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By D. Murray

A 2-hectare uranium tailings area has been reclaimed. The exposed tailings of 1.4 hectares were capped with glacial till and vegetated with grasses and legumes. The water running through the tailings was diverted around the tailings in a line ditch and treated with sodium hydroxide and barium chloride. Difficulties occurred in placing the till capping because of the low bearing strength and the uneven surface of the tailings. This led to varying thicknesses of till and the need for manual labour in some areas. Total reclamation costs were $32,200, with vegetation establishment costs at $13,700 per hectare. This report provides a record of work for use in assessing the long-term suitability of these treatments.

Jan 1, 1979

By R. Laucournet, E. Billy, M. Joulié

Today Li-ion batteries are considered as one of the most attractive available energy storage solutions. However in order to overcome environmental, legislative and economic issues, the management of used batteries has to be considered and mainly the recycling. The present paper deals with the recycling of used Li-ion batteries and the recovery of high value metals from active materials of electrodes. Lithium nickel cobalt aluminum oxide (NCA) and lithium manganese nickel magnesium oxide (LMNM) cathodes, which contain most of valuable elements typically used in the composition of active materials for Li-ion batteries are investigated by a hydrometallurgy route. The process is divided into two steps: the materials leaching and the elements recovery by a selective chemical separation. Some experimental parameters (acid nature, concentration, time and temperature) are studied to determine the most efficient conditions of dissolution. Then, the valuable elements such as nickel, cobalt and manganese are selectively recovered with a high efficiency close to 100 % and with a high purity by precipitation. By this study, an adaptable hydrometallurgy process can be defined according to the composition of Li-ion batteries to recycle.

Jan 1, 2014

By J. A. Finch, M. Mimezami, M. S. Hashemi A.

The adsorption of magnesium and calcium ions on sphalerite and pyrite is discussed. These ions are common in process water and often considered be detrimental in sulphide flotation. The study attempts to characterize the adsorption mechanism, which has been less studied than the oxide system. Generally for oxides metal ion uptake occurs when cations are hydrolyzed. Our findings reveal that magnesium and calcium adsorb on sulphides at pH below hydrolysis, but adsorption is not chemical. At higher pH, charge reversal occurs that does correspond to presence of hydrolysis products. Advances

Jan 1, 2009

By J. Dennett, M. Faris, M. Antonio, M. Collins, N. Tuffrey, R. Ellenwood, V. Reddy

"In January 2012, AngloGold Ashanti Córrego do Sítio Mineração, with assistance from Sherritt International Corporation, commissioned a new autoclave for pressure oxidation of refractory gold concentrate at the Córrego do Sítio operation in Brazil. Start-up of the plant occurred in a few weeks and enhanced gold recovery was realized almost immediately, with 94% gold extraction achieved in carbon in leach (CIL), compared to less than 70% without pressure oxidation. This paper describes start-up and commissioning of the plant and provides an overview of plant performance over the last five years.INTRODUCTION In 2008, AngloGold Ashanti purchased the former São Bento property from Eldorado Gold, which, along with AngloGold Ashanti’s existing Córrego do Sítio mine, was renamed AngloGold Ashanti Córrego do Sítio Mineração (AGA Mineração). Later that year, the Sherritt Technologies division of Sherritt International Corporation (Sherritt) was contacted to begin batch and continuous pilot plant tests to determine the amenability of the AGA Mineração refractory gold concentrates to the pressure oxidation process. Based on the results of the batch and pilot plant tests, AGA Mineração requested basic and detailed engineering studies to be conducted by Sherritt, eventually leading to commissioning of the plant in January 2012. AGA Mineração’s plant is located in southeastern Brazil in the state of Minas Gerais, near the city of Belo Horizonte. AGA Mineração`s Phase 1 mine plan covers three sites in the Laranjeiras, Carvoaria Velha and Cachorro Bravo ore bodies, and is designed to process 60,000 tonnes of refractory gold concentrate per year to produce 140,000 ounces of gold per year with an 11 year life of mine (AngloGold Annual Financial Statements, 2010). Recovery of gold at AGA Mineração is based on Sherritt`s pressure oxidation technology for refractory gold concentrates (Berezowsky et al., 1991; Collins et al., 2011a; Collins et al., 2011b). This process had previously been applied to the recovery of gold at the São Bento site (Carvalho et al., 1988; de Silva et al., 1989), in a plant that was operational between 1986 and 2007 (Silva et al., 2004)."

Jan 1, 2017

By W. de Klerk, M. B. Thorpe

Golden Star Resources Bogoso operates in Ghana’s Western Region. The gold recovery plant includes; a flotation circuit producing a concentrate for the BIOX® process that oxidizes sulphides before a CIL circuit; and a dedicated CIL circuit. BIOX® uses bacteria, therefore water from the BIOX® and CIL plants remained separated; CN water could not be introduced into the flotation / BIOX® circuit. The operation built a process water inventory with high TDS and installed a process water treatment plant (PWTP). Water was released in compliance the permits but containing some thiocyanate. The PWTP brine was returned to the TSF, further exacerbating the TDS. The operation experienced a drought removing the traditional water sources; the team evaluated the options to maintain production - various water streams were laboratory tested provided options for water use. The paper presents the story (treatment chemistry and process chemistry) of continued operations by treating stored water and PWTP discharge water with peroxide; brine usage within the CIL circuit, which increased gold recovery (laboratory testing) and reduced the TDS. Water flows were further modified to include hydraulic tailings re-mining to a CIL circuits. Details of the recovery, basic chemistry and costs savings are provided.

Jan 1, 2014

By D. Van Tonder

ABSTRACT The comparative economics of ion exchange and direct precipitation have been analyzed by developing indicative CAPEX/OPEX models for typical alkaline leach uranium circuits. An agitated tank ore leach application is considered, comparing resin-in-pulp and direct precipitation as recovery options. Capital and operating cost estimates are derived from rates and factors used in recent studies and projects. The analysis showed the main economic drivers to be the ore grade and resin loading. The resin loading is impacted by the prevalence of competing ions, especially chloride. At resin-in-pulp solution chloride concentrations below 3 g/L and uranium grade below 640 g/t U3O8, resin-in-pulp is more economical, whereas at chloride concentrations above 3 g/L, direct precipitation is more economical.

Jan 1, 2012

By G. D. Garland

"IntroductionALTHOUGH the presence of rock salt in the Carboniferous basin of northern Nova Scotia has been known for at least one hundred and twenty years, and salt has been mined at Malagash continuously since 1919, certain characteristics of the deposits make exploration by drilling or surface examination difficult. The surface rocks of the basin are, in general, of Pennsylvanian age, while the salt occurs in the Mississippian Windsor group. The latter rocks are brought to the surface only along anticlinal folds, or as irregular fault blocks. Because of the limited areal extent of these Windsor exposures, and their complicated internal structure, geophysical surveys, especially gravimetric, can be of considerable aid in outlining the more favourable areas.The present paper describes the results of recent investigations by the Dominion Observatory, in cooperation with the Nova Scotia Department of Mines. It includes a regional study of that section of the Cumberland basin lying between Springhill and Malagash ( Figure 1), and a much more detailed survey of the immediate vicinity of the Malagash deposit itself. This deposit had been studied by Miller (6, 7) with the torsion balance nearly twenty years before, and a direct comparison between the results given by the two types of instruments is therefore possible."

Jan 1, 1955

By H. F. Maulson

For the benefit of those who are not familiar with the history of the western Provinces-Manitoba, Saskatchewan, and Alberta-as regards our natural resources, a few words of explanation may be in order before taking up the consideration of the Mines Act of 1930. In 1867, The British North America Act was passed by the Imperial Parliament. That Act, which is our constitution, created a union between the provinces of Nova Scotia, New Brunswick, and Upper and Lower Canada (now known as Ontario and Quebec respectively) under the name of the Dominion of Canada. Provision was made therein for embracing other parts of Canada from time to time. That portion of Canada which today comprises the Provinces of Manitoba, Saskatchewan, and Alberta and the lands to the north of them, was then known as Ruperts Land and the North West Territory. In the year 1670, King Charles II had granted by Letters Patent to Prince Rupert and his associates, known as ?The Governor & Company of Gentlemen Adventurers of England, Trading into Hudson's Bay?, commonly known as the Hudson's Bay Company, the lands and territories therein described, being roughly all the lands adjacent to and west of Hudson's bay; also the gold and silver to be found or discovered therein and other rights as more fully described in said Letters Patent. The land so granted was called 'Ruperts Land'.

Jan 1, 1930

By W. Almdal

"To compete in the ever expanding global market, companies must continuously improve. Benchmarking, a tool that can help determine where the best areas for improvement are, is more than comparing measures, it is comparing how business is carried out and how decisions are made. The key to success is in integrating benchmarking results into the organization, so that those most affected by the results own them and are empowered to use them as a positive change agent. This is a necessary step to achieving substantive change to practices and achieving optimum performance improvement. IntroductionBenchmarking is a powerful tool that can assist in the continuous goal of improvement. Benchmarking is more than comparing productivity rates or unit costs, it is seeking out best practices and assimilating them into a business to provide a positive change agent.Benchmarking is a continuous process - is time consuming, labour intensive, and requires a lot of discipline. There are no easy answers and no easy solutions, just a lot of work. The results, however, are nothing short of spectacular. More and more companies are adopting benchmarking practices because it is a key tool of the learning organization and will become part of the way business is done, part of the way it is managed. Business must change to stay ahead or to get ahead and benchmarking can accelerate the process of business change. Improvements in an organization can happen faster and more effectively with a benchmarking approach."

Jan 1, 1994

By I. A. Kovalevska

Considered problems: elaboration and implementation of resource-saving technologies, low-cost support systems improvement, openings security and support, based on wallrock condition control with supreme implication into the rock pressure occurrence counteraction work. Results of analytic and underground investigations using computer simulation of the finite elements in order to calculate stressstrain state of the multivariable geomechanical systems are presented. Solutions of concrete objectives are found using spatial geomechanical model of solid motion around openings, considering real geomechanical parameters formation of support forms with proper conditions of their contact and real mechanical characteristics. Ultimate solutions of resource-saving technologies implementation based on the analysis of multivariate vertical, horizontal, and reduced stresses components calculation and also near-contour rock, support bearing components and security constructions movements are found. Results of experimental investigations of combined supports and security constructions, which increase openings' stability in difficult conditions of flat coal seams are presented.

Aug 1, 2013

By J. Fixter, P. Prangnell, Z. Pinter, E. Eimer, B. Chehab

"High deposition rate Wire and Arc Additive Manufacture (WAAM) can provide benefits to the aerospace industry, including a reduction in lead time, reduced material waste and, through higher solidification rates, refinement of the as-built microstructure relative to a cast material. However, candidate 2xxx series high strength alloys for this process normally require a solution treatment, which is problematic for large near-net-shape components, and age hardening to achieve maximum mechanical properties. With each layer being subject to multiple thermal cycles, exploiting the thermal conditions in the WAAM process to avoid post-build solution treatment is therefore of interest. A solutionisation model has been developed for the WAAM process, based on diffusion controlled dissolution using DICTRA, which was validated through thermal simulations combined with 2D and 3D image analysis. The model has subsequently been used to simulate the solutionisation behavior during a typical WAAM thermal cycle and to explore what could theoretically be achieved by, for example, refining the starting microstructure.INTRODUCTION There is currently great interest in exploiting additive manufacturing (AM) in the aerospace sector due to several benefits it can potentially provide; including reduced material waste, shorter product lead times and greater design freedom (Herzog, Seyda, Wycisk, & Emmelmann, 2016). However, with aluminium alloys the material properties obtained are generally inferior to those of conventional high-strength wrought products; therefore more research is required to explore the potential for exploiting the unique process conditions in AM to improve the as-deposited microstructure. A range of AM techniques are now available (Debroy et al., 2018), which differ in terms of the feedstock type and power source and it is necessary to match the appropriate technology to a particular application. This generally requires a compromise between the build rate and shape resolution. Wire and plasma-arc additive manufacturing involves using an electric arc to melt wire onto a substrate, and fabricates a part by building up overlapping layers of deposited weld beads (Addison et al., 2015; Williams et al., 2015). The benefits of this process over other AM methods are the much higher deposition rates (e.g. kg’s/hour) achievable and lower capital equipment costs relative to powder bed techniques, which makes it suitable for large scale applications. However, limitations include a lower part complexity, lower solidification rates and a greater need for post-process machining (Frazier, 2014)."

Jan 1, 2018

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By H. J. B. Couto, J. G. S. Puelles, M. L. Torem, R. H. Rojas, A. G. Merma

Understanding the limits of fine particle flotation is fundamental to achieving a significant and selective separation. Conventional flotation processes are not suitable to treat these particles because of their low collision efficiency. This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. In this sense, this study assesses the effect of current density and pH on bubble size in a binary electroflotation cell. An increase in the bubble generation rate was reported with an increase in current density. In addition, at acid pH values, the size of oxygen bubbles increased and conversely decreased at basic pH values; this may be due to the electrostatic attraction between the oxygen bubbles and the anode resulting in a greater nucleation time. An opposite trend was observed with the hydrogen bubbles. These results are in agreement with their electrokinetic studies, which reported that at acid conditions the bubble surface may be positively charged for both the hydrogen and the oxygen bubbles. Finally the bubble size was slightly affected by the electrolyte concentration, resulting in smaller diameter bubbles at higher concentrations.

Jan 1, 2016

By T. Motegi

Semisolid casting provides grain refinement of the cast structure and prevents macro-segregation. The conventional semisolid slurry is obtained by electromagnetic or mechanical stirring. In our process, the magnesium alloy (AZ31) slurry is made using an inclined cooling plate instead of the conventional methods. The slurry obtained is cast into a twin-roll caster and makes a continuous sheet of 2 or 3 mm thick. The most important factors that influence the sheet casting are the casting temperature and twin-roll speed.

Jan 1, 2007

By Edward Rybinski

Compañía Minera Antamina is a polymetallic mining complex that produces copper and zinc concentrates as primary products and molybdenum and lead/bismuth/silver concentrates as by-products. In 2007, Metso Process Technology and Innovation (PTI) was contracted to increase SAG mill throughput by integrating and optimising blast fragmentation, crushing and grinding for the harder M4/M4A (CuZn) ores. Following the implementation of recommendations provided by Metso PTI, the SAG mill throughput increased from 2750tph to reach an average of 3600tph for the remainder of 2007. Due to continued application of mine to mill integration and optimisation philosophy, by 2010, the concentrator consistently exceeded the target of 4400tph while processing harder CuZn ores.

Jan 1, 2012

By M. Mahdi, L. So, A. MacMillan, D. Metcalfe, J. Woloshyn, D. Sauter, N. Uys, JP. Janse van Rensburg

For city smelters, with limited real estate, efficient slag cleaning furnaces followed by water granulation to produce an iron silicate product is the preferred process approach. Water granulation, however, consumes large volumes of water and requires high maintenance due to abrasive slag/water slurries. Air granulation offers an alternative to water granulation, which eliminates water use and has low maintenance requirements. Although full-scale operation has not been implemented for copper slags, full-scale operation for platinum group metal (PGM) converter slag has been implemented. A review of full-scale air granulation performance for PGM converter slag is provided. Based on PGM converter slag granulation performance, parallels to copper slag granulation are drawn and full-scale operation for copper slag is modelled using computational fluid dynamics (CFD). INTRODUCTION Typical slag management practices in the copper industry include dumping, slow air cooling, and water granulation, as shown in Figure 1. Dumping is the most commonly used slag handling method for most metal production plants, but presents challenges including the requirement for a large slag pit, requirement for expensive/high-maintenance “hot” mobile equipment, risks associated with transportation of molten slag, and no value recovery from slag as a sellable by-product or from slag as a source of heat.

Jan 1, 2019

By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By W. R. Tyson

Imperfections such as lack-of-fusion and undercut are inevitable in field welding of pipelines. Above a certain size, such defects must be removed or repaired. In the present state of the art, determination of allowable defect size is done by Engineering Critical Assessment (ECA). This requires measurement of toughness, and comparison of toughness with crack driving force. ECA methods used in current international pipeline standards will be reviewed and compared.

Jan 1, 2010

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By W. D. Bonisteel

In 1976, Rio Algom Limited began the expansion of uranium production facilities at Elliot Lake. Quirke Mine was the only property in operation at the time, and plans were made to expand its milling capacity from 4,500 to 7,000 tons of ore per day. Following this expansion, other properties in the area will be reactivated to fulfill long-term contracts for uranium. As part of the expansion program, it was decided that in view of the escalating cost and impending shortage of energy, heat reclaim and conservation would be employed wherever practicable. In general terms, heat reclaim applications fall into three main classifications: ventilation, utility and process. Two of the ventilation applications and one process application will be described in some detail. Several other systems will be presented briefly as a matter of general interest. Some future possibilities will also be mentioned, together with their potential for economical heat recovery.

Jan 1, 1979