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By P. Tracy

An advanced real-time monitoring system, called a "Tapblock Diagnostic System" is under development to help furnace operators manage the operation and maintenance of their tapblocks. The life of a water-cooled tap block in a smelting furnace ranges from several months to several years, depending on the operating conditions. Tapblocks are typically replaced at regular maintenance intervals; a strategy based largely on historical records and not on the actual condition of a particular tapblock. The Tapblock Diagnostic System monitors the tapblock throughout its life and accumulates probable wear events to help the operator assess the residual integrity of the tapblock. Benefits of this system include the ability to provide early warnings of tap block wear to provide improved safety and maintenance planning. Using cooling-water flow together with copper and water temperature measurements, the system performs calculations that compare the present tapblock performance with the expected operating envelope using a multivariate statistical method (Principle Component Analysis). The operating envelope is pre-calculated for a wide range of operating conditions using transient thermal modeling (Computational Fluid Dynamics). A state indicator in the form of a green, yellow and red light is used to inform operators of the tapblock performance and health status.

Jan 1, 2007

By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By F. Parada

During copper smelting and converting processes, slag generated is pyrometallurgically cleaned and then disposed, containing around 1 % of this metal. However, important amount of molybdenum initially contained in concentrates also goes to the slag phase. Research on molybdenum recovery from water granulated slags using acid leaching at low temperatures was conducted to find an efficient way for molybdenum extraction with lower magnetite in the slag. However because of the high fayalite content high acid consumption was found. Molybdenum can be recovered from solution using ionic exchange resins, but high silica content interferes with extraction. Some studies addressed to minimize silica extraction as well as alternatives of selective silica precipitation in order to develop a technically feasible process.

Jan 1, 2007

By V. Concha, M. Hashemzadeh

"The objective of this study was to gain a better insight into the kinetics of chalcocite leaching in an acidic ferric sulfate media. Chalcocite leaching in acidic media is known to occur in two sequential stages, with the first stage being much faster than the second. The leaching residue from the first stage is typically assumed to be a covellite type of material. This study hypothesized that the mineralogy after the first-stage leaching varies in response to different leaching conditions. We investigated the dependency of the mineralogy of the first-stage leaching residue on temperature and initial ferric concentration. The experimental results showed that chalcocite leaching behavior altered upon temperature and initial ferric concentration. A proposed combined reaction model was found to be able to describe the experimental data. The first stage was described very well by the shrinking core diffusion model while the second stage was described very well by the shrinking core chemical reaction model. This finding has important implications for mine operations to manipulate leaching conditions to create the desirable leaching kinetics.INTRODUCTION The kinetics of chalcocite leaching in sulfate media has been extensively studied (Cheng & Lawson, 1991; Fisher, 1994; Fisher, Flores, & Henderson, 1992; Niu, Ruan, Tan, Jia, & Sun, 2015). Sullivan (John D. Sullivan, 1930) proposed a two-stage process for chalcocite leaching in an acidified ferric sulphate solution. The two-stage leaching of chalcocite is presented as the following reactions:"

Jan 1, 2017

By R. M. Porter

PILLAR extraction at the Sullivan Mine bas been in progress for over twenty-five years and bas .involved progressively larger pillars. The largest pillar blasted to date exceeds one million tons and is described in this paper. This blast is believed to be one of the largest to take place entirely under-ground. The Sullivan Mine, owned by The Consolidated Mining and Smelting Company of Canada Limited, is located in the southeastern corner of British Columbia on the east flank of the Purcell range overlooking the twenty-mile wide Rocky Mountain Trench (Figure 1). The orebody is a bedded replacement deposit in argillites, varying in thickness up to 300 feet, but averaging about 80 feet. Above the 3900 Level, the dip varies from nearly horizontal to 40 degrees; be-low the 3900 Level it varies from 45 to 20 degrees (Figure 2). Pillar extraction follows a plan of retreating outward from caved areas. The size of each blast is determined by the effect which the removal of support

Jan 1, 1961

By MacKenzie Dickson

"INTRODUCTIONGold is found in many natural states, native nuggets, loose grain in river sands, veins in rock, as well as associated with sulphides, oxides, etc., disseminated more or less minutely.Its high value in recent years has spawned new technologies to win values from sources once considered too lean for commercial recovery. Cyanide leaching from fine milled ore or tailings, from upstream recovery operations, coupled with adsorption onto relatively coarse granules of activated carbon, concentrate the gold enough to be converted to bullion by time-honoured methods.The carbon granules are fragile. Size degradation in handling must be minimized not only to prevent loss of gold on fine fragments of carbon that could pass with the barren tailings, but to maintain adsorption efficiency. Besides, the granulated carbon itself is costly. Circular Vibroscreens are winning acceptance for dewatering carbon granules thanks to their gentle yet effective performance in gold recovery systems around the world. The system at Equity Silver is illustrative.BackgroundEquity Silver Mines Ltd., Houston, British Columbia, first began production in September 1980. In 1984, a feasibility study showed that additional gold and silver could be economically recovered through cyanide leaching of the flotation tailing.Although the carbon-in-pulp (ClP) or carbon-in-leach (CIL) process is commonly used for extracting precious metals from slurries, the use of circular vibrating screens, and Vibroscreens in particular, for the carbon circuit is an innovation that cuts costs.Rectangular vibrating screens have been the conventional separation mechanism of choice across North America. In contrast, the use of Vibroscreens has been proven to be less costly for the initial purchase and installation. Also, these circular vibrating screens require less power and less space. A description of Equity Silver Mines' process shows how these screens have been successfully integrated into the system."

Jan 1, 1989

By T. Gerritsen, C. Martinez, F. Stober, T Ma, J. R. Frias, M. Sedighy, J. Janzen

Electrode control systems regulate power by physically positioning electrodes. Due to the weight and inertia of the electrodes and hoist equipment, this is a relatively slow process where power fluctuations of less than a few seconds are not fully corrected. Nickel laterite AC furnaces operating in high voltage, shielded arc mode typically incur frequent power variations of approximately +/- 20% or more around the power set point. To provide enhanced power control, Hatch has recently supplied, at commercial scale, a thyristor-switched reactance system called an SPLC. The SPLC incorporates predictive control software to operate furnaces at the maximum transformer rating by reducing the large power swings experienced without the SPLC. The resulting higher average power enables higher production, without increasing transformer or power plant capacity. A 60 MW production version of the SPLC has been commissioned on Falconbridge Dominicana's laterite nickel furnace, yielding excellent results with a 3 to 1 reduction in power fluctuations.

Jan 1, 2005

By C. Caballero, M. Rosales, C. León, A. Valencia, R. Fuentes, A. Moyano

Slopping is the formation of waves in the converter due to the gas injection by tuyeres. Those waves produce a premature wearing of the refractory lining of the reactor due to its great amplitude. The affected zones are the tuyere line (outlet gas from tuyeres) and the front of this line. In the present work, a theoretical and experimental study is made to develop a theory that determines the variables involved in slopping, characterizing the more important parameters of operation in the phenomenon of slopping. In addition, this theory will allow for determination of new technological alternatives of the blast injection permitting to depress the slopping phenomenon.

Jan 1, 2007

Cominco began investigations about ten years ago relative to noise abatement in underground operations. As a result of intensive research, this study has advanced so that the practice now has wide application. Automotive mufflers are used on vane-type blasthole diamond drills. Exhaust hoses are attached to longhole percussion drills. Hand-held drills, such as airlegs and stopers, are equipped with mufflers which are either part of the drill, as received from the manufacturer, or are light rubber de-vices developed, fabricated and installed by Cominco. Ear defenders are in general use. The paper reviews details of practices employed, and assesses the success achieved. Noise is generally associated with some of the basic equipment used in mining. About ten years ago, in order to improve on this situation. The Consolidated Mining and Smelting Company of Canada Limited began investigations relative to noise abatement in its underground operations. As a result of intensive research, this study has advanced to the point

Jan 1, 1964

By H. A. Oaks

FROM 1921 to 1939, the aeroplane played an increasingly important role in Canadian prospecting and mine development. This service has been interrupted by the war, but undoubtedly it will be accelerated in the postwar years, if suitable aircraft are available. The purpose of this paper will be to review the uses to which the aeroplane has been put in prospecting and development in the past, and its future possibilities as an aid in prospecting. If by review, and deduction, we get a clear picture of what we expect the prospecting plane to do, we may be able to arrive at a very close approximation of its required characteristics and, from this, an idea of costs. 'Function' is defined as the mode of action by which it (the aeroplane) fulfills its purpose. We will endeavour, therefore, first to find what this purpose is, or should be, so that our expectations will not be too limited nor too great-and then find, by analysis, what performance we require in an aeroplane to meet our reasonable expectations at an economic price.

Jan 1, 1945

By Q. Han, W. Dai

Al-Ti-B type master alloys have been widely used in the grain refinement of aluminum since 1940s. The introduction of Al3Ti and TiB2(AlB2) particles reduces the grain sizes down to about 200 micrometer level and makes cold work possible. However, the mechanism for the grain refinement is still not clear, though it is believed that TiB2 in the presence of Al3Ti nucleate a-Al grains in solidification. This paper presents our finding on the formation of (Ti,Al)B2 solid solution, which leads to a proposed theory on grain refinement by Al-Ti-B type master alloys that upon addition into aluminum melt stable TiB2 particles react with aluminum slowly and release titanium into the melt. The titanium thus released in combination with titanium in the melt through dissolution of Al3Ti maintains a transient titanium-rich layer on the surface of (Ti,Al)B2. This layer offers a low crystal mismatch with a- Al and promotes the nucleation of aluminum grains.

Jan 1, 2014

By J. Karonen, M. Tiihonen, J. Guentner, L. Haavanlammi, Outotec GmbH, E. Kolehmainen

"Rare earth elements have obtained significant attention during the last few years due to predicted increase in their demand. Several projects worldwide are at pre-feasibility or feasibility stage aiming to commence production. Deposits of rare earth elements are typically complex and multi-metallic of nature. This means that production processes are often also complex and therefore, various metallurgical unit processes are needed. Outotec’s equipment and technology portfolio is very comprehensive and includes hydrometallurgical and pyrometallurgical apparatus and processes applicable to the efficient exploitation of rare earth deposits. Outotec has gained useful experience relevant to the processing of rare earths through several assignments including those for Alkane Resources Ltd. (Dubbo Zirconia Project), Greenland Minerals and Energy Ltd (Kvanefjeld Project), Frontier Rare Earths Limited (Zandkopsdrift project), Tantalus Rare Earths AG (Madagascar), Quest Rare Metals (Strange Lake project) and Orbite Aluminae Inc. (HPA project). The hydrometallurgical test work of two process flowsheets is presented in the paper. A roasting or acid baking step is common to several proposed rare earth projects. In the past, rotary kilns have been used, but Outotec has developed a new process concept to handle the rare earth material in fluid bed reactors. The basis for this development is long experience in fluid bed technology of Outotec in Germany. One advantage of fluid bed roasting is the higher throughput per unit. In combination with the roasting and baking, Outotec offers the gas cleaning and acid plant and provides a complete and closed concept.INTRODUCTIONRecovery of rare earth elements (REE) has obtained significant attention during recent years. It has been estimated that their demand will be boosted because of their need in many technology areas. REE can be utilized in magnets, batteries, displays, catalysts, optical devices etc. (Jordens, Cheng, & Waters, 2013; Zhang & Edwards, 2013). The production of REE is focused in China, which means that production outside of China is very scarce. However, there are multiple active development projects worldwide working towards production of REE containing products outside of China (Chen, 2011)."

Jan 1, 2016

By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By W. Fergusson

This paper takes a look at the use of rubber to provide corrosion resistance and wear resistance in the mining industry. The longer life and reduced down time involved with the use of rubber are stressed, and examples are given of applications in grinding mills, skips, discharge chutes and screens.

Jan 1, 1979

By Navid Bahrani

The grain-based model (GBM) has resolved the difficulty of matching both the directtension (sc) and unconfined-compressive (st strengths of typical brittle rock by providing a synthetic material that mimics deformable, breakable polygonal grains cemented along their adjoining sides with deformable, breakable interfaces modeled as smooth-joint contacts. In this paper, a GBM utilizing a parallel-bonded base material is calibrated to match both st and sc of Lac du Bonnet granite and then used to simulate a Brazilian test. The Brazilian strength (sB) is slightly overestimated and the failure mode includes ductile post-peak response that is not representative of what occurs in laboratory Brazilian tests. By reducing the grain tensile strength, grain failure occurs during the Brazilian test and a more realistic failure mode that includes brittle post-peak response is obtained. However, the unconfinedcompressive strength of the modified material is too low. Sensitivity analysis on the grain and grainboundary strength properties demonstrates that the grain tensile strength controls the sB/sc ratio. Because the grain strength is controlled by the parallel-bond properties and the lowest achievable st/sc ratio in a parallel-bonded material is ~0.25, it is concluded thatsc, st and sB for a typical brittle rock cannot be matched with a GBM that utilizes a parallel-bonded base material.

Jun 1, 2012

By B. Hart, D. J. Miller, J. T. Francis, M. C. Biesinger, Smart. R. St. C.

Diagnosis of the surface chemical factors playing a part in flotation separation of a valuable sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Time of flight secondary ion mass spectrometry (ToF-SIMS) can be used to identify sufficient particles of a specific mineral phase for reliable statistics determining a mean value for each species with 95% confidence intervals (1). Using the region of interest (ROI) facility in the Tof-SIMS software, a mass spectrum from each particle, at 1-2 monolayer sensitivity, is recorded and stored. This analysis is reported for a chalcopyrite / pyrite / sphalerite mineral mixture conditioned at pH 9 for 20 minutes in order to study transfer of copper from chalcopyrite via solution to the other two mineral surfaces since this mechanism can be responsible for their inadvertent flotation in copper recovery. Analysis from mineral selection based on specific ToF-SIMS signals (eg. Pb, Zn, Cu, Fe, Fe/Cu) indicated no statistical difference in the copper intensities on pyrite and sphalerite after this conditioning. Principal component analysis (PCA) of the ToF-SIMS imaging data identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from mass spectra recorded at each of 256x256 pixels in a selected area of particles. PCA is a better method of selecting minerals due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The method has been extended to samples from an operating plant again with excellent phase recognition and diagnostic surface chemistry.

Jan 1, 2004

By A. F. Matheson

"Bankfield Consolidated Mines, Limited, and Tombill Gold Mines, Limited, in the Little Long Lac area, Ontario, mined an orebody that was common to both. The discovery' of this orebody was made by surface prospecting in May, 1932, on Bankfield ground, following an original discovery made in the same manner on the same property on a small reef in Magnet lake in October, 1931. The production from the two mines between 1937 and 1942 was approximately 135,000 oz. gold from about 420,000 tons of ore, an average grade of 0.32 oz. a ton. Production was nearly equally divided between the two properties. Both mines are now closed, the ore exhausted.""The ore is mainly sheared and fractured greywacke and porphyry impregnated by silica and small amounts of metallic minerals. To a lesser extent there are definite quartz veins in the ore zone""(l). The metallic minerals present were principally pyrite, arsenopyrite, pyrrhotite, and native gold .As at other mines in the Little Long Lac area, an elongated, broad, deep trough of folded, steeply dipping volcanic and sedimentary rocks, striking roughly east-west and surrounded by younger granite, is host to the orebodies of the Bankfield and Tombill. In the immediate area of the two mines iron formation and conglomerate bands occur nearby both north and south of an intrusion of porphyry-Cliorite, suggesting repetition of beds and folding. Although considerable drag folding is in evidence, folding on the above scale has neither been proved nor disproved."

Jan 1, 1954

By A. B. Szwilski

The paper outlines the factors taken into account for the selection of steel arch supports. The results are based on experience using the long wall system of coal mining where roadway closure can be extreme. Results of tests on scale-model steel arches and full-scale yield elements are also presented.

Jan 1, 1979

By E. M. De Souza, P. Lausch, D. O. DeGagné, J. F. Archibald

"The potential use of industrial and municipal waste glass as a partial pozzolanic replacement for Normal Portland cement in mine backfill has been investigated. Considerable quantities of glass are currently discarded into landfill sites at high cost to municipal and industrial users with no foreseeable environmental benefits being gained by such disposal. This research study was undertaken to assess the viability of using ground waste glass materials as partial binder replacement of Portland cement fractionswithin consolidated mine backfill materials. The program was implemented to review various factors that could influence successful incorporation of glass waste replacement of cement, these factors being the feasibility of glass waste procurement, determination of process economics and the physical and chemical suitability of ground waste glass materials to generate adequate backfill strength when replacing Normal Portland cement fractions. A series of laboratory assessment trials were established to evaluate backfill component characteristics and mixture strength properties for both standard Portland cement-consolidated and blended Portland cement/ground waste glass-consolidated backfill materials. Side-by-side review of the strength behaviour of various component backfill/cement mixtures was designed to permit comparative evaluation of the capabilities of ground waste glass and Portland cement products as backfill consolidating agents"

Jan 1, 1995

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005