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By Lorna Ortiz-Soto

A series of titiania- and silica-supported Au, Pt and Pt-Au catalysts prepared through different synthetic routes have been investigated in terms of their structural properties, adsorption of CO, and catalytic activity for the selective catalytic reduction of NO by propylene and the oxidation of and CO. Catalysts prepared by incipient wetness impregnation from individual Pt and Au precursors, exhibited characteristics very similar to those of monometallic Pt catalysts. This behavior is consistent with a model in which the two metals remain segregated due to their miscibility gap, and only Pt participates in the adsorption of CO and the reactions under consideration. In contrast, catalysts prepared from a Pt2Au4(C=CtBu)8 organo-bimetallic cluster precursor exhibited different behavior both in terms of CO adsorption and their catalytic activity for the three reactions examined. The combination of the kinetic, spectroscopic and structural characterization data suggests that in this case Pt and Au remain intimately mixed in the form of Pt-Au bimetallic particles, and that the presence of Au modifies the behavior of Pt.

Oct 1, 2003

By Owen Owens, W. P. Armstrong

The process of arriving at the size and grade of: (a) a newly-discovered body of mineralization, (b) a potential ore resource, (c) an orebody proposed for mining, or (d) the ore reserves in a mine, requires fundamental geological, and geometrical determinations as well as physical and chemical analyses. This paper outlines geological and geometrical features considered critical, in the authors' experience, in realistic reserve determination. These are discussed under the headings "The Four Cs". They include the Character, type or nature of the mineralization; the Continuity of various types of mineralization in the deposit; various key concerns in the Calculation besides the mathematics; and the Classification section which refers to basic considerations in classifying a mineral estimate. It is suggested that the responsibility for the calculation of a Resource or Reserve should be that of a geologist experienced in the ore type under review. Further, it should be the responsibility of the board of directors of the company owning the deposit to ensure that a sufficiently experienced person is chosen to carry out the process.

Jan 1, 1993

By Enrique I. Acuña

Creighton Mine is part of the mining history of Sudbury with more than 100 years of operation. Currently the deeper levels of the mine are reaching the 8000 ft level without implementation of mechanical refrigeration system as a result of the use of the Natural Heat Exchange Area (NHEA) over the past decades. The NHEA of Creighton Mine is part of an old block caving area divided into 4 blocks of trenches that were used to extract the ore. Currently, it is used year round to condition the outside temperature before the airflow enters the fresh air system of the mine. As the mine is progressing deeper, underground temperatures in the lower levels are starting to approach the limit of Vale?s guidelines for working in heat. This paper presents the study developed to improve the management of the NHEA to obtain cooler temperatures at the intake of the ventilation system and outlines the impact to the mine in terms of the additional level(s) that could be operated underground without the use of mechanical refrigeration. This is another of the efforts currently under development for energy conservation and to reduce the capital and operational costs of Creighton Mine while extending the expected life of the mine.

Oct 1, 2010

By C. J. Cattarello

"The Langmuir Mine is located seventeen miles south-east of South Porcupine in Langmuir Township.The property was developed as a Joint Venture between Noranda Mines Limited and the International Nickel Company of Canada with Noranda responsible for the operation of the property.The Mine came into production in June 1973 at a rate of 700 tons per day of nickel ore.MINING The mining method selected for the Langmuir Project was a sub-level retreat method. This consisted of driving sub-levels longitudinally in the ore body at 35 foot, intervals with the sub-levels being connected by a ramp from each main level for the use of trackless mining equipment.GENERAL GEOLOGY OF THE LANGMUIR MINE The deposit is situated about 1,000 feet west of the shore of Carmen Bay at the south of Nighthawk Lake in Langmuir Township. The area is underlain by andesite and rhyolite flows with iron formations which are intruded by gabbro, diorite, peridotite and late precambrian diabase dikes."

Jan 1, 1975

By W. Marnette

The copper demand is booming. New epicentres with strong dynamic economic growth have arisen in China and other emerging markets. Furthermore, Europe contributes to higher copper demand due to positive economic growth. China and India are therefore expanding their smelter industries, with the backing of a coordinated policy of global raw material sourcing, which includes investments in raw material deposits and state-run measures to support their international trade and competition. Likewise, Europe faces scarcity of copper raw materials. The copper industry in Europe is historically grown and shows excellence in environmental protection and technical leadership. Recycling has always been an important sector. This reiterates the recycling-know-how which exists in the European sector. However, Europe still relies on importing a considerable amount of raw materials from foreign countries. As a result, the global competition for copper and copper raw materials has increased. Tough competition as regards industrial location and costs, the emergence of corporate concentrations and the use of protectionist trading practices by countries like China and India, which distort the markets, now determine the picture. Hence, a copper smelter in Europe is forced to develop tailor-made concepts to safeguard and improve its international competitive position. It is imperative that this is also flanked by improved conditions on the local level and a European raw material policy which takes account of the changed situation on the world market.

Jan 1, 2007

By Michael Samis

NOFLEX valuation results ? CF deviations and net CF risk discount factors ??Cash flow deviations indicate average cash flow variability. ??Net cash flow riskdiscount factors (NCFRDFs) indicate the size of the risk adjustment applied to a cash flow. NCFRDFs profile should change with variations in cash flow uncertainty since the risk adjustments applied to the project cash flow reflect investor sensitivity to uncertainty.?DCF and RO will often produce different NCFRDFs for the same project since they use different methods of risk-adjustment.

May 1, 2006

By R. Liu

As Building Information Modeling (BIM) becomes widely adopted by the construction industry, it holds undeveloped possibilities for supporting Facility Management (FM). Some FM information systems on the market claim to address the needs for FM requirement. However, the question of whether the functionalities provided by the current BIM-based FM software companies are those actually required by the FM Professionals still need to be answered. The data is required by FM professionals in the operation and maintenance phases of facilities and type of maintainability problems that frequently occur, which can be solved early in design phase, have not yet been addressed. The aim of this paper is to clarify the frequently occurring maintainability problems and to investigate the potential areas that can use BIM technology to solve the maintenance problems in early the design phase. A survey was conducted to collect perspectives from the industry practitioners for the maintenance problems and their frequency. The survey results indicated that maintainability considerations should be taken into consideration during the facility design phase. The results also address the perceived areas by practitioners that need maintainability consideration in design phase.

Aug 1, 2013

By Christopher H. Clement

The International Commission on Radiological Protection (ICRP) is an independent, international organization that advances for the public benefit the science of radiological protection, in particular by providing recommendations and guidance on all aspects of protection against ionizing radiation. This presentation touches on aspects of The 2007 Recommendations of the ICRP, a fundamental document that lays out the system of radiological protection for all exposure situations and types, and focuses on other recent publications relevant to the uranium industry. Of particular relevance are the 2009 ICRP Statement on Radon and the accompanying report on lung cancer risk from radon.

Aug 1, 2010

By K. A. Hughes

Under the oxidizing conditions of the McClean Lake Tailings Management Facility (TMF) hydrocarbons entrained on the surface of tailings material from mill processes are gradually converted to soluble bicarbonate ion. This has been observed to be a process occurring over approximately three years likely encouraged by the presence of a microbiological community within the tailings mass and in the water column. A recent tailings sampling campaign has provided evidence that bicarbonate ion is participating in the conversion of gypsum to calcite. In older tailings, equilibrium with calcite appears to be controlling the terminal bicarbonate ion concentration.

Aug 1, 2010

By Patrick R. Stephenson

The Australasian Code for Reporting of Mineral Resources and Ore Reserves (the ?JORC Code?) has been operating successfully for 14 years, and has an ancestry dating back over 30 years. Together with complementary developments in stock exchange listing rules, the Code has brought about substantially improved standards of public reporting by Australasian mining and exploration companies. The Code is regarded as a world leader in its field, and has been used as a basis for the development of resource/reserve reporting standards in other countries. The reasons for its success are varied, foremost amongst them being its adoption in full by the Australian and New Zealand Stock Exchanges, and the ability and willingness of mining industry organisations to bring Competent Persons to account when necessary. The latest revision of the JORC Code was undertaken in 2002/03, based in part on releases of upgraded reporting standards in Canada, United Kingdom/Western Europe and South Africa, and the 2003 edition is expected to be released mid-year. Two of the more significant changes are: the introduction of a requirement for a Competent Person to be responsible for the documentation upon which Exploration Results are reported; and inclusion in the definition of a Competent Person of a reference to ?Recognised Overseas Professional Organisations?, being overseas professional organisations to which Competent Persons may belong for the purpose of preparing documentation for the submission of reports to the Australian Stock Exchange.

May 1, 2003

By P. M. Chapman

Risks to aquatic receiving environments from uranium mining and milling fall into three categories: physical (habitat change), chemical (e.g., uranium, selenium, total dissolved solids [TDS], metals including vanadium), and radiological. Although all categories of risk need to be managed, chemical risks are the most significant and are typically chronic rather than acute. For instance, selenium toxicity is primarily manifested as reproductive impairment due to maternal transfer, resulting in embryotoxicity and teratogenicity in egg-laying vertebrates. Risk is best assessed using a weight of evidence approach focused on ecosystem services. Risk management should be based on both risk assessment and adaptive monitoring.

Aug 1, 2010

By I. Bakry

Uncertainty is an inherent characteristic of construction projects. Neglecting uncertainties associated with different input parameters in the planning stage could well lead to misleading and/or unachievable project schedules. The objective of this paper is to present a new approach towards scheduling repetitive construction projects while accounting for uncertainty. The paper presents an algorithm that quantifies anticipated delays resulting from different sources of uncertainty in the form of fuzzy time buffers. Through inserting the time buffers in strategic places in a time schedule, the algorithm provides protection against those main anticipated delays. The presented algorithm comprises two integrated components, a scheduling component responsible for producing a basic Linear Scheduling Method (LSM) schedule with deterministic activity durations, and a buffer component that handles fuzzy buffers sizing and insertion. The presented algorithm offers four different buffer insertion techniques covering different cases of interrelations between successive activities. The algorithm is implemented in a spreadsheet application, which automates calculations, yet allows users to fine tune the algorithm to fit the project at hand. With a focuses on highway construction projects as an example of repetitive construction projects, this paper accounts for sources of uncertainty such as weather, site conditions, change orders and equipment related delays. A hypothetical case is studied and explained to further demonstrate how the proposed algorithm works.

Aug 1, 2013

By Trung Nguyen

Midwest is a unique uranium deposit with exceptionally high arsenic content. The ore body is located 17km west of the McClean Lake operation. The McClean Lake mill will be modified to process Midwest ore and handle solid wastes coming from the Midwest water treatment plant. This paper describes the modifications required of the McClean Lake mill, process challenges associated with treatment of the arsenic, and the possibility of recovering nickel and cobalt as a by-product. It also reviews the complexity in the design of the Midwest water treatment facility which incorporates reverse osmosis technology with conventional physical-chemical water treatment.

Aug 1, 2010

By Rebecca L. Jones

The paper addresses the application of XPAC AutoScheduler at the Fort Hills Energy Oil Sands Project to complete fast turn around ?what if? scenario testing of different mine schedules. Traditional scheduling approaches involve engineers making a ?best guess? at the required mining sequence, loading this sequence into a scheduling package and testing the results to determine if the schedule meets corporate objectives. This process is iterative and can be very time consuming. Autoscheduling techniques, on the other hand, are based on the engineer pre defining the mining rules and constraints of the deposit. The software then automatically selects a sequence of mining which the schedule should try and achieve, based off specified corporate objectives. Under this system the engineer is able to adjust the objectives and rules to evaluate numerous scheduling scenarios quickly and easily. An XPAC AutoScheduler model was built, documented, and implemented by Runge and Petro-Canada Oil Sands Inc. personnel in a month. It is currently being used by Petro-Canada Oil Sands Inc. to run multiple schedule scenarios, most taking less than ten minutes configure and ten minutes to schedule. The results of each schedule are tabulated with supporting graphs on; the bitumen grade profile, strip ratio, ore inventories and mined tonnage. In addition to this, the block model may be animated to show the progression of the resources mining the schedules.

May 1, 2008

The Boleo project is located in Mexico close to the town of Santa Rosalia on the Baja Peninsula. The Boleo deposit contains copper, cobalt, zinc and manganese values as oxides with minor sulfides. The Boleo deposit is metallurgically challenging due to: 1) the requirement to recover four separate metals; 2) the presence of high levels of clay in the deposit resulting in difficult solid-liquid separations, and; 3) the need to use seawater for the bulk of the processing. Baja Mining, Bateman Engineering and SGS Lakefield Research have collaborated to develop and test a process flowsheet to recover copper, cobalt, zinc and manganese products at Boleo. The key steps in the flowsheet are: ? Feed preparation (scrubbing and ball milling of oversize) in copper raffinate ? Ore leaching using oxidative and reductive leaching ? CCD washing using high rate thickening technology ? Copper SXlEW ? Treatment of a bleed solution for cobalt, zinc and manganese recovery The process for cobalt, zinc and manganese recovery involves iron and aluminum removal followed by cobalt/zinc bulk extraction using CSIRO's DSX solvent extraction system and selective zinc and cobalt stripping. The zinc strip solution is evaporated to produce zinc sulfate monohydrate crystals to market and cobalt is recovered via a further SXlEW process as high purity metal. Manganese is precipitated as manganese carbonate from the DSX raffinate solution. This paper will review the Boleo process flowsheet and provide detailed results from the 2006 pilot plant operation conducted at SGS Lakefield in Canada.

Jan 1, 2007

By K. C. Sole

In most copper solvent-extraction operations, an important consideration in choice of extractant is the requirement for high selectivity of copper over iron. Ester-modified aldoxime extractants presently offer the best Cu:Fe selectivity. In some plants, however, the process feed liquors contain significant amounts of manganese but little iron. Although manganese is not chemically extracted by oximes, trace amounts are carried over to the electrowinning circuit by physical entrainment. This may result in anodic oxidation of manganese which, in turn, can cause oxidative degradation of the organic phase when returned to the solvent-extraction circuit in the spent electrolyte. Many of these operations prefer to operate with higher levels of iron reporting to the advance electrolyte, as appropriate control of the Fe(II)/Fe(III) couple will ensure that manganese remains in the benign Mn(II) form. A new reagent, LS 4202, designed by Cytec, now offers the possibility of tailoring the iron co-extraction, so that appropriate Cu:Fe selectivity can be achieved in the solvent-extraction operation to maintain an electrolyte Fe:Mn mass ratio of >10:1, while retaining the other benefits offered by ester-modified aldoximes. The results of an integrated solvent extraction-electrowinning pilot-plant trial are presented, in which the performances of the conventional extractants ACORGA® M.5774 and LIX® 984N are compared with LS 4202. The Cu:Fe selectivity is demonstrated, along with results on the transfer of other impurities to the advance electrolyte.

Jan 1, 2007

By Ahmad Hemami

A working code is developed to simulate the forces that are involved in the process of penetration of a bucket into bulk media during loading and excavation. The result of this work can be integrated with the simulation software that many manufacturers of heavy earthmoving machines introduce for training purposes. The simulator programs for machines such as backhoes, loaders, LHDs and the like, used for operator training, are usually only based on the kinematics of the machine. As a result, there is no indication of the effect of the medium when the cutting tool of such a machine touches the excavation material. This is like moving the machine in the air. Feeling the resistance force of medium to cutting by a bucket or blade during loading and excavation is more realistic, both mentally (by vision) and physically (feeling resistance in pedals and levers). The results from force simulation can be used by feedback in creating simulated resistance in these training gears, similar to what is done in flight simulators for aircrafts. In addition to serving for the above purpose, the results of this work can be used as a tool for examination and verification of the effect of a control policy for automation of loading and excavation of bulk media. So far no commercial product has been introduced that has such a capability, despite some extensive research on the subject.

Aug 1, 2013

By M. D. Evans

"Note: The views expressed herein are those of the author, not of the Government of CanadaThe mining industry has a significant opportunity to capitalize on past learnings to build better social relationships. The industry’s relationship with society is critical and under pressure. Rising levels of public opposition and social conflict are already having material impacts on operations around the world. The industry has an opportunity to shape the future direction of this social engagement, build public trust, and proactively respond to a material risk to operations, but first it needs to better understand the nature of the challenges and the urgency of addressing them.RÉSUMÉ L’industrie minière a actuellement une excellente occasion de tirer profit de ses expériences antérieures pour établir de meilleures relations sociales. Les relations entre l’industrie et la société sont critiques et elles subissent de grandes pressions. L’escalade de l’opposition par le public et les conflits sociaux ont déjà des impacts physiques sur les opérations partout à travers le monde. L’industrie a l’occasion de façonner la future direction de son engagement social, d’accroître la confiance du public et de répondre de manière proactive à un risque matériel aux exploitations, mais elle doit tout d’abord mieux comprendre la nature des défis et l’urgence de les traiter."

Jan 1, 2015

By C. Barlow

The White Mesa Mill (WMM) began operating in 1980 as a regional processing mill owned by Energy Fuels Nuclear, Inc. Original mill design was for 656,000 Mtpa of U ore producing 1,250 tpa of U3O8 concentrate. Sustained market downturns delayed facility upgrades during most of the 1980s and 1990s. The new owners of WMM, Denison Mines, elected to advance the regional mill concept in 2007 with the modernization of these facilities. This paper details decisions taken and lessons learned in plant redesign, choice of leading-edge instrumentation, motor controls and process automation, training and some example benefits from process control stabilization.

Aug 1, 2010

By W. Qin

The nucleation of d hydride in Zircaloy-4 has been studied using electron backscatter diffraction. Hydrides prefer to nucleate at intergranular rather than intragranular sites. (0001) a -Zr//(111) d -ZrHx is the most common crystallographic relationship. The hydride platelets are generally interlinked each other and form a chain-like configuration. Based on thermodynamic model, the formation mechanisms of the hydrides at different sites and the interlinked structure were analyzed. We found that the misorientation of two adjacent grains has a crucial effect on hydride nucleation sites, and the tensile stress near the tips of hydride platelets is a key factor affecting the appearance of interlinked structure.

Aug 1, 2010