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By R. J. Twigg, S. D. Chang

"The production of heavy water, the moderator in a CANDU reactor, is examined following a flow sheet of a typical Canadian plant. The process involves the extraction and concentration of deuterium from natural water through a chemical exchange mechanism with hydrogen sulphide. Consequently, corrosion problems associated with sour environments – the use of hydrogen sulphide - are an everyday problem and have led to the development of a highly refined materials selection and testing program to prevent equipment from failing prematurely.IntroductionHeavy water is a naturally occurring compound in ordinary water and is formed from the combination of two deuterium atoms and one atom of oxygen. Deuterium is a heavy hydrogen atom which has a nucleus of on e proton and one neutron. Hence, heavy water is a combination of heavy hydrogen and oxygen and is chemically known as deuterium oxide. It looks and tastes like ordinary water but it freezes at 3.8°C and boils at 101.4°C. The molecular weight of heavy water is 20 as compared to 18 for ordinary water; the density of heavy water is ten per cent greater than that of ordinary water.Although heavy water and ordinary water exhibit only small differences in their chemical and physical properties, there are large differences in their nuclear properties, the most important of which is the neutron moderating ratio, used to measure the ratio o f the slowing down power to the neutron capture characteristics. For heavy water the ratio is 21000 and for ordinary water it is 50. This high moderating ratio is essential for achieving a high neutron economy. Heavy water is, therefore, chosen as the moderating and heat transport fluid in the CANDU reactor."

Jan 1, 1983

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By Samuel Frimpong

Green house gases have become a major concern within the international community over the last two decades due to their potential link to global warming. Carbon dioxide (CO2) is the principal greenhouse gas. In the Kyoto Agreement, Canada has committed to reduce emissions by 6 % below 1990 levels by 2012. This presents a serious economic challenge to Canada and Alberta. Over the next decade, oil sands production expansion, population and industry growth and energy demand will increase CO2 emissions. Current and future CO2 emissions and their economic implications in Alberta will be critical in formulating a comprehensive and balanced policy for dealing with concerns in this area. Disposal of carbon dioxide (CO2) in land aquifers is a potentially viable option for Alberta in dealing with long-term CO2 emissions. Studies have confirmed the existence of appropriate aquifers in the Alberta Basin for CO2 storage over a long geological period. Carbon dioxide is an ideal candidate for aquifer disposal because of its high density and solubility in water at relatively high pressures. In this study, the authors develop a computer simulation model of a scaled aquifer disposal system. The scaled model consists of an injector well, aquifer environment with dominant Ca++ and Mg++ cations. Liquefied CO2 is injected at an appropriate pressure and concentration through an injector well model. The injected CO2 migrates from the point of contact between the injector well and the aquifer domain to the main regime of the latter. The rate of migration is a function of porosity, permeability, cations, aquifer fluid flow regime and CO2 injected pressure. These models are validated using flue gas data from the 546 MW Wabamum Power Plant in Alberta. The total energy requirements for aquifer CO2 disposal system are distributed between a minimum of 105 MW and a maximum of 172 MW, with a mean of 132 MW and a coefficient of variation of 10%. The results show that there is significant variability in all the energy requirements for the CO2 disposal system. The total energy requirements for the disposal system as a fraction of the total power generated by the Wabamum plant of 546 MW could be between 0.19 and 0.32. This is a very significant energy requirement and thorough analysis must be carried out to reduce this variability and energy requirements.

May 1, 2001

By T. H. North, A. G. Glover, R. J. Pick

"Girth welding operations represent the rate-limiting step in pipeline construction. A joint industry-university program was set up to establish the field welding characteristics of large-diameter, high-strength line pipe.Theoretical work carried out at the University of Waterloo showed that pipe wall thickness and joint misalignment prior to welding has a marked influence on the lifting stresses acting on the root pass of girth welds. Pipe diameter and pipe ovality had negligible effects. Super-position of lifting and residual stress (caused by the fusion welding operation) highlighted regions of the weld bead most susceptible to hydrogen-induced cracking.The field welding characteristics of 1219-mm-diameter, 13.72-mm-wt Grade 483 line pipe were evaluated using a specially designed test rig. The principal test variables were lift height, delay time after root pass deposition, preheat temperature, pipe composition and joint misalignment prior to welding. For any given life, preheat and joint misalignment prior to welding had the most significant effect on cracking tendency.The output of this program has industrial significance and illustrates the beneficial features of university-industry collaboration.IntroductionField welding operations comprise the rate-limiting step during pipeline construction. Crack-free girth welds must be made in a wide range of weather conditions and consequently the field weldability of line pipe compositions directly affects pipeline integrity and construction economics.Pipe-laying practice comprises root bead deposition followed by a skidding operation involving lifting (or lowering) the pipe length onto skid s so that the next pipe length can be aligned prior to welding. Consider pipeline construction using 24.4-m lengths of 1219-mm-diameter , 13.72-mm-wt Grade 483 pipe weighing approximately 10,000 kg. Skidding involves loading a 3-mm-thick root bead by moving the free end of the pipe through vertical distances of up to 700 mm . The likelihood of cracking in these circumstances depends on the inherent crack susceptibility of the pipe composition employed, on the hydrogen content of the deposited weld metal and on how well the joint handles the external stressing caused byskidding."

Jan 1, 1981

By P. Venkatasubramanian

"In recent years, computer based ""expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts requiring empirical knowledge, judgment, experience, developing a ""best solution "" by the use of plausible reasoning. Mining method selection is an appropriate area for the application of an expert system because extensive and detailed knowledge is required to make a ""best"" interpretaion of frequently ambiguous geological information. The expert system model presented here would enable users to apply expert knowledge to the evaluation of methods for coal deposits mineable by underground methods. IntroductionIn an increasingly complex and specialized world, human expertise spanning scientific, economic, social and political issues plays an increasingly important role in all branches of engineering. This is especially true of mining engineering. The number of scientific and professional disciplines involved in mine planning and evaluation, illustrates the problem. A conservative list includes geology, geophysics, geotechnics, hydrology, mining, environment, and economics.Engineers are almost obliged to be experts in at least one of the above disciplines if they are to handle the volume of information required in the planning process. Although computers have become indispensable tools in many endeavours, there is continued reliance on the human expert's ability to identify and synthesize these diverse factors, to form judgments, evaluate alternatives , and make decisions . This is especially true with regard to problems that are not easily amenable to precise formulations.The precious resource of human expert is also fragile and transient. The departure of a crucial expert from an organization ma y cause serious dislocations. Senior experienced people impart their knowledge of younger colleagues, but the demand for their talent may not leave sufficient time for such educational efforts. In recent years, computer based "" expert systems"" have been taking on large complex tasks for which no exact algorithmic solutions are feasible; tasks previously reserved for human experts, requiring empirical knowledge, judgment , experience, developing a ""best solution"" by the use of plausible reasoning."

Jan 1, 1988

By E. J. Wasp, T. L. Thompson, T. C. Aude

The paper will deal with some of the more important technical aspects of slurry pipelines as they apply to the mineral field. In addition, the use of these technical concepts in arriving at realistic economic figures will be discussed.

Jan 1, 1970

By J. D. Botsford

Westmin Resources Limited's H-W orebody on Vancouver Island is a copper/lead/zinc massive sulphide deposit that has been in production since 1985. The sulphur content of the ore averages 28% and in some stopes is as high as 53%. Several minor secondary sulphide dust explosions have occurred in development headings and cut and fill stopes, but as yet no known explosions have occurred in blasthole stopes. This pa:per reviews the history of sulphide dust explosions in the H-W Mine, factors contributing to the explosions and the preventative measures taken to control them.

May 11, 1988

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By J. E. Danoczi

Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne area kimberlite field in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as ?gently? as possible since essential to the diamond liberation process is the minimization of diamond damage, particularly for the larger, high value diamonds. The Southern African diamond mines traditionally use Jaw and Gyratory crushers as their primary comminution method. However, these diamond mines generally process the harder, competent kimberlite that is located in the diatreme zone as well as the root zone of the volcanic pipe. Softer kimberlite is typically located in and around the crater area of a volcanic pipe and it is this source of kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills, this being the preferred method of comminution for minimizing diamond damage.

Nov 1, 2011

By K Morrison

Different individuals have calculated the boundary stresses around elliptical openings in an infinite elastic medium for various conditions of loading. With caution, such calculations are useful in indicating stress trends in mining. This paper illustrates an application to caving operations and suggests that abnormal field stress would have an adverse effect. Introduction GELDART and Udd (1), applying elastic theory, confirmed, and set out graphically, the stress distributions on the surface of elliptical openings with axis ratios varying from 1.0 (a circle) to infinity (a crack). The loading conditions varied from uniaxial to hydrostatic, and inclinations for the opening, with respect to the stress axis, varied from 0° to 90°. As most mine openings can be generalized into this elliptical conception, the usefulness of the presentation lies in the fact that given reasonable estimates for the stress ratio, the axis ratio, and its inclination, then the trend in stress concentrations as an opening develops can be readily approximated.

Jan 1, 1964

By A. David MacPhail

"Highland Valley Copper is a large volume producer of copper and molybdenum concentrates. Production is by conventional truck and shovel operation combined with an extensive ore handling in-pit crushing and conveying system.Grade of the two orebodies is low at 0.4% copper and 0.007% molybdenum and this demands a production rate in excess of 260 000 tpd at a stripping ratio of 1: 1. Mining cost has to be kept at minimum levels to keep the mine profitable and thus, it is necessary to keep in the forefront: of technology. As well as the in-pit crushing system, the mine has pioneered the use of shovel weighing coupled with a state-of-the-art dispatch system.Maintenance of the equipment is carried out at the on-site mine maintenance shop with assistance from local shops for engine and wheel motor rebuilds and other large jobs such as those requiring stress relieving. Shovel and truck rebuilds are undertaken by mine crews. Both long- and short-term planning is designed and scheduled in the mine engineering section. Outside consultants are used to assist in slope design, reclamation and blasting technology."

Jan 1, 1992

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By Noel Billette, Jean-Luc Chouinard

"An analysis of the number of industrial injuries shows that the mining sector is particularly affected, since mining is one of the most dangerous industrial activities in Canada. This has led to numerous inquiries, and supports the need for an in-depth study aiming at the identification of factors responsible for these accidents. One possible factor often pointed at is the small crews incentives and this paper presents a scientific approach applied to check a potential link between bonus and accidents at two mining companies located in northwestern Quebec.The data required to do so were the accidents, the salaries and the number of hours worked at each mining site by the hourly paid personnel for the period from June 1979 to January 1982. The analysis of the results derived from the initial information shows different behaviours of the frequency rate vs the bonus rate at these mines. The number of days lost per accident is independent of the bonus rate at both mine sites, as shown by Khisquare tests on contingency tables.IntroductionA wide variety of opinions has been pinpointed by a survey of the literature related to individual or small crew incentives and industrial accidents in sectors of activity where it applies. In addition, various formulae of mining contracts take place in the industry on one part, and statistics from this sector indicate a high accident frequency rate on the other part. These fact s have lead to this scientific investigation which does isolate the direct impact of the bonus on workers' accidents. This study was undertaken with the full support of the Quebec Metal Mining Association.The conclusions of this preliminary phase of the researchproject are presented for two mining complexes in northwestern Quebec. The procedure is somewhat similar to the approach of the Belmoral Commission, with the underlying assumption that bonus has a direct impact on accidents."

Jan 1, 1986

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated, For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases, This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge, By contrast, when mechanistic conditions prevail, significant growth occurs in the depth, When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By W. A. Jankola, M. T. Martin

"The world's first zinc pressure leaching plant at Cominco's Trail operations started production in 1981. Sullivan zinc concentrate is leached at the rate of 190 tpd in a four-compartment autoclave at elevated temperatures and oxygen pressures to produce a zinc sulphate solution and elemental sulphur. Zinc extraction exceeds 98% and sulphide to elemental sulphur conversion exceeds 95%.The sulphur is recovered from the discharged slurry in the underflow of a hydrocyclone, and is upgraded as a flotation concentrate. The concentrate is dewatered, melted and filtered to produce a polished sulphur product of better than 99% purity. An alternative sulphur recovery process employs an unique sulphur separation method that recovers over 90% of the sulphur in the molten state. The remaining sulphur is recovered by flotation following flash discharge of the slurry. The product slurry containing the zinc sulphate solution and the iron-lead residue joins the existing roast-leach zinc plant for purification and zinc electrowinning.IntroductionIn 1981, Cominco Ltd. commissioned the world's first commercial zinc pressure leaching plant at their Trail operations in British Columbia. As part of a $700 million modernization and expansion program for lead and zinc started in 1977, the company installed the first o f two autoclave trains.Prior to pressure leaching, zinc production was closely tied to acid and fertilizer production. Sulphur dioxide produced from roasting the concentrates had to be converted to sulphuric acid. Thus, any expansion of zinc operations with the roast-leach technology would have required extensive modifications to the acid and fertilizer plants as well as to the roasters. Zinc pressure leaching, on the other hand, offered a one-step dissolution of zinc from the concentrates with high extraction, and production of elemental sulphur. The associated dust and sulphur dioxide generated in the roasting process are both eliminated from the working environment of the pressure leach facility. The flexibility allowed by producing elemental sulphur, and the opportunity to break the sulphuric acid link for about 25 per cent of the targeted 272,000 tonnes per year zinc production was very appealing. The process was successfully demonstrated at a pilot plant in 1977(1-6)."

Jan 1, 1985

By R. B. Fermor

"The tyndalloscope is used in Europe for dust-hazard assessments in both coal and metal mines. Dust-hazard conditions can be directly evaluated by the tyndalloscope in many underground working situations, once the basic standard table or tables have been prepared from representative mine-rock samples.The tyndalloscope is excellent, in many cases, for diagnostic dust sampling during a working shift, because individual readings can be taken to within three-minute intervals. The limitations of the tyndalloscope are also discussed.The author suggests that a combination of both the tyndalloscope and gravimetric sampling methods would be an ideal match for most mine dust-hazard assessments."

Jan 1, 1970

By G. R. Guillet

"Bricks made from local Paleozoic shales, and floor and wall tiles made from imported clays, both established record production volumes in 1985 and are the strongest segments of Ontario 's clay products industries. However, renewed interest in traditional materials also supports a good market for clay flower pots and flu e liners, and innovative processing studies are showing promise for possible new production of clay roofing tiles. This paper reviews the highlights of a comprehensive study of Ontario's clay products industries, completed in 1986. IntroductionFor some years now, Ontario' s clay products industries have been unspectacular in their attempt to cope with the recent recession and the impact of alternative materials. But a strong demand for bricks in recent years has done much to dispel the gloom.Bricks, drainage tiles, sewer pipes, flue liners, structural and partition tiles, and flower pots have been commonly referred to as ""heavy"" clay products, and they have been based largely on local clays and shales. To this list might be added expanded aggregate and mineral wool. Clay refractories, sanitary ware, electrical porcelain , art pottery, and floor and wall tiles are not considered heavy clay products, and are commonly made from a variety of ceramic materials, many of which are imported.Production facilities for heavy clay products often began in Ontario as small family enterprises, using whatever clay was available locally to supply the local market with building bricks and other clay products needed for construction. Improved road systems increased the market range for these plant s, and new technology and industry standards resulted in gradual"

Jan 1, 1988

By J. E. Dutrizac

A pyritic Zn-Pb-Cu ore waspercolation leached with acidified ferric sulphate solutions; zinc and copper were leached, lead was oxidized, but not dissolved, and pyrtte was essentially unattacked. High zinc extractions were achieved after a few months leaching, and substantial zinc solution concentrations could be produced by recycle of the oxidized solution. The leaching rate was generally controlled by the transport of the ferric sulphate oxidant. Zinc extractions increased with increasingferric ion concentration or flow rate, but were essentially independent of the concentrations of sulphuric acid, ferrous sulphate, cupric sulphate or chloride ion. The leaching rates were insensitive to the height of the ore column once a minimum height had been exceeded (0.8-1.0 m). Elemental sulphur was the principal sulphidic reaction product, but variations in the ratio of sulphur to sulphate produced anomalous temperature effects.

Jan 1, 1979

By K. Fumimura, T. Nishimura, M. Kohno

When applying numerical techniques to problems of deformation of rocks, the body to be analyzed is divided into small portions and is represented by a system of points linked together with the neighboring points. In the so-called distinct element modeling, the particles in the system are directly connected by springs and a contact law is used to specify forces on the particles to simulate the mechanical behavior of the body. The relation between the spring stiffness and commonly measured material properties, such as the Young’s modulus and the Poisson’s ratio, should be known a priori. For the general case of a random packing of particles, the relation is found by means of a process in which a system of particles and set of parameters are prepared to simulate a set of specimen-size test and then the input parameters are chosen to match the measured material properties. The validity of the numerical result is only demonstrated by comparison model behaviors with the measured responses. The process includes trial-and-error manner, therefore, no model is complete to reproduce the mechanical properties. In this paper, a relation between the spring stiffness and the elastic constants; the Young’s modulus and the Poisson’s ratio, is introduced to a three-dimensional distinct lattice spring method. Two simple numerical examples will be presented to demonstrate the performance of the method with the procedure for the determination of the spring stiffness.

Jan 1, 2015