briancin, M. Achimovicová

"Faculty of Mining, Ecology, Process Control and Geotechnology, Technical University, Košice, Slovakia An industrial eccentric vibratory mill was used for direct and short-time mechanochemical reduction of ilmenite concentrate (FeTiO3) and anatase (TiO2) with magnesium metal powder in order to reduce Fe and Ti resp. and hereby to convert them to the more soluble phases suitable for further hydrometallurgical processing. X-ray diffraction analysis of FeTiO3 after 60 min of milling with Mg confirmed the presence of Fe0 and Mg2TiO4 phases and for TiO2 after 180 min of milling the new TiO and MgO phases have appeared. X-ray photoelectron spectroscopy has detected Fe0 (metal) and Mg2+ species which are corresponding to the product of FeTiO3 mechanochemical reduction. The product of TiO2 mechanochemical reduction has revealed XPS spectral lines corresponding to Ti2+, Ti4+ and Mg2+ species on its surface. Morphology of mechanochemically reduced samples was studied by scanning electron microscopy analysis. Subsequent leaching of mechanochemically reduced FeTiO3 and TiO2 was performed in dilute HCl and H2SO4 at 80oC and compared with mechanically activated samples. The recovery of Ti has reached 100% for FeTiO3 and 79% for TiO2 after 60 min of leaching. Based on this study the flowsheet for possible processing of natural refractory titanium ores patented by author was adapted and documented. INTRODUCTION Ilmenite (FeTiO3), along with rutile (TiO2) represents the most important titanium resource necessary for titanium industry, for production of titanium metal, alloys and pigment grade TiO2 which are becoming more important and versatile for various industries such as an aircraft and aerospace, navy, chemical, automotive, medical and offshore wind industries, for machine and plant engineering and architecture as well, mainly due to high corrosion resistance. Pigment grade TiO2 is utilizing in pigment, plastic, glass, paper and rubber industries (Zhang, 2011). There are obvious research efforts for development of the potential alternatives to the expensive thermo-chemical commercial processes of titanium raw materials processing. Zhang (2011) has summarized conventional thermo- a electrochemical processes which involved a combination of pyrometallurgical, hydrometallurgical and electrometallurgical technologies and highlighted the improved hydrometallurgical routes promising for commercial application in the future. Such improvement could also be mechanical activation of FeTiO3, TiO2 by high-energy milling which causes their structural disordering, the changes of physical and chemical properties, consequently and has a positive effect on the dissolution kinetics (Achimovicová et al., 2014a, 2017, Baláž, 2008). The various types of mills such as a planetary ball mill, a vertical ball mill, a drum mill, an attritor were used for mechanical activation of FeTiO3 as a pretreatment process for subsequent leaching (Achimovicová et al., 2014)."

Jan 1, 2018

By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By S. Vimalnath

The bioremediation capability of Pseudomonas aeruginosa cells was investigated for the biosorption of lead ions from aqueous solution. The various parameters such as pH, kinetics, biomass loading and concentration of lead affecting the biosorption process were studied. Complete bio removal of lead could be achieved for an initial concentration of 12.4 mg/L at pH 6.2, corresponding to typical industrial effluents. The biosorption isotherm followed Langmuirian behavior and the Gibbs free energy (?G) was determined to be-30.8 kJ/mole, indicative of chemisorption between the functional groups of the bacterial surface and lead. The biosorption kinetics adhered to a pseudo-second order model. The possible mechanisms of interaction of lead with the bacterial cells are discussed. A carbon paste electrode with a coating of biomass was developed for lead ion detection in aqueous solution using cyclic voltammetric technique. Concentrations of lead up to 5x10-5 M could be successfully detected using cyclic voltammetry, which could be improved to a detection limit of 1x10-8 M adopting differential pulse anodic stripping voltammetry (DPASV). Keywords: Pseudomonas aeruginosa, bioremediation, lead, voltammetry

Sep 1, 2012

By E. Szelag

The adsorption and stabilization of mineral dispersed systems by using Pluronic copolymers with different molecular weights and EO content has been studied. The role of sequential adsorption of EO-PO copolymers and cationic surfactant (CTAB) on the carbonate particle properties and in determining the stability of their suspension was studied with particular attention to the conformation of the polymer at the solid-liquid interface. The purpose of this work was to investigate the flocculation phenomena, influence of polymer molecular size on stability of suspensions of magnesite and dolomite and the effect of addition mode of polymer and surfactant. The suspension stability measurements and the determination of sedimentation speed were carried out using an optical analyser (Turbiscan). In most of investigated cases, the biggest floccs and the fastest sedimentation were found for low concentrations of copolymers.

Jan 1, 2014

By V. A. Ivanova, T. N. Perunkova, N. O. Dorozhanova, G. V. Mitrofanova

"Oxyethylated compounds are used as reagents-regulators in the flotation of non-sulfide ores, in particular, apatite-containing ores. Thus, the necessary degree of selectivity in the flotation separation of two calcium-containing minerals of apatite and calcite is achieved only by using, in addition to a collector, regulators-reagents from the nonylphenol ethoxylates class. In order to establish the most optimal structures, this paper presents a comparative assessment of the physical-chemical and flotation properties of several classes of oxyethylated compounds - alkylphenol ethoxylates, aliphatic alcohol ethoxylates and oxyethylated carboxylic acid. The authors have studied their dispergating ability with respect to the air phase and calcium soaps of the carboxylic collector. Dependences of foaming properties of regulators on the degree of oxyethylation have been determined. Adsorption isotherms of sodium oleate on apatite and calcite in the presence of regulators have been obtained. It has been shown that the presence of oxyethylated compounds in the solution reduces the amount of the adsorbed fatty acid collector. The influence of the considered classes of regulators on apatite flotation has been studied. The interrelation of flotation properties of oxyethylated compounds and their molecular structure has been established.INTRODUCTION Flotation plays a leading role in complex apatite-containing ores processing. However, two calcium-containing minerals - apatite and calcite, which compose apatite-carbonate ores, are characterized by close flotation properties. Selective separation of these minerals is a difficult task, the solution of which is impossible without using reagents-regulators. One of the ways to ensure the selectivity of the flotation separation of calcium-containing minerals is the use of reagents-depressants such as sodium silicate, starch, cellulose derivatives, and others (Liu et al., 2016; Rao et al., 1989). Another method is the application of nonionic reagent regulators (Filippov et al., 2016; Filippova et al., 2014; Ignatkina, 2017), which contribute to the adsorption of the ion collector (Filippov and Filipova, 2006 Rao and Forssberg, 1997) and stability of formed froth (Sis and Chander, 2003)."

Jan 1, 2018

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018

By M. Kinnunen

Handling of municipal solid waste (MSW) and control of its potential resources is becoming increasingly important in modern society. The OECD (Organization for Economic Co-operation and Development) average on municipal waste produced in 2003 was that of around 570 kg per inhabitant. In European Union countries around half amount is of MSW landfilled. In Finland still 88% of MSW was landfilled in 2004. Since incineration reduces MSW volume significantly while producing heat energy, it has become one of the most common waste handling techniques. The shortcoming of incineration is however, that incinerated MSW is often not pre-sorted and it produces slags and ashes as side streams from which recovery of metals is difficult. This paper looks into possibilities of scrap metal recovery for recycling from municipal solid waste incineration (MSWI) bottom ash. In order to do that, a flow sheet of physical separation methods was developed and tested with Finnish rotary furnace MSWI bottom ash. In addition, an empirical model for estimation of the recoveries of scrap metals with physical separation methods for treatment of MSWI bottom ash was developed. According to the results of this study, for 1 Mt of incinerated MSW with 30% mass reduction, a minimum resource potential of 100 kt for magnetic metal scrap of roughly 24 % grade and about 19 kt of non-magnetic metal scrap of roughly 65 % grade. In other words, 57 kg magnetic scrap and 12 kg non-magnetic scrap per inhabitant at the mentioned grades, respectively. Although wide variations of parameters affect the MSWI bottom ash quality, it can be said that a considerable amount of metals is drained into MSWI bottom ash. Results of this study show that from MSWI bottom ash significant material streams metal scrap can be reintroduced into the resource cycle which would otherwise be lost.

Jan 1, 2014

By Andrei Yevdokimov, Ivan Sidorov, Olga Lanchakova, Olga Khmelnitskaya, Tatiana Chikina

"The paper focuses on the results of the research on development of hydrometallurgical process of gold recovery from refractory sulfide flotation concentrates based on fine and ultrafine grinding. Refractory concentrates (the degree of refractoriness is 16.9%-82.6%) were chosen for testing. The efficiency of the process based on fine and ultrafine grinding to treat flotation concentrates with gold intergrown with sulfides and rock-forming minerals was shown. Based on the test work conducted, the process option was chosen. In included grinding of flotation concentrate to the size of 98% minus 20µm in a bead mill, lime treatment with air blow, CIL, filtration and detoxification of liquid phase of the slurry. This process (compared to the basic option) provides the recovery of gold from 82.6%, up to 94.0% and decreases the residual grade in the tailings from 3.3g/t to 1.1g/t at the consumption of 12.6NaCNkg/t. Based on the results of the test work and pilot plant testing, project design criteria of flotation circuit at a Russian plant was developed."

Jan 1, 2014

By B. Y. M. Bueno

Biosorption of heavy metals can be an effective process for the removal of heavy metals ions from aqueous solutions. In this study, the adsorption properties of Rhodococcus opacus biomass for Pb(II) and Cu(II) ions was investigated. The effects of initial pH, initial metal concentration and biomass concentration on biosorption efficiency were studied in a batch system. Results showed that the initial pH would play an important role in the Pb(II) and Cu(II) ions removal by R. opacus and affected the zeta potential of R. opacus. The equilibrium adsorption was reached with 60 min. The Langmuir and Freundlich models were used for describing of adsorption isotherm data. The maxi-mum adsorption capacities of biomass were determined as 94.3mgg-1 and 32.2 mgg-1 for the Pb(II) and Cu(II) ions, respectively. The experimental data fitted to pseudo second order kinetic model. Adsorption capacity of Pb(II) ions was found to be reduced by the presence of the other competing metal ions in the system. The FT-IR results of R. opacus biomass showed that biomass has different functional groups and these groups are able to react with metal ions in aqueous solution.

Jan 1, 2014

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003