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By Inga Tuzovskaya1i

Three types of gold species were observed for gold-zeolites, prepared by reduction of ionexchanged Au species in a series of zeolites: (i) Au3+cations, (ii) neutral Au0 n or charged Aus+ n clusters suggested to be inside the zeolite channels, (iii) Au nanoparticles with diameter varied from 2 through 20 nm located on the external surface of zeolite microcrystals. Contribution of the gold species formed in zeolite after the ion exchange was found to depend on zeolite type, acidity of zeolite, temperature of reduction and time of storage of the exchanged and reduced Au-containing zeolites. Au3+ ionic species and clusters Aun were formed after the ion-exchange procedure (in contrast with the familiar production of Agn in same zeolites). Gold nanoparticles were observed only as the result of reduction of the Au-exchanged forms at elevated temperatures due to reduction of Au3+ species and aggregation of clusters.

Oct 1, 2003

By CIM Mineral Resource

On January 9, 2018, the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Council formed the CIM Mineral Resources and Mineral Reserves Committee (CIM MRMR Committee), which is a combination of the previous Standing Committee on Reserve Definitions and the Best Practices Committee. As part of its mandate, the CIM MRMR Committee updates guidelines for use by Industry, which include the Uranium Practice Guidelines. The 2024 CIM Uranium Leading Practice Guidelines were adopted by CIM Council on November 22, 2024, and supersedes the 2003 version. The main principles and guidelines relating to preparation of Mineral Resource and Mineral Reserve (MRMR) estimates are provided in the CIM Estimation of Mineral Resources and Mineral Reserves Best Practices Guidelines (MRMR BP Guidelines, as updated from time to time). The MRMR BP Guidelines provide information pertaining to metalliferous and other deposits and many sections are readily applicable to the preparation of MRMR estimates for uranium deposits. However, additional guidance is appropriate for uranium deposits due to the radioactive nature of uranium, and its amenability, in some cases, to in situ recovery (ISR) mining methods.

Nov 1, 2024

By J R. M Hutcheson

Advocate Mines Limited came into initial production on June 30, 1963, with an annual capacity in excess of 60,000 tons of high-quality chrysotile asbestos fihres, thus strengthening Canada's position in world production. The history of this development is traced from discovery through initial exploration, financing, orebody delineation and evaluation, pilot-plant production and product evaluation, construction of the plant, construction of deep?-sea shipping facilities, provision for a closed shipping season, and provision for the remoteness and for the lack of services, through to realization of full production capacity. The many unique aspects of the project are given special attention, particularly in the light of the first year of full-capacity operation. The marketing of the products in a highly competitive world market is reviewed, with special emphasis on product evaluation, quality control and the shipping of high-quality products to consumers throughout the world. C ANADA'S newest asbestos producer, Advocate Mines Limited, is located at the north end of the Burlington Peninsula, White Bay District, Newfound-

Jan 1, 1965

The Anglo Platinum Mogalakwena North concentrator was one of the first three hard rock mineral processing applications to utilise a HPGR circuit in preference to a SAG milling circuit. This was driven by the extreme competence of the ore that had given rise to throughput issues on the original South Plant. Despite more than adequate capacity and performance of the individual comminution units, the circuit has struggled to obtain full design capacity. A thorough review of the integrated performance of the circuit revealed a wide range of bottlenecks and underutilised parts of the circuit arising from design issues. Interestingly, the major opportunities lie in materials handling issues and mismatch of loads about the circuit. This paper presents the high-level outcomes and the associated opportunities, and is pertinent to all HPGR circuit designs.

Jan 1, 2012

By E. Y. Carlson

"IN A SHORT PAPER it is impossible to do much more than to list the industrial minerals found in Saskatchewan and to give a brief description of the activity associated with each. I will not attempt to discuss the geology. It is sufficient to say that the settled part of the Province is covered by glacial drift which varies in thickness from a few feet to several hundreds of feet, and that this has hindered the search over much of the Province.CLAYA notable exception to this is the Cypress Hills area in the southwest corner which did not suffer any glacial action and where we find some of the large exposures of Cretaceous clays. In this area, the majority of the deposits are of stone-ware clays which are •an excellent raw material for such products as face brick and sewer pipe. Although the clay cannot be transported over any great distance it is used extensively in Alberta and Saskatchewan in the production of these products."

Jan 1, 1959

By Ch. Wenzl

Anodes must have a certain physical and chemical quality in order to provide uniform anodic corrosion and meet the requirements of electrorefining, i.e. to achieve a high current efficiency, low energy consumption, low amount of anode scrap and low effort together with high cathode quality. Various properties of the anodes can be influenced directly by the casting process, which is the interface of pyro- and hydrometallurgy of copper. The aims of anode casting ? high output and long mould lifetimes ? are not consistent with good physical anode quality. The physical requirements of an anode are smooth surfaces, uniform weight and thickness, minimal edge effects, minimal distortion of the body and the lugs, as well as a homogeneous microstructure, in order to achieve uniform dissolution behaviour. The chemical quality of the anode copper is a task of electrorefining operations, but the elemental distribution within the anodes, which should be as homogeneous as possible in order to provide uniform anodic corrosion, can be influenced by the casting process.

Jan 1, 2007

By B. W. Smee

Glacial lake sediments or glaciolacustrine deposits form a significant portion of the Canadian, Scandinavian and Russian landscapes. Furthermore, 50 per cent of the Archean volcanic belts within the Canadian Shield area are covered wholly or in part by these deposits. Because of the high electrical conductivity and low hydraulic conductivity of these compact sediments, the application of geophysical (electrical) and geochemical techniques in such areas becomes a difficult task. The presence of these sediments has therefore hampered exploration for metallic sulphide deposits in some of the most important metallogenic environments of Canada. Similar problems exist in some tropical countries, such as Australia, where the overburden may be very conductive. In this paper, the extent and provenance of the glaciolacustrine deposits within the Canadian Shield are described. The geochemical and geophysical factors that hinder exploration in the clay belts are reviewed, with case histories of successful and unsuccessful applications of some of these techniques. The most successful geochemical technique used within glacial clay belts is the sampling of lodgement till beneath the clay cover, and the analysis of the heavy mineral fraction of that till. Surficial sampling has not been successfully applied. Some geophysical techniques, more specifically electromagnetic and magnetic induced-polarization techniques, have detected mineralization beneath substantially deep clay or saline overburden layers. Some suggestions have been made, such as the use of anions in hydrogeochemical surveys and the use of wide-band multi-frequency EM systems. When implemented, they will hopefully make the current geochemical and geophysical methods more effective in exploration for base metal sulphides within clay-covered terrains.

Jan 1, 1979

By F. Grant

"General *The mining experiences of the coal mining industry in Western Canada have been extremely varied, with the mining companies having to adjust their operations or fail due to the harsh economy of the country in the first part of the century. The bituminous or mountain mines had the railways as main consumers with, at times, optimism that potential steel producers would require metallurgical coal. The prairie and foothills mines mainly provided household fuels, with the fine coal sold to local thermal power plants at discounted prices. In practically all cases fuel competition was very keen, and the less successful mines ceased operations in short-time spans. Knowledge of the parameters that governed the success or failures of the past coal operations should be of value to the present and future mining companies. The initial coal mines were small and were started to supply local demand. These mines had little in the way of capital machinery, engineering, or transportation equipment; therefore the mining methods and mine plans were very simple. The first industrial-sized mines imported most of their management and mining methods from other mining areas, mainly Great Britain. It took time to change the bias of management and mining methods to the requirements of strata characteristics, with rapid closure to those mines that were slow to adapt working methods. The main markets for coal were for household fuel, thermal power plants and railways, with very few other industrial markets developed. The economy of the period was harsh and cyclic and the coal mines were affected more than most industries by these boom and bust periods. It led to the survival of the fittest or the most efficient. Due to the economy, mechanization was introduced to the mines very slowly, with the inability to sell coal fines at a profit being another reason for the delay. Manual labour with hand tools was the main means of production. The work was heavy and arduous, and the pay was based on contract coal tonnage; therefore both men and management paid close attention to details so that nonessential work could be eliminated. Mine openings were dimensioned so that coal could be loaded easily by hand and support requirements were kept to the minimum. Transporting and handling the timber supports required heavy labour; thus the most efficient dimensions were chosen to suit the strata. On the other hand, during the main production seasons the mines tried to make the strata stress work for them so that the pressure was kept on the coal face to keep the coal loose while the strata, a short distance back, was induced to cave to minimize the abutment stresses. This caused mining to be an art, using skills developed by experience with the strata. This led to the development of efficient mine layouts with the openings dimensioned to the strength of the strata and the type of support available. The lack of capital and mechanization, and the manual labour, induced the mines to correlate their service and haulage systems with their mining methods. This caused many innovations that proved very practical."

Jan 1, 1985

By X. -G. Chen, K. Liu, N. Parson

"Precipitation-strengthening 6xxx alloys are widely used for building and construction and automobile industries due to their high strength, good weldability and corrosion resistance. However, their elevated-temperature properties (250–300°C) decrease rapidly due to the fast-coarsening of precipitates. On the other hand, dispersoid-hardening is one of the most efficient approaches to improve the elevated-temperature properties. Therefore, the evolution of dispersoids during heat treatment in Al-Mg-Si-Mn alloys was investigated in the present work. Various heat treatments with temperatures ranging from 300–500°Cfor up to 24 hours were performed. Electrical conductivity and microhardness were measured while optical and scanning electron microscopy combined with image analysis, were used to characterize the dispersoids. Special emphasis was placed on the evolution of the size and number density of the dispersoids under different heat treatment parameters. It was found that dispersoids started to precipitate at 350°Cfor 1 hour. Nucleation and growth were the main mechanisms at temperatures up to 400°Cwhile coarsening occurred at temperatures above 450°C. The quantitative results indicated that dispersoids precipitation reached the optimum condition after treatment at 400°Cfor 2–4 hours with a fine size and high number density, resulting in the highest hardness.INTRODUCTIONThe precipitation-hardening 6xxx aluminum alloys with major alloying elements of Mg and Si are one of the most widely used aluminum alloys for building and construction and automobile industries (Dinaharan & Murugan, 2012). In recent years, there have been increasing demands for aluminum structural components to be used at elevated temperatures (250–300°C) for different applications. However, the mechanical properties of 6xxx alloys at elevated temperature are typically reduced due to the rapid coarsening of precipitates at 250–300°C. It has been reported that the yield strength (YS) of AA6061 in the peak-aged condition drops from 276 MPa at room temperature to only 30 MPa at 315°C(Kaufman, 1999). Therefore, it is a key concern to improve the elevated-temperature properties of 6xxx alloys to expand their range of applications."

Jan 1, 2018

By Gonzalo Díaz, Diego Mesa, Willy Kracht

"It is well known that frothers affect the amount of water that is transferred to the froth, which has an effect on both the froth stability and the water recovery. On the other hand, since non-selective recovery by entrainment is directly related to water recovery, it can be said that frothers have an indirect effect on flotation selectivity. Recent research on this subject has shown that the non-selective recovery by entrainment, which is characterized by the entrainment factor, is frother dependent. In other words, the entrainment factor is not unique, but depends on frother type.Having different entrainment factors implies that for the same water recovery, the amount of undesired particles reporting to the concentrate may vary if one changes the frother type, which suggests, as a possible explanation, that it is not only the amount of water in the froth what is affected by frother type, but also the froth structure.The purpose of the current work is to study the effect of frother type on foam structure (two phase froth). A quasi-2D cell operated with a slot sparger was used to study the foam structure in the presence of three different frothers: Methyl Isobutyl Carbinol (MIBC), OrePrep®549, and Octanol at the same gas flow rate and reagent dosage. The foam structure was studied using image analysis, and an algorithm based on textural analysis was developed to classify the foams. The results show that it is possible to classify foams according to the frother used, which proves that frothers have an effect on the foam structure.INTRODUCTIONFrothers are usually dosed paying attention to froth stability, condition that is commonly estimated by sight, according to the operator's criteria and experience. This happens because there is not an established procedure or technique for frother characterization, generating qualitative descriptions such as “powerful” or “selective” frothers, which lack of scientific thoroughness and remain under subjective factors. Nevertheless, several works have been done in this line of research. Moyo et al. (2007) classified frothers based on their water-carrying capacity, proving that this characteristic is related with gas holdup and frother type. Previously, Trahar (1981) had related water recovery and gangue particles recovery, defining the entrainment value (ENT). Nowadays it is known that entrainment affects both hydrophilic and hydrophobic because it is not a selective process. In the last decade some studies (for example the one of Konopacka and Drzymala (2010)) delved into different entrainment behaviours dependent mainly on the flotation type (batch or continuous, agitated or columnar, etc.), but there were no studies on the effect of frother type regarding entrainment, since Rahal et al. (2001) argued that the ENT factor was independent of the frother type and concentration, and froth height."

Jan 1, 2016

By CIM Mineral Resource, Mineral Reserve Committee

The CIM Mineral Exploration Best Practice Guidelines (the Exploration Guidelines) have been prepared to assist professional geoscientists and engineers to conduct consistently high-quality work in order to maintain public confidence. The Exploration Guidelines are meant to assist professional geoscientists and exploration practitioners in planning, supervising, and executing exploration programs. In Canada, there are generally two types of public resource reporting: “Disclosure”, as defined by NI 43-101, is the reporting of technical information to the public and market participants for securities legislation purposes where a Qualified Person (QP) must be involved, and reporting of exploration information for governmental agencies to support obligations under laws including the Mining Acts of each of the Provinces and Territories. The Exploration Guidelines are also relevant where the results will not be publicly reported but are intended for internal company use. While this document is intended as guidance for work conducted or supervised by geoscientists in Canada, many of the practices described herein can be adapted to mineral exploration activities in other countries. The Exploration Guidelines are not intended to inhibit original thinking, or to prevent the application of new approaches that may develop into fundamental components of successful mineral exploration programs. Rather than provide prescriptive solutions to specific issues, they include general guidelines for current professional practice and to demonstrate and defend the merits of new methods. These guidelines do not preclude individuals and companies from developing more detailed guidelines specific to their own requirements. The initial version of the Exploration Guidelines was prepared by the Canadian Institute of Mining and Metallurgy and Petroleum (CIM) Exploration Best Practices Committee and adopted by CIM Council on August 20, 2000. On January 9, 2018, CIM Council formed a new committee, the Mineral Resources and Reserves Committee (CIM MRMR Committee) with a mandate to, among other things, update the Exploration Best Practice Guidelines. The mandate for the committee was accepted by CIM Council on March 2, 2018. The new document was adopted by the CIM Council on November 23, 2018.

Nov 23, 2018

By S. Abu-Samra

By virtue of its complex nature, the construction industry comprises a wide spectrum of interrelated variables and factors. This multifaceted character of the construction industry puts the use of engineering modeling tools and techniques on top of project management necessities. This research introduces a macro-level earthmoving management system using Genetic Algorithms (GAs) to reach the optimum allocation of earthmoving equipment. The Earthmoving Equipment Management System (EEMS) functions through four integrated modules: (1) A Central Database containing information about projects and available equipment; (2) An Equipment per Segment Selection module that calculates the cut and fill quantities, plots the Mass Haul Diagrams, and selects the equipment types to be used for each segment; (3) An Equipment Pool module which determines the production and cost for each available equipment, based upon the project site conditions; and (4) An Optimization Engine equipped with a GA optimization solver. This engine formulates the optimum earthmoving cost for all projects, by changing the number of allocated equipment. The Optimization Engine takes into account the number of available equipment and calculates the weekly equipment allocation. The EEMS model was implemented on an earthmoving company conducting five different projects on hand. The model proved to be an effective tool in providing decision makers with optimum equipment utilization on a multi-project scale to minimize the earthmoving cost. The results were then compared with the company?s existing micro-level management system, demonstrating better performance on the level of savings, amounting to 13% of total earthmoving cost.

Aug 1, 2013

By K. Yamaguchi

"This Precious metals content copper scrap is treated with a copper smelting process, and copper and precious metals are recovered. The precious metal lost in the slag is increasing with increasing of treated scrap amount. To determine the portion of the precious metals chemically dissolved and that associated with the mechanically trapped matte in the slag will be a key factor to improve the recovery of those metals. The distribution of precious metals between copper matte and FeOx-SiO2 slag phases is determined at 1300 oC and a fixed partial pressure of SO2 of 0.1 atm for the matte grades from 40 to 70 mass% of copper. The distribution ratios show a tendency to increase when the grade of matte is increased. In addition, the solubility of platinum and rhodium in the FeOx-SiO2-CaO slag under the air and the solubility of platinum in the FeOx-SiO2 slag equilibrated with a pure platinum or the Pt-Cu alloy were determined at 1300oC in the range of oxygen partial pressure from 10-9 to 10-7. The solubility of platinum and rhodium in the slag tends to increase with increasing content of copper in the slag and oxygen partial pressure. INTRODUCTIONThe stringency of the supply and demand of platinum group metal (PGM) intensifies by localization for resources and increase of the demand for PGM, furthermore, smelting and the recycling of PGM in the nonferrous smelting process take an important role. Scrap containing a precious metal for the purpose of collection of PGM is treated by copper smelting recently. With increase of the treatment amounts, loss of PGM in slags is the serious problem.In considering of PGM loss in slags, knowledge of the distribution behavior for PGM between slag and matte phases or slag and copper phases and the PGM solubility in slags is important. The distribution ratios of silver and gold between the FeOx-SiO2 slag and the Fe-Cu matte were reported by Roghani (Roghani et al., 2000), Shinha (Shinha et al., 1985) and Takeda (Takeda et al., 1993) However, there is no data for the PGM distribution ratio. On the other hand, the PGM solubility in slags was reported by Sano (Sano et al., 1997) However, there is very few report for the solubility of PGM in the nonferrous smelting slags."

Jan 1, 2012

By E. E. N. Smith

"Uranium exploration by Eldorado prospectors north of Lake Athabasca began in late 1944 and resulted in initial discoveries in 1946 in the Beaverlodge region with mill production starting in early 1953. The operation was closed in mid-1982 having produced 21,457,947 kilograms U30 8 from the Eldorado FayVerna mine, Eldorado satellite operations and from other district producers on a custom basis.The Fay- Verna mine consists of pitchblende-brannerite orebodies spatially associated with both sides of a regional eastwest structure, the St. Louis Fault. The orebodies in the footwall (Fay) are elongate deposits of two types raking steeply to the southwest along the 50 degree south dip of the fault.One type consists of networks of fractures and veins filled with pitchblende, calcite and quartz in chlorite, epidote-altered mylonitized mica schists and amphibolites of the Middle Aphebian Tazin Group. The other type is comprised of fragments of mylonitized metasomatic quartz-feldspar granite of Late Middle Aphebian age cemented with a matrix of pitchblende, brannerite, calcite and some quartz. The vein networks lie en echelon in the footwall of the breccia ore bodies which, in part, are capped by the mud gouge of the St. Louis Fault; in other places, the breccia orebodies are overlain by basal conglomerates, grits and arkoses of the late Aphebian Martin Formation which itself immediately underlies the plane of the fault.Orebodies in the hanging wall (Verna) are a series of irregular, tabular deposits lying within a tightly overturned syncline of Tazin mica schists, amphibolites and siliceous mylonites. They consist of pitchblende, calcite-filled fractures grouped into zones and deposits displaying stratabound habits within individual rock types.Also described are several Eldorado satellite properties which were significant producers of uranium and which display complementary geology to that in the Fay- Verna mine.In general, uranium deposits in the Eldorado Beaverlodge region are closely related to minor structures associated with major faults. Uranium appears to be best concentrated where the rocks are well mylonitized and brecciated. Pitchblende fills networks of veins and fractures in metasediments and metavolcanics as well as matrix material cementing brecciated, mylonitized granite. All deposits in the Beaverlodge region lie in close proximity to the unconformity between the Martin Formation and the underlying Tazin Group."

Jan 1, 1986

By E. L. Martheleur

The use of electricity in coal mines dates almost from the time when it was realized chat it could be used to produce mechanical power. The first motor put in service underground was installed to drive a small pump nearly 40 years ago, and since then the use of electricity in mines has reached an extent undreamed of at that time. We now find its universal adoption in all the mining countries of the world. Great progress has been made in the development of mining electrical apparatus in the last decade, and excellent and adequate material is now available for the use of electricity underground. Although mining accidents, due to the use of electricity, are not frequent, the miner is justified in demanding chat all electrical apparatus for installation below ground be constructed with a greater degree of safety than that used on the surface. That this view is shared by the authorities of the different mining countries is evidenced by governmental regulations relative to the use, erection, and maintenance of electrical apparatus below ground. Those with which we are specially concerned are the regulations for the installation and use of electricity in the coal mines of Nova Scotia. The potential dangers of electricity in coal mines are: Shock or burns by contact from live parts. Shock or burns by contact with parts which, although normally dead, have become accidentally alive. Fire. Explosion of gas or coal-dust Explosion of apparatus.

Jan 1, 1928

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By B. K. Ayres

Modern management of uranium mine or mill waste storage facilities (WSFs) often requires that they be remediated or decommissioned with a cover system. In addition to creating a self-sustaining landscape that supports the end land use, cover systems are intended to reduce long-term risks to human and ecological receptors from the stored waste to acceptable levels. The performance and longevity of a cover system will be strongly influenced by the features or shapes of the WSF final landform. Hence, cover systems and landforms must be thought of as an integrated design. Based on the author’s experience, the most important elements of the design process for maximizing the potential of WSF final landforms / cover systems being sustainable over the long term are noted in this manuscript. Several key items that must be considered and addressed during the planning phase of constructing a WSF final landform are also described. Various methods for monitoring performance of a WSF final landform are also reviewed. Key aspects associated with decommissioning a tailings WSF and waste rock pile at the former Cluff Lake uranium mine in northern Saskatchewan are included to illustrate many of the practical insights provided in this paper.

Jan 1, 2020

By C. Mawdsley

The Tata Steel mill at Skinningrove in the North East of England produces top hat sections for mineshaft guides in sizes 102 and 150 mm. The top hat section is the technically preferred shaft guide choice for modern deep mine shafts. This paper explores the relative service performance of top hat and square hollow section guides in service. Comparative corrosion performance is reviewed and the paper describes work commissioned by Tata Steel (as Corus) undertaken by Aker Kvaerner Engineering to evaluate relative winding speeds, relative loads and fatigue life in service. The experience of supply to UK Potash mining is discussed and the future view of high capacity hoisting and larger section size market need and availability is assessed.

Aug 1, 2013

By G. B. Bosworth, M. J. Lake, J. W. Hogg

The Quintette Coal operation in northeastern British Columbia has one of the world's largest Preparation Plants, with a design capacity of 6.5 million tonnes per year of clean coal.This paper will discuss several innovative aspects of the flowsheet and plant design with particular reference to the selection of process equipment, materials handling and control systems.The operations and maintenance experience during the first two years of production will be described and discussed in relation to the design objectives.

Jan 1, 1987

By C. Doyle, J. Brennan, C. Díaz, J. Hrepic, K. Cushnie

"In 1991/1992, INCO undertook a successful R&D program aimed at extending the lining lives of the top blown rotary converters (TBRCs)at its Copper Cliff Nickel Refinery (CCNR) and the electric furnace at INMETCO. At the laboratory scale, this effort was divided into three phases. In the first part, mineralogical work was performed on six refractories that were either currently being used to line these vessels or were considered suitable alternatives. In the second part, this mineralogical knowledge was used to help determine the compositions of slags that would not corrode the bricks at the operating temperature (1600°C) of the above furnaces. Finally, several important properties of the six refractories were measured to complete their evaluation as candidate linings. This paper reports the results of all three phases of the laboratory scale R&D work.The mineralogical work showed that rebonded fused grain magnesite-chrome (RFG-MC) bricks consist principally of periclase with minor amounts of free chromite and trace quantities of silicates monticellite and sometimes olivine. The bricks are principally held together by periclase-periclase direct bonding. Of note, the bulk of the chromite exists as exsolved precipitated blebs within the periclase grains. These likely redissolve at high temperature.Slags on the periclase liquidus coexist stably with these refractories. Examples are presented using CaO-MgO-Al2O3-SiO2 slags at~1600°C.Finally, the two refractories manufactured using close to 100% fused grain material generally outperformed the others in terms of physical properties and certainly were superior in their resistance to slag penetration damage."

Jan 1, 1997