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By Mohamed Hamoud

Relative permeability curves represent an important element of special core analyses, but challenges remain in obtaining valid results and the extrapolation and use of existing permeability results is problematic. This situation is compounded in cases where core properties are altered from changes in effective stress. During the production of oil and gas reservoirs, the effective stress changes as a result of changes in pore pressure or temperature. Therefore, changes in rock properties such as porosity and permeability will occur and will consequently influence reservoir performance calculations. An experimental program was carried out to understand the behavior of dense, reconstituted sand samples at low effective stress states. Drained triaxial compression tests were set up to study the effect of stress alteration on relative permeability data through porous media. Initially, a saturation stage was performed followed by isotropic loading to bring the core sample to reservoir fluid and stress conditions. Then, while axial (deviatoric stress) loading was applied to the sample, a series of absolute and relative permeability tests was performed under steady state flow at different levels of strain during pre and post peak shearing stress. The stress-strain behavior results from the study revealed that the absolute permeability decreased during isotropic loading (compaction) and increased during shearing (dilation). However, the shape of relative permeability curve changed from contraction to dilation and showed higher initial kro and the lower initial kro respectively. The goal of this project was to understand the behavior of both absolute and relative permeability at different stresses. It is expected that geomechanical processes will be adopted for special core analyses to support the current integration of geomechanics into reservoir engineering. This will be required if, during SAGD, conventional and/or unconventional reservoir simulation, reservoir engineers implement a proper set of relative permeability data at each in situ state of stress, instead of constant curves throughout the field?s life.

Jun 1, 2012

By Jarret Thomson

An understanding of groundwater flow is essential for many aspects of mining. This is especially true for the process of shaft sinking through the sandstones of the Manitou Falls Group in the Athabasca Basin of northern Saskatchewan. Experience has shown that the hydraulic conductivities of these sandstones can be relatively high, especially in zones containing natural fractures. To develop a better understanding of the inflow potential into a shaft, a laboratory testing program was undertaken to investigate the hydraulic conductivity of fracture core samples from the Manitou Falls Group. This program involved the measurement of hydraulic conductivities under steady-state flow conditions, while cycling the effective confining pressure across a span that is representative of in-situ conditions. The change in fracture aperture was simultaneously recorded at each confining stress level. It was found that existing relationships relating aperture and flow did not accurately capture the behavior of the samples tested. The effects of fracture staining and infilling were also investigated, and were found to have a notable impact on the hydraulic conductivity.

Jun 1, 2012

By J. R. Smith

"The Lake Dufault orebodies were discovered by deep surface diamond drilling. When a reasonable amount of outline drilling had been completed, the decision to go into production was made. The fact that shaft sinking, lateral development, the detailing of the orebodies and stope preparation were to be carried out as rapidly as possible necessitated very close scheduling.After a study of varions possible mining methods, an open-stoping system using long-hole blasting was chosen. Diesel-powered Transloaders were selected for the mucking and transportation of ore from the drawpoints to the orepass.At the time of writing, the choice of mining method appears to have been fully justified, although more time will be required to arrive at true operating costs and efficiencies."

Jan 1, 1966

By Louis R. Bernier

Most systematic studies carried out on passive treatment systems incorporating the use of limestone drains, under aerobic or anaerobic conditions, essentially deal with the treatment of effluents from mines in the USA. A limestone drain typically comprises a trench filled with crushed limestone rocks surrounded by impervious materials. In the case of anoxic drains, the trench is generally isolated under a geomembrane liner covered with soil. Contaminated mine effluents flow by gravity towards these limestone drains where the passive treatment consists in bringing the carbonates into solution, thus increasing the pH and alkalinity. Factors to be considered in the design are: chemistry of the contaminated mining effluent ([metals, [Al], [sulfates], dissolved oxygen, acidity, pH), desired residence time, nature of the rock, grain size, density, void ratio and mass of the limestone rock used, alkalinity, life span and hydraulic behaviour of the drain. Certain secondary effects (saturation by sulfates, co-precipitation, adsorption) may either be beneficial (lowering the sulphate and metal load) or harmful (armoring the limestone rock and clogging of the drain). This paper gives a brief status report on the available knowledge on the use of limestone drains for passive treatment of mining effluents heavily loaded with metals. Examples given include the old Lorraine mine (Ni-Cu), Témiscamingue, where limestone and dolomite rock drains were installed in 1998 when a cover with capillary barrier effects was placed over the tailings site.

Nov 1, 2002

By Michael Magerstädt

Material loss by abrasion of contact surfaces of pipes, chutes, pumps, and other equipment in contact with ore is one of the main reasons for downtime of mining operations. Abrasion protection materials in use range from expensive tungsten carbide overlay to hardened steels, ceramics, as well as polymers, particularly polyurethanes (PUR). This paper describes abrasion protection products made from High Performance Polyurethane Elastomers. An interior pipe coating was developed that exhibited outstanding abrasion resistance and an extremely high adhesion to steel. Years of field testing in oil sands tailings as well as applications in slurry lines (e.g., phosphate slurries) have proven the performance of this material. A proprietary field joining process was developed and successfully applied in the field. This joining process requires only one field weld per joint very similar to the joining of uncoated pipe. No internal re-coating is necessary adding savings during pipe laying to the significant savings of reduced down time. Using the building-kit chemistry of polyurethane synthesis, similar high performance elastomers were used to extend the life time of ball mills. An intelligent system was developed in which wear parts contain sensors reporting the actual wear thereby optimizing maintenance interval leading to significant cost savings for the operator. Test data as well as field experience with High Performance PUR Elastomers for abrasion protection in mining are presented.

Aug 1, 2013

By D. R. Schmitt, N. Ong, R. S. Kofman

Shales and mudstones comprise about 75% of all the sedimentary rocks. In, particular, organic rich shales are considered as a petroleum source rock and more recently with the advent of hydraulic fracturing technology to be a reservoir in their own right. In this sense, the aforesaid motivates our work with laboratory measurements of elastic properties of these geologic materials, which are known to be anisotropic. As such, assuming Vertical Transverse Isotropy (VTI) symmetry, the dynamic and static moduli of a series of cores from various geological formations in Alberta, Canada are simultaneously investigated as a function of confining pressure using the ultrasonic pulse transmission method and strain gages. Dynamic moduli were obtained from ultrasonic P- and S-wave velocities measured on a prism cut with faces perpendicular, parallel and oblique to the assumed vertical axis of symmetry. Static moduli were calculated from strain-stress curves obtained along the directions perpendicular and parallel to the assumed axis of symmetry as well. Velocity measurements show that samples are highly anisotropic, but that the pressure-dependent behaviour of the wave speeds differs. VP(90°) and VSH(90°) both with layer parallel propagation and polarizations change little with pressure while VP(0°) and VS(0°) (both with layer perpendicular propagation) display significant nonlinear responses particularly at pressures < 25 MPa. These characters transfer to the derived full set of elastic constants. In order to effect a proper comparison of the dynamic and static moduli, we convert the dynamic elastic constanst to linear compressibilities pependicular (Kdyn1) and parallel (Kdyn3) which are directly comparable to the static tangent compressibiities obtained by differentiation of the observed strains. Both sets highlight the anisotorpic nature of the material but most interestingly Kdyn1 _ Ksta1 but Kdyn3 > Ksta3 by nearly 40% for one of the samples. The other samples measured respond similarly suggesting that conceptually the structure of such materials could be considered to be constructed of alternating stiff or compliant layers. This finding has implications in the response of the formation to stress particularly during hydraulic fracturing and the interpreation of acoustic logs in providing appropriate measures of elastic properties for engineering purposes.

Jan 1, 2015

By D. G. Sediako

Chemical composition and the casting/rolling production routes determine the cost and properties of the wrought material. For example, the coarse-grained structure frequently associated with DC casting requires complex rolling schedules to refine the grain size. Hot forming (rolling/forging/extrusion) results in a strong crystallographic texture, which is responsible for the tension-compression strength asymmetry frequently exhibited by magnesium alloys. Understanding the influence of alloy composition on texture evolution during forming provides useful practical information to optimize industrial hot-forming technologies for magnesium alloys. In this study, a series of Mg-based alloys containing varying combinations of Al, Rare Earths, Zn, Ca, and Sr were subjected to identical casting and extrusion processes in order to isolate the effects of alloy composition on texture evolution. Textures were measured by neutron diffraction at the NRC Canadian Neutron Beam Centre. The ability of neutrons to penetrate deeply into materials allowed information to be retrieved from all regions of the bulk specimens without destructive and time-consuming sectioning operations, thereby providing true bulk texture data. {1010} , (0002), {1011}, and {1012} pole figures were generated for all of the as-processed alloys, from which Orientation Density Functions were obtained. The were then used to reconstruct the pole figures and to extract semi-quantitative texture data showing how the (0002) and {1010} planes align themselves with respect to the extrusion axis. It was found that varying the concentration of aluminum (3-4 wt%) and Rare Earths (2-3 wt%) in AE alloys had a weak effect on texture development. All of the alloys showed similar magnesium extrusion textures, in which the (0002) poles align themselves preferentially with the extrusion axis. The substitution of Sr for Rare Earths also did not have a significant impact on texture development. On the other hand, while the presence of small amounts of Zn and Rare Earths did not have a strong effect on texture development, alloys with higher concentrations of these alloying additions (in combination) showed an enhanced tendency for the {1010} poles to align themselves with the extrusion axis. The addition of Ca also enhanced the alignment of the {1010} poles with the extrusion axis. These textures can complicate further processing and introduce a significant anisotropy that could influence creep properties.

Jan 1, 2007

By J. A. Hillier

"IntroductionThe purpose of sampling is to remove a portion of material from a stream which is representative of it in size, moisture and mineral content.To prevent the effects of segregation, generally caused by the way in which a conveyor, pipe or launder is loaded or directed, the sampler should cut proportionally the entire cross section of the stream.If one conveyor transfers to another at a right angle, fines may be dropped on the near side, and the coarse material thrown to the opposite side. Segregation can also occur as a result of the motion of a conveyor belt passing over the idlers causing the coarse material to roll to the sides of the belt.When slurry changes direction of flow in a launder or pipe, the heavier and coarser fraction will centrifuge to the outside of the curve and tend to remain on one side of the stream. Similarly, if two streams joining in a common launder are not mixed at the point of confluence, they will continue down the launder unmixed . This effect is particularly noticeable in a plastic lined launder.Therefore, a proportional sample is usually accomplished by a constant rate of cutter travel across the entire stream, making certain that the cutter is not full or splashing over before reaching the end of travel.The cutter should operate on a constant interval based on time, tonnage and uniformity of flow. The opening should be at least three times the width of the largest piece to be sampled. The cutter width is more critical with ore samples where particle sizes are large. With slurry samples, the opening is usually much larger than the minimum in order to obtain sufficient samples"

Jan 1, 1989

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016

By R. J. Chase, C. Davies

"Abstract- The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilirnajaro International Airport and in close proximity to the towns of Moshi and Arusha . The graphite mineralization is hosted by relatively undeformed linear Proterowic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasibility studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 8o/o graphitic carbon . Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.ln addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence."

Jan 1, 1994

"Some of the tools developed for the processing of nickel laterite ore by resin-in-pulp (RIP) may be applicable to the remediation of metalliferous mine drainage (MMD). In both cases, recovery of metal value and production of a stable waste stream appropriate for long term storage is desired. MMD typically has the additional challenge of management of toxic low-value metals. Seen in this light, innovations in RIP reactor configuration, selective elution strategies and novel synthetic ion exchange resins become useful tools for taking on the MMD challenge in a way that maximizes both environmental and economic benefit. INTRODUCTIONAcid mine drainage (AMD) is a common problem in any country with significant past mining activity. When sulphide containing minerals, tailings or slag are exposed to water, oxygen and sulphur oxidizing bacteria, AMD will result. Abundant and reactive iron sulphide minerals leach first, providing acidity and the ferrous/ferric couple that can enhance the oxidation kinetics of other minerals. If this runoff contacts encounters acid consuming carbonates or silicates, the acidity may be neutralized, but certain heavy metals remain in solution and can continue to be an environmental hazard (Gray, 1997). For this reason, the remainder of this paper will refer to the broader term metalliferous mine drainage (MMD) rather than acid mine drainage. In either case, such drainage, containing high heavy metal concentrations and often significant acidity, is toxic to aquatic life and can lead to significant damage to ecosystems and to public watercourses. MMD is a problem most commonly associated with now defunct sulphide mineral mines, but similarly toxic streams can result from many types of waste, such as poorly stabilized leach tailings, slag heaps, and coal flotation tailings (Johnson and Hallberg, 2005; Lee et al., 2002; Sainz et al., 2002; Schüring et al., 1997). In any case, the management and remediation of MMD is an important ongoing problem for the resource industry, particularly for the many mines in Canada closed before the advent of more stringent environmental standards. MMD remediation represents a significant long term expense for the resource industry. Multi-disciplinary efforts to understand and mitigate this problem range from creation of artificial wetlands (Poulin and Lawrence, 1996; Sheoran and Sheoran, 2006) to sophisticated biochemical reactors and precipitation processes (Hatami, 2010). Certain remediation technologies such as ion exchange offer methods to make a saleable product by recovering valuable dissolved metals. This paper will show how these technologies can help defray the cost of remediation, and offer potential to turn a dangerous waste stream into a useful product."

Jan 1, 2012

By Aysan Molaei, Kristian E. Waters

"Solvent extraction is the one of the most common techniques for recovering metal ions from aqueous systems. However, it is not efficient in the extraction of low concentration metal ions from aqueous solutions. Predispersed solvent extraction (PDSE) is an alternative method for solvent extraction which implies colloidal liquid aphrons as extracting agents in order to reach higher interfacial area and lower reagent consumption. This work investigated important parameters in PDSE of nickel ions from dilute aqueous solutions by fractional factorial design of experiments. Four experimental parameters, the initial extractant concentration, initial surfactant concentration, equilibrium pH and phase volume ratio (organic to aqueous ratio) were investigated. The important parameters were determined as well as important interactions between these parameters. It was found that extractant concentration, phase volume ratio, and equilibrium pH are the most significant experimental parameters. However, the interaction between surfactant concentration and other parameters was determined as significant interactions.INTRODUCTIONNickel is one of the key components found in cars, mobile phones, rechargeable batteries, kitchen appliances, and steel industry (Anyadike, 2002). It is one of the most important metals produced by Canada which is in the five top nickel producers in the world. Despite a 24% decrease in the nickel prices from 2011 to 2014 the nickel global mine production increased by 36% between these years (U.S. Geological Survey, 2015; Nickel - Statista Dossier, 2015), which shows the increasing demand for nickel. This high demand leads producers to consider the production of nickel from low grade ores and other secondary sources such as process wastewaters. The removal of nickel ions from process wastewater is also important due to environmental considerations. Nickel is known to be a human carcinogen and it may cause serious lung and kidney problems, pulmonary fibrosis, gastrointestinal distress, and skin dermatitis if it exceeds the critical level (Borba et al., 2006; Fu & Wang, 2011)."

Jan 1, 2016

By Carlos Palacios M., Brian K. Townley

"Abstract - The mainland Aysén region of Chilean Patagonia (44°15&apos; - 47°30&apos;S) is a representative segment of the South American active continental margin, distinct with respect to northern and central Chile. Mineralization consists mainly of polymetallic deposits, with important Zn-Pb mines and more recently discovered Au-Ag deposits, unlike the central Andes, which are dominated by Cu mineralization. On a regional scale, rocks may be grouped in four main map units: 1) the Paleozoic metamorphic basement; 2) upper Jurassic-Cretaceous calc-alkaline volcanic and marine sedimentary rocks; 3) the Patagonian batholith, and 4) upper Cretaceous to Miocene basalts and marine and continental sedimentary rocks. The upper Jurassic-Cretaceous rocks and the Patagonian batholith formed in a volcanic arc and back-arc setting superimposed on the Paleozoic metamorphic basement.Based on geographic location and geologic and tectonic setting, ore deposits in this region are assigned to three groups, from south to north: El Faldeo, Fachinal, and El Toqui. The El Faldeo group (south of 47°05&apos;S) includes upper Jurassic Zn-Pb skarn and associated polymetallic massive sulfide vein deposits locally overprinted by Au-rich epithermal mineralization, hosted by volcanic and sedimentary rocks and/or by rocks of the metamorphic basement. The Fachinal group (46°05&apos; - 47°05&apos;S) consists of volcanic-hosted lower Cretaceous Au-Ag epithermal deposits, except for the Mina Silva and Manto Rosillo deposits, which are metamorphic basement-hosted Zn-Pb skarns. The El Toqui group (44°30&apos; - 46°05&apos;S) comprises lower Cretaceous Au-rich Zn-Pb skarns and associated polymetallic veins, as well as Au-Ag-rich epithermal deposits, hosted by volcanic, intrusive, and marine sedimentary rocks. Galena lead isotopic signatures for each deposit group indicate a decreasingly radiogenic trend from south to north, suggesting different lead sources or differences among underlying crust. Three metallogenic provinces and two metallogenic epochs are proposed for the Aysén region: the El Faldeo metallogenic province of Late Jurassic age; and the Fachinal and El Toqui provinces of Early Cretaceous age. Résumé - La partie continentale de la région d’Aysen (Patagonie chilienne, 44°15&apos; - 47°30&apos;S), est unsegment représentatif de la marge continentale active d’Amérique du sud, différent des segments du nordet du centre du Chili. La minéralisation, qui consiste essentiellement en des dépôts polymétalliques, avec d’importantes mines de Pb-Zn, et des dépôts d’Au-Ag récemment découverts, différe de celle des Andes centrales où domine la minéralisation cuprifère. A l’échelle régionale, les roches peuvent être regroupées en quatre unités cartographiques principales : 1) le socle métamorphique paléozoïque, 2) les roches volcaniques calco-alcalines et les sédiments marins du Jurassique supérieur-Crétacé, 3) le batholite patagonien, et 4) les sédiments marins et continentaux ainsi que les basaltes du Crétacé supérieur-Miocène. Les roches du Jurassique supérieur-Crétacé et le batholite patagonien, formés dans un contexte d’arc volcanique et d’arrière-arc se superposent au socle métamorphique paléozoïque.Fondé sur la localisation géographique ainsi que sur le cadre tectonique et géologique, les dépôts de minerais de cette région se répartissent en trois groupes, du sud au nord, El Faldeo, Fachinal et El Toqui. Le Groupe El Faldeo (sud de 47°05&apos;S) contient des skarns à Pb-Zn du Jurassique supérieur associés à des veines de sulfures massifs polymétalliques, localement recoupées par des minéralisations épithermales, riches en Au, et contenus dans des roches sédimentaires et volcaniques et/ou dans des roches du socle métamorphique. Le Groupe Fachinal (46°05&apos; - 47°05&apos;S) consiste en des dépôts épithermaux Au-Ag, se trouvant dans des roches volcaniques du Crétacé inférieur, excepté pour les dépôts de la Mine Silva et Manto Rosillo, où des skarns à Pb-Zn, se trouvent dans le socle métamorphique. Le Groupe El"

Jan 1, 1999

By Mory Ghomshei

Pebble Creek Geothermal Power project is associated with a massive recent volcanic eruption in Southwestern British Columbia Canada. Slim holes drilled to depths 1100 m in the prospect area, show very high temperature gradients around 80?100?C/km. The temperature and chemistry of the Pebble Creek hot springs indicate the possibility of a steam reservoir in the prospect area. In addition to high temperature gradients, presence of host rocks with high permeability, along with abundance of recharge waters (from the Lillooet River) provides clear signature of a high-grade geothermal power reservoir at depth 2000 to 3000 m. Data show that over five hundred Megawatt of green power can be generated from the prospect area in a commercially viable manner. The generated power will be base-load, which in comparison with large hydro has the advantage of lower capital costs and a significantly smaller footprint. The final hurdle to overcome, before starting the development phase, is deep exploratory drilling for resource confirmation. This paper is a summary of the data available on the Pebble Creek geothermal power prospect, presented in the context of viability of the resource for large-scale commercial power generation.

Aug 1, 2013

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By D. M. Maijer, S. M. Mohseni, A. B. Phillion

The microstructure evolution kinetics of aluminum alloy B206 during artificial aging has been investigated using non-isothermal calorimetry. A combination of differential-scanning calorimetry (DSC) and tensile tests have been utilized to develop an Avrami model to predict the precipitation kinetics as a function of the thermal processing parameters. The Avrami coefficients, found based on a Kissinger analysis, compare well against those reported in the literature for aluminum-copper alloys. The rapid precipitation kinetics predicted by the Avrami model at temperatures higher than 200°C were assessed through a qualitative comparison against hardness measurement results. In contrast to the continuous hardening observed at 150°C, the material softens with continuing heat treatment at 250°C resulting in an overaged state. This can be attributed to the rapid precipitation kinetics at this temperature, leading to the termination of the precipitation-hardening effects at early stages of artificial aging.

Jan 1, 2015

By G. J. Desroches, E. Ozberk, M. J. Collins, B. D. Krysa, I. M. Masters

The zinc refinery of Hudson Bay Mining and Smelting Co., Ltd. went through a major modernization in 1993, when the roaster and the calcine and fume leach circuits were replaced by a new Sherritt zinc pressure leach plant. The HBMS plant, in Flin Ron, Manitoba, represents the first commercial application of the Sherritt two-stage zinc pressure leach process, with /00% of the zinc concentrate feed processed in autoclaves. The process design of the new plant required definition of the deportments of elements such as antimony, arsenic, chlorine, cobalt, fluorine, germanium, magnesium, manganese, selenium, tellurium and thallium. This paper describes the deportment of these elements in the commercial zinc plant during the first nine months of pressure leach operation, and compares these results with operations prior to the introduction of pressure leaching, and with the results of tests carried out in the She"itt laboratory during the process development phase.

Jan 1, 1995

By Technische Universität Braunschweig, K. Saksl, J. Furste, P. Eschenbacher, F. Brunke, D. Wolter, M. Kohnke, C. Siemers, J. Kiese, M. Schlemminger

"In general, titanium alloys combine outstanding mechanical properties with corrosion resistance and biocompatibility and are, therefore, used in many challenging applications. Nevertheless, for special products, well-tailored properties are required which might not be achievable by a specific design so that new or modified alloys are needed. In this overview paper, alloy development strategies performed at the Institute for Materials of the Technische Universitat Braunschweig are discussed at different examples, namely, (1) oxidation-resistant, microstructural-stabilized and cold-workable alloys for exhaust applications, (2) aluminum- and vanadium-free, medium-strength and cold-workable alloys for implants and osteosynthesis applications and (3) free-machining alloys by the addition of particles with low melting points for non-safety critical light-weight constructions to replace heavier steels, e.g. in automotive applications. A special focus is set on the alloy development techniques and the analyses carried out to achieve well-balanced properties by the optimization of the alloy compositions. INTRODUCTIONTitanium belongs to the allotropic metals and can therefore exist in two different equilibrium lattice modifications. Pure titanium crystallizes at 1668°C in a body centered cubic (bcc) structure called ?- titanium which at 882°C transforms to a hexagonal close packed structure (hcp), the a-titanium. A martensitic ?-to-a-transformation is possible at large cooling rates. This thermally induced hexagonal martensite is called the a'-phase. The transformation temperature named ?-transus-temperature (T ?) can be influenced by alloying elements (Peters & Leyens, 2002).For titanium alloy production typical alloying elements are aluminum (Al) and oxygen (O), both a-stabilizers shifting the ?-transus temperature to higher temperatures, whereas tin (Sn) and zirconium (Zr) only show a limited influence on the ?-transus temperature. The ?-stabilizing elements are subdivided into two groups: Niobium (Nb), molybdenum (Mo) and vanadium (V) stabilize the ?-phase between the melting point and room temperature and are therefore called isomorphous -stabilizers. Elements like copper (Cu), iron (Fe) or silicon (Si) also stabilize the ?-phase to lower temperatures but undergo a eutectoid reaction during cooling. ?-titanium then dissociates to a-titanium and an intermetallic compound. Consequently, these elements are called eutectoid ?-stabilizers (Boyer, Welsh & Collings, 1994)."

Jan 1, 2016

By Randy Billing, J. Fraser Wilson

"IntroductionThe job of designing and implementing effective environmental management sounds like what one executive, assuming responsibility for a very sick organization with lots of potential described as, ""an insurmountable opportunity"".Effective environmental management is an opportunity, no doubt. Its an unusual, if not unique opportunity. Insurmountable? Maybe not! Indeed, in the authors&apos; experience, the keys to unlocking this opportunity are not in new or complicated technicalities; they are in the existing strengths and successful experience that one has in managing other complex and exacting management issues.To begin, it is necessary to understand what these issues of sustainable development mean to business. What is the nature of this opportunity? What makes it look unsurmountable?New Games: New RulesLawyers have described some of the new rules companies are facing and there is a new game being played; a game characterized by unique challenges.Take two, for example: • The ecological problems to be faced are Mother Nature&apos;s business, the political solutions required are our business. This combination of natural problems and political solutions requires the development of new management mechanisms, to bridge the gaps among us, as individuals, as professions, as interest groups and so on; indeed, even as countries;• and gaps there are : about as many gaps as the people involved : many of them with new and changing expectations, often mutually exclusive and not negotiable.The challenge of these relationships and communications among so many different interests is one of the keys to effective environmental management.Like any game, this one has rules and they are new, too. These rules are evident not just in new legislation - tough legislation with draconian penalties; they are also evident in new and exacting business policies, value driven and just as unforgiving of poor performance. Senior management of many companies are speaking about the role of enlightened corporate policies and how important it is for everyone involved that these policies drive and reflect business practices. Absence of day to- day behaviour which evidences the words in action, the policy on the wall of a corporate office or published in an Annual Report is first evidence for the prosecution , not the defence.The challenge of practical policies is another key to effective environmental management.This is a new game, with new rules: the challenge of change."

Jan 1, 1991

By P. E. Weidmark

"Energy, Mines and Resources Canada has published the first in a new series of reports that will examine selected mineral products that are imported.""Vanadium - An Imported Mineral Commodity"" looks at one of the 32 raw materials for which Canada currently is totally dependent on foreign sources of supply. Vanadium is used in Canada mainly as an alloying element in the manufacture of high-strength, low-alloy (HSLA) steels.The series will examine the supply systems for various selected imported non-fuel minerals, as an aid to developing policies that might lead to reduced dependence on external sources. Each report in the series will address a numberof questions:What countries do the mineral and its principal sub-products come from?How do they get to Canada?What are they used for?How vulnerable is the supply chain to disruption?Are there alternative sources?Are substitute materials available?In summary - how serious is Canada&apos;s supply problem for the mineral in question, and what should be done about it?Mineral Bulletin MR 188, ""Vanadium - An Imported Mineral Commodity"", is available for $3.00 ($3.60 outside Canada) from authorized government bookstore agents and many other bookstores, or by mail from the Canadian Government Publishing Centre, Hull, Quebec, KIA OS9."

Jan 1, 1981